Progress Report On IAEA/RCA Project Improving Regional Capacity for Assessment, Planning, and Response to Aquatic Environmental Emergencies (RAS/8/095) H1 Extension January 2007 Prepared by R. Szymczak ANSTO Institute for Environmental Research Project Lead Country Coordinator RAS/8/095 1. OBJECTIVES To improve the regional capacity for the management of aquatic environmental risks and to develop capacity in the RCA countries to assess, plan, and respond to pollution in coastal aquatic environments. 2. BACKGROUND Pollutant materials in the aquatic environment may be derived from natural or anthropogenic sources and may be of radionuclide, organic or inorganic origin. These pollutants in large bodies of water can be dispersed by active forces such as wind, tides and currents. The health and livelihoods of populations living in coastal marine environments may be placed at risk as a result. The growth of the mining and other industry-related activities in the Asia and the Pacific region has increased the level of contamination in receiving waters, leading to reduced populations of the flora and fauna through direct toxic effects, as well as increasing the concentrations of non-radioactive pollutants in staple aquatic foods. For example, arsenic deposits have been found in the Mekong Delta region in association with mining activities in Thailand. The accumulation of contaminants in the water, flora, and fauna can impact local communities' sources of food supply as well as their sources of livelihood. The project will demonstrate and transfer technologies for the assessment of the impact of contaminants on aquatic organisms. It will also address the problems of water-dispersed pollutants by developing and verifying hydrodynamic models of polluted aquatic environments. The hydrodynamic models can then be used to accurately predict the dispersion of pollutants in the aquatic environment. They provide powerful tools for planners who can then predict if pollutants will reach and affect specific marine resources. They can also use such models to predict the impact of changing the hydrodynamics of an area through the construction of manmade structures. The project originally planned for 2003–2004 is extended to 2005–2006 because all the activities planned for 2003–2004 could not be completed as scheduled as a result of the unexpected delay in finalizing the Exchange of Letters (EOL) between the Agency and AUSAID, which is funding this project. 3. EXPECTED OUTCOMES 1. The expertise and knowledge transferred to the RCA Member States on the use of computer codes for quantitative assessment of ecological risk, associated with the release of contaminants into estuarine and coastal environments. 2. Capability of using hydrodynamic models for analysing dispersion of pollutants in aquatic environments under local environmental conditions established. 4. PERFORMANCE INDICATORS FOR OUTCOMES 1a. Thirty-five persons trained in two regional training courses in computer modelling of dispersion of pollutants in the aquatic environment before the end of 2006. 1b. Four expert missions implemented and 30 persons trained in ecological risk assessments before the end of 2006. 2a. At least five of the RCA Member States will have acquired the capability of using hydrodynamic models to predict dispersion of pollutants in aquatic environment in order to provide data needed by planners to mitigate the effects of aquatic pollutants before the end of 2006. 5. EXPECTED PROJECT IMPACT The project will enhance the regional and national ability to assess, plan, and respond to aquatic environmental emergencies and therefore reduce the risks to the economic well-being and health of communities in the region. The trans-boundary nature of the problems being addressed underlines the need for a regional response. 6. ACTIVITIES AND ACHIEVEMENTS IN 2006 6.1 Mission to Indonesia – Validation of Hydrodynamic Model - Radiotracer Study Jakarta Bay, Indonesia, 24 April – 6 May 2006 This mission aimed to demonstrate field techniques for the collection of data to validate and calibrate a hydrodynamic model. It included conduct, in conjunction with the Indonesian National Nuclear Energy Agency (BATAN) and Indonesian Institute for Sciences' Research Centre for Oceanography (P2O-LIPI), of a series of radiotracer studies over 4 days using Tc-99m to trace the transport of contaminated water from Jakarta canals/rivers to Jakarta Bay and the circulation of contaminated waters in the bay. In addition physical parameters required in calibration or driving of the model (e.g. current, water depth, salinity, temperature) were collected. Duty stations: Centre for Research and Development of Isotopes and Radiation Technology (P3TIR-BATAN), National Nuclear Energy Agency, Jakarta, Indonesia; Research Centre for Oceanography (LIPI), Indonesian Institute for Sciences, Jakarta, Indonesia. Experts: Dr Cath Hughes and Mr Ron Szymczak (ANSTO) Dr Will Glamore (UNSW) also attended for 5 days to assist with the radiotracer study (under separate Hydrodynamic Modelling contract) The key tasks/requirements of this pre-project mission were: In consultation with the counterpart, provide advice and assistance in the conduct of a radiotracer study in Jakarta Bay as per the report submitted to the IAEA from the planning mission (RAS/8/095-01-01). Specifically assist BATAN in: Design and operation of a radioisotope tracer injection system. Conduct of safety and environmental assessment for the radiotracer study for use in licensing including liaison with the Indonesian nuclear regulator, the Nuclear Energy Control Board (BAPETEN). 2 Operation of radiation detection, Global Positioning System (GPS) and associated equipment to monitor the tracer plume in situ. Field operations. In consultation with stakeholders P2O-LIPI and the Bandung Institute of Technology (ITB) provide advice and assistance on the collection of ancillary data including the deployment of Accoustic Doppler Current Profiler (ADCP), Conductivity/Temperature/Depth profiler (CTD), tide, wave and current gauges, and the development of stage discharge curves for Jakarta rivers and canals. Determine achievable goals and scenarios for ecological risk assessment and determine data sources and gaps. Summary: The field demonstration very successful. Four radiotracer injections of Tc-99m were made from 1 to 4 May 2006, one per day, using a 4 Ci Technetium 99m generator supplied by BATAN. Injections were carried out using local fishing vessels specifically chartered for this activity and involved the active participation of staff from the various stakeholders, BATAN, LIPI and ITB . The dispersing tracer was tracked successfully by two boats using waterproof NaI detectors connected to scalar ratemeters. The countrate data and GPS positions were logged into ANSTO’s Radiotracer Data Acquisition software and the position of the detector and activity of the tracer displayed onscreen in real time. A sample of the results from Day 2 of the demonstration is shown below. During the four day field demonstration P2O-LIPI installed an acoustic Doppler current profiler on board the survey boat and collected current and depth data. In addition CTD (conductivity, temperature and depth) profiles were collected periodically. This data will be used in interpretation of the tracer data and to run the hydrodynamic model. 3 Full details are available in the Expert Mission Report (Hughes & Szymczak, 2006). 6.2 Mission to Pakistan - Strengthening of Expertise on Assessment, Planning and Response to Aquatic Environmental Emergencies in Pakistan, 30 October – 4 November 2006 The Isotope Ecology Research Laboratories of the Radiation and Isotope Application Division (RIAD) at PINSTECH, Islamabad are very actively participating in the national activities of the IAEA/RCA Project RAS/8/095 (Improving Regional Capacity for Assessment, Planning and Response to Aquatic Environmental Emergencies). However, team members from the National Nuclear Institute (PINSTECH) and various end-user departments (National Institute of Oceanography-Karachi; Center of Excellence in Marine Biology-Karachi University, Maritime Security Agency-Karachi, Marine Fisheries Department-Karachi/Gwadar, etc.) have certain weak areas with respect to technical/theoretical knowledge in aquatic risk assessment modelling, conduct of radiotracer validation experiments, enhanced sampling and analysis protocols and bioaccumulation of toxic metals by aquatic organisms with special reference to laboratory aquarium experiments (via water and sediments). Accordingly, in the six monthly progress report (Period Jan-June, 2006) for the RAS/8/095, the Pakistan National Coordinator of the RAS/8/095 Project mentioned his request to the RCA/IAEA for provision of AQUARISK Model and experts for one week training event on assessment, planning and response to aquatic environmental emergencies in Pakistan for the benefit of the nuclear institute and the end-user institutions. Duty station: