Session C4 109 Disclaimer—This paper partially fulfills a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering. This paper is a student, not a professional, paper. This paper is based on publicly available information and may not provide complete analyses of all relevant data. If this paper is used for any purpose other than these authors’ partial fulfillment of a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering, the user does so at his or her own risk. TANDEM PEROVSKITE SOLAR CELLS: IMPROVING THE CAPABILITIES OF SOLAR PANELS Sydney Winner, [email protected], Sanchez 5:00, Olivia Yasser, [email protected], Sanchez 5:00 Abstract—As a society we are currently reliant on nonrenewable and unsustainable energy sources; however, recent developments in solar technology may make it a strong competitor as a sustainable energy source. Through the use of perovskite structures layered in tandem within solar cells, solar energy may be more efficient than it has ever been before. While still in the research phase, lab results of tandem perovskite solar cells are continuously improving. In fact, recent studies have shown that perovskite is the most efficient solar cell in current lab research, far beyond the efficiency of any other current photovoltaic technology. Perovskite is a unique molecular structure that, in the case of solar cells, allows photons to pass through their structure creating voltage that can be harnessed. We will address the advantages of perovskite solar cells in tandem and also explore the ethical dilemmas the use of this technology presents. We intend to show how the advantages of perovskite in both sustainability and cost efficiency far outweigh any disadvantages this technology may pose. Perovskite solar cells in tandem are a technology that could revolutionize solar energy as we know it. Key Words— Lead in Perovskite, Perovskite, Perovskite Solar Cell Efficiency, Perovskite Solar Cell Cost Effectivity, Perovskite Solar Cells in Tandem INNOVATING SOLAR ENERGY The growing need for sustainable energy has become an undeniable fact in modern society. In 2015, only 10% of the energy used by the United states was renewable and of that 10% only 6% was comprised of solar energy [1]. With the sun continuously cycling over our planet every day, why do we leave so much energy to go to waste? A large factor is that currently manufactured solar panels do not have high enough efficiency or cost-effectiveness to make them a smart purchase for the consumer. For many years, it seemed as though there was nothing to be done to improve the efficiency of solar cells, especially with the efficiency of the widelyused silicon asymptoting at 25.6% in laboratory research [2]. Thankfully a new, expeditiously improving technology has come to the forefront of solar research: perovskite solar cells layered in tandem. Perovskite solar cells offer the unique University of Pittsburgh Swanson School of Engineering 1 02.03.2017 advantage of being both cheaper to produce and more efficient as a photovoltaic technology. When layered in tandem, perovskite has the potential to deliver efficiencies far above any photovoltaic technology we have seen before. Throughout our paper, we will outline the science behind the technology to better explain the potential benefits of perovskite solar cells layered in tandem for the future of solar technology. Furthermore, we will explore solar technology as a more sustainable source of energy for the future. CURRENT SOLAR CELLS Molecular Structure of Silicon Solar Cells Crystalline silicon solar cells are the most common solar cells used in commercially available solar panels today, mainly due to their reliability and stability. Silicon is an atom that has the ability to share four of its valence electrons. This is useful for crystalline silicon solar cells because the silicon atoms are arranged in such a way that each silicon molecule connects with four other silicon atoms around it. This structure creates such a pure material that only .0001% of the atom is not silicon [3]. Unfortunately, crystallized silicon cells that are this pure are poor absorbers of light and can be dense and rigid. Because of this, manufacturers put silicon structures through a process called doping. In this process, semiconductors, in our case silicon, are doped to modulate their electrical properties. This allows researchers to separate electrons from the hole formed by the photon entering the solar cell. Furthermore, this also allows researchers to measure the amount of electricity the solar panel produces. In the doping process, dopants are used to produce the desired electrical characteristics in semiconductors, in this case, solar cells. For silicon cells, the typical dopants used are boron (ptype), which is neutrally charged, and phosphorus (n-type), which is positively charged. These impurities are put onto the silicon structures, which have different numbers of valence electrons. In Figure 1, it can be seen how the top of the cell is