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Chapter 5: The Periodic Law

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Chapter 5: The Periodic Law
Section 1: History of the Periodic Table
In September of 1860, Stanislao Cannizzaro presented a method for measuring the
relative masses of atoms
Mendeleev and Chemical Periodicity
In 1869, Mendeleev published his first periodic table
The elements were placed in order of increasing atomic mass and similar properties
Mendeleev’s periodic table contained several blank spaces, which were filled in 1886
Moseley and the Periodic Law
Moseley is credited as the chemist who discovered and defined atomic number and
atomic patterns
Periodic Law: The physical and chemical properties of the elements are periodic
functions of their atomic numbers
When elements are arranged in order of increasing atomic number, elements with similar
properties appear at regular intervals
The Modern Periodic Table
Periodic Table: An arrangement of the elements in order of their increasing atomic
numbers so that elements with similar properties fall int the same column, or group
The Noble Gases
John William Strutt, Sir William Ramsay, and Friedrich Ernst Dorn discovered the noble
gases
The Lanthanides
The lanthanides are the group 14 elements from atomic numbers 58 to 71
The similarity of the lanthanides resulted in tedious separation and identification
The Actinides
The actinides are the group 14 elements from atomic numbers 90 to 103
The actinides and lanthanides are set off from the main periodic table to save space
Periodicity
Periodicity id described as the pattern among elements of the periodic able
Periodicity, with respect to atomic number, can be observed in any group of elements in
the periodic table
Periodicity is explained by the arrangement of electrons around the nucleus
Chapter 5: The Periodic Law
Section 2: Electron Configuration and the Periodic Table
The electron configuration of an atom’s highest occupied energy level governs the atoms
chemical properties
Periods and Blocks of the Periodic Table
The length of each period is determined by the number of electrons that occupy the
sublevels being filled in that period
The period of a specific element can be determined by the element’s electron
configuration
Based on these electron configurations, the period table can be divided into four blocks:
S, P, D, and F
The name of each block is determined by whether an s, p, d, or f sublevel is being filled
The S-Block Elements: Groups 1 and 2
The elements of the S block are chemically reactive metals and the outer energy levels
contain a single S electron
The elements in group 1 are more reactive than the elements in group 2, which are more
reactive than the elements in group 3, etc…
The elements of group 1 are the Alkali metals
The elements of group 2 are the Alkaline-Earth metals
Hydrogen and Helium
The properties of Hydrogen do not resemble those of any group, so it is set apart from the
other elements
Although Helium has and ns² configuration, it is placed with the group 18 elements
because it is generally un-reactive
The D-Block Elements: Groups 3-12
Some elements of the d block do not have identical electron configurations
The group 3-12 elements are sometimes referred to as the transition metals
The P-Block Elements: Groups 13-18
The p block elements together with the s block elements form the main group elements
The properties of the p block elements vary greatly
The elements on group 17 are called the Halogens
P block metals are harder than those of the s block, but softer than those of the d block
The F-Block Elements: Lanthanides and Actinides
The F block elements are located between groups 3 and 4 and in periods 6 and 7
Lanthanides are similar in reactivity to group 2
Actinides are radioactive and most are synthetic elements
Chapter 5: The periodic Law
Section 3: Electron Configuration and Periodic Properties
Atomic Radii
Atomic Radius: One-half the distance between the nuclei if identical atoms that are
bonder together
Period Trends
The trend to smaller atoms across a period is caused by the increasing positive charge of
the nucleus
Group Trends
In general, the atomic radii of the main group elements increase down a group and
decrease from left to right across a period
Ionization Energy
An electron can be removed from an atom if enough energy is supplied
Atom + Energy = Positive Ion + Electron
Ion: An atom or group of bonded atoms that has a positive charge or a negative charge
Ionization: Any process that results in the formation of and ion
Ionization Energy: The energy required to remove one electron from a neutral atom of an
element
Period Trends
In general, ionization energies of the main group elements increase across each period
Group Trends
Among the main group elements, ionization energies generally decrease down a group
Removing Electrons from Positive Ions
Second Ionization Energy: The energy required for the removal of an additional electron
from an atom—IE , IE , IE ,etc
Electron Affinity
Electron Affinity: The energy change that occurs when an electron is acquired by a
neutral atom
Atom + Electron = Negative Ion
An ion produced in this way, gaining an electron, will be unstable and lose the added
electron spontaneously
Period Trends
In general, as electrons add to the same p sublevel in group 17, electron affinities become
more negative across each period within the p block
Group Trends
Electrons add with greater difficulty down a group
The increase in nuclear charge and atomic radius affect the electron affinities of a group
Adding Electrons to Negative Ions
For an isolated ion in the gas phase, it is always more difficult to add a second electron to
an already negatively charged ion. The second electron affinities of these ions are all
positive
Ionic Radii
Cation: A positively charged ion
The formation of a cation by the loss of one or more electrons always leads to a decrease
in atomic radius
Anion: A negatively charged ion
The formation of an anion by the addition of one or more electrons always leads to an
increase in atomic radius
Period Trends
Within each period of the periodic table, the metals at the left tend to form cations and the
nonmetals at the right tend to form anions
Cationic Radii decrease across a period because the electron cloud shrinks due to the
increasing nuclear charge acting on the electrons in the same main energy level
Anionic Radii decrease across a period for the elements in groups 15-18
Group Trends
As they are in atoms, the outer electrons in both cations and anions are in higher energy
levels as one reads down a group
Therefore, just as there are gradual increases of atomic radii down a group, there is also a
gradual increase of ionic radii
Valence Electrons
Valence Electrons: The electrons available to be lost, gained, or shared in chemical
reactions
Valence electrons are often located in incompletely filled main energy levels
For main group elements, the valence electrons are the electrons in the outermost s and p
sublevels
The elements of groups 13-18 have a number of valence electrons equal to the group
number minus 10
Electronegativity
Electronegativity: A measure of the ability of an atom in a chemical compound to attract
electrons
The value of other elements are calculated in relation to Fluorine, F, electronegativity 4.0
Period and Group Trends
Electronegativities tend to increase across a period, although there are exceptions
Electronegativities tend to either decrease down a group or remain about the same
Periodic Properties of the D and F Block Elements
The properties of the d block elements c\vary less with less regularity than those of the
main group elements
Electrons in incompletely filled d sublevels are responsible for many characteristic
properties of the d block elements
Atomic Radii
The atomic radii of the d block elements generally decrease across periods. This decrease
is less than that for the main group elements because the electrons added to a d sublevel
shield the outer electrons from the nucleus
As the number of electrons in the d sublevel increases, the radii increase because of
repulsion among the electrons
In the sixth period, the f block elements fall between lanthanum and hafnium. Because of
the increase in atomic number that occurs from lanthanum to hafnium. The atomic radius
of hafnium is slightly less than that of zirconium, the element immediately above it
The radii of elements following hafnium in the sixth period vary with increasing atomic
number in the usual manner
Ionization Energy
As they do for the main group elements, ionization energies of the d block and f block
elements generally increase across a period
In contrast to the decrease down the main groups, however, the ionization energies of the
d block elements generally increase down each group
Ion Formation and Ionic Radii
The order in which electrons are removed from all atoms of the d block and f block
elements is exactly the reverse of the order given by the electron configuration notation
Electrons in the highest occupied sublevel are always removed first
Electronegativity
The d block elements all have Electronegativities between 1.1 and 2.54
The d block elements also follow the general trend for electronegativity values to
increase as radii decreases
The f block elements all have similar Electronegativities, which range from 1.1 to 1.5
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