Pakistan Institute of Nuclear Science and Technology (PINSTECH) Islamabad, Pakistan Experts: Mr Ron Szymczak (ANSTO), Mr John Twining (ANSTO) and Dr Michel Warnau (IAEA-MEL) The key tasks/requirements of this pre-project mission were (i) Provision of AQUARISK Computer Modelling Software Complete Package to RIAD/PINSTECH (through IAEA/RCA Project Funds for RAS/8/095) for aquatic risk assessment evaluations. (ii) Installation, demonstration and training of AQUARISK Modelling Software Package. (iii) Advice on up-gradation of Radioecology Laboratory and bioaccumulation experimentation at the Radioecology Laboratory, PINSTECH, Islamabad. (iv) Lecturing at IAEA/RCA sponsored “National Workshop on Assessment, Planning and Response to Aquatic Environmental Emergencies in Pakistan” to be held in Islamabad. (v) Field demonstrations for aquatic risk assessment in Rawal Lake/Khan Pur Lake/ associated tributaries. Summary: Interest for the National Workshop was totally over whelming. Although approximately 20-30 delegates were anticipated, by the day prior to the National Workshop, 64 delegates had been accepted for registration. Delegates came from a great variety of institutes and agencies, having interest in a diverse number of environments (mountains, forest, saltmarsh, mangrove, freshwater, marine). As well as specific interest from delegates associated with aquatic and marine issues, great interest was expressed by delegates working in alpine conservation (World Wildlife Fund – WWF) and climate change issues (Global Change Impact Studies Centre, Pakistan). A list of beneficiary and end-user organisations is provided in Annex 3. 4 The facilities provided by PINSTECH and COMSATS were excellent for conducting the AQUARISK training and National Workshop. 22 computer were provided (in anticipation of approx. 20-30 delegates), around which 64 delegates were divided into groups to each get practical experience in running the ecological risk assessment modelling code. The field tracer injection demonstration was successfully conduct with the assistance of the Pakistan Navy, Naval Headquarters in Islamabad by provision of several small boats on Lake Rawal to function for demonstration and observation vessels. The Rhodomine dye was injected in a tributary of Lake Rawal and followed for several hundred meters by collection of water samples and fluorescence analysis using the detector provided. Proir to the field demonstration, briefing lectures were presented by Dr Qureshi (PINSTECH) and Mr Szymczak (ANSTO) on theory and applications of radiotracers and the fluorescent dye. Following the tracer activity Dr Qureshi and Mr Szymczak discussed the results obtained and how they may be applied to hydrological and contaminant transport studies. The desired outcomes of the mission were well achieved where PINSTECH staff and National Workshop delegates acquired an enhanced theoretical knowledge of the behaviour of contaminants in aquatic systems and radiotracer applications for geochemical, hydrological and bioaccumulation studies to evaluate the environmental fate of contaminants in aquatic systems. The session on ecological risk assessment and demonstration of AQUARISK code applications was well received, providing a valuable introduction to this model and information on data requirements required for future risk assessment activities. The recruited experts functioned very well together as a team, displaying a high level of efficiency and integrity with a strong commitment to achieve the outcomes of the mission. Their complementary set of expertises proved to be an excellent resource, both for the delivery of lectures, training and field demonstrations and in provision of ad hoc advice and information on associated issues particular to their own activities. Full details are available in the Expert Mission Report (Szymczak & Twining, 2007). 6.3 Regional Training Course on Combining Contaminant Transport and Ecological Risk Assessment Models for Response to Environmental Emergencies, Qingdao and Haikou, China, 5-13 December 2006 The course provided specific training in the theoretical background, practical applications and interpretation of state-of-the-art probabilistic ecological risk assessment modelling (AQUARISK) for radionuclides and non-radioactive contaminants. It brought together the various theoretical and practical training and demonstration experiment activities previously undertaken in RAS/8/095 and represents a state-of-the-art combination of contaminant transport modelling with biological contaminant dose response for “best world practice” ecological risk analysis. The course composed of a series of lectures, laboratory exercises and demonstrations of probabilistic ecological risk assessment modelling and contaminant transport modelling. Each participating country was provided with printed guidelines and lectures notes. Participants were assessed on their acquired knowledge on the completion of the course. As part of the training course, participants also attended the QingDao Symposium on Marine Pollution Monitoring and Assessment (Qingdao 10-11 Dec) and participated in the PEMSEA East Asian Seas (EAS) Congress 2006 (12-13 Dec), where the results of a contaminant transport model for Jakarta Bay, developed within the Project, were presented and used as an example scenario for application of AQUARISK. Outcomes of the Regional Project and National Project activities were presented. Anticipated outputs were that the participants were expected to achieve: 5 - an enhanced knowledge of the behaviour of contaminants in aquatic systems; - an enhanced knowledge of the development and application of water quality criteria for contaminants in aquatic systems, and; - practical experience in the application of probabilistic ecological risk assessment using the AQUARISK software. Following this training the participants will be expected to undertake a series of defined activities to disseminate information in their own countries in association with their National Project Team. Summary: A primary outcome of this Project has been the development and transfer to member States of an experimentally-field-validated dilution and dispersion model which would generate contaminant concentrations downfield from a specified source. This could then be used as input to a quantitative, probabilistic, ecological risk assessment, based on regionally relevant doseresponse data and filtered to reflect specific environmental foci. This demonstration was comprehensively successful. The acquisition and reformatting of the ASEAN database was an unplanned bonus and made the overall Project deliverables even more beneficial to the participating RCA Member States. The participants demonstrated a keen interest in the computer codes presented and asked many questions which showed that they had acquired a substantial comprehension of the applications. This was recognised by the demonstrators when devising detailed questions to test the depth of knowledge and use of the codes. All participants passed the test well and appeared keen to use the tools in future. The participants selected to attend the meeting were assessed as generally being very well suited for this RTC. In addition to their competence, the participants interacted very well and this should facilitate continuing networking between them. Member States should encourage and facilitate ongoing contact between the participants. Several of the participants were keen to discuss new projects and it was suggested that they should develop their proposals more fully between national institutes with a view to review by the experts prior to submission of a concept document to the National RCA/IAEA Representatives for consideration. The participants were well selected and all took on the training with considerable enthusiasm. Feedback from them showed that they considered the course content to be of a high calibre and the pace of the training programme to be appropriate. The desired outcomes of the course were achieved and all participants acquired an enhanced knowledge of the behaviour of contaminants in aquatic systems and practical experience in the application and interpretation of nuclear techniques for evaluating bioaccumulation and environmental fate of contaminants in aquatic systems. The session on ecological risk assessment and demonstration of AQUARISK code applications was well received, providing a valuable introduction to this model and information on data requirements required for future project activities. The complementary set of expertises of the recruited lecturers proved to be an excellent resource for the participants, both for the delivery of lectures, demonstrations, practical exercises and in provision of ad hoc advice and information on associated issues particular to their own activities. During the training course all participants expressed their appreciation of the knowledge of the speakers, the value of the materials being presented and relevance to