Agenda / Inhalt Soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati Integrated solution for the degradation, or alternatively, for the recovery of the digestate’s nutrients L.P. BZ 13.12.2006, n. 14 - “Innovation” Determines the financing Consorzio ALPI BIOGAS n. 5/08 23. gennaio 2014 1 Alpi Biogas Soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati The centre of competence Alpi Biogas focusses his energies in the following activities: Research & Development: The innovation and application of new technologies in plants and processes are the objectives of R&D. The research is targeted on low volume agricultural plants and on specific solutions for the industry. The transfer of the know-how: We spin webs for connecting the right partners and build bridges between the research’s and the economy’s worlds. Experiment and monitoring: The pilot plants and demonstration plants permit the scientific monitoring of the research’s projects up to their concrete realization. 23. gennaio 2014 2 Alpi Biogas Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati Research Development farmers Industrialization of the plants and processes «Agro-energetic» centre of research and application Energetic companies January 23th 2014 Transfer of the know-how Control, monitoring craftsmen Center of formation Pilot plants Designers and technicians 3 Alpi Biogas Soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati Scientific level University of Trento Agrarian Institute of S. Michele technical-energetic R&D project development E&T SYNECO Renertec Engineering design agro-energetic R&D construction, distribution exercise, financing Schmack Biogas SEL spa Ecorott Biomass consortium Energetic exploitation MATTONI GASSER Agrigas Farmers Union Operative level 23. gennaio 2014 4 Alpi Biogas Soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati Scientific level University of Trento Agrarian Institute of S. Michele technical-energetic R&D project development E&T SYNECO Renertec Engineering design agro-energetic R&D construction, distribution exercise, financiing Schmack Biogas SEL spa Ecorott Biomass consortium Energetic exploitation MATTONI GASSER Agrigas Farmers union Operative level 23. gennaio 2014 5 SYNECO Soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati Syneco is a company offering consultancy and accompanying to companies and public institutions in the field of the sostainable development. Our customers can count on an interdisciplinar team compound of experts cooperating in different sectors: economic, technical, scientific and legal. It‘s our task to bring concrete benefits and added values to our customers, with innovative company models based on sostainable development principles. In other words we improve their economic, environmental and social performance. Our aim is the perfect SYNERGY between ECONOMY and ECOLOGY. Therefore the name SYNECO. 23. gennaio 2014 6 Posttreatment project The REASON Soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati BIOGAS POWER PLANT WITH WASTE: Digestate = waste = Costs for the recovering/disposal It’s important to reduce the fraction to dispose – Discharge possibility in surface or sewage waters AGRICULTURAL BIOGAS POWER PLANT: Digestate = 23. gennaio 2014 fertilizer, but a lot of regions have a nitrogen eccess NITRATE DIRECTIVE 7 Posttreatment project The REASON – agricultural field Soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati All regions in the centrenord have a nitrogen eccess! 23. gennaio 2014 8 Posttreatment project Primary objective Soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati To find a solution in time: small Simple to manage With reasonable costs The existent solutions are in large part too expensive (e.g. technologies coming directly from the treatment of urban wastewaters) or in development phase. 23. gennaio 2014 9 Posttreatment project Project and partner structure Soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati POSTTRATTAMENTO SOTTOPROGETTO DEMON STRIPPAGGIO OBIETTIVO: RIDUZIONE AZOTO RECUPERO AZOTO TIPO TRATTAMENTO BIOLOGICO TERMICO SPECIFICAZIONE ANAMOX STRIPPAGGIO NECESSITÁ RICERCA SENSIBILITÁ MO AL CONTENUTO ELEVATI DI SALI e sostanza organica FABBISOGNO SPITNO DI PRE-TRATTAMENTO RIDUZIONE EMISSIONI IN ATMOSFERA PARTNER Atzwanger; DICAM - Università di Trento Università Innsbruck (Ara Consult) BTS DICAM - Università di Trento Istituto agrario MACH CRPA 23. gennaio 2014 10 DEMON Soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati The process ANAMMOX (ANaerobic AMMonium OXidation) converts the ammonium directly in molecular nitrogen. The reactions are: Nitrification (partial): Anammox: 2NH4+ + 1.5O2 => NH4+ + NO2- + H2O + 2H+ NH4+ + NO2- => N2 + 2H2O ACIDO The process is done by specific microorganisms – organisms «ANAMMOX» (Planctomycetales): autotrofic anaerobic bacteria observed for the first time in 1995 they contribute at 70% to the nitrogen cycle in the oceans 23. gennaio 2014 11 11 Stripping General Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati Nitrogen drawdown by means of a chemical process of desorption producing ammoniac in gaseous phase. The ammoniac produced is sent to a cleaning column (scrubber) from where it comes out in form of salt (ammonium sulphate). Actually this technology is not covered in the BAT (Best available technology). January 23th 2014 12 Stripping Principle January 23th 2014 Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati 13 Stripping Principle Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati It’s necessary to increase the pH values (10,5 – 11,5) and temperature values for rendering possible the stripping. January 23th 2014 14 Stripping Chosen site Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati Agricultural company Green Energy S.R.L. in Telgate (Bg) Beginning of operation: 2012 Electrical power biogas: 999 kW Feeding scheme: • Poultry manure • Liquid manure • Corn • Triticale • Molasses January 23th 2014 15 15 Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati 1st heating Heat recovery from the treaten digestate T 50 – 60°C January 23th 2014 16 Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati 2. Add of CaO Heat recovery from the treaten digestate T January 50 – 60°C 23th 2014 17 Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati 2nd heating Heat recovery from the cogenerator T 75 – 80°C Heat recovery from the treaten digestate T 50 – 60°C January 23th 2014 Add of CaO 18 Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati Stripping of NH3 Heat recovery from the treaten digestate T January 50 – 60°C 23th 2014 Add of CaO Heat recovery CHP T 75 – 80°C 19 Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati (NH4)2SO4 Heat recovering from the treaten digestate T January 50 – 60°C 23th 2014 Junction of CaO Heat recovering CHP T 75 – 80°C Stripping of NH3 Air cleaning 20 Soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati 23. gennaio 2014 21 Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati January 23th 2014 22 22 Stripping Project objectives Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati Investment and operative costs projection Impose eventually possible optimizations Analysis of the gaseous emissions of the process Analysis of the produced liquid solution – ammonium sulphate (available concentrations, impurities,…) Projection of the pretreatment needed of the digestate (the singular plant has been projected for being able to treat every kind of digestate!) January 23th 2014 23 Stripping Monitoring scheme Biogas in aree alpine: soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati 2014 January 23th 2014 2015 24 Agenda / Inhalt Soluzione integrata per l‘abbattimento o, in alternativa, il recupero dei nutrienti nei digestati Via Marie Curie 17 │ 39100 Bolzano Tel +39 0471 301731 │ Fax +39 0471 326000 [email protected] c/o SYNECO Srl Via Marie Curie 17 │ 39100 Bolzano Tel +39 0471 301731 │ Fax +39 0471 326000 [email protected] 23. gennaio 2014 25
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