Direct Reduction Iron Plant Group Golf Selimos, Blake A. Arrington, Deisy C. Sink, Brandon Ciarlette, Dominic F. (Scribe) Advisor : Orest Romaniuk 1 Table of Contents 3 – Previous Questions 4 – Design Basis 5 – Block Flow Diagram 6 – Overall ASPEN Simulation 7 – Closer look: Primary Reformer and Heat Exchangers 8 – ASPEN Sim: Primary Reformer and Heat Exchangers 9 – Energy Sinks and Loads: Primary Reformer 10– Energy Sinks and Loads: Heat Exchangers 11– Energy Sinks and Loads: Overall Process 12– Equipment Sizing 13-14 – ASPEN Process Economic Analyzer 15– Profit Economics 16– Transportation 17– Shipping & Storage 2 Previous Questions • What type of catalyst will we be using in the primary reformer? • What is the lowest purity of oxygen the oxygen fuel booster can operate with? • Impurity concerns iron ore feed. 3 Design Basis • 106 thousand lbmols/day of natural gas feedstock will be supplied for process from Gas Treatment Plant; natural gas is the main source for Carbon for the reformer. • Supply portion of top-gas CO2 to Industrial Gases Plant, 148.8 thousand lbmols/day. • Air Separations and Syngas Plant will supply 0.5 thousand lbmols/day of O2 for the Oxy Fuel Booster. 4 Block Flow Diagram 10. 19. Compressor 9. 1. 8. Recycle Guard Bed 17. Top Gas Scrubber Fuel Gas 2. 24. 7. 18. Removal 5. Main Air Blower 3. EjectorStack Stack Ejector Iron Ore Shaft Furnace 13. 11. 15. 22. Oxy Fuel Boost Reformer 6. Midrex Reformer Heater 23. 12. 21. 16. 4. 20. 14. Iron Briquettes 5 Overall ASPEN Simulation 6 Closer look: Heat Exchangers & Primary Reformer 5 10 1 3 8 2 Midrex Reformer Heater 9 7 4 6 1 2 3 4 5 6 7 8 9 10 Feed CH4 & recycle stream Exhaust going to ejector Air coming from air blower Heated process gas Reduction gas going to Oxy Fuel booster CH4 to combustion chamber Recycle gas to combustion chamber Heated gas from combustion Heated air to combustion chamber Recycle gas from CO2 Removal CH4, H2, CO, CO2, H20, N2 CO2, H2O, N2 N2, O2 CH4, H2, CO, CO2, H20, N2 CH4, H2, CO, CO2, N2 CH4, N2 CH4, H2, CO, CO2, H20, N2, O2 CO2, H2O, N2 CH4, H2, CO, CO2, H20, N2 CH4, H2, CO, H20, N2 7 ASPEN simulation: Heat Exchangers & Primary Reformer 77 F 14.7 psi 180 F 75 psi 724 F 14.7 psi 420 F 14.7 psi 1650 F 75 psi 1878 F 14.7 psi 438 F 14.7 psi 1076F 75 psi 180 F 14.7 psi 615 F 14.7 psi 180 F 75 psi Thousand lbmols/day Stream Names CH4 H2 CO CO2 H2O N2 o2 Total flow 3 4 5 11 12 13 14 21 22 23 FeedIn FeedOut Redux1 Air ToCombus Recycle CH4 Comb Exhaust1 Exhaust2 88 47 26 223 327 12 724 88 47 26 223 327 12 724 5 260 146 270 364 12 1,056 184 52 236 184 52 236 2 31 17 218 5 274 1 1 3 31 17 0 218 189 52 511 21 256 189 21 486 8 21 256 189 21 486 Energy Sinks and Loads: Primary Reformer COMBUST REFORMER 1076ºF 75 psi IN 1650 ºF 75 psi OUT Q= 280 mmBtu/hr 438º F 14.7 psi IN 1878 ºF 14.7 psi OUT Q= - 280 mmBtu/hr 9 Energy Sinks and Loads: Heat Exchangers 1076º F 75 psi 77º F 14.7 psi AIROUT FEEDOUT 1878º F 14.7 psi FEEDHEAT 724 ºF 14.7 psi 724º F 14.7 psi EXHAUST2 EXHAUST1 420º F 14.7 psi AIRHEAT EXHAUST3 EXHAUST2 1650 F 75 psi 180º F 75 psi AIRIN FEEDIN Q=113 mmBtu/hr Q=27 mmBtu/hr 10 Energy Sinks and Loads: Overall process 11 Equipment Sizing Heat Duty (mmBtu/day) Size (ft2) Feed Heat Exchanger 113 1142 Air Heat Exchanger 27 1270 Reformer 28 57600 (foot print) Equipment Primary Reformer Tubes: 10 in. Diameter, 26 ft. length f = Maximum heat flux thorough tube walls = 21,000 Btu/ft2*hr d = Heat duty through primary reformer (from Aspen) = 279,515,872 Btu/hr a = Total needed surface area of reformer tubes = d/f = 14,167 ft2 t = a / 73 ft2 per tube = 194 tubes needed 12 ASPEN Process Economic Analyzer 5 Units analyzed • Primary Reformer • Heat Exchanger 10 1 3 8 2 Midrex Reformer Heater 9 7 4 6 Other Reports - Project Equipment Summary - Total Cost Project Title: Project Name: Proj. Location: Estimate Date: Component REFORMER&COMBUST AIRHEAT FEEDHEAT DRI Plant Golf North America 10MAR13 17:48:56 Component Total Equipment 34,190,000 616,000 623,000 35,429,000 21,500,000 31,000 37,000 21,568,000 Piping 3,800,000 500,000 500,000 4,800,000 Civil Steel 890,000 3,000 3,000 896,000 920,000 920,000 Instrumentation 4,000,000 31,000 21,000 4,052,000 Electrical 240,000 240,000 Insulation Paint 2,600,000 46,000 56,000 2,702,000 240,000 5,000 6,000 251,000 13 14 Profit Economics Production (ton/year) 1,840,000 Production cost ($/ton) Materials, Utilities, Transportation, Wages 295 Product Sell Price ($/ton) 425 Profit per ton ($/ton) 130 Total profit per Year ($) 240,000,000 15 Transportation Costs By Rail For Feed/Product • Basis of 1.84 mm ton produced 5,041 (ton/day) • Average rail car holds 80 tons. With a maximum load per train of approximately 15,000 ton and 150 cars • Plant will need a train every 2 days of approximately 130 cars. • Average cost to ship by rail 0.03($/ton mile) • Assuming a discounted rate of 25% for large volume of material transported. • Using northeast Minnesota for iron oxide source and northwest Indiana for product shipment. • Cost to ship 23.00($/ton) to ship product 12.00($/ton) import raw material. 16 Shipping/Storage • Installed equipment cost for a private rail line with loading/unloading site at our capacity will be around $15 million. • Storage facility with installed in-loading/outloading conveyor system, a negative pressure dust/climate management system, and a 150 ton capacity will cost around $10 million. 17 Summary • Producing 1.84 mm Ton/year DRI. • Heat from combustion drives primary reformer and preheats gas entering primary reformer and combustion. • Typical primary reformer size: 57600 ft2. • Cost of reformer & heat xers: $38 million. • Yearly profit: $240 million. • Transportation: 130 car train every 2 days. • Storage: 2-week buffer for unexpected delays. 18 Work in Progress • Finish process simulation in ASPEN. • Run ASPEN economic analysis on whole process. • Size all equipment. 19 Questions 20 21 Typical Plant layout 22 23 24 25
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