their needs. Participants were solicited for specific feedback on the venue, modelling exercises, course materials, visual aids, the ability of speakers to gain attention, speakers’ knowledge of the subjects, overall impressions and comments on individual lecture topics (see Annex 9). Feedback from them 6 ranked various aspects of the course to be very good to excellent. The training topics selected were also rated by them as very good to excellent. Attendance of the Qingdao Marine Pollution Symposium and PEMSEA East Asian Seas Congress (a) proved to be very beneficial for participants, in being delivered detailed presentations on several regional and international activities as well as gaining valuable experience in delivery of presentations at this prestigious level; and (b) provided valuable exposure for RCA Project activities. A significant number of delegates showed a great deal of interest in our activities and identified several potential future interactions, including requests for further dissemination of our developed technologies and ecological risk analysis strategies via similar training courses and indications for specific collaborative studies A high degree of network development was apparent from these activities (see list in Annex 11). The training which had been discussed and applied during the previous week was pertinent to many of the problems and issues discussed at the conference. Hence, we were regularly able to contribute worthwhile comments across the week and we have had discussions with several local and international experts and research groups with whom common interests were held and with whom future collaboration should be considered. These regional and international network liaisons represent a valuable outcome for the RCA Project and should contribute to sustainability and regional diffusion of nuclear and isotopic technologies. An indication of the increasing importance of these marine pollution studies and the significant contribution that nuclear techniques can make to the solution of such problems, China has allocated very significant funds through the State Oceanographic Administration for the purchase of nuclear instrumentation to enhance and extend their capabilities for ocean monitoring and pollution studies Full details are available in the Regional Training Course Report (Szymczak, Twining & Hughes, 2007). 6.4 Member State Activities and Achievements – Country Reports June 2006 6.4.1 Indonesia (Annex 1) Main Achievements: Demonstration of the project from 24 April to 6 May 2006 in Jakarta Bay for implementing the RAS/8/095 project. This activity has been assisted by 3 experts, i.e; Mr. Ron Szymczak and Ms. Cath Hughes from Australian Nuclear Science and Technology Organisation (ANSTO), Australia and Mr. William Glamore from Water Research Laboratory, University of New South Wales, Australia. National collaboration with stakeholders are with Bandung Institute of Technology (ITB) and Research Center for Oceanography (P2O-LIPI). This project has there main activities: 1. Develop hydrodynamic model of pollutants dispersion in Jakarta Bay using initial data of Jakarta Bay. 2. Radiotracer experiment for validation of hydrodynamic model Validating of hydrodynamic model was done in Muara Karang, Jakarta Bay using radioisotope Tc-99m. There were 4 times injections and tracings of radioisotope Tc-99m to cover the area of the experiment. Instead of radiotracing experiment, the physical parameters of Jakarta Bay have also measured in collaboration with P2O-LIPI. Some parameters were measured for 1 month and the others were measured during the radiotracing experiment. 7 3. Develop AQUARISK software using specific data of water quality and ecotoxicology of Jakarta Bay Data of water quality of Jakarta Bay have been supported by Jakarta Metropolitan Environmental Management Agency. AQUARISK software will be developed by P2O-LIPI and BATAN using water quality and ecotoxicology data of Jakarta Bay. 6.4.2 Pakistan (Annex 2) On site monitoring of marine pollution along coastal areas of Karachi, Sonmaini and Gadani, was completed. This included physiochemical and bacteriological (Coliform) analysis of seawater samples at these location during low and high tidal conditions. Harmful Phytoplanktons were identified in coastal waters of Karachi. Trace element analysis and selective radionuclide analysis of water/sediment and biota samples is still in progress. A mussel watch programme has been initiated. In the laboratory, aquarium experiments have been conducted to study the bioaccumulation/up-take rates of metal radiotracers (137Cs, 65Zn, 51Cr and 56Cd) by green mussels (Perna Viridis) at varied environmental conditions w.r.t. salinity and temperature. 6.4.3 Philippines (Annex 3) The activities of these project are incorporated in the activities of the Partnerships for Environmental Management of the Seas of EastAsia (PEMSEA) of the International Maritime Organization and the Department of Environment and Natural Resources (DENR). The PNRI is the chair of an interagency group that formulated the integrated monitoring program for Manila Bay. Membership in this group includes the University of the Philippines and other government agencies with mandates covering the use of Manila bay for fishing and other economic activities. Manila Bay is a complex system in that the coastline is shared by five political units; rivers that pass through large industrial and agricultural areas drain into Manila Bay; the water provides livelihood and food to a large number of people; international and domestic ports are in the bay; and about a fourth of the country’s population is within its watershed. Three reports covering the pilot monitoring activities of PNRI were prepared and accepted by IMO-PEMSEA-DENR: Sombrito E.Z., L.A. Del Castillo and V.S.Calix “Elemental Analysis of Manila Bay Sediments” report submitted for the Pilot Study Report of the TWG Environmental Monitoring Program for Manila Bay under the Manila Bay Environmental Management Program of DENR-IMO-PEMSEA. Sombrito E.Z., A. dM. Bulos, E.J.Sta. Maria and R.U.Olivares “137Cs and 210Pb Distribution in Manila Bay Sediment” report submitted for the Pilot Study Report of the TWG Environmental Monitoring Program for Manila Bay under the Manila Bay Environmental Management Program of DENR-IMO-PEMSEA Sombrito, E. , M.V. Honrado and M. dC. Tangona “Tributyl Tin Contamination in Mussel and Marine Sediment in Manila Bay” report submitted for the Pilot Study Report of the TWG Environmental Monitoring Program for Manila Bay under the Manila Bay Environmental Management Program of DENR-IMO-PEMSEA 8 The analyses performed on the sediment samples gave an indication of areas that may be at risk with respect to the following: a. Trace element b. Tributyl tin contaminations c. Pesticide contamination (Cs-137 as indicator of eroded soils from agriultural area) d. High sediment load (Pb-210 analysis) Under the project “Application of Nuclear Techniques to Address Specific Harmful Algal Bloom Concerns: Development and Application of Predicting , Controlling and Mitigating (PCM) Techniques for Harmful Algal Bloom (HABs) in Selected Mariculture Sites in the Philippines”co- funded by the Department of Science and Technology and being implemented by the University of the Philippines Marine Science Institute (MSI) and National Institute of Geological Sciences, Bureau of Fisheries and Aquatic Resources and the PNRI, a hydrodynamic model of Malampaya Sound in Palawan, Philippines, was prepared by the MSI (Dr, Cesar Villanoy and associates) . Aquatic emergency arising from harmful algal bloom in the area can be assisted by modelling the hydrodynamic behaviour in the area. Sediment cores from the area were also analyzed for HAB cyst and dated using Pb-210 method. These data can be useful in assessing the potential risk of pyrodinium bloom in the area. Nuclear and isotopic techniques were used in trace element, Cs137 and Pb-210 analyses. The use of computer codes for quantitative assessment of ecological risk associated with the release of contaminants into estuarine and coastal environments will have to implemented. 