Mitigating The Adverse Impact of Particulates on Indoor Air Views and Conclusions from the FINE Particles – Technology, Environment and Health Technology Programme Rauno Holopainen, Merja Hautamäki, Kaarle Hämeri, Esko Kukkonen, Ilpo Kulmala, Jarek Kurnitski, Matti Lehtimäki, Tero Lähde, Jari Palonen, Pertti Pasanen, Olli Seppänen, Jorma Säteri, Aimo Taipale, and Eija Vartiainen Edited by Peter Herring Mitigating The Adverse Impact of Particulates on Indoor Air Views and Conclusions from the FINE Particles – Technology, Environment and Health Technology Programme Part of a series of five reports that cover energy and industry, traffic and transport, measurement technology, indoor air, and health and the environment. Contact information: • Helsinki University of Technology, Laboratory of Heating Ventilating and Air-Conditioning (Rauno Holopainen, Jarek Kurnitski, Jari Palonen, and Olli Seppänen) • Finnish Society of Indoor Air Quality and Climate (FiSIAQ) (Esko Kukkonen and Jorma Säteri) • University of Helsinki, Department of Physical Sciences (Kaarle Hämeri, Tero Lähde, and Eija Vartiainen) • University of Kuopio, Department of Environmental Sciences (Merja Hautamäki and Pertti Pasanen) • VTT, Technical Research Centre of Finland (Ilpo Kulmala, Matti Lehtimäki, Aimo Taipale) • Finnish Institute of Occupational Health (Merja Hautamäki, Kaarle Hämeri, Tero Lähde, and Eija Vartiainen) Layout by Quickmac Oy Printed by Libris Oy, Helsinki ISBN 952-457-247-8 Copyright Tekes 2006. All rights reserved. This publication includes material protected under copyright law, the copyright for which is held by Tekes or a third party. Material contained here may not be used for commercial purposes. The contents are the opinion of the writers concerned and do not represent the official Tekes position. Tekes bears no responsibility for any possible damage arising from the use of this material. The original source must be mentioned when quoting from this publication. Preface T he air we breathe exposes us to a growing number of airborne contaminants, including particulate matter invisible to the eye, as a result of ever-growing traffic volumes and ever-higher levels of energy generation, as well as other factors. Fine particulates are known to have major health implications, and result in the premature death of over 300,000 people in the EU annually alone. Advances in technology are allowing us to measure smaller and smaller sizes of particles and gain a better understanding of how they impact health and the environment, however. The more we learn about the very real harm caused by these types of emissions, the more the benefits of introducing tougher air quality standards become clearer. Typical of the initiatives being introduced in this area is the European Commission’s Clean Air for Europe (CAFE) programme, the results of which will be used to enhance European air quality from 2010 onwards. Tekes launched a four-year programme in 2002 known as the FINE Particles – Technology, Environment and Health Technology Programme – together with the Academy of Finland, the Ministry of Transport and Communications, and the Ministry of the Environment – to address some of these challenges. In particular, to generate new research data, leverage the existing broad range of Finnish expertise in fine particles and develop it further, and catalyse business opportunities in the field. The programme’s ultimate goal has been to improve our understanding of the impact emissions of this type have on health and the environment, identify the potential for new technological innovations, and encourage their commercialisation. The FINE programme involved over 50 individual projects and close to 60 companies and 20 research institutions, and focused on emissions and technology in five main areas: energy and industry, traffic and transport, measurement, indoor air, and health and the environment. A summary report has been produced on each of these areas. Drawing on the work of 11 projects – seven coordinated by universities and research institutes and four by companies – this summary report focuses on the particulate challenge in buildings and occupational environments. The FINE projects in this area covered a range of areas linked to extending our knowledge of the phenomena involved and reviewing the technological and business potential open to today’s and tomorrow’s technologies. We would like to thank all the researchers and authors that have contributed to the Fine Programme, and whose work has made the publication of this report and the others in the series possible 3 Contents Preface 4 3 1 Introduction Sources and concentrations of indoor particulates The regulatory environment The focus of the FINE Programme 5 6 8 10 2 The indoor-outdoor particle connection and particle dynamics indoors Outdoor particle size distribution in urban areas The indoor-outdoor connection Indoor aerosol dynamics Conclusions 13 13 13 14 15 3 The impact of ventilation on particle concentrations in indoor air Natural and mechanical ventilation Air distribution in ventilated rooms Personal ventilation Local exhaust ventilation Room air cleaners Pressure control Problems with systems in residential buildings Modelling tools Conclusions 17 17 17 18 19 20 20 20 20 20 4 Filtration Fibrous filters Electrostatic precipitators Decentralised air cleaning Room air cleaners Conclusions 21 21 24 25 26 27 5 Market potential Market drivers in North America and Europe 29 29 6 Conclusions 33 References and literature 34 1 A Introduction number of epidemiological studies have shown that ambient particulate pollution has an adverse effect on human health. Observed effects include increased respiratory symptoms, reduced lung function, elevated respiratory morbidity, and elevated cardiopulmonary mortality (Pope et al. 1995). Figure 1 illustrates the possible cardiovascular mechanisms resulting from exposure to particulates. The volume of hospitalisations is also higher (Linn et al. 2000), with the elderly, young children, and people with chronic cardiopulmonary disease, influenza, or asthma the most susceptible (Pope 2000). Less attention, in contrast, has been paid to indoor particles and their impact on health, despite the fact that indoor air particle exposure may be even more harmful than exposure to ambient particulate pollution. Indoor particle concentrations are often lower compared to outdoor levels due to supply air filtration, but they can be much higher in the workplace, where particle composition can also be very different. Welding fumes, for example, contain metals such as chromium, nickel, and manganese that can impact health adversely, depending on their toxicity. The role of particle size, mass, and number is still unclear. It is suspected that ultrafine particles may be more harmful than larger particles. As particle size decreases, surface area and particle number per unit mass increases. Combustion processes, such as smoking tobacco, burning wood, and cooking produce largely ultrafine particles with a large surface area per unit mass that can deposit deep in the respiratory track and access the pulmonary interstitium (Donaldson et al. 2001, Oberdörster 2001). Figure 1. Inflammation-induced cardiovascular effects after particle exposure (modified after Donaldson and MacNee 2001). 5 Sources and concentrations of indoor particulates perature than MS (Witschi et al. 1997). The concentration of some carcinogens, such as nitrosamines, is higher in SS than in MS (Hoffman et al. 1987). Smoking can increase indoor air particle concentrations significantly. Koistinen et al (2001) report a mean PM2.5 concentration in smoking homes in Helsinki of 21 μg/m3 and 8.2 μg/m3 in non-smoking homes. Kleeman et al. (1999) and Klepeis et al. (2003) identified particles with a mass median diameter (MMD) of 0.3–0.4 μm and 0.2 μm under chamber conditions. According to Nazaroff et al. (1993), nearly all the particulate matter in environmental tobacco smoke is smaller than 2.5 μm. The concentration of environmental tobacco smoke particles in indoor environments varies temporally and spatially. Temporal variation depends to a large extent on smoking frequency, while spatial variability is influenced by airflow rates and building characteristics. The typical particle mass emission rate for cigarettes is 0.7–0.9 mg/min, according to Klepeis et al. (2003). A In homes and non-industrial environments, such as offices and schools, the concentration of particulate matter is usually 20–200 μg/m3. Extreme values can go as high as 1000 μg/m3 (Mølhave et al. 2004). Indoor levels show temporal and spatial variation reflecting outdoor particulate concentrations and indoor sources. Concentrations of indoor air particles depend on human activities and the physical activity of occupants, ventilation, air change rates, and building characteristics (Abt et al. 2000a, Wallace et al. 2002). Temperature and relative humidity contribute to microbial numbers. Indoor chemical reactions generate secondary organic aerosols, typically monitored as ultrafine particles (Weschler 2004, Weschler and Shields 1999). The presence of these indoor sources may raise indoor air particle concentrations above outdoor air concentrations. These short-duration events indoors tend to generate high particle concentrations, sometimes several orders of magnitude higher than background particle levels. OUTDOOR AIR INDOOR AIR GENERATION Smoking Pets Cooking Heating Candles Microbes Secondary particles Ventilation, filtration, penetration through gaps Resuspension Deposition (Vacuuming, dusting, movement of people) Deposition Figure 2. Indoor particle sources in a residential building. The main sources of indoor air particulate matter are tobacco smoke, cooking, resuspension of settled particles, combustion, and outdoor air (Abt et al. 2000a, Wallace et al. 2002, He et al. 2004). See Figure 2. recently published study showed a PM2.5 and submicrometer particle emission rate of 0.99 mg/min resulting from smoking (He et al. 2004). Cooking Environmental tobacco smoke Environmental tobacco smoke (ETS) is a major contributor to indoor air particle concentrations. Smoking at home in Finland is quite uncommon today, however. Only 10% of respondents in the EXPOLIS study, covering 434 subjects living in Helsinki, reported smoking at home. These subjects were exposed to an average of 0.37 hours/day of ETS (Jantunen et al. 1999). ETS is a mixture of gases and particles generated by the combustion of tobacco products (Nasaroff and Klepeis 2004), and consists of 15% mainstream smoke (MS) and 85% sidestream smoke (SS). These have a different chemical composition, as SS is generated at a lower tem6 Cooking, such as frying, grilling, toasting and sautéing, also generates particles, the size and number of which depend on the methods and conditions employed and the type of food cooked. Gas and electric stoves can generate different particle profiles. Frying meat produces 10–20 times higher levels of particle concentrations than frying potatoes, regardless of the type of stove used, according to Flückiger et al. (2000). Dennekamp et al. (2001) noted that frying fatty foods such as bacon generated significantly higher concentrations of ultrafine particles than frying vegetables, again regardless of the stove used. Candles Candles can generate high indoor particle levels, especially in the ultrafine size range. Afshari et al. (2005) measured a maximum