doped with boron and the other cells are doped with phosphorus, resulting in the ability to harness more light [3]. Sydney Winner Olivia Yasser photons. In order to obtain electricity from the light rays coming into the solar panels, photons go into the cell and bounce into the valence electrons that are present from the ptype and n-type semiconductors. Valence electrons are present in the outermost orbit of the electron cloud that surrounds an atom. Because they are so far from the positive nucleus at the core of the atom, there is less attraction between the valence electrons and the core than there is between the inner electrons and the core. Therefore, only a small amount of energy is needed for the electron to separate from the atom and travel freely throughout the solar cell. Once the electron is removed, a hole is left behind. This causes the electric field to be pulled toward the p-type semiconductor, while the hole is pulled toward the n-type semiconductor. This forces all the free electrons that were let loose from the photon to move to one side of the cell. Ultimately, this forms the electric current necessary to produce a valid source of electricity in the solar panel [4]. To further complicate this process, not all photons create a hole when the electron is set loose. Only electrons that have enough energy to knock an electron out of its place can form the hole in the solar cell. Each photon in the light waves that hit the solar panels carry a specific amount of energy in electronvolts (eV). To knock an electron out of the electron cloud around a silicon atom, it takes 1.1 eV. This is called a bandgap, which requires a different amount of energy for every type of solar cell. [4]. The process of how the band gap is formed when the photon moves out an electron is shown in figure 2. An understanding of band gaps is also essential in understanding perovskite tandem structures. FIGURE 1 [4] This shows how molecular impurities are formed through the doping process. After both the n-type semiconductors and the p-type semiconductors come in contact, the free electrons from the n-type semiconductors jump across the junction between them and fill the open spots on the p-type semiconductors. The p-type now becomes a negatively charged region because it is full the electrons from the n-type semiconductors and the n-type now becomes a positively charged region after losing its electrons. In between these two regions becomes a depleted region because it is neutral of charge, this is where the electrical field is formed. If an electron is stuck in the depleted region, it is pulled towards the positive side [3]. PEROVSKITE SOLAR CELLS Perovskite as a Mineral Perovskite is an organic-inorganic mineral that is composed of a combination of class materials with similar structures. The original form of perovskite was calcium titanium oxide (CaTiO3), the name has generalized to a whole class of materials with the same crystallized structure. The structure of the perovskite mineral is what gives the basis to the structure of perovskite solar cells. It is perovskite’s unique structure, size, and efficiency rates that make it outshine other developing technologies, such as polymer and dye-sensitized solar cells. A typical perovskite structure takes the form of ABX3, in which A and B are cations (positively charged molecules) and X is an anion (negatively charged molecule), in which A is larger than B [5]. The typical structure of perovskite generally has a cubic structure, which gives it a more stable and strong outer structure. It is created by placing the A molecule at the center, the B molecule at the corners of the cube, and the X molecules at the center of each side of the sub. This can be seen in Figure 3 [6]. FIGURE 2 [4] This shows how a band gap is formed when light photons enter the solar cell. However, this does not allow the crystallized silicon solar cell to produce electricity from the incoming light 2 Sydney Winner Olivia Yasser perovskite is 1.54 eV with the valence band (VB) at -5.4 eV and the CB at -3.9 eV.” [6]. As depicted by Figure 4, the valence band and combination band are both in line with each other in this perovskite structure which indicates that perovskite has a direct band gap. This means that all of the photons harnessed by perovskite can go directly into producing energy. If the bandgap was indirect, as depicted on the right-hand side of Figure 4 below, then energy that could be harnessed from the photons would be lost as phonons and heat. FIGURE 4 [6] This shows the difference between a direct (left) and indirect (right) bandgap in harnessing photons. FIGURE 3 [6] This shows the 2D and 3D models of the perovskite structure. The purple molecule is the A element, the black/blue is the B element, and the yellow is the X atom. Researchers at the Moscow Engineering Physics Institute recently worked on optimizing the relationship between efficiency and thickness of solar cell. The research found that efficiency and thickness