6.4.4 Thailand (Annex 4) Main Achievements: Thaile Noi In the wet season, Thale Noi was governed mostly by acid water (pH<7.0). In addition, SS and COD were notably high, particularly in the upper part of the basin. This can be attributed to high water discharge from Kuan Kreng marsh land where soil is acid and sediment and organic matter are exceptionally high. Particulate Phosphorus (P) makes up a largest portion of phosphorus pool (62%).This results, in part, from some phosphate prone to adhere to particles, whereas, nitrogen pool is dominant by dissolved organic N (65%). Dissolved inorganic N (DIN) accounts only 2% which nitrate is a major component (mean = 7.6 uM). Biologically useful P (mean = 0.28 uM) is substantially less than DIN (mean = 8.7 uM) However, its geographical pattern of variation resembles that of DIN. As a consequence, N: P ratio of inorganic nutrients greatly deviates from the Redfield ratio (16:1), the ratio which inorganic nutrients are normally used by phytoplankton and released from mineralization of organic matter. This implies that Thale Noi is N enrichment ecosystem, and P is a limiting factor for phytoplankton production. Thale Noi is classified is as eutrophication in terms of algal biomass which chlorophyll a ( chl-a) being remarkably high ( range = 3.5 -14.0 ug/l, mean = 44 ug/l) . Visual inspection reveals that spatial distribution of chl-a is similar to that nutrients. Phytoplankton production in Thale Noi is controlled in part by available P, as is evident from a significantly positive between chl-a and total P ( r = 0.45, p<0.1,n = 55) . For DIN , only ammonia has significantly positively correlate with regenerated nitrogen as a primary source for their growth. This, together with limitation of available P, leads to 9 nitrate remaining unconsumed, as can be seen from residual nitrate which is relatively high. Nakorn Nayok River Ongkharak Nuclear Research Center is located at latitude 14o 07/N longitude 101o 02 E, about 60 km northeast of Bangkok. The total area of the site is 505,600 m2. / Nakorn Nayok River is located about 1 km west from ONRC. It collects the flow from Khaokhieo and Khaoyai. The flow rate of this river is around 300 m3 /s in the rainy season and much less in the summer. However, the Nayok dam, which is located on Nakhon Nayok River northeast of the site, was built for irrigation water supply and flood control. Therefore, the flow rate near the site is less than that shown in above reference. The study of the preliminary survey of the ecology system around the site that was conducted in 1999 revealed; Most land uses within 10 km around the ONRC site was predominantly abandoned area (31.06-24.68%), active paddy (32.31-29.7%), inactive paddy (26.3212.51 %) and others. Soil around the site was considerably homogeneous and most was clay. Soil was very acidic, which elevated dissolved Al (plant toxic) concentration in soil and limited nutrient bioavailability such as P. In contrast, the concentration of some nutrient such as Cu was remarkably high (Cu=116 ppm) in some stations. E.C. (Electric conductivity) at some station was high (E.C. = 3.08-3.78 and 1.041-1.389 mil.mol/cm, normal= 0.05-0.4 mil.mol/cm). However, the E.C. such this high is still safe for shallow roots plant such as rice. The organic carbon content was moderate and decrease with depth. Ca, Mg, Na, and K founded were moderate amount but still sufficient for plant. The maximum recorded rainfall during ten years (1996-1986) was 30.1mm in March 1991. Inflow rate to the river ranged -15-26 m3/s in dry season and 43-53 m3/s in rainy season Outflow ranged 35-48 m3/s in dry season and 58-65 m3/s in rainy season. Nakorn Nayok River water is classified as class 3 for Surface Water Quality Standards (Notification of the National Environmental Board, No. 7, 1994). An investigation in 1999 indicated that the water quality in general was acceptable, that was the values of most parameters were within the Surface Water Quality Standards, that was: BOD = 1-3 mg/l, COD = 4-4.9 mg/l, SS = 2-245 mg/l, TDS = 20-235 mg/l, Te = 0-0.0146 mg/l, Mo = 0-0.356 mg/l, K= 0.929-9.486 mg/l ,Ca= 0.076-24.452 mg/l, DO = 0.2-7.5 mg/l, pH = 3.8-7.3 , Conductivity = 40-4500 mil.mol/l, Salinity = 0-2.5 ppt, and T = 26-32oC. Phytoplankton group of Cyanophyta especially Oscillatoria limnetica was found most in river water. Zooplankton, Anthropod and Rotifera sp was the most dominant species. Benthic animals, tubicids, crustaceans, insect larvae and mollusk found in the river with crustaceans; river shrimp, Palaemonidae family was the most abundance and found at every stations. Radiological monitoring around the site was summarized in Table 1: Table1: Radioactivity baseline of environmental sample from the vicinity of ONRC construction site; at pre-construction period (1997-1999). 10 Sample Gross alpha1 Gross beta 1 40K 1 137Cs 1 90Sr 2 226Ra 2 Surface water 0.037 0.145 <3.301 <0.195 5.073 1.105 Ground/underground water 0.042 0.135 <3.301 <0.195 3.131 3.305 Aquatic Fish) animal ( 2.303 29.050 30.770 0.030 ND 0.012 Aquatic animal river shrimp) ( 18.071 82.398 51.780 <0.195 ND 0.767 Aquatic edible) ( 4.117 128.837 56.024 0.031 ND 0.071 Aquatic plant ( not edible) 2.813 65.637 37.903 0.087 ND 0.031 Vegetables 3.075 57.961 31.920 0.079 ND 0.135 Fruit( Banana) 3.786 92.702 76.424 0.050 ND 0.008 Milled rice ( polished) 0.517 37.005 12.530 0.081 ND ND Under-milled ( home-pounded) rice 2.382 83.272 52.740 0.107 ND ND Ricegrass/ paragrass 2.208 170.703 168.065 0.136 ND 0.965 plant 1= Unit in Bq/l or Bq/kg 2= Unit in mBq/l or mBq/kg ND= Not detectable 6.5 Member State Activities and Achievements – Country Reports December 2006 Unofficial Country Reports were presented by participants at the China RTC in December 2006. These are provided, in full, in the Regional Training Course Report in Annex 10. In general, RCA Member States demonstrated a significant acceptance of the nuclear and isotopic technologies transferred in this project. Particular enhancements of National capabilities were evident in the understanding of contaminant behaviour in aquatic systems, radiological contaminant analyses, and bioaccumulation/radioecology studies. In the final activitiy (China RTC), all participants from the various Member States were able to successfully operate and apply contaminant transport model and ecological risk assessment model codes, which is a significantly positive overall outcome for the project. 7. SCHEDULE FOR FUTURE PROJECT ACTIVITIES 11 The Jakarta Bay model is still to be deliver to stakeholders in Indonesia and this is being planned for early 2007. A request for an expert mission to Thailand for training in hydrodynamic modelling was not able to be completed in 2006 due to unavailability of specialist experts and if funding was still available, this could be satisfied in 2007. A great deal of interest was developed in the application of AQUARISK Model and its combination with the Contaminant Transport Model following the very successful RTC and the follow up events at the Qingdao Symposium on Marine Pollution Monitoring and Assessment and the PEMSEA East Asian Seas Congress. Several of the participating countries expressed interest is expert assistance for application of this strategy to their own study situations. This interest may be able to be satisfied during the new RCA project on marine pollution. Unfortunately IAEA lead time requirements for implementation of expert missions under this project would not be compatible with the completion of the project by the end of the 2006/07 FY as required by AusAID. 8. CONSTRAINTS ON PROJECT IMPLEMENTATIONS AND RECOMMENDATIONS The deterioration in the security situation in parts of the Asia Pacific region, particularly following bombings and other civil unrest since 2003 has impacted on the timing and location of some activities. Travel advisory warnings by the Australian Department of Foreign Affairs and Trade has advised Australian travellers to defer all unnecessary travel to some countries or specific areas in a country. Such advice has caused difficulties for travel by Australian experts and for the implementation of the planned partnering arrangement with some RCA Member States. Future security considerations may also have implications on the location and timing of RCA activities. However maintaining partnering arrangements is a high priority ad should be adhered to as long as practicable. Constraints reported by RCA Member States are summaries below: 8.1 Indonesia Conduct of modern radiotracer studies of sediment or contaminant transport requires depends on good data acquisition and positioning systems that allow for continuous collection, logging and display of data on a computer screen. ANSTO has provided a copy of their data acquisition software to BATAN and we can assist in modifying the inputs to suit BATAN equipment if requested. However, BATAN’s environmental radiotracing capability is severely limited by the age and condition of their detection system, and by the lack of modern GPS systems. During the April 2006 mission we identified that BATAN’s existing detector connections are no longer waterproof which prevents use in marine applications. Their scalar ratemeters are analogue systems, and whilst BATAN have rigged up a analogue to digital conversion circuit to allow logging to a computer, this is not necessarily a long term solution. In addition they do not have a GPS that can be logged continuously by computer. For this project the provision of an appropriate GPS system has already been identified in the budget and can be arranged by ANSTO. However, repair or replacement of the existing detectors and provision of a new digital scalar ratemeter is beyond the budget of the project. 