concentration of 241,500 particles/cm3 from burning two pure wax candles. The estimated source strength was 3.65 × 1,011 particles/min. Ultrafine particles predominated during burning, but the volume of particles ranging from 0.3 to >1.0 μm increased rapidly after the candles were extinguished. Heating Household fireplaces and stoves can increase indoor particle concentrations. The amount of supply air can also have a strong impact on particle size distribution and emissions of particle-bound polycyclic aromatic hydrocarbons (Hueglin et al. 1997). The count median diameter of particles generated from wood burning with a flame is 80 nm, and without a flame 55 nm (John 2001). There are no substantial differences between heating systems, according to Moriske et al. (1996), who looked at homes heated by coal, a wood-burning fireplace, and central heating. Total suspended particulate (TSP) measurements showed no significant differences, although the amount of sedimented dust was higher during the winter than in the summer in homes with coal- or woodburning appliances. Secondary organic aerosols Reactions between indoor air pollutants can increase the size of particles or even form new particles. Secondary fine aerosols are formed from gases in nucleation, condensation, and reaction processes. Products that have sufficient low vapour pressure may form particles. The conversion of sulphur dioxide (SO2), for example, produces sulphuric acid droplets (H2SO4) (Lippmann 2000). Chemical reactions in indoor air generate secondary organic aerosols (SOA). Terpenes and ozone are often causative to these reactions. Ozone is usually transported indoors from outside. Photocopiers, laser printers, electrostatic precipitators, and ozone generators are also sources of ozone indoors. Terpenes are commonly used in consumer products such as solvents, cleaners, odorants, and air fresheners. Unsealed wood products also emit terpenes (Weschler 2004), and Weschler and Shields (1999) have concluded that ozone/terpene reactions can produce a significant increase in the mass and number concentrations of submicrometer particles. Office equipment Photocopiers and printers are also sources of indoor particles in office environments. Dry process photocopiers can produce respirable particle concentrations of 46–50 μg/m3 while operating (Brown 1999). Laser printers have been found by Lee et al. (2001) to produce the highest PM10 concentration (65 μg/m3), compared to ink-jet printers (20–38 μg/m3) and all-in-one units (41 μg/m3). In addition, secondary organic particles are produced from ozone and VOC emissions emitted by printers and photocopiers (Wolkoff 1999). Ironing Ironing also generates particles in indoor air. When looking at particulate emissions from ironing cotton sheets with and without steam in a full-scale chamber, Afshari et al. (2005) measured peak concentrations of 7,200 ultrafine particles/cm3 from steam ironing and 550 UFPs/ cm3 from non-steam ironing. A recent study in Finland (2005) showed that steam-ironing towels produces mainly ultrafine particles, with a maximum total concentration of 3.6×104 particles/cm3 (unpublished data). Bioaerosols Bioaerosols consist of dust mites, moulds, pollen, bacteria, viruses, amoebae, fragments of plant materials, and human and pet dander from both indoor and outdoor sources. Outdoor sources include soil, plant surfaces, water, sanitary vents, and building exhaust; while typical indoor sources include humans, pets, indoor plants, showers, and heating and ventilation systems (Morawska and Salthammer 2004). The size of viruses ranges from 0.02 to 0.3 μm, and that of bacteria from 0.5 to 10 μm (Morawska and Salthammer 2004). The size of bacterial spores range from 0.5 to 3 μm (Reponen et al. 2001). Pollen particles are typically 10–100 μm, and dust mites about 10 μm (Morawska and Salthammer 2004). The size of fungal spores varies between 1.5 and 30 μm (Reponen et al. 2001). Dust mites and mite faeces are the most common allergens in indoor air. Mites live in carpets, sheets, mattresses, pillows, and upholstered furniture, and feed on skin scale, fungi, and organic debris (Ledford 1994). Spores are often resistant to environmental stresses such as dryness, cold, heat, and ultraviolet radiation (Reponen et al. 2001); and live in soil, plant tissues, stored organic material, and damp indoor environments, such as basements, windowsills, showers, carpeting, air conditioning systems, and humidifiers. In addition to fungal spores, fungal fragments are released from surfaces contaminated with fungi. These immunologically reactive particles are smaller than fungal spores and their amount can be much higher than spore levels. Fungal fragments may comprise pieces of spores or be formed through nucleation from secondary metabolites (secondary organic compounds) of fungi. The release rate depends on air velocity. Even gentle air velocity (0.3 m/s) can aerosolise these fragments into the indoor air (Górny et al. 2002, Górny et al. 2003). Bacteria colonise in humidifiers and air-conditioning equipment. Researchers have found that indoor concentrations of bacteria can be higher than concentrations of fungi in dwellings with or without mould problems. Toivola et al. (2004) found total bacteria levels of 60,600 7 cells/m3 in homes, 86,400 cells/m3 in personal samples, and 145,000 cells/m3 at the workplace. The numbers of viable bacteria were 338, 715, and 1,090 cfu/m3, respectively. The size of airborne cat allergens – such as Fel d I – ranges from 2.5 to 10 μm, and they are found in cat pelt, saliva, basal squamous epithelial cells, and sebaceous gland excretion. The major dog allergen – Can f I – is detected mostly on the dog coat and in saliva (Ledford 1994). Allergens can be carried into homes without pets on the clothing of visiting pet owners. Geometric mean concentrations of Can f I and Fel d I in homes with a cat or a dog have been measured at 69 and 200 μg/g, respectively. In homes without indoor pets, concentrations have been measured above 1.0 μg/g (Arbes et al. 2004). Man-made mineral fibres Fibre dust particles have a length of >5 μm and a diameter of <3 μm. The length/diameter ratio for fibres is typically 3:1. Man-made mineral fibres (MMMF), such as glass wool, rock wool, and ceramic fibres are used in acoustic and thermal insulation products. A study by Skov et al. in Denmark (1987) identified airborne MMMF levels in 14 town halls with a mean concentration of 5 fibres/m3 (range of variation 0−60 fibres/m3). Schneider et al. (1990) measured dust in buildings with MMMF ceiling boards, such as nurseries, kindergartens, schools, and office buildings. The average concentration ranged from 17 to 210 respirable MMMF/m3. The lowest fibre levels were measured in mechanically ventilated, clean rooms. House dust House dust is a mixture of biological material, such as animal dander, hair, and fungal spores, and deposited particulate matter, such as textile fibres, from indoor air aerosols. It also includes soil particles brought indoors by shoes. It consists of solid inorganic and organic materials from a variety of natural and synthetic origins (Morawska and Salthammer 2004). Particle size distribution and content varies between sampling locations. Lewis et al. (1999) found the highest mass (22.7%) in a particle size fraction of 53–106 μm in residential house dust. Mølhave et al. (2000) measured floor dust samples collected from offices and found the following size distributions: 0–3 μm (<0.1%), 3–6 μm (0.1%), 6–10 μm (0.4%), 10–25 μm (6.3%), 25–50 μm (12%), 50–125 μm (41%), and >125 μm 40%. House dust from kindergartens consists mostly of inorganic materials, such as sand and clay, while house dust in residences of animal owners contains largely organic material (Morawska and Salthammer 2004). Resuspension Human activity and cleaning can resuspend settled particles, thereby increasing PM concentrations in indoor 8 air. Dusting, vacuuming, making a bed, folding clothes and blankets, and movement, such as walking through a room, all cause resuspension. Resuspension rates are higher for coarse particles than for fine and ultrafine particles, due to adhesion and detachment forces (Morawska and Salthammer 2004). Several studies have reported increased particle concentrations from resuspension. Ferro et al. (2004) found dusting and movement resulted in indoor PM2.5 concentrations of 32 μg/m3 and 15 μg/m3, respectively. Resuspension rates also vary according to particle size. As particle diameter gets larger, the resuspension rate gets higher as well. Thatcher and Layton (1995) observed that the resuspension rate is the highest for particles larger than 5 μm, whereas particles smaller than 1 μm showed almost no resuspension, even with vigorous activity. Wallace (2000) reported that a major source of coarse particles in a townhouse is the physical movement of the residents. Lioy et al. (1999) tested the performance of 11 vacuum cleaners in collecting fine particles and reported motor emission rates ranging from 0.028 to 176 μg/min. Vacuum cleaning resuspended coarse particles effectively, but also released fine particles into indoor air. The majority of the particles released were 0.3−0.5 μm in diameter. Vacuum cleaners equipped with highefficiency filters (HEPA) showed the lowest particle emission rate. In summary Indoor particle sources have a significant impact on levels of particulates in non-industrial buildings. This is particularly the case in homes, where ventilation systems are often less effective than in public buildings. Indoor particle generation is often short in duration, but can increase particulate levels substantially for an extended period. Properly fitted and maintained ventilation and kitchen exhaust hoods are essential, therefore, to remove particles indoors. Table 1 provides a summary of the types of particulates found in indoor environments and the deposition rates that have been measured for their incidence. In industrial environments, the use of personal protective gloves and respirators, as well as local exhaust ventilation, is appropriate, due to the higher impurity levels encountered in these environments. In addition, the particles generated in industrial workplaces are often more toxic. The regulatory environment Indoor air quality in industrial workplaces is often much lower than in non-industrial buildings, and the concentration of impurities in workplace air is limited using HTP values (HTP 2005). In respect of residential locations, a directive issued by the Finnish Ministry of Social Affairs and Health in 2003, and based on the Health Source Methods Particle size Emission or infiltration rate/factor Reference Smoking 48 h condensation particle counter measurements in residences, time activity diary PM2.5 and submicrometer particles 1.92×1011 particles/min He et al. 2004 Smoking Chamber tests, estimation 0.1–1.0 μm (MMD 0.2 μm) 1.03–1.79 mg/min Klepeis and Nazaroff 2002 Smoking Chamber tests Respirable particles 17 mg/cigarette Leadeder and Hammond 1991 Candles Chamber tests 0.1–10 μm 11.8 mg/h Fan and Zhang 2001 Afshari et al. 2005 Candles Chamber tests Ultrafine, fine 3.65×1011 particles/min Cigarette Chamber tests Ultrafine, fine 3.76×1011 particles/min Afshari et al. 2005 Cooking 48 h condensation particle counter measurements in residences, time activity diary PM2.5 and submicrometer particles Cooking: 0.11 mg/min Frying: 2.68 Microwave: 0.03 Oven: 0.03 Stove: 