Curing On the UV LED wavelength UV LED technology featured at the last drupa show in 2008, and since then, a significant amount of effort has gone into research and development aimed at gaining greater understanding and expanding usage in the printing sector. By David Atkinson. lengths that range from UV through visible light to IR. The quartz envelope of the arc lamp itself gets very hot (in the order of several hundred degrees centigrade) and this, along with the incident IR energy, means that a lot of heat is directed at the substrate. This makes it necessary, when printing thin heat-sensitive substrates, to temperature control the web itself by means of chill rollers, as well as extracting heat from the lamp head. Advantages Hönle’s PureUV Powerline s a technology, LED (light emitting diodes) has already infiltrated our day to day lives to such a degree that we are all familiar with it in one form or another, be it in a torch, low energy lighting or car lighting. The advantages that LED technology offers in applications that we are familiar with, such as long lamp life and low running cost due to low power consumption, are fundamental attributes of LEDs that are available benefits for those in the printing industry working with energy cured inks. It is hardly surprising then that the industry is showing great interest in the technology. To date, energy cured inks have typically been cross-linked (dried) by means of ultraviolet light emitted by low pressure mercury arc lamps or more exceptionally by means of EB (electron beam) technology, but it is also possible to cross-link energy cured inks by means of LED. A The technology LEDs are solid state devices (diodes) that emit energy in the form of light when an electrical current passes through them in the forward biased April 2012 direction. The wavelength of the emitted light depends on the material from which the diode is made, with each material emitting light in a very narrow waveband that is almost monochromatic. Solid state UV LED devices can be constructed from diodes outputting wavelengths of 365 nm, 385 nm, 395 nm, 405 nm and 410 nm (nm=nanometre), LEDs with outputs at 365 and 395 nm in the UVA range being the most popular for current applications. UV LEDs convert about 10% to 25% of the electrical energy they receive into light, with the rest being converted into heat that is emitted from the back of the array, hence the need for cooling. They do not emit IR energy. The higher the irradiance of an LED, the greater the amount of heat generated. As the output of these devices increases, the more energy it takes to drive them and the greater the amount of heat that needs to be effectively eliminated. This is quite different to the situation with conventional medium pressure UV mercury arc lamps, which emit a broad spectrum of wave- UV LED has a number of advantages to offer compared with conventional UV lamps, and these can be broadly grouped into environmental advantages, cost advantages and processing advantages, plus a few miscellaneous advantages. The main environmental advantages are that LEDs are mercury free, do not produce ozone and consume less energy than medium pressure conventional UV lamps. Economic advantages include lower energy consumption in their running state, and because LEDs switch on and off instantly, no warming up time is required. As a result, it is not necessary to keep LEDs on standby power, as is the case with conventional UV lamps, and this further reduces energy consumption. Lamp life is in excess of 10,000 hours compared with between 1000 to 2000 hours for a conventional UV lamp, which reduces the cost of consumables as well as the amount of downtime as a result of having to replace lamps. Processing advantages include the means to cure inks on heat sensitive substrates without the need to install expensive chill rollers, as the absence of direct IR radiation from LEDs means that it is a cool running technology. The relatively long wavelength of LEDs can penetrate inks more deeply and this facilitates through cure so thick ink films can be more readily cured. Other advantages include a light and compact design, which enables them to be easily integrated into existing presses, and a simpler 21 Curing design because there is no need for the shutters or head rotation that is required for conventional UV lamps when in standby mode. In addition, there is the ability to manufacture LED units at any length and width, and they also offer greater safety in the work place. Challenges to be resolved These advantages are offset to some degree by a number of ongoing challenges that the manufacturers are currently addressing. Process speeds are largely dependent on the UV output of the lamps and in particular the surface cure is dependent on the peak irradiance reaching the web. The output of UV LED systems is increasing rapidly and performance has almost doubled year on year to date. This is, however, a bit of a balancing act because higher output requires higher electrical input and this translates to increased running cost, which reduces the cost benefits of