8.2 Pakistan Feasibility of organizing studies related to sediment erosion in Makran coastline could not initiated due to bad conditions in the area. Establishment of AQUARISK Modelling Facilities in Pakistan are subject to provision of the model by ANSTO-Australia through the IAEA/RCA . The project relies on the successful implementation of other projects being funded by other international and local agencies. Thus it has to follow the timetable and activities of these projects 12 8.3 Philippines The project relies on the successful implementation of other projects being funded by other international and local agencies. Thus it has to follow the timetable and activities of these projects 8.4 Thailand Delay of funded by the government due to the re-organization of the institute. Change of climate i.e. storm and heavy rain caused sampling delayed. Delay of assistances from IAEA. 9. ASSESSMENT OF PERFORMANCE INDICATORS FOR OUTCOMES 1a. Thirty-five persons trained in two regional training courses in computer modelling of dispersion of pollutants in the aquatic environment before the end of 2006. Aspects of computer modelling of pollutants in the aquatic environment were covered in RTCs in Thailand (2005 – 18 participants) and more comprehensively in China (2006 – 22 participants). It is not feasible to provide complete training in model development under the auspices of this project, as this requires lengthy university-level studies, however this project was able to provide training in model requirements, execution and application (see 2a below. 1b. Four expert missions implemented and 30 persons trained in ecological risk assessments before the end of 2006. Expert missions were undertaken in January 2005 (Thailand), September 2005 (Indonesia), September 2005 (Thailand), April/May 2006 (Indonesia), October/November 2006 (Pakistan) and December 2006 (China). During the Thailand RTC (Sept 2005) 18 participants, and Pakistan Mission (Oct/Nov 2006) 64 participants were introduced to the AQUARISK Ecological Risk Assessment modelling code. In the Pakistan Mission (Oct/Nov 2006) 3 staff members from PINSTECH, and in the China RTC (Dec 2006) 22 participants received detailed training in use of the code and were assessed to be competent in its operation and application. 2a. At least five of the RCA Member States will have acquired the capability of using hydrodynamic models to predict dispersion of pollutants in aquatic environment in order to provide data needed by planners to mitigate the effects of aquatic pollutants before the end of 2006. In the China RTC (Dec 2006) 22 participants received detailed training in use of the hydrodynamic contaminant transport code (RMA 11) and were assessed to be competent in its operation and application. These participants also demonstrated the ability to input the contaminant distribution outputs of the RMA 11 model to a quantitative, probabilistic, ecological risk assessment using AQUARISK, based on regionally relevant dose-response data and filtered to reflect specific environmental foci. 10. CONCLUSIONS A primary objective of this Project has been to improve regional capacity for assessment, planning, and response to aquatic environmental emergencies via the development and demonstration of, and provision of training in the use of an experimentally-field-validated dilution and dispersion model which would generate contaminant concentrations downfield from a specified source. This could then be used as input to a quantitative, probabilistic, ecological risk assessment, based on regionally 13 relevant dose-response data and filtered to reflect specific environmental foci. This demonstration was comprehensively successful. The acquisition and reformatting of the ASEAN database was an unplanned bonus and made the overall Project deliverables even more beneficial to the participating RCA Member States. . Activity participants demonstrated a keen interest in the computer codes presented and asked many questions which showed that they had acquired a substantial comprehension of the applications. This was recognised by the demonstrators when devising detailed questions to test the depth of knowledge and use of the codes. All participants passed the test well and appeared keen to use the tools in future. The participants selected to attend the meeting were assessed as generally being very well suited for this RTC. In addition to their competence, the participants interacted very well and this should facilitate continuing networking between them. Member States should encourage and facilitate ongoing contact between the participants. Several of the participants were keen to discuss new projects and it was suggested that they should develop their proposals more fully between national institutes with a view to review by the experts prior to submission of a concept document to the National RCA/IAEA Representatives for consideration. The complementary set of expertises of the recruited lecturers’ teams proved to be an excellent resource for the participants, both for the delivery of lectures, demonstrations, practical exercises and in provision of ad hoc advice and information on associated issues particular to their own activities. Attendance of the Qingdao Marine Pollution Symposium and PEMSEA East Asian Seas Congress (a) proved to be very beneficial for participants, in being delivered detailed presentations on several regional and international activities as well as gaining valuable experience in delivery of presentations at this prestigious level; and (b) provided valuable exposure for RCA Project activities. A significant number of delegates showed a great deal of interest in our activities and identified several potential future interactions, including requests for further dissemination of our developed technologies and ecological risk analysis strategies via similar training courses and indications for specific collaborative studies A high degree of network development was apparent from these activities. These regional and international network liaisons represent a valuable outcome for the RCA Project and should contribute to sustainability and regional diffusion of nuclear and isotopic technologies. The deterioration in the security situation in parts of the Asia Pacific region, particularly following bombings and other civil unrest since 2003 has impacted on the timing and location of some activities. Travel advisory warnings by the Australian Department of Foreign Affairs and Trade has advised Australian travellers to defer all unnecessary travel to some countries or specific areas in a country. Such advice has caused difficulties for travel by Australian experts and for the implementation of the planned partnering arrangement with some RCA Member States. Future security considerations may also have implications on the location and timing of RCA activities. However maintaining partnering arrangements is a high priority and should be adhered to as long as practicable. 11. RECOMMENDATIONS To the IAEA To support and encourage the RCA Member States in acquiring the full benefits from the inputs of training and expertise supplied through this project. Provide licensed AQUARISK model packages for Member States not already in possession of this code. 14 To RCA Member States To proactively engage the broader marine pollution community and seek cooperative ventures to utilise and exploit their interest in the application of the techniques and skill acquired from this project. To support the training of younger scientists in established facilities in the region for extended training in the technologies promoted in this project and where possible consider the use of the IAEA Fellowship and Scientific Visits programme to facilitate the support. To encourage and facilitate ongoing contact between the RTC participants and TCDC interactions. To use the results of this project to prepare a “Success Story” for distribution through the RCA Regional Office and other appropriate mechanisms. 15 ANNEX 1 REGIONAL COOPERATIVE AGREEMENT (RCA) 2005/2006 FIRST PROGRESS REPORT- June 2006 1. Administrative information 1.1 Member State: INDONESIA 1.2 Project Title and Number: REGIONAL CAPACITY FOR ASSESSMENT, PLANNING AND RESPONDING TO AQUATIC ENVIRONMETAL EMERGENCIES, RAS/8/095 1.3 National Project Coordinator: ALI ARMAN LUBIS 2. Regional Activities Participation in Regional Events Title of the Event Participant/s IAEA/RCA RTC on Application of Ali Arman Lubis Nuclear Techniques to Studies of Bioaccumulation and Contaminant Yulizon Menry Analyses for the Development of Susilaningsih Lestari Emergency Response Strategies for Aquatic Environments (5-16 September 2005), Thailand Member of the Project Team Yes Yes No - - Yes/No - - Yes/No a) Are there any constraints faced in nominating members of the National Project Team for participation in regional events? No b) Have the participants of the Regional Training Courses shared the knowledge gained with other member of the project team? Yes c) Is the training received relevant to the project activities? Yes, particularly in the bioaccumulation, it is very useful to develop AQUARISK software for risk assessment with the site specific data. d) Any other comments on regional events. 