ヨウ素系重合開始剤
Iodine-Containing Initiators for Living Radical Polymerization
R-I
モノマー
非金属触媒
Effective for BA ( Bu4NI at 110 oC )
Effective for MMA ( Bu3MePI at 70 oC )
Ph CH I
C O
O Et
Ph CH I
CN
Et O
O C C I
C O
O Et
C I
CN
CH I
CN
CH2 C
I
C O
O
n
( PMMA-I )
( PhCN-I )
( PhE-I )
( EEMA-I )
( CP-I )
( CE-I )
BCMH
PAME
MMMF
PNMM
PNMH
2500
100
88
74
69
104 ka (M-1 s-1) =
(70 oC )
( EA-I )
( E-I )
IBME
RAME
AAME
23
5
<1
62
アクリレート選択的
O
C I
C O
OH
O
I
O
O
I
CH2 I
C O
O Et
( EMA-I )
メタクリレート選択的
I
O
O
CH I
C O
O
CH I
C O
O Et
C I
C O
O Et
I
ABA triblock copolymer
O
O
( EMA-II )
BBDG
( PhE-II )
BPDG
OH
I
Telechelic polymer
O
O
I
O
O
Functional
group
iodine
第63回高分子学会年次大会
May 28th,2014
1F13
I
O
O
Star polymer
( EMA-III )
TBTP
【有機触媒を用いたリビングラジカル重合の休眠種開始剤の検討】
（京大化研）
（合同資源産業）
○雷 琳・ 谷嶋 美保・ 後藤 淳 ・ 梶 弘典
宮本 充彦
URL: http://www.godoshigen.co.jp/
E-mail: [email protected]
本
社
HEAD OFFICE
千葉事業所
CHIBA OFFICE
〒104-0031
東京都中央区京橋二丁目12-6
TEL 03-3566-0341
12-6 Kyobashi 2-Chome, Chuo-ku, Tokyo 104-0031, JAPAN
(+81-3-3566-0341)
〒299-4333
千葉県長生郡長生村七井土1365
1365 Nanaido, Chosei-mura, Chosei-gun, Chiba 299-4333, JAPAN
FAX 03-3566-0340
(+81-3-3566-0340)
TEL 0475-32-1111
FAX 0475-32-1115
(+81-475-32-1111)
(+81-475-32-1115)
ヨウ素系重合開始剤
Iodine-Containing Initiators for Living Radical Polymerization
α-Iodo Esters
AAME
GSS-0006
RAME
Ethyl 2-Iodoacetate
[623-48-3]
C4H7IO2 (214.00)
GSS-0003
BAME
Ethyl 2-Iodopropanoate
[31253-08-4]
C5H9IO2 (228.03)
GSS-0019
Ethyl 2-Iodobutyrate
[7425-47-0]
C6H11IO2 (242.05)
α-Iodo
Carboxylic Acid
AAMH
GSS-0007
2-Iodoacetic Acid
[64-69-7]
C2H3IO2 (185.95)
RAMH
VAME
GSS-0023
Ethyl 2-Iodovalerate
[31253-09-5]
C7H13IO2 (256.08)
α-Iodo
Lactones
GSS-0004
IBMH
2-Iodopropanoic Acid
[598-80-1]
C3H5IO2 (199.98)
GSS-0014
2-Iodoisobutyric Acid
[7425-20-9]
C4H7IO2 (214.00)
IBME
BLMH
GSS-0008
AAMM
Ethyl 2-Iodoisobutyrate
[7425-55-0]
C6H11IO2 (242.05)
α-Iodo
Amides
GSS-0042
RAMA
GSS-0017
EBMH
Benzyl Iodide
[620-05-3]
C7H7I (218.03)
GSS-0046
IBMB
Methyl 2-Iodoisobutyrate
[67194-53-0]
C5H9IO2 (228.03)
GSS-0021
ANMH
GSS-0013
2-Iodoacetonitrile
[624-75-9]
C2H2IN (166.95)
PNMH
GSS-0030
Benzyl 2-Iodoisobutyrate
[NA]
C11H13IO2 (304.12)
α-Iodo
Nitriles
2-Iodopropionamide
[19221-80-8]
C3H6INO (198.99)
α-Iodo-γ-butyrolactone
[31167-92-7]
C4H5IO2 (211.99)