0.24 Toasting: 0.11 He et al. 2004 Cooking Hamburger and chicken cooking tests with charbroiler, emission rate measurement PM2.5 Hamburger: 15 g/kg McDonald et al. Chicken (with skin): 7.2 g/kg 2003 Cooking Particle concentration measurements, time-activity recordings, modelling PM2.5, PM10 PM2.5: 1.7 mg/min PM10: 4.1 mg/min Wallace L 1996 Cooking Chamber tests Ultrafine, fine Frying meat: 8.27×1011 particles/min Electric stove: 6.8×1011 particles/min Afshari et al. 2005 Ironing Chamber tests Ultrafine, fine With steam: 0.06×1011 particles/min Without steam: 0.007×1011 particles/min Afshari et al. 2005 Deposition Deposition rate measurements 0.014–10 μm from cooking in 14 houses PM2.5: 3.61 h-1 He et al. 2005 Resuspension 48 h condensation particle counter measurements in residences, time activity diary Sweeping floor: 0.02×1011 particles/min Vacuuming: 1.57×1011 particles/min He et al. 2004 Resuspension, Aerosol number concentration 0.3 –> 25 μm human activity and particle size measurement in two-story residence at summer, estimation of resuspension rates (four residents in the study house performing normal light activities) 0.3–0.5 μm: 9.9×10-7/h 0.5–1 μm: 4.4×10-7/h 1–5 μm: 1.8×10-5/h 5–10 μm: 8.3×10-5/h 10–25 μm: 3.8×10-4/h >25 μm: 3.4×10-5/h Thatcher and Layton 1995 Resuspension, Modelling indoor and outdoor cleaning particle size distribution data collected in four homes in Boston PM0.7–10 15.1 μm3/cm3/h Abt et al. 2000b Vacuum cleaner Chamber tests with full bag Ultrafine, fine 0.35×1011 particles/min Afshari et al. 2005 Outdoor PM2.5–PM10 Infiltration factors: PM2.5: 0.74 PM10: 0.28 Long et al. 2001 Particle characterisation study in Boston, continuous particle measurement indoors and outdoors PM2.5 and submicrometer particles Table 1. Particle emission and deposition rates for indoor particle sources. 9 Protection Act (763/94), covers regulations regarding physical, chemical, and biological factors in housing and other residential premises, and the methods for measuring these factors and interpreting the results. The Finnish building code (ME 2003) provides regulations and guidelines for new ventilation systems. These aim at ensuring healthy, safe, and comfortable indoor air quality in new buildings. Ventilation systems must be designed and installed so that they are clean before commissioning and can be maintained without difficulty. Outdoor air intakes should be located away from pollutant sources. The minimum distance depends on the sources, and normally ranges between 0.9−8 m. Supply air must be filtered using F7 and G4 (or better) filters in urban areas and rural areas, respectively. Outdoor airflow rates must be equal or higher than 6 dm3/s/person (0.35 dm3/s/m2), which corresponds to an air change rate of 0.5 times an hour in a room 2.5 metres high. The carbon dioxide concentration in an occupied room should not exceed 1,200 ppm. The Finnish FiSIAQ 2001 guideline was developed as a tool for achieving healthy and comfortable indoor air quality in new buildings, and introduces good design and construction practices, as well as prudent material selection. The classification includes three categories for indoor environments: S1, S2, and S3. The highest of these, S1, can be achieved by using M1-classified building materials and by following P1 instructions. Category S3 corresponds to the official Finnish building code (ME 2003). The focus of the FINE Programme The FINE Programme involved 11 projects with a special focus on buildings and occupational environments, seven coordinated by universities and research institutes and four by companies. A total of 17 research groups and 24 companies participated in the projects, which accounted for about a quarter of the funding allocated to the FINE Programme as a whole. Projects focused both on office-type environments, in which the outdoor-indoor connection is of central significance and the main source of indoor air particles is outdoor pollution, as well as traditional industrial environments in the wood and metal industries, where the main sources of aerosol particles are inside buildings and the focus is on preventing employee exposure to fine and ultrafine particles. Particle emissions from grinding operations in a plywood plant were studied in the FineWood project (Welling et al. 2005). Plywood grinding generated fine and ultrafine particles in the 200–400 nm and 20–40 nm size ranges. Grinding medium-density fibreboard (MDF) resulted in the highest particle emissions. Dust filtering systems removed fine particles from the recirculation air effectively. Filters collected 80% of particles in the 0.2–0.3 μm size range. Fibre exhausts from sound attenuators used in ventilation ducts were examined using laboratory and field measurements as part of the ILMI project. Laboratory tests included disturbance periods caused by changes in airflow, brushing, and shaking. Fibre concentrations varied between 0.01 and 3,000 fibres/ m3, depending on the test method and sound attenuator used. Based on the test results, researchers suggested new classification limits for the sound attenuators in the ventilation ducts. Field measurements were conducted in office buildings. Fibre concentrations on 7000 dN/d log dp (cm-3) 6000 Outdoor air (measured) Indoor air (measur e d) Indoor air (model) 5000 4000 3000 2000 1000 0 0 6 12 18 24 30 36 42 48 Time (24 - 25 April, 2004) Figure 3. Concentrations of particles with a geometric mean diameter of 0.103 μm in outdoor and indoor air, together with data for modelled indoor concentrations (Holopainen et al. 2005). 10 Figure 4. A typical system installed to handle welding fumes. surfaces and in the air were <0.1–14.9 and <0.01 fibres/ cm3, respectively. In the HALVI project, a mathematical model was constructed to simulate time-dependent particle concentrations in indoor air and evaluate the exposure of occupants (Holopainen et al. 2005). The model was validated with laboratory (Björkroth et al. 2006) and field measurements (Holopainen et al. 2006) in the VALIDI project. The model can be used to evaluate the indoor/outdoor particle ratio and the exposure of occupants. Figure 3 presents particle concentrations in the outdoor and indoor air on April 24–25, 2004, and modelled particle concentration in indoor air (Holopainen et al. 2005). The results show that particle concentrations in indoor air can be roughly estimated from particle concentrations in outdoor air when the indoor air has only minor particle sinks and sources, and particles transfer from the outdoor to the indoor environment mainly via ventilation system. However, particle penetration through cracks in the building envelope (leakage airflow) may have a significant impact on the indoor/outdoor particle ratio, especially when supply air is filtered through a high-efficiency filter (Holopainen et al. 2006). The HIPHI Project focused on fine and ultrafine particles emissions formed during welding and cutting (see Figure 4). Particulate emissions in the welding fume, as well as their transformation in air, were studied, with the aim of identifying the key operating parameters involved and reducing emissions of fine particles. Experi- ments were conducted both in the laboratory and in the field. The fine particles in the fume were measured using cascade impactors (ELPI, DLPI) and a scanning mobility particle sizer (SMPS), and the number of particles in different size classes, and their composition, shape, reactivity, and other properties were determined. Both personal welding helmets and fume extraction welding guns were tested, in the laboratory and in industrial workshops. The main observation was that particle concentration is dominated by fine and ultrafine particles that do not contribute significantly to the total mass. Both size and concentration were functions of the operating parameters, and emissions can be controlled by careful selection of these parameters. The BIOFINE Project focused on investigating the fine particles that microbial damage to a building generates. The study was conducted by measuring fine particle size distributions and characterising the microbial fraction of the airborne fine particulate matter qualitatively and quantitatively using modern molecular biological and chemical techniques. The investigations were carried out in pairs of buildings, one of which had moisture and microbial damage and where workers reported buildingrelated symptoms, while the other was an age- and building frame-matched control with no signs of moisture or microbial damage or adverse health effects. The results indicate that significantly higher fine particle concentrations were present in the indoor air of the building with mould damage. 11 12 2 The indoor-outdoor particle connection and particle dynamics indoors I ndoor aerosol particle concentrations and size distribution depend on particle transport from outdoors to indoors, indoor emission sources, and aerosol dynamics indoors. Transport indoors depends on several factors: the type of ventilation and air exchange rate, filtration, leaks in the building structure, etc. The main aerosol dynamical processes are deposition (particle attachment to surfaces), condensation (particle growth from vapours) and nucleation (particle formation from vapours), evaporation, and occasionally agglomeration (particle collision and attachment). All of these processes depend on particle size distribution, and detailed studies on indoor aerosols require information on size distribution. The origin of indoor particulate matter depends to a large extent on ventilation methods and indoor activities. The main source of indoor particulate matter is typically outdoor particulates, particularly in buildings with no strong emission sources, such as offices. Outdoor particle size distribution in urban areas Urban outdoor particle number size distribution is typically trimodal. Size distribution consists of a strong nucleation mode with a geometric mean diameter (GMD) of <30 nm, an Aitken mode with a GMD of between 20−100 nm, and a weak accumulation mode with a GMD of >90 nm (Hussein et al. 2004b). Number size distribution in nucleation and Aitkenmode GMDs, as well as in accumulation-mode particle concentrations, has been shown to be dependent on the distance between the measurement location and the main source, traffic. Close to the centre of Helsinki, nucleation-mode GMD was 11.7 nm, Aitken mode GMD was 37.3 nm, and accumulation GMD was 150.5 nm, GMDs measured 3 km out of the centre and 200 metres from a major highway were bit higher, at 13.8 nm, 42.5 nm, and 151.8 nm respectively. The long-term mean number concentrations in central Helsinki were 7,000 cm-3 for nucleation mode, 6,000 cm-3 for Aitken mode, and 1,000 cm-3; and number concentrations 3 kilometres from the centre were 5,500 cm-3, 4,000 cm-3, and 1,000 cm-3, respectively. Particle total number concentrations may exceed 100,000 cm-3 during the rush hour, however. Measured nucleation-mode GMD is approximately the same as in other parts of Europe, but both Aitken and accumulation-mode GMDs are a little larger in Europe than in Helsinki (Hussein et al. 2004b, Birmili et al. 2001). Temporal variation was also seen in distribution GMDs and total particle concentration on a seasonal, weekly, and daily basis. Nucleation and Aitken-mode GMDs and concentrations have been shown to vary both at the daily and weekly level, depending on traffic densities and global radiation. No such