16 3. Status of Implementing the National Work Plan Please attach a copy of the National Work Plan for implementing this project, and indicate the status of implementation of the Work plan. A simple format for the Work Plan is given below. Activity Activity 2005 2006 Status No Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 4. Main achievements Please list the main achievements of the project during the period January- June 2006. If you are reporting on the past achievements for continuity, please indicate when they were achieved. Demonstration of the project from 24 April to 6 May 2006 in Jakarta Bay for implementing the RAS/8/095 project. This activity has been assisted by 3 experts, i.e; Mr. Ron Szymczak and Ms. Cath Hughes from Australian Nuclear Science and Technology Organisation (ANSTO), Australia and Mr. William Glamore from Water Research Laboratory, University of New South Wales, Australia. National collaboration with stakeholders are with Bandung Institute of Technology (ITB) and Research Center for Oceanography (P2O-LIPI). This project has there main activities: 4. Develop hydrodynamic model of pollutants dispersion in Jakarta Bay using initial data of Jakarta Bay. 5. Radiotracer experiment for validation of hydrodynamic model Validating of hydrodynamic model was done in Muara Karang, Jakarta Bay using radioisotope Tc-99m. There were 4 times injections and tracings of radioisotope Tc-99m to cover the area of the experiment. Instead of radiotracing experiment, the physical parameters of Jakarta Bay have also measured in collaboration with P2O-LIPI. Some parameters were measured for 1 month and the others were measured during the radiotracing experiment. 6. Develop AQUARISK software using specific data of water quality and ecotoxicology of Jakarta Bay Data of water quality of Jakarta Bay have been supported by Jakarta Metropolitan Environmental Management Agency. AQUARISK software will be developed by P2O-LIPI and BATAN using water quality and ecotoxicology data of Jakarta Bay. 5. Constraints for successful implementation of the project. 6. Any additional information that could be relevant . 17 ANNEX 2 REGIONAL COOPERATIVE AGREEMENT (RCA) 2006 PROGRESS REPORT Jan - June 2006 1. Administrative information 1.1 Member State: PAKISTAN 1.2 Project Title and Number: IAEA/RCA Project (RAS/8/095) “Improving Regional Capacity for Assessment, Planning and Response to Aquatic Environmental Emergencies” 1.3 National Project Coordinator: Riffat Mahmood Qureshi Deputy Chief Scientist (DCS) Head Radiation and Isotope Application Division Pakistan Institute of Nuclear Science and Technology Pakistan Atomic Energy Commission P.O. Nilore, Islamabad, Pakistan. Phone: 92-51-2207228, Fax No. 92-51-9290275 E-mail: <[email protected]> 2.0 Regional Activities Participation in Regional Events Title of the Event IAEA/RCA Regional Training Course on Application of Nuclear Techniques to Studies of Bioaccumulation and Contamination Analyses for the Development of Emergencies Response Strategies for Aquatic Environments” 5-16 September 2005 in Bangkok, Thailand NIL Participant/s One participant namely, Mr. Abdul Jabbar attended the RTC, Thailand Member of the Project Team Yes The participant is a member of the National Project Team e) Are there any constraints faced in nominating members of the National Project Team for participation in regional events? No f) Have the participants of the Regional Training Courses shared the knowledge gained with other member of the project team? Yes g) Is the training received relevant to the project activities? 18 N.A. h) Any other comments on regional events. Nil 3. Status of Implementing the National work Plan Please attach a copy of National work plan for implementing this project, and indicate the status of implementation of work plan. A simple format for the work plan is given below. Sr# Activity 2005 Q1 1. 2. 3. 4. 5. 6. 7. 8. Nomination of National Project Coordinator (NPC) Identification of National Project Team (NPT) Strengthening of working relationship with end-user Enhancement of end-user awareness Applied Research & Development Work In-kind support for Project Activities On site monitoring of marine pollution along coastal areas and collection of water/ sediment sampling Capability Enhancement of Ecological Research Group in terms of : (i) Manpower training for national nuclear institute and end-user institutions (ii) Field sampling and insitu analysis Equipment Q2 2006 Q3 Q4 Q1 Q2 Q3 Status Q4 Completed Completed Continued Continued As per requirement of applied projects Is being provided Completed Requested from IAEA. Radiotracers for routine use are being produced at PINSTECH. IAEA is requested to provide experts for an NTC event tentatively in October 2006 9. Radionuclide and chemical analysis 10. HAB Cyst analysis and Toxin Quantification 11. Establishment of AQUARISK Modelling 19 In progress In progress Subject to provision of Facilities at national nuclear institute Model/Code from ANSTO/Australia or IAEA-MELMonaco (RIAD-PINSTECH ) 12. Participation in regional training Courses/ Workshops 13. Feasibility of organizing radiotracer studies related to sediment erosion in Makran coastline 14. Interpretation of acquired chemical, biological and isotopic data / Compilation of Report 15. Participation in final project meeting 4. Subject to organization by RCA/IAEA To be initiated with the help of PLCC and IAEA Experts In progress Also PEMSEA Conference, China Main Achievements: Please list the main achievements of the project during the period Jan-June 2006. If you are reporting on the past achievements for continuity, please indicate when they were achieved. On site monitoring of marine pollution along coastal areas of Karachi, Sonmaini and Gadani, was completed. This included physiochemical and bacteriological (Coliform) analysis of seawater samples at these location during low and high tidal conditions. Harmful Phytoplanktons were identified in coastal waters of Karachi. Trace element analysis and selective radionuclide analysis of water/sediment and biota samples is still in progress. A mussel watch programme has been initiated. In the laboratory, aquarium experiments have been conducted to study the bioaccumulation/up-take rates of metal radiotracers (137Cs, 65Zn, 51Cr and 56 Cd) by green mussels (Perna Viridis) at varied environmental conditions w.r.t. salinity and temperature. 5. Constrains for successful implementation of the project. (a) Feasibility of organizing studies related to sediment erosion in Makran coastline could not initiated due to bad conditions in the area. (b) Establishment of AQUARISK Modelling Facilities in Pakistan are subject to provision of the model by ANSTO-Australia through the IAEA/RCA . In this regard, we request IAEA/RCA to provide the following assistance through the RAS/08/095 Project Funds: Sr. # 1. Tasks / Targets 1. Training of National Team Members for ecological risk Assistance Required from the IAEA/RCA to meet the Tasks / Targets Expert Mission of the following Scientists from ANSTO/Australia and IAEA-MEL, 20 assessment modeling 2. Cost Free Provision of AQUARISK Model to Environmental Modelling Group at PINSTECH, Islamabad 3. Support for visit of IAEA/RCA Experts, NPC and selected Members of the National Team to polluted harbours and creek systems along Pakistan Coast (mainly, Karachi, Gawadar coasts) for suggestions on transport model development and radiotracer validation experiments, bioaccumulation and ecological risk assessment modeling and make better plans of action for the next phase of the Project and to align national projects with the regional project concept. Provision of nuclear (& nonnuclear) contaminant analysis of selected inter-tidal sediment profiles from polluted and pristine coastal locations along Pakistan Coast (Karachi, Ormara, Pasni, Gawadar, Jiwani) to evaluate pollution levels, records and sediment erosion rates. Monaco to PINSTECH / Islamabad, Pakistan 1. Mr. Ron Szymczak (Leader, ANSTO Marine Systems Analysis Task) IAEA/RCA Project Lead Country Coordinator PMB 1 Menai, NSW AUSTRALIA 2234 Ph: 61-2-9717-9221; fax: 61-2-9717-9260 2. Dr. John Twining (AQUARISK expert) ANSTO, PMB 1 Menai, NSW AUSTRALIA 2234 Ph: 61-2-9717-9221; fax: 61-2-9717-9260 3. Dr. Ross Jeffery, IAEA Marine Environment Laboratory (MEL), Monaco Venue: RIAD / PINSTECH, Islamabad, Pakistan Tentative Dates: One week during October, 2006 Pesticide & PAHC Analysis 137 14 Cs, 210Pb analysis C dating of mussel shells 6. Any additional information that could be relevant The progress of the project may be enhanced if IAEA/RCA partly funds our national project through sub-contracts. IAEA Technical Officer and selected experts from Member States may visit the model sites for advice and technical advice and project evaluation/monitoring. Pakistan intends to host a national training course in Islamabad/Karachi (comprising of lectures/training demonstrations along Karachi Coast and/or Gawadar coast) on use of nuclear techniques and aquatic risk assessment models for study of aquatic resources emergencies subject to acceptance by the IAEA/RCA and final approval by PAEC/Government of Pakistan. 