were directly linked by perovskite’s band gap [6]. This optimization utilized a drift diffusion approximation based on the Possion equation, a partial differential equation that is able to be interpreted for many engineering purposes. It also related the properties of perovskite as a photovoltaic to properties of superconductors. Through these methods, it was determined that the optimal thickness for a perovskite solar cells was between 500-600 nanometers [8]. This determination is important to note because it is a relatively small number that lends perovskite its flexibility. The advantages of this flexibility are especially notable in the comparison between silicon and perovskite solar cells. In an organic-inorganic perovskite structure, the A compound typically consists of from a small monovalent (having only one valence electron) organic cation. Typical examples are methylammonium or formamidinium. The element B is always an inorganic cation from the Group 14 metals on the periodic table, such as lead (Pb), Tin (SN), or Germanium (Ge). Finally, the X element is a slightly smaller halogen anion, usually chloride (Cl-) or iodide (I-). Since a variety of atoms and molecules can be used to create the perovskite structure, the stability and properties of these solar cells are heavily dependent on what type of molecules are used. The way the electrons and molecules are aligned in its structure gives perovskite an array of properties including superconductivity and magnetoresistance [7]. The perovskite structure is extremely beneficial for use in solar cells because it maximizes the way energy is transferred and how electrons can jump across the energy gap. PEROVSKITE IN TANDEM While perovskite shows great potential for increased efficiency, the next big leap in solar cell capabilities will come from layering perovskite in tandem with small band gap solar cells. A tandem solar cell involves layering two solar cells on top of each other in various architectures in order to harness more energy and maximize efficiency. The ability to harness more energy is granted through the integration of a large band gap solar cell and a small band gap solar cell. The difference in the band gap size allows the different parts of the tandem cell to harness photons of different energy levels. This is achieved without losing energy due to heat and phonons as Perovskite Solar Cells Perovskite is particularly advantageous for its use within a solar cell. This is due to the relative simplicity of the structure while maintaining a high ability to convert light to energy. In research done on perovskite by Dr. Prasenjit Kar at the Indian Institute of Technology, it was found that, “the direct band gap of the methylammonium lead iodide 3 Sydney Winner Olivia Yasser described earlier because the bandgap is not misaligned with the energy levels. The tandem cells catch energy similar to two strainers of different fineness catching items of different sizes based on their straining holes. This allows for a greater number of harnessed photons and higher efficiency. A single junction solar cell is modeled to have an ideal efficiency of 33.7% while a tandem perovskite solar cell is modeled to have an ideal efficiency of 46.1% [2]. Figure 5 depicts both a single junction cell and a double junction cell. The figure illustrates the ability of the double junction cell to harness more energy because it harnesses the different energy level photons in different steps, allowing for the creation of both high and low voltage, instead of just low voltage in the single junction cell. Each architecture offers its own unique advantages. Mechanically stacked tandem architectures are currently the most practical to implement. The mechanical stacking process involves fabricating the top and bottom cells independently. The two cells are then assembled together into one solar cell. This is advantageous because it allows single junction solar cells to have a layer of perovskite added to it in order to create a tandem cell and boost their individual efficiencies [2]. The compatibility of the voltage limits this process. The perovskite cells to be layered in tandem can be engineered to match the current or voltage in the already existing cells allowing for smooth integration. Mechanically stacked tandem architectures are also advantageous because they allow for the separate binning of the tandem sub cells. Binning is a process of testing solar cells for a specific power class, or amount of wattage they are able to produce [9]. Since manufacturing processes aren’t always precise, a few different power classes of solar cells can come from the same production line. By sorting the solar cells through binning, manufacturers can align perovskite solar cells with manufactured solar cells of the same bin and therefore the same voltage. This allows for the smoother integration of the large and small bandgap solar cells and ultimately higher efficiency [2]. Monolithically stacked tandem solar cells promise