Study Buddy: Electron Terms Description Wavelength ( ) distance from crest to crest or trough to trough Frequency ( f ) the number of wave cycles per second Amplitude ( A ) height of a wave’s crest or trough Photon a quantum of light; a discrete bundle of electromagnetic energy that interacts with matter similarly to particles Energy Level or Orbit The specific energies an electron can have in an atom based on Bohr’s atomic model; orbits farther from nucleus have higher level numbers and energy Orbital 3D region of space around the nucleus where there is a high probability of finding an electron; based on math equations used in the quantum mechanical model Diagram/ Example unit: meters (m) unit: 1/sec, Hz (Hertz) # times wave passes a point in given time unit: meters (m) Ground State Excited State Lewis Valence Electron Dot Structure The arrangement of electrons of an atom in its ground state into various orbitals around the nuclei of atoms Electron in orbit 1 or orbit 2 http://www.uq.edu.au/_School_Science_Lessons/TWI magesatoms.html lithium (Li) 1s Formed when electrons occupy the orbits or orbitals closest to the nucleus; the lowest possible energy state of an atom Formed when electrons are further from the nucleus than in the ground state; the energy of an atom is higher than the ground state A notation that depicts valence electrons as dots around the atomic symbol of the element or 1s22s1 2s hydrogen (H) or 1s1 hydrogen (H) or H 2s1 Li Circle the EM spectrum section with largest frequency; place a square around the section with the largest wavelength. What is the relationship between frequency and wavelength? Frequency and wavelength are inversely proportional; as wavelength increases frequency decreases and vice versa. Look at the energy for the 6.63 x 10-14 J waves with the largest and Energy 6.63 x 10-30 J smallest frequency. What is the relationship between frequency and energy? Frequency and energy are directly proportional; as frequency increases energy increases (has a larger exponent) and vice versa. 10/26/15 SCIE_CHEM_ELEC_MAT_STUDYBUDDYTE_AL copyright © CFISD 2015 1 http://mynasadata.larc.nasa.gov/scienceprocesses/electromagnetic-diagram/ Electron Configuration Ephoton, Joules Based on the EM Spectrum graphic, why is ultraviolet light more dangerous than infrared? The energy of EM waves is directly proportional to the frequency of the wave. Since UV waves have a higher frequency than IR, they are more energetic and can cause more harm to cells. The Bohr models to the right of statements A and B represent an atom by showing its first two energy levels/orbits. Draw in electrons to represent their movement for the observations given. A. An atom absorbs a quantum of energy equivalent to the difference in energy between orbits 1 and 2. B. An atom emits a photon of red light equivalent to the energy difference between orbits 1 and 2. C. If a more intense red light was observed than in B, describe what would change on the Bohr model? For a more intense light, more photons of the same energy would be released; more electron jumps between orbits 1 and 2 would occur in a given time. Wave calculations: 1. Calculate the frequency of light that has a wavelength of 600.nm (6.00 x 10-7 m). c=fλ 3.00 x 108 m/s = f (6.00 x 10-7 m) f = 5 x 1014 1/s = 5 x 1014 s-1 = 5 x 1014 Hz 2. What is the energy of violet light with a frequency of 7.50 x 1014 Hz? E=hf E = 6.63 x10-34 J·s (7.50 x 1014 1/s) E = 4.97 x 10-19 J Representing Electrons: A. Fill in the Orbital Diagrams and write the corresponding electron configurations in the blanks. 1. O 1s 2s Valence electrons= 6 Lewis Dot= O Valence electrons= 8 Lewis Dot= O-2 2p 1s2 2s2 2p4 2. O-2 1s 2s 2p 1s2 2s2 2p6 3. Na Valence electrons= 1 1s 2s 2p 2 3s 6 Lewis Dot= Na 3p 1 1s 2s 2p 3s 2 4. As Valence electrons= 5 1s 2s 2p 3s 3p 4s 3d 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p3 4p Lewis Dot= As B. Determine the number of valence electrons and write the Lewis Dot structure for each. C. What is the relationship between the number of valence electrons for a neutral isotope and its location on the periodic table? For main group elements valence electrons equals the group number if it is a single digit, or the last number if it is two digits; 8 valence e- maximum. 10/26/15 SCIE_CHEM_ELEC_MAT_STUDYBUDDYTE_AL copyright © CFISD 2015 2
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