1P067 Poly(3 hexylthiophene)薄膜の形態変化の電子構造 の影響

1P067
!
"#$%&'()*+%$,)-#.)*/*01234567389:;<3=>!
?@ABCDEF GHIJCEKLMNOP!
QRS! TC GHUV! W OHXY! Z[ GH\]! ^_ GHC`! Za G!
!
bcd! efghijklmno8Y?")#,#! p#$,q-r! s!
"pPt8uvwxyz{j|&}-*$~! €€*r,! ‚q/ƒ-ƒ,#‚! s!
}0 „ … † ‡ ˆ ‰ Š ‹ ˆ m Œ 8  Ž  9 "#$%!
&'()*+%$,)-#.)*/*0!&"'0‘’“”•–Œ—˜™†š
›œžŸ ¡Š‹ˆm¢} :;3£¤¥j¦‰§¨©
ª«¬‘ ­®G!r¯O°ƒ ±²³´‹µ›œefghijklm
12£¤¥j¶´‹‘·Ž3¸±¹´‹ˆm¢ G º©œ
"' ¶ »¼½¼¾(")*/%$! ¿¼G! ÀÁ,%‚-r! qr-~! ¯*,)%$! *ƒ,*‚!
! 1. Poly(3-hexylthiophene)"#$%
&"¿ÂÃ0¶3ÄÅ2†šm&ÀÁ$Æ()*,*‚#!ÇÁ/r,-#/ :;20±ÈÉÊËk‡ˆ©”•12no8Y†
‘œ·ŽÈ6ÌvÍ Î®¼! ϶”•12no8Y3ІюˆÈ6Ìvͱ¹ÒÓ¶ÔÕÖ¡Š
‹ˆm¢O! "' 12‘רÙFÒmÚklۋÜÝ7ÒmÓ¶ÔމŠ‹µ›œßàk£¤¥já
Ôâ㡊m¢´¦´œ"' 123ÜÝ:;äåÔæçè醜”•Ët8ê¶3uëkµ
ìm·Ží”îï! &ðÃð0E·ñòí”îï! &óôÃð0±Ðõ¶´©89:;3ïö÷øE89
îïùúûü389:;kýˆ‹‘þÿlž¦Û‹ˆûˆ
Ô!žšm¢ákœòí”îï3
÷´‹‘ÕÖ¡Š‹ˆûˆ¢ÓЉ3Þ"‘”•89£¤¥j3#$tŽ%7±&'Òm(†
)W†šm¢*ӆœ+,-†‘œ×ØÙFklm "' 1234567k./89:;367
kýˆ‹ÕÖ±0/¢!
b&1d+Ÿ †‘Üݍ2(k./ "' 1232:;367± 3 4E5678È89È9
?3":Eô":Pœ;È89È9?<":P†=>©¢?@klmA7±BCm©¨kD@EFGH3
IhJKLMNj`†jOzPJx9±‡ˆ‹³2´œCGQRÒmÚûžSTUkŒVœWŽ5
6H†È89ÈST±0Û©¢XYk‘ <ð ±‡ˆœZixzœ¥[gh\]J^3_†`a´
©bœcdzÙF±0Û©¢"' 123e¡‘ 3 4fgÍST3Üw±å´©¶ÓhœGi/¯ j
¬¶§ºÛ©¢jOzPJx¡Š©12‘ßIhJKLMNj`3kMxglJx(† G àmœG­­nœ
º©‘ Go­n†×ØÙF´©¢3": 3Èpk‘qr7¡Š© s$!tu4&)vwGxi¼®¼!*p0œô": k‘
*yz{4&)vwOG®OO!*p0œSTà356¬‘ 3": † G|G­(G­!¯Âœô": † Î|G­(¼!¯Â †šm!
¢3":Eô": 3Z}y¥~Jk‘&'()#*+,-."/0(Omicron 12 EA 125)345
67<": 389pk‘Ú÷€3ñ¡t‚ƒñ„†Ø89…†Ô‡Óm¶ˆ/ˆ‰¦‰ Âqð
±‡ˆœÈ3І‹k‘Œ˜k :‚}Oœ! t¿$ ±Ž¡©‘z’^xhz±‡ˆ©¢º©œSTà
356¬‘ O|G­(i!"q †šm¢!
bÜw“”•d! – O k¹
´©l/kœ×ØÙF„
¬ÔŽžûmkýŠ‹œ
3—˜ †‘ q ™é23Ü
Ý ³ ˆ k š © m
"'&G­­0OJNԛž
œS¡Šml/kû›œ
ôp(-ƒ ÉÊjžNx^
†‘œŸ ¡Jm†3¢
(¢
£
¤ªkš©m
¼­­/¯ 3OJNÔ³ˆ´
‹ˆmӶԏ۩¢Ó
! 2. (a)[
P3HT 89: XRD =>?@,:\]^_(b) UV-vis =>?@,:ABC
DEFG7`a:6bcJde:=>?@,fWX67
Љ3Ó¶¦‰ÜÝ7¬
Ô ¥ C ´ ‹ˆ m Ú± ¦
§ìmÑ3¶”C‰Šm¢!
è霖 ' 3È89
ȶ;È89Èjž
Nx^±¹´©¢89:
;†367‘œ¨©œ
2:;3ÜÝ7Ô¥C
ÒmkýŠ‹ª’^«
J«‘Mg‘¬¡žûÛ
‹ˆžÓ¶ÔމŠ‹ˆ
mԜ"' 3­Å‘×
ØÙF„¬3(®¶z
kÜÝ7Ô¥C¡Š©
3kѦ¦¯‰°œª’
! 3. P3HT 89:;)#-<;)#=>?@,:ABCDEFG7H:!IJK*+
,-.LM@NOJPIOQ,RSTUV:=>?@,3WXY5Z7
^«J«‘MgԝÔmá±û89:;67±ÒmÓ¶Ô²‰¦kûÛ©¢,-†‘œœS¡Š©
234567¶3÷³kýˆ‹´µ±0û/¢!
b¶”·¸d!
G
!®!:-‚‚-/¹)qÁƒ!*,!q$½!ºq,Á‚*!&ó#/~#/0!G»»»½x­G½!¼iÎ!
O
!î!˜®!<‚¼-/!*,!q$½!"ºs:!O­­iHG­Î½!Ooi'!
!
b½¾d!
+Ÿ ‘¿À ¼ Ák$ÂኩÄ÷èÅÆÇ3H†0¯Šº´©¢ÈÉkʛº´©÷ËÈ3
Ì͌kδ‹ÏžÐ½Ñ´(ÒºÒ¢!