dependence has been shown for accumulation mode. The sources for accumulation-mode particles in the Helsinki area have been identified as regional combustion processes or long-range transport (Pakkanen et al. 2003, Hussein et al. 2004b). Particulate mass size distribution has been shown to be trimodal in the Helsinki area, with the most dominant, traffic-originated mode in the 0.15–0.24 μm size class (Pakkanen et al. 2003). The indoor-outdoor connection Outdoor particle matter is transported indoors through ventilation ducts, windows, doors, and cracks in the building envelope (Thatcher et al. 2001). Buildings can be divided into two main categories on the basis of the type of ventilation mechanism employed: mechanical supply and exhaust ventilation with supply air filters, and exhaust (natural or fan-driven) ventilation with envelope infiltration. The ratio of indoor particle concentration to outdoor particle concentration (I/O) differs between these two categories. Mechanical supply and exhaust ventilation Indoor air in mechanically ventilated buildings is mainly exchanged through fans. The supply air is typically also filtered, and exhaust air is often re-circulated when temperatures outside are low. The main route for particulate transport indoors is through filter assemblies. The particle size-segregated I/O distribution curves follow roughly the known filter penetration efficiency curves. Typically, the I/O ratio falls sharply as particle size drops below 100 nm (Zhu et al. 2005, Koponen et al. 2001, Hussein et al. 2004a and 2005). The I/O ratios measured by Koponen et al. (2001) and Hussein et al. (2005) are both below the ideal penetration efficiencies of the filters used in the measured buildings. Particulate deposition on ventilation duct and indoor surfaces enhance particulate losses both in the ultrafine and in coarse size ranges (Lai 2004). Koponen et al. (2001) have also found that I/O ratios in the 8 nm to 25 nm particle size range decreased when ventilation systems were switched on. Modelling shows that air exchange rates increase the I/O ratio in this size range (Hussein et al. 2005). 13 Exhaust ventilation Indoor aerosol dynamics Particulates move indoors primarily through the building shell in structures without a mechanical air supply. (Thatcher et al. 2001). Small cracks in the building envelope may raise the penetration factor to nearly unity (Liu and Nazaroff 2003). I/O ratios have been shown to be a little higher in buildings without a mechanical air supply throughout the measured size range. Building age also plays a major role in I/O ratios or penetration factors, as the shells of older buildings are less enclosed and the penetration factor may be close to unity (Thatcher et al. 2003). In buildings without a mechanical air supply, I/O ratios vary strongly in line with outdoor pollution levels, and increase as outdoor concentrations increase (Franck et al. 2003, Zhu et al. 2005). No clear outdoor particulate concentration dependency is seen for buildings with a filtered supply air. The difference in small particle fraction (diameter <10 nm) I/O ratios, measured in buildings with and without mechanical air supply, has at least three explanations. It could be a measurement artefact deriving from the statistical inaccuracy of measurement devices; a loss of volatile materials from particles during infiltration; or there could be an unidentified indoor source in indoor space (Zhu et al. 2005). The volatility of ultrafine particles is smaller indoors than outdoors (Kuhn et al. 2005). The indoor particulate population is modified by all the typical aerosol processes, such as deposition, condensation, nucleation, evaporation, and coagulation. The dominant process influencing population size distribution is particle deposition. Deposition Deposition lowers indoor particle concentrations, and is a strongly size-dependent aerosol process. Small particles (diameter below 100 nm) are deposited due to Brownian or turbulent diffusion, electrical forces, or thermophorecy; and large particles (diameter above 1000 nm) as a result of gravitational forces or ‘turbophorecy’ (Lai 2004). Overall deposition depends to a large extent on room airflows and room furniture (Thatcher et al. 2002). Deposition is considered to be the only process that lowers particulate concentration indoors in buildings without a mechanical air supply. Deposition also affects particle concentrations in buildings with a mechanical supply and exhaust, but exhaust airflows also reduce particle concentrations. Deposition rates increase with higher air exchange rates (He et al. 2005). Condensation and nucleation The condensational growth of particles depends on condensing vapour concentrations to a large extent. In- I/O size distribution Vs. distance from freeway 1,2 1 I/O 0,8 0,6 0,4 0,2 Zhu 35 m Zhu 60 m Zhu 37 m Zhu 35 m eas t 0 1 10 diameter [nm] 100 1000 Figure 5. I/O ratios calculated from the results measured at different distances from the road under different ventilation conditions. All measurements except Zhu 35 m east were taken on the west side of the road. (Data adapted from Zhu et al. 2005). 14 door condensation and nucleation have been connected to ozone-terpene reactions recently. Terpenes are found in cleaning agents and air fresheners, and particles are formed through the ozone-terpene reaction in indoor air (Fan et al. 2005). Terpene-based condensation nucleation has been found to be strongest in indoor spaces with a low air exchange rate (Weschler 2003). Evaporation Traffic-originated particle volatility changes when particles migrate indoors. Indoor particles are less volatile than outdoor particles. Large particles (with a diameter from 50 nm to 100 nm) are more volatile than small ones (diameter≈ 30 nm), and particles are more volatile in indoor spaces near traffic than those further away from traffic sources (Kuhn et al. 2005). Outdoor-originated particulate chemical composition changes due to evaporation indoors (Lunden et al. 2003). Some interesting changes in I/O ratios linked to the distance of an indoor space from a major road have been measured by Zhu et al. (2005), and are illustrated in Figure 5. The authors have speculated that the high indoor concentrations of fractions below 10 nm might be residues of partially volatilised particles. The I/O ratio of the size range is higher near the road. Agglomeration Agglomeration rate depends on the second power of total particle concentration, and the agglomeration process typically occurs where there are strong particle sources, such as cigarette smoke, present in indoor spaces. Agglomeration has not been considered to have a strong influence on indoor particle size distribution (Nazaroff 2004). Conclusions Although indoor particulate dynamics and the indooroutdoor connection are attracting a lot of attention in the scientific world today, they are quite poorly understood phenomena. Simultaneous aerosol processes such as deposition and filtration, and unidentified indoor sources, as well as the diversity of indoor spaces and measurement methods, together with the strong size dependency of the phenomena involved, make it hard to generalise. Assuming that there are no indoor sources, one could suggest that particulate concentrations will be lower in mechanically ventilated indoor spaces than outdoors. The I/O ratio is typically lower in indoor spaces with a mechanical supply of filtered air, and is strongly sizedependent in both ventilation cases. 15 16 3 The impact of ventilation on particle concentrations in indoor air V entilation plays an important role in maintaining indoor air quality. Ventilation supplies clean, fresh air to buildings and extracts contaminants. Although the ventilation of industrial premises focuses on controlling airborne contaminants, and that of non-industrial premises on controlling room temperature, humidity, and odour, the same kind of equipment is used in both types of applications. Industrial systems require some unique and specific design features, however. Natural and mechanical ventilation Natural ventilation depends on wind and buoyancy forces due to density differences or a combination of both forces. Mechanical ventilation uses fans to supply and remove air from a space. Natural ventilation and mechanical exhaust ventilation have been popular in apart- (a) (b) (c) (d) ment buildings in Finland in recent decades. Due to the requirements of the current building code (ME 2003), mechanical supply and exhaust ventilation has become the dominant solution in new apartment buildings. In office buildings, mechanical supply and exhaust ventilation with supply air filter has been the most popular system since the 1960s. Air distribution in ventilated rooms The ventilation principle is based on the airflow pattern in a room. The two main principles are mixing and thermally controlled ventilation. In addition, piston flow and short circuit flow are possible. Figure 6 shows the principle of airflow patterns and contaminants distribution in a room. Figure 6. Principle of room airflow patterns: (a) piston flow, (b) displacement ventilation, (c) complete mixed ventilation, and (d) short circuit flow. 17 Piston flow Mixing ventilation The aim of piston flow is to provide a unidirectional airflow field over a room by supply air. Piston flow has the shortest possible air change time. In one configuration sometimes referred to as vertical laminar flow rooms, cleaned air enters the room through the floor and exits through ceiling grilles or through continuous outlets in the walls at ceiling level. The aim of mixing ventilation is to provide uniform conditions throughout a ventilated room. Airflow pattern in the room is typically controlled by high momentum supply airflow. Contaminant removal efficiency in complete mixing ventilation is equal to one. However, if part of the supply airflow fails to ventilate the occupied zone (short circuit flow), efficiency may be below one. Displacement ventilation Short circuit flow The aim of displacement ventilation is to provide a similar temperature and contaminant distribution throughout a room. Room airflow pattern is created by replacing the airflow leaving the room with supply air. Room airflow patterns are controlled mainly by buoyancy, i.e. the natural convection flows are the engine of displacement ventilation (DV 2001). Air quality in the occupied zone is generally better than with mixing ventilation. Contaminant distribution in a displacement-ventilated room depends on the position of the contamination sources and heat sources, if they are also contaminant sources. Thermal flow around a person may provide them with cleaner air to inhale in the case of displacement ventilation (Mundt et al. 2004). This local modification of concentration distribution may affect personal exposure when the vertical temperature gradient of room air is available (Mundt et al. 2004). See Figure 7 (a). Poor system performance is found in the case of a passive contaminant released in the lower part of the room close to the occupants. Figure 7 (b) shows an example of contaminant removal effectiveness as a function of supply airflow rate (Mathisen 1984). Short circuit flow takes place when supply air goes from inlet to outlet without passing the occupied zone. Direct loss of supply air occurs when the air discharged from the supply travels only a short distance before it reaches the extraction device. Personal ventilation Personal ventilation systems have been developed to improve the temperature and quality of air for people in open-plan offices (Melikov 2004, 2006). Personalised supply air systems include individual control of airflow rate, and provide air directly to occupants’ breathing zones. Systems have the potential to improve the quality of inhaled air and ventilation efficiency compared to conventional mixing ventilation systems, but their performance depends on the supply air terminal device. Figure 8 presents the principle of personalised supply air systems and their efficiency, depending on the position of personalised air terminals (Melikov 2006). The exposure of exhaled air is low and independent of the room air distribution when a high-efficiency personalised air terminal is used. It is possible to provide high heat load low heat load 40 1.1 m above floor 1.7 m above floor 20 <¡c> 10 5 2.5 1.25 0.6 4 (a) (b) 6 8 10 12 14 16 q (m3/hm2) Figure 7. (a) Thermal flow around a human may give cleaner inhaled air using displacement ventilation (Mundt et al. 2004). (b) An example of contaminant removal effectiveness as a function of supply airflow rate and heat load (Mathisen 1984). 