IBMM
Methyl 2-Iodoacetate
[5199-50-8]
C3H5IO2 (199.98)
Benzyl Iodides
BNMH
GSS-0015
α-Iodo
Ketones
GSS-0022
2-Iodopropionitrile
[104024-32-0]
C3H4IN (180.98)
APMH
PNMM GSS-0044
2-Iodoisobutyronitrile
[19481-79-9]
C4H6NI (195.00)
GSS-0031
2-Iodoacetophenone
[4636-16-2]
C8H7IO (246.05)
Functionalized Compounds
GSS-0005
NTMH
(1-Iodoethyl)benzene
[10604-60-1]
C8H9I (232.06)
GSS-0045
IBMO
4-Nitrobenzyl Iodide
[3145-86-6]
C7H6INO2 (263.03)
GSS-0036
PAMO
2-Hydroxyethyl 2-Iodoisobutyrate
[NA]
C6H11IO3 (258.05)
GSS-0039
2-Hydroxyethyl 2-Iodo-2-phenylacetate
[NA]
C10H11IO3 (306.10)
Highly Activated Compounds
PAME
GSS-0009
TAME
Ethyl 2-Iodo-2-phenylacetate
[78489-65-3]
C10H11IO2 (290.10)
GSS-0034
NPME
Ethyl 2-Iodo-2-(4'-methylphenyl)acetate
[NA]
C11H13IO2 (304.12)
GSS-0026
PAMH
Ethyl 2-Iodo-2-(4'-nitrophenyl)acetate
[NA]
C10H10INO4 (335.10)
GSS-0018
α-Iodobenzyl Cyanide
[63450-93-1]
C8H6IN (243.04)
MMMF
GSS-0010
MAME
Diethyl 2-Iodo-2-methylmalonate
[119368-33-1]
C8H13IO4 (300.09)
PMMH
2-Iodo-2-phenylacetic Acid
[615256-95-6]
C8H7IO2 (262.04)
Highly Activated Compounds
BCMH
GSS-0020
GSS-0011
FLMH
Iododiphenylmethane
[29704-39-0]
C13H11I (294.13)
GSS-0012
9-Iodo-9H-fluorene
[64421-01-8]
C13H9I (292.12)
Multi-Iodinated Compounds
GSS-0032
PXDH
Ethyl 2-Iodo-2-methylacetoacetate
[1005452-92-5]
C7H11IO3 (270.06)
GSS-0001
ADDF
p-Xylylene Diiodide
[30362-89-1]
C8H8I2 (357.96)
GSS-0016
Diethyl 2,5-Diiodoadipate
[165334-67-8]
C10H16I2O4 (454.04)
Multi-Iodinated Compounds
PXDL
GSS-0027
BBDG
1,4-Bis(1'-iodoethyl)benzene
[NA]
C10H12I2 (386.01)
GSS-0024
BPDG
Ethylene Glycol Bis(2-iodoisobutyrate)
[NA]
C10H16I2O4 (454.04)
GSS-0037
TBTP
Ethylen Glycole Bis(2-iodo-2-phenylacetate)
[NA]
C18H16I2O4 (550.13)
GSS-0025
MSTK
Glycerol Tris(2-iodoisobutyrate)
[NA]
C15H23I3O6 (680.05)
GSS-0028
1,3,5-Tris(1'-iodoethyl)benzene
[NA]
C12H15I3 (539.96)
URL: http://www.godoshigen.co.jp/
E-mail: [email protected]
本
社
HEAD OFFICE
千葉事業所
CHIBA OFFICE
〒104-0031
東京都中央区京橋二丁目12-6
TEL 03-3566-0341
12-6 Kyobashi 2-Chome, Chuo-ku, Tokyo 104-0031, JAPAN
(+81-3-3566-0341)
〒299-4333
千葉県長生郡長生村七井土1365
1365 Nanaido, Chosei-mura, Chosei-gun, Chiba 299-4333, JAPAN
FAX 03-3566-0340
(+81-3-3566-0340)
TEL 0475-32-1111
FAX 0475-32-1115
(+81-475-32-1111)
(+81-475-32-1115)