LED technology. Also the higher the output the greater the amount of heat generated, so the ability of the supplier to remove the heat in a cost-effective manner becomes a more crucial aspect of the system. UV intensity can also be increased by focusing LED output, and when this is done, it is possible to achieve better surface cure and UV LED curing process higher processing speed. Curing in the absence of air by using a nitrogen blanket is yet another way of improving curing speeds, and early tests indicate that a significant improvement in curing speed can be achieved with this approach. The cost of a UV LED unit, increases in direct proportion to its 22 size, because the larger the unit the greater the number of LEDs required to build it. With conventional UV systems, the price difference between lamps of different widths is not so great. As a result, where wide presses are concerned, the capital cost of a UV LED unit is higher than that of an equivalent width conventional UV lamp. As demand for UV LED systems increases, this should lower their manufacturing cost and the price differential between the two systems. Because LEDs have a low output compared to conventional UV lamps, it is necessary to place them within a few millimetres of the substrate for efficient curing. Having to place the lamps so close to the substrate can cause difficulties with some applications and it may be necessary to redesign certain aspects of various presses. As with all energy curing technologies, the absorption spectrum of the inks has to be closely matched to the peaks of the lamp emission spectrum and this requires suitable materials for formulation. Lack of commercially available ink systems is probably the main factor restricting uptake of the technology at the moment. That said, a number of ink companies, including Sun Chemical, Flint Group, Zeller+Gmelin, Siegwerk and Marabu (which primarily produces inks for screen printing and inkjet applications) have already developed various inks for use with LED and the list of suitable base materials is growing. Because the output of LEDs is near the visible end of the spectrum, there is a greater risk of inks curing with exposure to daylight than is the case with conventional UV inks. There is the possibility of shorter wavelength LEDs being developed in the future, but experience to date indicates that in general the shorter the wavelength of the device, the higher the production cost of the LED. In the longer term, ink development will have to be led by demand from printers. As demand increases Phoseon Technology’s watercooled FirePower 300 so will availability of inks. At the moment it is a bit of a ‘chicken and egg’ situation, with ink companies waiting for demand from printers and printers searching for suitable inks. For specialised applications, where demands are much more focused, development on the ink front has been greater. System suppliers It is early days still, but a number of manufacturers are already offering UV LED lamps of various descriptions, which may be suitable for flexo applications. Phoseon Technology has a number of products that are said to be well suited to flexo applications, including its FireLine and FireFlex, which can be sized to cover any web width. It also offers the watercooled FirePower range. With UV LED peak irradiance outputs of 12 W/cm2 and 16 W/cm2, this unit should offer the highest potential press speeds. Hönle AG, supplier of conventional UV curing systems, has developed the PureUV Powerline for pinning and full curing in wide format and web printing applications. The unit is watercooled and available in a range of wavelengths. It can be extended in 40 mm steps and the output can be varied in 1% steps between 10% and 100%. Because it is of a modular construction, it is possible to selectively switch modules on and off so as to match the output to the width of the print. Lumen Dynamics Group Inc recently launched its Excelerate FC-200 series of aircooled full cure UV LED products. The units have been designed for single pass narrow format digital applications. They deliver an irradiance of 9 W/cm2 at 2 mm working distance and the company said that this is the highest irradiance available from any aircooled UV LED system for the digital print industry. IST has drawn on its experience in the production of conventional UV curing systems for the development of LUV, its new modular watercooled UV LED system, which is available in five different wavelengths (typicalApril 2012 Curing ly 365–395 nm). Each module is 50 x 70 mm, and by combining modules, the lamp length can be extended in 70 mm increments until the required length is achieved. A maximum intensity of 10.5 W/cm2 can be achieved at 395 nm. If one of the LEDs should fail, the output of the remaining LEDs in the module remains constant and the service life is not affected. If failure does occur, it is detected by means of a current control operation. Output can be varied in 5% steps from 0% to 100%. Integration Technology Limited (ITL), which works in collaboration with IST combining the range of curing systems, has