18 1.6 Personal exposure index Local ventilation efficiency 1.49 1.4 1.34 1.24 <¡c> 1.2 1.0 1.12 1.02 1.03 0.8 0.6 0.4 (a) (b) Displacement diffuser Top desk grill Under desk grill Figure 8. (a) Principle of personalised supply air systems. (b) A comparison of the personal exposure index and efficiency for three types of personalised ventilation system (Melikov 2006). 100% clean air to the breathing zone when the supply air device is located close to the face. Properly managed personal ventilation has a greater potential to prevent the transmission of contagious contaminants between occupants than total volume ventilation (Melikov 2004). Early results suggest that combining mixing ventilation with personal ventilation will protect occupants from the airborne transmission of infectious agents and will be superior to mixing ventilation alone. Personal ventilation promotes the mixing of exhaled air in rooms with displacement ventilation. The air change rate of a room needs to sufficiently high, even where personal ventilation is used. Local exhaust ventilation Tobacco smoke and cooking odour from other flats are the most commonly occurring indoor-related odour problems in apartment buildings (Palonen 1998). Local ventilation, such as kitchen exhaust hoods, is an efficient method for reducing the exposure of occupants. Capture efficiency should be the prime criterion when designing local ventilation systems of this type. Figure 9 illustrates the principles involved and some typical design parameters. The smaller the living space, the more important it is to reach high capture effectiveness at the lowest exhaust airflow, due to the problems in ensuring qle _ _ y z ms ms D (a) (b) Figure 9. (a) Principle of the kitchen hood. (b) Typical design criteria for receptor hoods (ACGIH 1992). 19 that outdoor air compensates for the exhaust airflow rate. When a kitchen hood is located in the middle of a kitchen allowing free movement around the unit, it is difficult to reach high capture efficiency. The shape and dimension of the hood do not have an effect on capture efficiency, according to Heinonen and Seppänen (1994). Room air cleaners Several studies have tried to prove the benefits of room air clearers in terms of health. There is limited exposure data available for those tests, however. Fisk et al. (2002) carried out comprehensive quantitative experiments to assess the capabilities of several air-cleaning devices to create a particle-free microenvironment as a therapy for sleeping people affected by allergic rhinitis and asthma. Six devices were evaluated, of which five were portable and intended to provide general air cleaning for bedroom-sized spaces. The sixth was intended for installation in front of the headboard of a bed and was designed to provide clean air in the immediate space occupied by the sleeper. It was found that the latter was clearly superior to all the other air-cleaning devices (Hacker and Sparrow 2005). Portable room air cleaners can be used to reduce exposure to outdoor fine particles in existing residential buildings and houses fitted with mechanical exhaust air systems. Effective airflow rate must be sufficiently high, however, and noise levels low, especially in bedrooms. Residents living in family houses are very sensitive to ventilation noise in their bedrooms (Kurnitski et al. 2005), and noise is the main reason cited for reducing ventilation fan speed. Small ventilation units are often placed in the middle of a flat, which requires quite long ducts between the outdoor air intake and the ventilation unit. Dust from outdoor air can accumulate in this section and cause potential odour problems. The quality of outdoor air filtration is low in existing flats or houses with mechanical exhaust system. Some outdoor air filters for outdoor air vents are available, but their filtration classes are G3 or less. It appears that the quality of the filtration of outdoor air in existing apartment buildings is not likely to improve in the immediate future. Budgets for modernising social housing are often unable to stretch to installing mechanical supply and exhaust ventilation systems and better energy economy. Privately owned buildings face large economical problems in meeting all their maintenance needs. Existing building codes (ME 2003) do not allow residents to make personal improvements to ventilation system in apartment buildings, and air cannot be discharged from small wall-mounted ventilation units. Modelling tools The motion of particles in indoor air can be evaluated using computational fluid dynamics (CFD) simulation and multizone models. To date, CFD simulation is the current method of choice for evaluating indoor air conditions in research (Etheridge and Sandberg 1996). A multizone model was developed as part of the HALVI Project, including well-mixed zones with sinks and sources, as well as particle interaction resulting from the coagulation process. Particle transportation between the zones is described using zone-to-zone airflows (Holopainen et al. 2005). Pressure control Conclusions Temporal pressurisation is used successfully in houses with fireplaces to prevent smoke penetration, by temporarily reducing the exhaust airflow rate while keeping the supply airflow constant. The same technology can also be used to prevent tobacco smoke penetration through cracks in the walls between two apartments. Ventilation systems are shut down in Finland during emergency situations, such as major fires and cases of radioactive fallout to reduce harmful exposure from outdoor pollutants. A survival room (bathroom) can be built in a family house, and the room pressurised with a separate supply air fan fitted with HEPA and gas filters (Siren and Paalanen 1994). Ventilation and air filtering play a major role in contributing to good indoor air quality. Particle concentrations can be reduced by mechanical ventilation systems and filtering supply air. The efficient filtration of supply air, in particular, reduces the transport of particles from outside significantly. The air distribution method affects personal particle exposure. Personal ventilation systems are the most promising air delivery systems for cutting the exposure of occupants. They are not yet widely applied in office environments, however, due to the problems of connecting supply air to terminal devices at workstations. Problems with systems in residential buildings Small supply and exhaust air ventilation units incorporating heat recovery have been quite popular in apartment buildings since the early 1990s. In many cases, outdoor air intakes are placed near balconies. This solution has caused a lot of complaints among neighbours, however, with tobacco smoke penetration into other flats. 20 4 Filtration Figure 10. Fibrous filter materials. E fficient filtration of supply air is one of the major tools for improving indoor air quality. In the past, air filters were primarily used for protecting ventilation systems against particulate contamination. The growing awareness of the adverse health effects of airborne particles has shifted the role of air filtration towards protecting people, and F7 and F8 class fine filters have become more and more common in public buildings. The threat of terrorism, in the shape of possible attacks using biological and chemical weapons, will probably encourage the demand for high-efficiency filtration. Glass fibre filters installed in a central unit are the most widely used air cleaning technique today. The role of traditional electrostatic precipitators has diminished in recent years, while the use of electrically charged air filters has increased. New techniques based on air cleaning in the terminal devices of the supply air system have also become available. Room air cleaners continue to be used to reduce the concentration of airborne particles. Fibrous filters A fibrous air filter works by collecting particles from the air stream on to the surfaces of a set of filter fibres. The process by which an aerosol particle is attached can be affected by several mechanisms, which makes the detailed modelling of the operation of a fibrous filter quite complicated. The basic filtration processes can be illustrated with reasonable accuracy using rather simple mathematical models, however. The removal efficiency of a fibrous filter medium is affected by many factors. The most important material properties are packing density and fibre diameter. The thickness of the filter material also has a major influence on efficiency. Charged air filter media are widely used today, which means that the fibre charge must be taken into account when discussing material parameters. Other parameters that influence the removal process are air velocity in the filter medium, particle size, particle density, the electrical charge of the particles, and their dielectric properties. Packing densities can vary rather widely (from 0.01 to 0.3) depending on the filter type. Fibre diameter can also vary widely (typically from below 1 μm to 40 μm) depending on the type and application of the filter. See Figure 10. The structure of a fibrous filter is open, and the fibres form a very large collection area. The surface area can be very high. In a filter medium with a packing density of 0.01, a fibre diameter of 1 μm, and a material thickness of 5 mm, the fibre surface area is 200 times higher than the face area of the filter. Thus, a typical bag filter with 10 m2 of face area contains 2,000 m2 of fibre surface area. 21 The performance of an air filter is linked to two parameters: efficiency and pressure drop. Efficiency is normally illustrated by removal efficiency, which provides information about the fraction of particles collected by the filter. However, the collected particles are not of great importance compared to the particles that penetrate the filter in most cases. As a result, filter penetration should be favoured over efficiency. In the case of a conventional fibrous filter, overall single fibre efficiency is governed by three major mechanical removal mechanisms: • interception • impaction, and • diffusion. In the case of a charged filter medium, particle removal is due to the combined effect of mechanical and electrical mechanisms. The pressure drop