21 ANNEX 4 REGIONAL COOPERATIVE AGREEMENT (RCA) 2005/2006 PROGRESS REPORT- June 2006 1. Administrative information 1.1 Member State : Philippines 1.2 Project Title and Number: Capacity for Assessment, Planning, and Response to Aquatic Environmental Emergencies (RAS/8/095) H1 Extension 1.3 National Project Coordinator: Elvira Z. Sombrito 2. Regional Activities: Participation in Regional Events – no regional event for the period Title of the Event Participant/s NA Member of the Project Team Yes/No Yes/No Yes/No i) Are there any constraints faced in nominating members of the National Project Team for participation in regional events? Not Applicable (no regional event during the period) j) Have the participants of the Regional Training Courses shared the knowledge gained with other member of the project team? Not Applicable (no regional event during the period) k) Is the training received relevant to the project activities? N.A.. l) Any other comments on regional events. m) 3. Status of Implementing the National Work Plan Please attach a copy of the National Work Plan for implementing this project, and indicate the status of implementation of the Work plan. A simple format for the Work Plan is given below. 22 Activity Activity 2005 2006 Status No Meeting with collaborating Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 x x x x x x On-going x x x x x x On-going national institutions to define & schedule details activities Compilation of existing data in preparation of the hydrodynamic & risk assessment model Initial sampling & x Sediment sampling measurement of completed, seawater will not contaminants radionuclide be analyzed anymore, biota concentrations in analysis partially done for seawater & biota toxic trace elements Scientific visit ANSTO/UNSW to No request made No participant from the Attendance of 1st Modelling Workshop & Tracing Validation Demonstration Philippines was accepted though nomination was done. Submission of IAEA subcontract request forms to IAEA Additional sampling & measurement of contaminants radionuclide concentrations in seawater & biota Not included in the project budget. x x x Activities related to saxitoxin uptake in field conditions are being implemented and data can be used for ecological risk assessment of PSP toxins. Scientific fellowship to ANSTO/UNSW Submission of initial results 2nd Modelling Training Workshop Attend final project meeting No request made x x x A paper will be presented during the PEMSEA Congress coinciding with the final project meeting in China. 4. Main achievements Please list the main achievements of the project during the period January- June 2006. If you are reporting on the past achievements for continuity, please indicate when they were achieved. 23 The activities of these project are incorporated in the activities of the Partnerships for Environmental Management of the Seas of EastAsia (PEMSEA) of the International Maritime Organization and the Department of Environment and Natural Resources (DENR). The PNRI is the chair of an interagency group that formulated the integrated monitoring program for Manila Bay. Membership in this group includes the University of the Philippines and other government agencies with mandates covering the use of Manila bay for fishing and other economic activities. Manila Bay is a complex system in that the coastline is shared by five political units; rivers that pass through large industrial and agricultural areas drain into Manila Bay; the water provides livelihood and food to a large number of people; international and domestic ports are in the bay; and about a fourth of the country’s population is within its watershed. Three reports covering the pilot monitoring activities of PNRI were prepared and accepted by IMO-PEMSEA-DENR: Sombrito E.Z., L.A. Del Castillo and V.S.Calix “Elemental Analysis of Manila Bay Sediments” report submitted for the Pilot Study Report of the TWG Environmental Monitoring Program for Manila Bay under the Manila Bay Environmental Management Program of DENR-IMO-PEMSEA. Sombrito E.Z., A. dM. Bulos, E.J.Sta. Maria and R.U.Olivares “137Cs and 210Pb Distribution in Manila Bay Sediment” report submitted for the Pilot Study Report of the TWG Environmental Monitoring Program for Manila Bay under the Manila Bay Environmental Management Program of DENR-IMO-PEMSEA Sombrito, E. , M.V. Honrado and M. dC. Tangona “Tributyl Tin Contamination in Mussel and Marine Sediment in Manila Bay” report submitted for the Pilot Study Report of the TWG Environmental Monitoring Program for Manila Bay under the Manila Bay Environmental Management Program of DENR-IMO-PEMSEA The analyses performed on the sediment samples gave an indication of areas that may be at risk with respect to the following: e. Trace element f. Tributyl tin contaminations g. Pesticide contamination (Cs-137 as indicator of eroded soils from agriultural area) h. High sediment load (Pb-210 analysis) Under the project “Application of Nuclear Techniques to Address Specific Harmful Algal Bloom Concerns: Development and Application of Predicting , Controlling and Mitigating (PCM) Techniques for Harmful Algal Bloom (HABs) in Selected Mariculture Sites in the Philippines”co- funded by the Department of Science and Technology and being implemented by the University of the Philippines Marine Science Institute (MSI) and National Institute of Geological Sciences, Bureau of Fisheries and Aquatic Resources and the PNRI, a hydrodynamic model of Malampaya Sound in Palawan, Philippines, was prepared by the MSI (Dr, Cesar Villanoy and associates) . Aquatic emergency arising from harmful algal bloom in the area can be assisted by modelling the hydrodynamic behaviour in the area. Sediment cores from the area were also analyzed for HAB cyst and dated using Pb-210 method. These data can be useful in assessing the potential risk of pyrodinium bloom in the area. Nuclear and isotopic techniques were used in trace element, Cs137 and Pb-210 analyses. The use of computer codes for quantitative assessment of ecological risk associated with the release of contaminants into estuarine and coastal environments will have to implemented. 24 5. Constraints for successful implementation of the project The project relies on the successful implementation of other projects being funded by other international and local agencies. Thus it has to follow the timetable and activities of these projects. 6. Any additional information that could be relevant None 25 REGIONAL COOPERATIVE AGREEMENT (RCA) 2005/2006 FIRST PROGRESS REPORT- June 2006 1. Administrative information 1.1 Member State Thailand 1.2 Project Title and Number Improving Regional Capacity for Assessment, Planning, and Responding to Aquatic Environmental Emergencies ( RAS/8/095) 1.3 National Project Coordinator Ms. Kanitha Srisuksawad 2. Regional Activities Participation in Regional Events Title of the Event Participant/s Member of the Project Team - - Yes/No Yes/No Yes/No n) Are there any constraints faced in nominating members of the National Project Team for participation in regional events? o) Have the participants of the Regional Training Courses shared the knowledge gained with other member of the project team? p) Is the training received relevant to the project activities? q) Any other comments on regional events. 3. Status of Implementing the National Work Plan Please attach a copy of the National Work Plan for implementing this project, and indicate the status of implementation of the Work plan. A simple format for the Work Plan is given below. 26 Activity No Activity 1 Thale Noi 1.1 Preliminary study of physical, hydrological, climatologically, water quality, and land used 1.2 2005 Q1 Q2 2006 Q3 Q4 Q1 Q2 Q3 Status Q4 literature review and secondary data collection Done Monitoring of geological and hydrological data Done Monitoring for surface water quantities and rate of evaporation Done Analysis of preliminary data and map construction Done Water quality monitoring Monitor for sampling point identification Activity Collection and analysis of sample Sample collection and analysis was done for wet season. Spatial and seasonal measurements of organic pollutants in the forms of BOD, COD and TOC As the above Spatial and seasonal measurements of nitrogen pollutant in the form of TN, NH4 and NO3 As the above Spatial and seasonal measurements of phosphorus pollutants in the form of PO4 As the above Spatial and seasonal measurement of pH, SS, DO and chlorophylls a As the above Activity 2005 2006 27 Status No 1 Thale Noi ( cont’) Q1 Q2 Q3 Q4 Q Q2 Q3 Q4 1 1.3 Study of sedimentation rates and environmental archives Monitoring for sampling point identification Done Collection of sediment core Analysis of 210Pb, 13C, and 15N organic matter nitrogen and phosphorus and N/P ratios. Analysis of 210Pb, organic matter, nitrogen and phosphorus will be commenced from Jan-June 2007. Analysis of 13C and 15N must require assistances from IAEA in form of fellowship or analytical provider. Data analysis Data analysis will be commenced in fourth quarter of 2007 1.4 Study primary production of the lake by C-14 tracer 1.5 Study phosphorus turnover rate of the lake by P-32 1.6 Food web analysis in ecological system of the lake by C-13 and N-15 ratios Need assistances from IAEA in form of fellowship or analytical provider 1.7 Modeling of organic pollutants and heavy metals transfer in aquatic environment Need assistances from IAEA on training on model development and RMA software. 