higher efficiency potential than even mechanically stacked tandem solar cells, but require major adjustments to solar cell manufacturing facilities [2]. Spectral splitting combines the idea of both mechanically stacked tandem and monolithically stacked tandem solar cells by integrating a small bandgap bottom cell (as pictured in Figure 6) with a perovskite top cell perpendicular to the small bandgap bottom cell. Bisecting these two layers is a dichroic mirror allowing the highest theoretical efficiency of all three tandem solar cells while also creating the least practical manufacturing system [2]. Due to the impracticalities of spectrally split solar cells, we will center our focus around the application of mechanically stacked and monolithically stacked tandem architectures. FIGURE 5 [2] This shows the ability of a tandem structure to capture more energy through having two layers. Tandem Architectures The way that a tandem cell is structured can greatly affect both its efficiency and its manufacturing process. There are three main tandem architectures: mechanically stacked (Figure 6 a), monolithically integrated (Figure 6 b), and spectrally split (Figure 6 c). Perovskite in Tandem with Silicon Mechanically stacked perovskite tandem architectures offer an interesting prospect for future solar cell manufacturing. Perovskite could theoretically be layered in tandem with any small bandgap solar cell. This leads to the interesting prospect of perovskite on perovskite solar cells through the use of the theoretical small bandgap perovskite solar cell [2]. However, since this technology is not thoroughly researched, we will investigate other prospects of perovskite in tandem, specifically perovskite layered in tandem with silicon. Due to the nature of the mechanically stacked tandem architecture (i.e. the separate manufacturing of the top and bottom solar cell layers) there is a very real potential to modify currently existing silicon solar cell FIGURE 6 [2] This shows the three different types of tandem architectures mechanically stacked (left), monolithically stacked (center), and spectrally split (right). 4 Sydney Winner Olivia Yasser manufacturing plants to create perovskite silicon tandem structures with relative ease. These perovskite silicon tandem structures would have higher efficiencies than technology currently in the market. A theoretical modeling of perovskitesilicon tandem structures using AFORS HET computer simulation was conducted at Sungkyunkwan University in Korea [10]. This modeling showed an improvement of efficiency by a factor of 1.39 compared to single junction perovskite and 1.59 compared to single junction silicon [10]. The overall modeled efficiency of the tandem cell was 24.92%. This model was conducted without accounting for the use of surface texture, a very common process to improve the efficiency of solar cells [10]. This means that with the use of additional solar cell technology, like surface texture, higher efficiencies could be achieved then the one modeled even up to 46.1% as predicted by researchers at Stanford University [2]. Another modeling of perovskite, which was published in IEEE’s Photovoltaic Specialist’s Conference looked at the factor that could cause a reduction in efficiency in the realworld implementation of perovskite silicon tandem solar cells when monolithically stacked. The study found that temperature, spectral irradiance distribution, and angle of incidence are the largest factors in the efficiency reduction in the real-world application of tandem solar cells. However, these factors only reduced the energy yield, or energy produced by the solar cell, by 4.5% [11]. With further technological innovations, the effect of real world factors on efficiency, and consequently energy yield, could be reduced. However, this study shows that while real-world factors may affect the operation of perovskite silicon tandem solar cells, it is not completely detrimental to their application. This would allow for real-world implementation of perovskite silicon tandem solar cells to begin in the near future, manufacturers allowing. chemical reaction with water. This leads to major degradation problems, including breaking down the bonds in the perovskite’s structure. As a result of these issues, perovskite researchers have found that perovskite devices may require thicker light-harvesting layers that would shelter the molecules from UV lights and moisture [5]. While adding a thicker layer would provide protection for the molecules, this would require more changes in the manufacturing facilities and would likely increase the cost of production. The Use of Lead In the ABX3 structure, the B element can have multiple Group IV elements in the divalent oxidation state; however, as the atomic number of these elements decreases, the stability of the structure decreases. As explained earlier, there a multitude of molecules that can be used as the B element. Among these, Pb is the most beneficial to perovskite’s stability