across the filter medium is directly proportional to the air velocity and the thickness of the filter layer, and inversely proportional to the square of the fibre diameter. The flow resistance of a filter material is often illustrated by permeability. The features of a good filter include low penetration (high removal efficiency) and low pressure drop. A practical measure of these properties is filter quality factor. Basic mechanical removal mechanisms Interception is probably the most straightforward removal mechanism, as the particles that follow the streamlines close to the surface of the fibre may become attached. This takes place at low velocity, and it is reasonable to assume that whenever a particle touches the fibre it becomes captured due to adhesion forces. Interception is not affected by air velocity, however, only by the properties of the filter and particle size. Impaction is another basic mechanism that affects removal particles from the air stream. Impaction is due to particle inertia, when particles cannot follow the streamline and impact on the surface of the fibre. They do not always attach, however, as they may have enough energy to bounce off. Impaction is characterised using a dimensionless parameter, known as the Stokes number, which depends on several factors, including particle velocity, particle density, the slip correction factor, and the viscosity of the air. Although the basic theoretical model is only a rough approximation, it provides a good estimate of the effects of various filtration parameters, such as the fact that the importance of impaction increases with air velocity. Interception and impaction are important mechanisms for large particles. The removal of very fine particles is governed by the third basic removal mechanism: diffusion. Small particles do not follow the streamlines completely, because of random motion or diffusion, and can find their way to the surface of the filter fibre. The efficiency of a filter depends on the overall effect of these three basic removal mechanisms. Each mechanism is particle size-dependent, which means that penetration is a complicated function of particle size. Dif- 100 Diffusion Interception 80 Penetration (%) Impaction TOTAL 60 40 20 0 0.01 0.1 1 Particle size (μm) Figure 11. Fractional efficiency of a fibrous filter. 22 10 (a) (b) Figure 12. Bag filters manufactured from glass fibre (a) and polymer (b). (a) (b) (c) Figure 13. Rigid cell air filters (a) and (b), and a pleated air filter (c). 23 fusion is an effective mechanism for very fine particles, while interception and impaction remove large particles effectively. In the intermittent region, none of the mechanisms is highly effective, which means that maximum penetration can be found at this particle size range. The combined effect of the basic mechanical removal mechanisms is illustrated in Figure 11. The penetration maximum of the fibrous air filter can be found in the 0.1 to 0.5 μm size range. Particle removal due to electrostatic force plays a very important role in the case of charged filter mediums. Charged air filters normally contain a layer of fibres that have been electrically charged or polarised during the manufacturing process. These fibres create local electric fields that can enhance collection efficiency considerably. therefore uses less energy than methods where separation energy must be applied primarily to the gas flow. High voltage electrode ( ion source) Neutral particle Gas ions Charged particle Gas velocity Electric field Drift velocity Collection electrode ( ground potential) Figure 14. Principle of electrostatic precipitation, showing the single-stage process. Filter design As air filters are normally constructed to provide an adequate amount of filter material in a reasonable volume, their geometry differs significantly from ideal plane filter geometry. The most commonly type of filter structure used in general ventilation systems is the bag filter, containing several filter bags installed side by side to form a compact filter with a large filter surface. Bag filters are manufactured from glass fibre and polymer fibre (Figure 12). In addition to bag filters, general ventilation systems can be equipped with rigid cell filters, as shown in Figure 13. The filter media used here is similar to that used in bag filters, but the structure of the filter is more compact. The depth of the rigid cell filter is typically 300 mm. Rigid cell filters are relatively common in the US, but quite rare in Finland. The structure of a rigid cell filter somewhat resembles that of a pleated air filter made of thin filter material (or filter paper). The depth of a pleated air filter is normally 20−100 mm, which is much smaller than that of a rigid cell filter. Pleated filters are widely used in applications where the available space is small, such as in vehicles and small-scale air cleaning applications. Pleated air filters are made from a variety of materials, including cellulose, glass fibre, and polymer. Pleated filter structures are also used in general ventilation filters, in V-shaped structures that reduce the face air velocity to a suitable level. Electrostatic precipitators Electrostatic precipitation is one of the fundamental means of separating solid or liquid particles from gas streams, and has been utilised in numerous applications, including industrial gas cleaning systems, air cleaning in general ventilation systems, and household room air cleaners. See Figure 14. This method is based on an electrostatic force applied directly to the particles rather than the entire gas flow, and 24 The operation of an electrostatic precipitator is based on three major factors: • particle charging • electrostatic collection of charged particles, and • removal of collected particles. Particle charging takes place with a continuous flow of gas ions across the space between two electrodes. One of the electrodes is connected to a high-voltage power supply, while the other is connected to ground. Particles become charged when passing through this region. The electric field between the electrodes produces an electrostatic force on the charged particles, leading to particle drift towards the grounded collection electrode. Particle charging and collection can take place in different sections, as illustrated in Figure 15. In this twostage system, particle collection takes place in a region without gas ions. High voltage electrode ( ion source) Neutral particle High voltage electrode Gas ions Electric field Charged particle Gas velocity Electric field Drift velocity Collection electrodes (ground potential) Figure 15. Principle of electrostatic precipitation utilising separate charging and collection sections. The electrostatic force is directly proportional to the net charge of an aerosol particle. Effective charging of the particles is, therefore, of great importance. Airborne particles are normally charged either due to their birth processes or due to charge transfer from gas ions to particles. The natural charging of particles is normally so weak that it has no practical importance for electrostatic air cleaning. Particle charging in electrostatic precipitators is caused by gas ions generated by a high-voltage corona discharge, which is utilised to create regions with a high concentration of unipolar gas ions. Electrostatic force is proportional to the particle charge and the electric field. A strong electric field is important for good performance. The principles of single-stage and two-stage electrostatic precipitators are shown in Figure 16. Single-stage units are rarely used in ventilation applications. There are exceptions to this, however, as in the case of the air cleaning techniques used in systems developed by Ion Blast and Genano. A two-stage electrostatic precipitator consists of separate sections for particle charging and collection. In practice, however, the two sections are integrated to form a compact unit. In principle, the major advantages of the electrostatic precipitator are its low flow resistance and the possibility to wash the contaminated collector regularly. This makes electrostatic precipitators ideal for fulfilling two important requirements for air cleaning: low operating cost and cleanliness of the filtration system. These properties are not widely used in conventional ventilation applications, however, probably because of two major drawbacks: the high initial cost of electrostatic precipi- Single-stage ESP Charging & collection section Corona discharge tator-based air cleaning systems and, in some cases, the poor reliability of the filtration they offer. Decentralised air cleaning Purifying air in buildings is normally carried out on a centralised basis, with air filters in a general ventilation system. This approach has many good features, such as ease of maintenance. One of its drawbacks, however, is inflexibility, as different levels of air treatment cannot be provided easily in different parts of a building. The flow of outdoor particles to indoor air can be reduced by improving the removal efficiency of air filters and minimising uncontrolled leakages in the building envelope. Increasing the filtration efficiency of existing HVAC systems is a straightforward approach for improving air quality. Greater flexibility can be achieved by utilising decentralised air filtration, using air filtration in terminal devices or room air cleaners. See Figure 17. An air filter can be installed in an air duct to serve several rooms or a single room. In principle, air filters can be integrated with terminal supply air devices. All these alternatives require that the pressure drop of the filter is low, to prevent any significant changes in airflows occurring. The space available for a terminal air filter may be small, however, making the use of conventional air filtration techniques unfeasible. However, terminal air filtration has been successfully accomplished with the aid of a sophisticated air cleaning technique that combines effective electrostatic particle filtration with chemical filtration based on activated carbon. Two-stage ESP Charging section Collection section Corona discharge Figure 16. Principles of single-stage and two-stage electrostatic precipitators. 