1.8 Kinetic study of uptake and loss of pollutants and organic matter using nuclear technique To be started in 2007 Activity No Activity 2005 2006 28 Status 1 Thale Noi ( cont’) 1.9 Ecological risk assessment using AQUARISK program 2 Nakorn Nayok River 2.1 Preliminary study of physical, hydrological data 2.2 Q1 Q2 Q3 Q4 Q1 Q2 Q3 Q4 To be commenced after training on AQUARISK literature review and secondary data collection Done Analysis of preliminary data and map construction Done Monitoring of geological and hydrological ( water level, rating curve) data Sub contracting Water quality monitoring Monitor for sampling point identification Done Collection and analysis of sample Spatial and seasonal measurements of organic pollutants in the forms of BOD, COD and TOC Spatial and seasonal measurements of Radioactivity 2.3 Model calibration Collection of hydrological ( water level and water quantity ) data on experimental date Injection of Rhodamine WT ( Batch release ) at discharge point, collection of data using single - Activity No 2 Activity Nakorn Nayok River ( 2005 Q1 Q2 2006 Q3 Q4 29 Q1 Q2 Q3 Status Q4 cont’) -fluorometer ( turner Designs 10 AU) Model calibration ( using MIKE 11 or RMA) . 2.4 Model verification Collection of hydrological ( water level and velocity ) data on experiment date Injection of Rhodamine WT ( Batch release ) at discharge point, collection of data using single fluorometer ( turner Designs 10 AU) . Model verification 2.5 Kinetic study of uptake and loss of pollutants and organic matter using nuclear technique 2.6 Ecological risk assessment using AQUARISK program To be commenced after training on AQUARISK 4. Main achievements Please list the main achievements of the project during the period January- June 2006. If you are reporting on the past achievements for continuity, please indicate when they were achieved. 4.1 Thale Noi Preliminary results from the first comprehensive field observation: In the wet season, Thale Noi was governed mostly by acid water (pH<7.0). In addition, SS and COD were notably high, particularly in the upper part of the basin. This can be attributed to high water discharge from Kuan Kreng marsh land where soil is acid and sediment and organic matter are exceptionally high. Particulate Phosphorus (P) makes up a largest portion of phosphorus pool (62%).This results, in part, from some phosphate prone to adhere to particles, whereas, nitrogen pool is dominant by dissolved organic N (65%). Dissolved inorganic N (DIN) accounts only 2% which nitrate is a major component (mean = 7.6 uM). Biologically useful P (mean = 0.28 uM) is substantially less than DIN (mean = 8.7 uM) However, its geographical pattern of variation resembles that of DIN. As a consequence, N: P ratio of inorganic nutrients greatly deviates from the Redfield ratio (16:1), the ratio which inorganic nutrients are normally used by 30 phytoplankton and released from mineralization of organic matter. This implies that Thale Noi is N enrichment ecosystem, and P is a limiting factor for phytoplankton production. Thale Noi is classified is as eutrophication in terms of algal biomass which chlorophyll a ( chl-a) being remarkably high ( range = 3.5 -14.0 ug/l, mean = 44 ug/l) . Visual inspection reveals that spatial distribution of chl-a is similar to that nutrients. Phytoplankton production in Thale Noi is controlled in part by available P, as is evident from a significantly positive between chl-a and total P ( r = 0.45, p<0.1,n = 55) . For DIN , only ammonia has significantly positively correlate with regenerated nitrogen as a primary source for their growth. This, together with limitation of available P, leads to nitrate remaining unconsumed, as can be seen from residual nitrate which is relatively high. 4.2 Nakorn Nayok River Ongkharak Nuclear Research Center is located at latitude 14o 07/N longitude 101o 02/E, about 60 km northeast of Bangkok. The total area of the site is 505,600 m2. Nakorn Nayok River is located about 1 km west from ONRC. It collects the flow from Khaokhieo and Khaoyai. The flow rate of this river is around 300 m3 /s in the rainy season and much less in the summer. However, the Nayok dam, which is located on Nakhon Nayok River northeast of the site, was built for irrigation water supply and flood control. Therefore, the flow rate near the site is less than that shown in above reference. The study of the preliminary survey of the ecology system around the site that was conducted in 1999 revealed; Most land uses within 10 km around the ONRC site was predominantly abandoned area (31.06-24.68%), active paddy (32.31-29.7%), inactive paddy (26.32-12.51 %) and others. Soil around the site was considerably homogeneous and most was clay. Soil was very acidic, which elevated dissolved Al (plant toxic) concentration in soil and limited nutrient bioavailability such as P. In contrast, the concentration of some nutrient such as Cu was remarkably high (Cu=116 ppm) in some stations. E.C. (Electric conductivity) at some station was high (E.C. = 3.08-3.78 and 1.041-1.389 mil.mol/cm, normal= 0.05-0.4 mil.mol/cm). However, the E.C. such this high is still safe for shallow roots plant such as rice. The organic carbon content was moderate and decrease with depth. Ca, Mg, Na, and K founded were moderate amount but still sufficient for plant. The maximum recorded rainfall during ten years (1996-1986) was 30.1mm in March 1991. Inflow rate to the river ranged -15-26 m3/s in dry season and 43-53 m3/s in rainy season Outflow ranged 35-48 m3/s in dry season and 58-65 m3/s in rainy season. Nakorn Nayok River water is classified as class 3 for Surface Water Quality Standards (Notification of the National Environmental Board, No. 7, 1994). An investigation in 1999 indicated that the water quality in general was acceptable, that was the values of most parameters were within the Surface Water Quality Standards, that was: BOD = 1-3 mg/l, COD = 4-4.9 mg/l, SS = 2245 mg/l, TDS = 20-235 mg/l, Te = 0-0.0146 mg/l, Mo = 0-0.356 mg/l, K= 0.929-9.486 mg/l ,Ca= 0.076-24.452 mg/l, DO = 0.2-7.5 mg/l, pH = 3.8-7.3 , Conductivity = 40-4500 mil.mol/l, Salinity = 0-2.5 ppt, and T = 26-32oC. Phytoplankton group of Cyanophyta especially Oscillatoria limnetica was found most in river water. Zooplankton, Anthropod and Rotifera sp was the most dominant species. Benthic animals, tubicids, crustaceans, insect larvae and mollusk found in the river with crustaceans; river shrimp, Palaemonidae family was the most abundance and found at every stations. 31 Radiological monitoring around the site was summarized in Table 1: Table1: Radioactivity baseline of environmental sample from the vicinity of ONRC construction site; at preconstruction period (1997-1999). Sample Gross alpha1 Gross beta 1 40K 1 137Cs 1 90Sr 2 226Ra 2 Surface water 0.037 0.145 <3.301 <0.195 5.073 1.105 Ground/underground water 0.042 0.135 <3.301 <0.195 3.131 3.305 Aquatic Fish) animal ( 2.303 29.050 30.770 0.030 ND 0.012 Aquatic animal river shrimp) ( 18.071 82.398 51.780 <0.195 ND 0.767 Aquatic edible) ( 4.117 128.837 56.024 0.031 ND 0.071 Aquatic plant ( not edible) 2.813 65.637 37.903 0.087 ND 0.031 Vegetables 3.075 57.961 31.920 0.079 ND 0.135 Fruit( Banana) 3.786 92.702 76.424 0.050 ND 0.008 Milled rice ( polished) 0.517 37.005 12.530 0.081 ND ND Under-milled ( home-pounded) rice 2.382 83.272 52.740 0.107 ND ND Ricegrass/ paragrass 2.208 170.703 168.065 0.136 ND 0.965 plant 1= Unit in Bq/l or Bq/kg 2= Unit in mBq/l or mBq/kg ND= Not detectable Plan for collection of data Eleven sampling points in Nakorn Nayok River were indicated. The sampling points cover the distance ~ 11 km up and down stream from discharged point of ONRC. Data required for modeling will be collected from sampling points: - Tidal elevations - Bed roughness ( Manning’s n) - Discharge rate of rivers - Radioactivity 5. Constraints for successful implementation of the project 32 1. Delay of funded by the government due to the re-organization of the institute. 2. Change of climate i.e. storm and heavy rain caused sampling delayed. 3. Delay of assistances from IAEA. 6. Any additional information that could be relevant None. 33
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