because it has the highest atomic number in the Group IV elements of the periodic table. Research has shown that the best solar performances come from molecules with higher atomic number because their radius is the largest and it takes less energy for photons to create band gaps when the solar cells absorb light. Although lead is one of the many solutions to perovskite’s structural stability, it causes major concern for potential environmental issues. Exposure to lead can cause detrimental health problems ranging from reproductive damage to cardiovascular issues to developmental diseases neurologically. For reasons such as these, lead was reduced in everyday objects and its concentration in society was brought down dramatically. The presence of lead in perovskite devices can be as damaging as lead being present in water pipes. Solar panels are built to withstand most degradation and decomposition; however, when exposed to precipitation lead could seep out into its surroundings. As explained by the Journal of Physical Chemistry, when a typical perovskite composition comes in contact with water, decomposition takes place. For instance, if methylammonium lead iodide is reacted with water, it decomposes to a simpler molecule and leaves lead iodide behind. When this compound is left behind it can be dangerous because the remnants of lead could find its way into the liquid waste of the solar panels and spread toxins into its surrounding area [13]. With lead being present in perovskite, there are many risk factors to the environment and the areas surrounding the solar panels. Although this is a setback to the development of perovskite devices, researchers have come up with some solutions that may better perovskites effect on the environment. The production of lead from raw ores can produce toxic residue and spread harmful chemicals into the environment [13]. However, using recycled lead from old car batteries can divert toxic materials from being spread. A ETHICAL DILEMMA Lifespan and Stability As with many new developing technologies, there are some ethical dilemmas that are casting a shadow over the development of perovskite solar cells. In perovskite’s current stage of research the only major unknown is the stability and lifetime of the devices as they operate. Research studies have shown that the devices exhibit specific degradation mechanisms and sensitivity to heating, UV illumination, and moisture [12]. During UV exposure, the light absorption of perovskite devices start to decrease because the individual materials that make up perovskite start to lose some of their abilities, such as conductivity, after 200 hours of UV exposure. This would affect perovskites long term ability to be efficient. Moreover, when perovskite is exposed to moisture, the chemicals in its structure tend to hydrolyze. Hydrolyzing is the chemical breakdown of a compound by a 5 Sydney Winner Olivia Yasser research team from MIT has been studying the effects of using old batteries in perovskite technology [14]. The team’s analysis shows that by using a single old car battery, it could fuel enough solar panels to provide for 30 households [14]. Moreover, the way the battery would be layered into the solar cells would protect it from precipitation that would leak lead into the surrounding areas [14]. These solutions greatly reduce the risk of using lead in the solar cells. Another solution that is currently being researched is using tin as a replacement for lead. Most of the current studies on solar cells are based on lead perovskite materials because, as of now, they are the most efficient way to convert sunlight directly into lead. For the first time, researcher at Northwestern University just successfully employed a tinbased perovskite that would provide a low-cost, environmentally friendly, and comparably efficient solar cell. The only setback with this solution is how it might change the overall stability of the perovskite structure [15]. Hopefully upon further research, this may be a viable option in the future. solar cells on the market. This shows a good outlook for a future of clean and renewable energy. Cost of Production Currently, the production of crystallized silicon solar cells is a long and complex process. Silicon is such a pure molecule that when manufactured into a crystallized structure for solar cells, needs to go through a doping process to create imperfections. This allows for photons to create band gaps when the light is absorbed through solar panels. Furthermore, traditional solar cells require high temperatures to purify their silicon bases during the doping process. This additional requirement is both costly and time consuming which largely decreases the value of using silicon-based solar cells in solar panels [16]. However, the production of perovskite is quite the opposite of the silicon solar cells. To create a perovskite solar cell, it is a simple and short process. MIT News details perovskite’s ability to be blended at a lower temperature, which