Unsaturated flow cases ⇒ Infiltration Hydrostatic conditions – q=0 Steady state flow – q = constant – no variations in time – variations with depth the process of water entry into the soil early stage: capillary forces dominate later stage: gravitational forces dominate – infiltration rate → Ks important factors: – initial suction Non-steady flow – variations with time and depth » infiltration » the general case – rainfall rate – soil properties 1 Let us consider a simple system homogeneous soil 1-D vertical system uniform initial conditions constant rainfall rate R 2 R < Ks θi 3 θa θs 4 1 Ks < R < ic R > ic θi θs θi θs Various formula have been developed for this case, e.g. by Philip (1956) 5 Theoretical observations 6 Water content profile during infiltration Theoretical analyses have shown that – infiltration rate approaches Ks – wetting front assumes a constant shape when the infiltration rate approaches a constant value – velocity of wetting front approaches a constant value given by Vf = K (θ s ) − K (θ i ) K (θ s ) ≈ θs − θi θs − θi 7 8 2 Green and Ampt infiltration model Green and Ampt infiltration model h0 h0 constant properties θs, Ks Flow equation hf − h0 L ( ψ f − L) − 0 = −K s L ψf = K s (1 − ) L i = −K s hf hf Mass conservation I = ( θ s − θ i ) L = ∆θ L 9 10 Green and Ampt infiltration model Green and Ampt infiltration model Combining the two equations and integrating The traditional formulation can be expanded to also predict the time of ponding ∆θψ f ) ⇒ I dI I − ∆θψ f = Ks ( ) ⇒ dt I I I + ∆θψ f ln(1 − ) = Kst ∆θψ f i = K s (1 − 11 12 3 Redistribution Characteristic flow velocities Redistribution refers to the water movement after infiltration Darcy flux q pore water velocity infiltration front velocity θi θs L v= q θ t=0 Z t>0 Vf = 13 Solute transport K (θs ) − K (θ) K (θs ) ≈ θs − θi θs 14 Dispersion Advection v= q θ Pore scale pore water velocity Dispersion Larger scale 15 16 4 Dispersion General formulation of the ADE equation Transport due to dispersion usually described by Fick’s law Flux of solute J s = qc r − θD Mass conservation ∂M ∂J =− s ∂t ∂z ADE equation ∂c r ∂ 2c ∂c = D 2r − v r ∂t ∂z ∂z J s = −θD ∂c r ∂z dispersion coefficient D = αv ∂c r ∂z (θ, q and D assumed constant in space and time) dispersivity 17 Effect of dispersion 18 Dimensionless variables 1. Dimensionless time defined as the number of porevolumes qt vt T= = θL L 2. Dimensionless distance z Z= L 3. Dimensionless concentration c C= r c0 19 4. Column Peclet number vL P= D 20 5 Dimensionless equation Boundary conditions Upper boundary ∂C 1 ∂ 2 C ∂C = − ∂t P ∂Z 2 ∂Z ∂c r ) z = 0 = qc 0 ∂z D ∂c r (c r − ) z =0 = c 0 v ∂z (qc r − θD This equation is the basis for CXTFIT software ⇒ discontinuity in concentration across the boundary Lower boundary ∂c r (L, t ) = 0 ∂z ∂c r (∞, t ) = 0 ∂z for no backmixing at the outlet, the boundary condition for the semi-infinite case is a good approximation, mathematically more convenient 21 Flux concentration ≠ Resident concentration 22 Flux concentration cf = cr: resident concentration (volume average) Js q J s = qc r − θD ∂c r ∂z cf = cr − D ∂c r v ∂z q = θv cf: flux concentration (flux averaged) 23 24 6 ADE in flux concentration mode Flux and resident concentrations ∂c f ∂ 2c ∂c = D 2f − v f ∂t ∂z ∂z 25 26 Effect of various processes on solute transport 27 7
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