25 General ventilation air filter Room air cleaner In-duct air filter Terminal device air filter Figure 17. Decentralised air filtration. Room air cleaners Air recirculation and filtration of room air is another alternative for reducing the concentration of impurities in indoor air. Recirculation can be implemented using compact devices known as room air cleaners, as shown in Figure 18. These units contain filters and a recirculation fan and are widely used in homes, offices, and restaurants. One of the advantages of room air cleaners is that they can be used in buildings without mechanical supply air ventilation and centralized air filtration systems. When evaluating the suitability and efficiency of a room air cleaner, the following aspects have to be carefully considered: • the volume of the space where the air cleaner will be used • the ventilation rate, and • the types and concentrations of impurities to be removed. The capacity of a room air cleaner must be dimensioned correctly to ensure a significant reduction in im26 purity concentration. This requires that the effective flow rate or clean air delivery rate (efficiency x flow rate) is significantly higher than the airflow rate due to ventilation or infiltration. In addition, the effective flow rate must be high enough to cause a reduction in concentration that clearly exceeds the speed of the natural decay of the impurity. The filters used in room air cleaners are selective, which means that their efficiency can be virtually 100% for one impurity, but almost zero for another. In the case of aerosol particles, filtration efficiency is usually dependent on particle size. Unfortunately, some air cleaners have only a marginal effect on particle concentrations in room air. Some with a reasonably high effective flow rate, however, offer true air cleaning potential. High flow rate is usually associated with a high level of noise, however. Combining good efficiency with low noise appears to be extremely difficult. In this respect, the low flow resistance and high efficiency of an electrostatic precipitator provides a good basis for effective room air cleaning. Figure 18. One of the advantages of room air cleaners like this is that they can be used in buildings without mechanical supply air ventilation and centralised air filtration systems. Courtesy Genano Ltd. Conclusions Air cleaning based on general ventilation systems will probably remain the primary technique for combating outdoor air impurities. The rising awareness of the harmful health effects of fine particles, and the risk of terrorist attacks with chemical and microbiological weapons, will increase the need for higher efficiency filtration and removing harmful gaseous impurities. Lower operating costs will also become a growing priority. Meeting these requirements means that new filtration systems will have to be developed, leveraging areas such as charged air filter media. Improving chemical filtration will call for new smart filtration media for specific compounds. In addition to fibrous filtration, the potential of electrostatic precipitators, a long-established technology, should not be overlooked. Utilising new materials and combining electrostatic precipitation with fibrous filtration techniques open up the potential for creating reliable and cost-effective systems. One of the key is- sues here will be to reduce the initial high cost of electrostatic precipitators. Decentralised air filtration has a lot to offer in terms of efficiency and flexibility over and above centralised systems. Some terminal devices provide an ideal location for air filters. Air cleaning can also be integrated with supply air duct systems to serve one room or a group of rooms. These applications require filters with high efficiency and capacity, and low pressure drop. Room air cleaners remain a potential tool for improving air quality in limited areas of a building. Achieving a significant improvement in air quality requires that the flow rates of air cleaners can be increased without generating excessive noise. In addition, the cost of air cleaners needs to be reduced if the technique is to gain wider acceptance. 27 28 5 T Market potential he demand for solutions to improve indoor air quality is growing due to the increased awareness of consumers and active marketing by manufacturers. Building users and owners are also paying more attention to health and productivity. New information on the adverse health effects of fine particles, and measures introduced to reduce exposure to them, will create new market potential for filters in ventilation systems and air terminal devices, room air cleaners, and supply and exhaust ventilation systems. The key questions are how fast this development will be, and can something be done to speed it up. Demand varies between building types. The clearest situation can be found in industries where production processes are highly dependent on the quality of indoor air. Examples of such premises include the clean rooms needed for DNA and nanotechnology work and some hospital environments. The technological challenge is to achieve high cleaning efficiency and reliability. Cost is not such an issue, compared to the value of the space. High-end commercial and office buildings are approaching these types of production facilities in terms of the premium they now put on good indoor air quality. Employers are beginning to understand the importance of a healthy and comfortable work environment on employee productivity. High-quality premises are also an important factor in creating corporate image. The spearhead of this development has been temperature control in the form of mechanical cooling. The trend is towards more individual control of the indoor environment, which could also mean the possibility to clean the air around individual workstations. The cost of creating a positive individual indoor environment is insignificant compared to the salaries of the personnel concerned, but the link between clean air and productivity has to be verified by building owners and employers. Many current public and office buildings have low targets for their indoor environment. The majority of these buildings in Finland, for example, have mechanical supply and/or extraction ventilation systems, typically fitted with low-performance filters. Reducing people’s exposure to fine particles can usually be achieved by relatively simple technological solutions, using conventional supply air filters. This group of buildings has a large market potential for high-volume products. The cost of filtering solutions is a major factor here, and the emphasis should be on increasing people’s awareness of the importance of clean indoor air. An extremely wide market potential could open up if air cleaning and supply air filtering solutions were to penetrate the residential sector. The majority of these buildings have no mechanical ventilation system, which makes it a difficult market for supply air filters. Northern European countries have a strong tradition of mechanical ventilation, so there are more possibilities here for filtering supply/inlet air. Another problem in the residential sector is the small influence that many residents, particularly in large buildings, have on the technical solutions in their home. People living in detached houses, in contrast, are somewhat differently placed. Local and governmental authorities will be key players in improving the situation. Some of the tools developed under the FINE Programme will give valuable input for this. A good example is the validated mathematical model that has been developed for simulating time-dependent particle concentrations in indoor air and evaluating the exposure of occupants. Using this model, it is possible to demonstrate the effects of various control techniques to residents and decision-makers. Market drivers in North America and Europe There are no clear regulatory drivers for indoor clean air technologies in North America. However, non-regulatory drivers are leading to increased demand for high-technology solutions, particularly in commercial buildings and R&D applications. The market potential in residential and industrial buildings is more limited. The key non-regulatory market drivers for commercial buildings are building vulnerability, sustainable design, and traditional IAQ issues. Building vulnerability relates to the potential of a structure to be impacted by materials such as chemical, biological, or radioactive agents introduced through an act of bioterrorism or through a HVAC system. Bioterrorism is perceived as a growing risk in North America, and building designers and owners are conducting growing numbers of building security evaluations including Threat and Risk Analysis (TARA) as part of the designs for new buildings and on-going operations for existing buildings. This type of evaluation is not currently required in the US, but many commercial building-owners are aware of the importance of this proactive approach. The US Green Building Council (USGBC) has developed a certification known as Leadership in Energy and Environmental Design (LEED), which has become a nationally recognised standard for developing highperformance, sustainable buildings. Credits related to indoor air can be obtained directly from the indoor environmental quality section or indirectly through the energy and atmosphere section. Many new buildings 29 and major modernisation projects for the public sector are seeking certification through the LEED programme. Three states are currently considering LEED adoption for state projects, and five states have proposed or passed bills to establish a green building tax credit based on the LEED rating system. In Europe, the overall market volume for IAQ-related ventilation products is valued at around €20 billion, of which Finland accounts for some €500 million. The market volume for air filters is in the order of €100-150 million for Europe as a whole. These figures reflect the large available potential in Europe, where the level of filtering is generally lower than in Finland and Scandinavia. The technology for controlling fine particles in indoor air (supply air filtering and air cleaning) is well developed in Finland, and this high level of technology will give Finnish companies a competitive edge. In addition to the market potential in buildings, there are other potential market areas as well, in the shape of cars, buses, aircraft, and metros – all places responsible for a significant proportion of human exposure to fine particulates. This has not yet been widely acknowledged, but public awareness is steadily rising, and we can expect to see the demand for vehicle solutions increase. Measurement instruments represent another market opportunity. Instruments demonstrating current exposure and the effects of mitigation technology are needed by building owners and HVAC manufacturers. There is still much room for development here, to make measurements easier to take and more precise. Another interesting new technology is detecting mould damage using particle monitors. There is a large market worldwide for these types of services, but the reliability of the methods behind them needs to be scientifically demonstrated before this potential can be realised. The service dimension offers the most opportunities here, rather than the hardware. Air filters Improved filtering of supply air will bring improved business opportunities in Finland, Europe, and worldwide. Competition in this area is tough, and success will depend on finding technologically superior products and/ or product lines. Supply and exhaust ventilation systems are common in Finland and Scandinavia, due to the region’s tough building codes. The requirements for supply air filtering in new construction have recently been tightened in Finland, and this trend is expected to continue in other EU countries. Many companies consider the pace to be too slow, however. The focus of regulations has been on coarser particles or TSP, but will gradually move to ultrafine particles. Companies expect traction from voluntary IAQ classification systems, such as the Finnish Indoor Climate Classification 2000 (FiSIAQ 2001). Regulations usually only guide new construction, which is in the order of 1% of the entire building stock, which 30 means that the market potential resulting from the regulatory framework is limited compared to that of existing buildings. In the case of the latter, it will be important to pay attention to non-regulatory drivers. Increased public awareness about fine particles and the indoor environment as a whole will be the key to these markets. Further