Unit 3 Periodic Properties - Lewis Structures and Ions Name:_________________ Pd:___ Answer the following questions: 1. How do you determine the number of valence electrons for an atom? 2. How many valence electrons do each of the following atoms contain? Potassium: Sulfur: Silicon: Calcium: Stability Full energy level - _______________________ Full sublevel (s, p, d, f) - __________________ Half-full sublevel _______________________ Electron Configuration Exceptions - Copper o Expect - ___________________________ o Actual - ___________________________ o Copper (all the other elements in its group) gains ________________ with a full dsublevel - Chromium o Expect - ___________________________ o Actual - ___________________________ o Copper (all the other elements in its group) gains ________________ with a full dsublevel Practice 1 • What is the electron configuration for the element Gold? Practice 2 What electron configuration for Carbon would provide the atom with most stable configuration? a) 1s2 2s2 2p2 b) 1s2 2s1 2p3 c) [He] 2s2 2p2 d) [He] 2s2 2p3 In what way does this provide the atom a more stable configuration? Lewis Electron Dot Structures • Use Valence Electrons (_________________ ___________________). • There can be as many as _____ valence electrons (______ from _____ and _____ from ____) • Use a _____ to represent each valence electron. • For example: Chlorine Name:________________________ Date:_____________________________ Pd:___________ Write the # of valence electrons and the dot diagram for each element: 1. Li 2. S 3. Ba 4. Sn 5. At 6. Si Ion- Atom’s which either ___________ or ____________ _____________________. - They do this to become more stable. - They become ISOELECTRONIC: - This is called the OCTET RULE: Fluorine ______ an electron and becomes _______ charged Sodium _____an electron and becomes ___charged F + e- F- Na Na+ + e- Practice 3: Fill in the table below for each element: Element Sr I In Total # Valence Electrons Closest Nobel gas to become isoelectronic with Will this element gain or lose electrons? How many electrons will it gain or lose? What is the new charge of the element? Is this a cation or anion? Name:________________________ Date:_____________________________ Pd:___________ Po Fr Fill in the chart below pertaining to Cations and Anions: Cation Anion Use your periodic table to help ______________________________ is the name given to the coulombic attraction in chemistry – It is the pull that an electron “feels” from the nucleus. Name:________________________ Date:_____________________________ Pd:___________ The closer an electron is to the nucleus, the more pull it feels. As effective nuclear charge increases, the electron cloud is pulled in tighter. (-) Electrons attracted to (+) nucleus 3 factors that effect this The more protons in the nucleus, the greater the Zeff The more distance between the nucleus and electrons the smaller the Zeff ______________________________________________________ _____________________________________________________ ______________________________________________________ The effective nuclear charge can be estimated from • • • Zeff = effective nuclear charge Z = # of protons (nuclear charge) S= shielding electrons (core electrons) Electron Shielding CORE electrons are closer to the nucleus and therefore have a stronger attraction to the positive nucleus. This “shields” valence electrons from feeling as strong of a pull from the positive nucleus. Examples: What is the effective nuclear charge for a valance electron of oxygen? What is the effective nuclear charge for a valance electron of fluorine? What is the effective nuclear charge of an electron in the third energy level for the element potassium? What about the fourth energy level? Cation is SMALLER than parent element because: Anion is LARGER than parent element because: - Name:________________________ Date:_____________________________ Pd:___________ Lewis Dot and Periodic Trends Wrap Up Classwork: Element Valence Electrons Ion with charge Equation for formation of ion (showing arrow and electrons) Ion Bigger or smaller than parent atom? O F Be Al K Br Explain the relationship between parent atoms and their ions - first find out how many valence electrons and then show how they will be gained or lost. Then indicate if the parent atom or the ion will be larger and explain WHY! 1. Na 2. Ca 3. F 4. O
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