DISTRIBUTION OF SPECIFIC ENERGY IN TWIN-SCREW COMPOUNDING EXTRUDERS USING ONE-DIMENSIONAL PROCESS SIMULATION Adam Dreiblatt, Century Extrusion, Traverse City, MI Eduardo Canedo, PolyTech, Campina Grande, Brazil Copyright 2016, Century Extrusion, all rights reserved Presentation outline Role of specific energy 1D simulation Energy distribution along screw axis Summary Specific (mechanical) energy Single value representing the cumulative mechanical energy for melting, mixing, conveying, pressurization Does NOT capture or differentiate between dispersive/distributive mixing Does NOT capture residence time or RTD Primary factor used for scale-up Specific (mechanical) energy – cont. Formulation specific Machine independent Influenced by operating conditions Can we reduce specific energy (e.g. energy savings) ? Why 1D simulation 1D simulation provides ‘insight’ into the compounding process yielding information not otherwise obtainable Specific energy predictions easy to validate Incremental energy consumption along screw axis can be validated (not so easy, but possible) Identify opportunities to reduce specific energy 1D Simulation example* Extruder: 70mm, L/D = 32, 1.55 D/d Operating conditions: 800 to 1600 kg/hr, 400 to 800 rpm Material: PP, MFR = 5 to 30 *PolyTech WinTXS™ Simulation Software Specific energy increases (0.108 to 0.124 kWh/kg) when increasing screw speed PP (MFR=5) @ 1200 kg/hr Although total kW increases, specific energy decreases (0.124 to 0.112 kWh/kg) when increasing feed rate PP (MFR=5) @ 600 rpm Barrel temperature has virtually no influence on specific energy PP (MFR=5) @ 1200 kg/hr, 600 rpm The influence of polymer viscosity on specific energy only appears AFTER polymer is melted…lower viscosity requires less mechanical energy to convey PP resins @ 1200 kg/hr, 600 rpm PS LDPE PA6 Specific energy is primarily a function of polymer enthalpy All resins run @1200 kg/hr, 600 rpm Essentially zero kW required in solids conveying PP resins @ 1200 kg/hr, 600 rpm The slope of this line indicates the large amount of power consumed to raise the temperature of solid polymer in the first kneading elements…up to 80% of the total kW (SME) is applied in these first kneading elements…which is WHY these elements wear so quickly! PP resins @ 1200 kg/hr, 600 rpm Extruder energy requirement What is pellet temperature approaching first kneading elements? Assumptions: - PP pellets enter machine at 25°C - PP is heated by conduction in barrel #2 (only conveying elements) - Using 70mm extruder as example, installed heater power on closed barrel = 7 kW - Heat capacity of PP, solid-state = 2.34 kJ/kg °C - Conservative estimate: all heater power conducted into polymer At 1200 kg/hr, barrel heaters only have enough power to increase temperature 9°C !! Extruder energy requirement Material: PP, Melt Flow = 5 to 30 dg/min (@230°C, 2.16 kg) Thermal properties: 2.34 kJ/kg °C (solid) 1.61 kJ/kg °C (melt @200°C) Energy to raise 1 kg PP from [25+9°C] to melting temp (160°C) = 0.082 kWh Heat of fusion (28% crystallinity) = 60 kJ/kg (0.016 kWh) Total theoretical energy for melting 1 kg: 0.098 kWh Energy to raise melt to discharge temperature = 0.021 kWh (208°C) - 0.031 kWh (230°C) Theoretical specific energy = 0.119 to 0.129 kWh/kg Assuming 95% motor and gearbox efficiency, this is 0.125 to 0.135 kWh/kg MELTING REPRESENTS 70-80 PERCENT OF TOTAL ENERGY INPUT ! Melting in kneading elements FLOW PLASTIC DEFORMATION Definition: frictional heating of SOLID polymer to raise the material temperature Melting in kneading elements FLOW RESIN MELTING Definition: adding heat of fusion for crystalline and semi-crystalline polymers Melting in kneading elements FLOW VISCOUS DISSIPATION Definition: frictional heating of MELT…dispersion starts after polymer is melted Energy distribution in melting Plastic Deformation Resin Melting Viscous Dissipation PS LDPE PA6 Melting position depends on crystallinity and enthalpy of polymer All resins @ 1200 kg/hr, 600 rpm The influence of polymer viscosity (on melting) is only seen once polymer is melted…affecting the viscous dissipation within the melting section PP resins @ 1200 kg/hr, 600 rpm The slope of these lines indicates the amount of power consumed to convey, mix and pressurize the melt. Notice slope does not change dramatically between conveying and mixing elements. PP resins @ 1200 kg/hr, 600 rpm Viscous dissipation represents the mechanical energy expended into the MELT (e.g. total kW minus melting kW) PP resins @ 1200 kg/hr, 600 rpm Replacing all mixing elements with conveying screws – virtually no change in specific energy ! PP resins @ 1200 kg/hr, 600 rpm Conclusions Up to 80% of specific energy is applied to the solid polymer to raise the temperature up to it’s melting range within the first few kneading elements. The remaining 20% of specific energy (aka viscous dissipation) is distributed along the remaining screw length - Changes in screw design after melting do not significantly affect specific energy Machine operating conditions can be optimized to minimize specific energy while maintaining compound physical properties - Minimum screw speed, maximum feed rate Can we reduce specific energy ? We cannot reduce melting energy requirement (without preheating polymer feed) There is a minimum energy required to move the melt through the machine; the only way to reduce this is to shorten the ‘wetted’ length of the extruder Do not believe claims “…this new ______ can reduce specific energy and lead to significant energy savings…” CPM Extrusion Group is a global leader in the supply of high performance twin-screw compounding systems, twin-screw extruders, replacement parts and services Century Extrusion – Traverse City, MI USA 100 Employees Sales, Service, Engineering, Manufacturing, Lab A CPM Company since 2006 Manufacturing center for CXE series twin screw extruder Manufacturing center for CX and APEX replacement parts Global engineering leadership Ruiya Extrusion – Nanjing China 130 Employees Sales, Service, Engineering, Manufacturing, Lab A CPM Company since 2007 Manufacturing center for TSE and APEX twin screw extruders 100% CPM Ownership www.centuryextrusion.com
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