research is needed to educate the public about the harmful effects of fine particles, and emphasis should also be laid on disseminating existing knowledge, over and above what has already been achieved. See Figure 19. In addition to marketing new products, it is important to stress the importance of maintaining existing systems appropriately. Meeting consumers’ expectations in terms of better indoor air requires HVAC systems to function faultlessly and for filters to be serviced regularly. This is likely to see higher demand for maintenance services and for tools for continuously measuring air quality. Room air cleaners In theory, room air cleaners could be used in every building and room, and can be installed independently of ventilation solutions. In practise, the market potential here is limited by the technological challenges involved. To clean indoor air effectively, the airflow through a cleaner must be higher than the ventilation airflow through a room. Creating such airflow without disturbing noise and draught is still a challenge for current solutions. New technologies and materials with low pressure drop can be expected to gradually close the gap, however. Another possibility is to deliver clean air directly to the breathing zone, which reduces the volume of air to be processed significantly and current technology can offer good results here. One emerging technology is to integrate room air cleaners into furniture. See Figure 20 for an example of how personalised air supply can be integrated into desks and space dividers in an office environment. The key market driver is consumers’ requirement for clean air. Regulations are unlikely to drive the market, although by setting the pace in new construction they could provide the foundation for developments in existing buildings. Increased public awareness of fine particles and the indoor environment as whole will again be key to these markets. Reliability and ease of maintenance will be required from consumer applications, and there will be demand for maintenance services. Environments with special indoor air quality requirements are an important application area for room air cleaners. These environments include industrial clean rooms, hospitals, or areas intended for people with allergies or respiratory illnesses. The recent SARS epidemic was a good example, pinpointing the need for clean air technologies. The ongoing risk of avian flu will keep demand active in hospitals and patient transport vehicles. In the industrial sector, the rapid development and application of DNA technology and nanotechnologies Figure 19. Air filters are particularly useful in improving air quality for people with allergies, such as children. Courtesy LIFA Air Ltd. 31 will increase the demand for customised clean room applications. Air cleaners also have significant market potential in vehicles. Solutions are particularly needed to protect employees spending all their working day in a vehicle. Meeting this demand will require new technological solutions. High outdoor concentrations of particles and gases, together with the small space available for equipment, pose a particular challenge. As the technological performance of different air cleaners do not differ significantly, the competition between products and manufacturers can be expected to remain tough. Filters in air terminal devices One possibility for introducing supply air filtering in buildings is to install filters in supply terminals or inlet devices. This is a more flexible solution than locating filters in central units, as it enables filters to be installed in only part of a building or even individual rooms. This could open up new markets in existing office buildings, as filtering solutions could be sold to the users of specific spaces rather than the overall owner of a building. These solutions usually require re-balancing of a ventilation system, however, which may make the situation more complicated. Filters with a low pressure drop are required to avoid problems with the ‘background’ ventilation system. Supply air inlets can also be equipped with filters in buildings with natural or mechanical exhaust ventilation. With natural (passive stack) ventilation, the available pressure difference, however, limits filtering capacity. In these distributed filter solutions, the number of service points increases significantly. Extra emphasis must be placed on ease of maintenance and the cost of filters. As of now, there are only a few solutions that are technically and economically feasible, and further development is clearly needed. Supply and exhaust ventilation systems The increased demand for clean supply air will also increase the need for supply and exhaust ventilation systems. These are the best solution for new construction, as they also include heating and cooling, as well as heat recovery. As the requirements for filtering become tougher, the market for supply and exhaust ventilation systems will increase, which means that the regulatory environment will play an important role in this sector. It will be important, however, to convince decisionmakers, such as building owners, construction clients, and architects, about the importance of a good indoor environment. New markets, such as those in residential buildings in particular, will bring new challenges. Customers will expect turnkey delivery and that systems meet the IAQ and energy requirements they have set. Quality issues and life cycle costs will be emphasised. As filtering in a central unit can be handled using several different technologies, this will give manufacturers the possibility to optimise their solutions. Pressure drop will be one of the key factors in selecting the most appropriate filter solution, because of the increased requirement to reduce electricity costs. Figure 20. Personalised supply air systems offer individual control of airflow rates, and provide air directly to occupants’ breathing zones. Courtesy Martela Oyj. 32 6 T Conclusions he impact of particulates on health has been widely investigated in recent years, and many studies have shown that these particles increase the incidence of respiratory and cardiovascular diseases. Mild inflammation and airway obstruction are also observed. Exposure to ultrafine particles may be more harmful than that to larger particles because ultrafine particles deposit deeper in the respiratory track. There is a lack of detailed data, however, on particle numbers and mass concentrations in different size classes emitted from indoor sources, which is essential to assess the health impact of particle exposure. The evidence currently available is inadequate, and more information will be needed to demonstrate the health impact of particles according to their source, size, and mass. Future research will also need to focus on the nanoparticles that are being used in increasing quantities in many fields of industry. The number of people exposed to these new nanomaterials, such as fullerenes, carbon nanotubes, and titan dioxide nanoparticles (TiO2), is growing, and they pose significant exposure potential, because they can be deposited in the lungs or on the skin and translocate within the body. Particle concentration and size distribution in indoor air are influenced significantly by outdoor air quality, as particles transfer into the indoor environment through leaks in the building envelope and ventilation systems. Events that generate particles indoors are often of short duration, but may increase particle concentration in the air considerably. If the aim is to reduce the exposure of occupants, actions to reduce fine particle concentration should be focused on the breathing zone. Ventilation and air filtering play a major role in creating good indoor air quality. Ventilation systems need to be designed, installed, and maintained appropriately to create a healthy, safe, and comfortable indoor environment. Particular attention has to be paid to the ventilation of rooms intended for special purposes, such as people with allergies. To date, personal ventilation systems are the most promising air distribution method for reducing exposure, but these systems have encountered many practical problems due to the difficulty of supplying fresh air directly to workstations in office environments. The threat of terrorism and attacks using biological and chemical weapons will probably fuel demand for higher-efficiency filtration in buildings. A major challenge in the future will be how to achieve high filtration efficiency, as well as a low pressure drop, as filtration systems need to be effective against gaseous impurities. 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Tekes – Your contact for Finnish technology Tekes, the Finnish Funding Agency for Technology and Innovation is the main publicly funded organisation for financing applied and industrial R&D in Finland. Tekes’ primary objective is to promote the competitiveness of industry and the service sector in Finland by enhancing the country’s technological potential – through such areas as diversifying production structures, increasing production and exports, and creating a more solid foundation for prosperity today and into the future. Tekes’ technology programmes are a key part of the Finnish innovation system, and have proved a highly efficient means of encouraging and stimulating cooperation and networking between companies, universities, and research institutes for developing innovative products, processes, and services. Programmes focus on specific sectors of technology or industry, and are designed to give business access to the latest research results. Together with the Tekes network in Finland and overseas, they also provide an excellent framework for international R&D cooperation. As a result of ever-growing traffic volumes and ever-higher levels of energy generation, the air we breathe exposes us to a growing number of airborne contaminants, including minute particulate matter. These particulates are known to have major health implications, and result in the premature death of over 300,000 people in the EU annually alone. Advances in technology are allowing us to measure smaller and smaller sizes of particles and gain a better understanding of how they impact our health and the environment, however. Tekes launched a four-year technology programme in 2002, known as FINE, together with the Academy of Finland, the Ministry of Transport and Communications, and the Ministry of the Environment, to focus on particulate emissions. This concentrated on five main areas: energy and industry, traffic and transport, measurement technology, indoor air, and health and the environment. All in all, the FINE Programme involved over 50 projects and close to 60 companies and more than 20 research institutions. A summary report has been produced on each of these areas. This report concentrates on the particulate challenge in buildings and occupational environments. The FINE projects in this area covered a range of challenges linked to extending our knowledge of the phenomena involved and reviewing the technological and business potential open to today’s and tomorrow’s technologies. Tekes, the Finnish Funding Agency for Technology and Innovation is the main publicly funded organisation for financing applied and industrial R&D in Finland. For more information, see www.tekes.fi ISBN 952-457-247-8
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