recently launched the miniature high-output UV LEDZero Module. Each module contains 25 closely packed individual LEDs and has a built-in heat sink. The output of the module is enhanced by a lens that directs laterally transmitted light towards the substrate. The modules are available in 365 nm, 385 nm, 395 nm and 405 nm wavelengths so that the output can be matched to the application. With this design, it is possible for end users to configure their own designs for various applications. ITL and Lumen Dynamics Group have just announced that they are to cross-license their patents. This will enable ITL products entry to the North American market and will give Lumen Dynamics enhanced access to its European counterpart. The patents allow for greater control of the curing process, while increasing its energy saving potential. Potential for flexo UV LED curing is able to offer a number of cost, environmental and processing advantages over traditional medium pressure UV lamp systems and these potential benefits are generating a lot of interest in the technology from the printing industry in general. The technology has already made inroads into digital inkjet printing, where it is reported to have captured about one-third of the energy curable market and is now moving into screen printing. Growing confidence outside the flexo markets has encouraged an increasing number of printers and suppliers to investigate and develop its potential for flexo. With the establishment of the International LED-UV Association in 2011, through the cooperation of a select group of technology, ink and 24 end users, the speed of adoption of this technology for flexo and offset litho is likely to increase. As LED technology has already started making inroads into screen printing, it may initially be of greatest interest to narrow web flexo printers with multi-process platform presses, and in particular, for companies that print on transparent films where a solid white ink is required to be laid down before being overprinted with coloured elements of a design. With conventional UV technology, white inks can be more difficult to cure than other colours, because white tends to reflect a lot of the incident UV energy. With LED, it is possible to cure very thick white ink films at effective cure speeds. This was shown three or four years ago by IST when it demonstrated the printing of a polypropylene film with a 10 micron thick screen ink at 50 m/min with UV LED lab system. With higher output LED systems now available, there is little doubt that greater speeds would be possible. There is also the possibility of hybrid systems consisting of medium pressure UV lamps with LED units, where the LED is used to partly cure (otherwise known as fixing and pinning) the ink, so that it can be readily overprinted. ‘Previously LED systems did not supply enough curing power for flexo manufacturers to take advantage of this technology. Now that LED systems provide 12 W/cm2 and higher, flexo machine builders are quickly evaluating LED systems and pushing their supply chain to provide complementary capabilities, such as inks, substrates and specialty finishes. Just as the digital inkjet market has quickly adopted LED technology, the flexographic market will rapidly transition from outdated arc lamps to new, solid state LED technology and bring along all the benefits associated with it: economic, advanced capabilities and environmental improvements.’ The future As with all new technologies, there are various challenges to be overcome, but the technology is constantly improving and over a relatively short time frame the radiation efficiency of UV LEDs has increased significantly. Various companies are already working in partnership to advance the technology specifically for flexo. At Labelexpo Europe 2009, UV LED curing technology was shown on a Gallus press fitted with Phoseon’s UV LED curing technology, which was used to cure Siegwerk UV LED inks. The view of Chad Taggard, vice president of marketing and business development at Phoseon, is very positive with regard to flexo. He commented, ‘The flexographic market can now benefit from UV LED curing technology with the introduction of higher power UV LED curing lamps. These lamps will enable smaller footprint flexo systems with simplified media paths and more varied substrate choices. End users will benefit with higher productivity, safer work environments, and reduced operating costs. Excelerate FC-200 from Lumen Dynamics It is unlikely that UV LED will have much impact on well established conventional UV flexo in the short term, especially where production speed is the overriding factor, but the usage of UV LED in flexo is sure to increase with time. As more printers adopt the technology, the production cost of the lamps is likely to reduce and greater adoption will put pressure on the ink companies to increase the number and range of available inks, thus making the technology more accessible to an increasing number of printers. The big question is, how long it will take? I April 2012
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