allows manufacturers of perovskite to cut out the costs of heating silicon. Furthermore, since perovskite solar cells are not composed of pure materials, they do not require the same doping processes that traditional solar cells need. There are already many imperfections within perovskite structures that allow for a shorter and less costly doping process [14]. Perovskite’s ability to be blended at lower temperatures and the fact that is does not need to be doped removes many of the production costs associated with solar cells. The production of perovskite would be financially beneficial to the manufacturers of solar panels. COST & EFFICIENCY Efficiency When perovskite was initially discovered and put into solar cells in 2008, it had a mere efficiency rate of just 3.8%. At this time, there had not been enough research on perovskite and it had not been engineered using the molecules it needed to give it a proper structure to capture sunlight and convert it to energy. By the time it was introduced to the market in 2012, it had a small, yet increased efficiency of 10%. This was surprisingly high for the minimal amount of engineering and research perovskite had, especially considering that many other materials tested for use in solar cells leveled off at an average solar energy capture efficiency of 14%. Most notably, however, was, at the beginning of this year when perovskite solar cells jumped to an extremely high performance efficiency of 22%, which matches the performance of current silicon cells [16]. Due to this sudden spike of efficiency from perovskite solar cells, the interest in research in sustainable energy has greatly increased. Many research laboratories and technology developers have started to shift their interests from renewable energy, to cost effective sustainable energy. This shows a good future for developments of new sustainable energy research and technology. Furthermore, many scientists have “even suggested that a layer of perovskite with silicon could lead to an un-imagined 44% efficiency as early as 2017. Even a double-stack, layering perovskite on top of each other could increase the efficiency to 30%, without the need to combine it with other materials already in existence” [16]. This has a significant impact on the future of sustainable energy. These prospective numbers are almost unheard of with the current SUSTAINABLILITY Fossil Fuels Nonrenewable energy sources, such as fossil fuels, are overall the primary source of energy in the world. In the United States, fossil fuels make up 81.5% of the energy consumption [17]. However, there is a finite amount of fossil fuels available for use in energy production. At the current rate of discovery and usage of fossil fuels, it is predicted the world will run out of available fossil fuels in the next 100 to 200 years [18]. Due to this fact, our current usage of fossil fuels for energy is not sustainable. Additionally, due to the increase in demand and usage of fossil fuels, there has been a worldwide increase in carbon dioxide emissions. As detailed in a Forbes article, “carbon dioxide emissions in 2015 were 36 million metric tons higher than in 2014, and marked the 6th straight year a new record high has been set” [19]. This increase in carbon dioxide emissions shows that fossil fuels are unsustainable due to their environmental impact. Carbon dioxide emissions are harmful to the environment because they trap additional solar energy in the atmosphere, leading to adverse effects. These effects include shrinking water 6 Sydney Winner Olivia Yasser supplies, an increase in severe weather, changes in food supply, and geographical changes [20]. All of these changes lead to damage in our natural environment. In turn, the resources we rely on from our planet become less sustainable. Even more alarmingly, some of these changes have direct and impending impacts on the sustainability of human life. As reported by the environmental protection agency, “in many areas, climate change is likely to increase water demand while shrinking water supplies” [21]. This could have a huge impact on farming and manufacturing as well as on supplying water to the general public. Due to these complications, fossil fuels are not sustainable in both a long-term usage and from an environmental impact perspective. The best chance we have at a long-term sustainable resource is renewable energy. We will examine the particular sustainability advantages of solar technology. As compared to fossil fuels, solar energy is more environmentally friend source of energy. Our traditional source of energy, fossil fuels, are the leading contributor to decreased air quality because they release carbon dioxide and methane emissions. Comparatively, solar cells release no harmful gasses into the atmosphere. The current amount of solar technologies currently installed in the United States is expected to offset about 16.8 million metric tons of carbon dioxide that would have been produced from the use of fossil fuels [23]. Furthermore, solar panels are more environmentally friendly toward water sources. Typical power plants, natural gas or coal facilities, require water to cool down their facilities. With the use of solar energy, there is no need for water to be used and, therefore, no water pollution [23]. Solar technologies are both more cost effective and environmentally friendly than traditional energy sources. Because of this, they are more beneficial for society and are more sustainable. However, the sustainability of solar panels will always need to be further developed and it can further improved when perovskite technology is added into the solar cell. As detailed throughout this paper, perovskite tandem technology in solar cells is both more cost efficient and harnesses more energy. With the potential addition of perovskite to mainstream solar panel technology, solar energy will only become more sustainable both in longevity and for the environment. Solar Technology As can be seen throughout this paper, the use of solar energy has been increasing throughout the years. This solar energy transformation is happening due to the economic advantages of solar technology and the positive impact it has on the environment. This makes these technologies more sustainable and appealing to society. At the end of 2016, solar panels were deemed to be the cheapest form of electricity. The Solar Investment Tax Credit has shown that in the last decade, solar power installations have experienced a growth rate of 60% [22]. Moreover, the cost to install solar technologies has dropped over 60% in the last decade. As seen in figure 7, the cost of installing solar technology is dropping as the installations of solar technology is increasing [22]. This cost improvement has led to the solar industry expanding into new markets and research companies to advance solar technologies, which makes it more sustainable and beneficial for society. For example, more research has been funneled into perovskite development because of the expanding solar industry. PEROVSKITE SOLAR CELLS FOR A RENEWABLE FUTURE Perovskite solar cells have the potential to create a breakthrough in the solar energy industry through their simple manufacturing process, low cost production, and their ability to be layered in tandem to improve the efficiencies of preexisting small band gap photovoltaics. As the unique perovskite structure creates a large band gap for harnessing more photons, perovskite is one of the most efficient solar cells being researched and its efficiency is only climbing with each new development. The spark of research in photovoltaic technologies due to perovskite creates hope for the field of sustainable engineering in general. With more bright minds working on perovskite solar cells, it becomes more and more likely that the breakthrough necessary to get perovskite to mass manufacturing will be achieved. Through investing in and implementing the use of perovskite solar cells layered in tandem in future solar technology, solar has the potential to become more affordable and efficient. Solar energy is a source of energy that is sustainable in both availability and environmentalism. These benefits have created a sustainable energy source that could rival the unsustainable fossil fuels we are currently dependent on. Perovskite tandem solar cells provide the potential for a sustainable energy future. FIGURE 7 [22] The growth of solar energy going down vs. the installations of solar energy 7 Sydney Winner Olivia Yasser Conference. 2016. Accessed 2.22.17 http://ieeexplore.ieee.org.pitt.idm.oclc.org/xpls/icp.jsp?arnu mber=7749896 [12] Panarina, N. “Stability Issues of the Next Generation Solar Cells”. Advances Science News. 4.26.2016. Accessed 2.3.2017. http://www.advancedsciencenews.com/stabilityissues-next-generation-solar-cells/ [13] B. Hailegnaw, S. Kirmayer, E. Edri, G. Hodes, D. 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Conference Record of the Twenty-Ninth IEEE Photovoltaic Specialists Conference. 2002. Accessed 2.24.2017. http://ieeexplore.ieee.org/document/1190548/?part=1 [10] M. Iftiquar, J. Yi. "Investigation of high efficiency methyl ammonium lead halide perovskite-Si tandem solar cell". 3rd International Workshop on Active-Matrix Flatpanel Displays and Devices. 2016. Accessed 2.23.2017. http://ieeexplore.ieee.org.pitt.idm.oclc.org/document/754368 2/ [11] B. C. Duck et al. “Energy yield potential of perovskitesilicon tandem devices”. IEEE 43rd Photovoltaic Specialists 8 Sydney Winner Olivia Yasser ACKNOWLEDGEMENTS We are very grateful for each other for our teamwork and hard work throughout this process. We would also like to thank our Engineering 11 professor Dr. Karen Bursic. We owe a lot of thanks to our conference co-chair Emelyn Haft, without whom our paper would not have been possible. Finally, we would like to acknowledge our writing instructor Ms. Emelyn Fuhrman for her invaluable insights on our assignments. 9
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