Warm Up Watch the Demo of Copper with Nitric Acid. List several evidences for chemical reaction. Chemical reactions are everywhere! Chemical Reactions: the process by which the atoms of one or more substances are rearranged to form different substances. Atoms are rearranged during the flash of lightning! Chemical Equations Reactants Products Reactants: starting substances Products: substances formed during the reaction *Shows the direction in which the reaction progresses. * means “yield” or “react to produce” Chemical Equations Symbols are used to show the physical states: solid(s), liquid(l), gas(g). “aqueous” (aq) substance is dissolved in water The Language of Chemistry Write the chemical equation that corresponds to the following reactions Example 1. Solid calcium oxide reacts with water and yields calcium hydroxide solution. 2. Zinc metal reacts with a hydrogen sulfate solution to produce a zinc sulfate solution and hydrogen gas. 3. A potassium bromide solution reacts with chlorine gas to produce a potassium chloride solution and bromine gas. Warm Up Write a balanced chemical equation for the following demo. Isopropyl alcohol (CH3)2CHOH when ignited (Oxygen gas) combusts to form Carbon dioxide gas and water. Observing and Predicting Reactions How do we know whether a reaction occurs? What clues does nature offer? Make a list. What clues does nature offer that a chemical reaction occurred? ppt crystal color gas fumes smoke temperature flames magnetic sound light solid decomp explosion solid dissol. odor elect. cond. pH change density electricity Moving On Go to next topic Precipitate Formation Ag+ + Cl- AgCl Cr3+ + 3OH- Cr(OH)3 Ba2+ + CrO42- BaCrO4 return Solid Decomposition (NH4)2Cr2O7(s) Cr2O3(s) + 4H2O(g) + N2(g) CuSO4.5H2O CuSO4 + 5H2O(g) 2NI3 N2 + 3I2 return Gas Bubbles Ca + 2H2O Ca(OH)2 + H2(g) Cr + 2H+ Cr2+ + H2(g) Mg + 2HCl MgCl2 + H2 return Fumes/Gas Formation Cu + 4HNO3 Cu(NO3)2 + 2NO2 + 2H2O 2H2O2 2H2O + O2 Zn + I2 ZnI2 return Smoke 2Al + 3Br2 2AlBr3 2Na + Cl2 2NaCl P4 + 5O2 P4O10 return Flames 2Na + Cl2 2NaCl 2CrO3 + 3C2H5OH Cr2O3 + 3CH3CHO + 3H2O return Light 2Fe + 3O2 Fe2O3 2CH3OH + O2 2CO2 + 4H2O 2H2 + O2 2H2O return Temperature Change Ba(OH)2.8H2O + NH4Cl Thermite: Al + Fe2O3 return Color Change Cl2 + 2I- 2Cl- + I2 Cu + 4HNO3 Cu(NO3)2 + 2NO2 + 2H2O return Crystal Formation/Solid Deposition Cu + 2Ag+ Cu2+ + 2Ag Zn + Sn2+ Zn2+ + Sn return Solid Dissolution Mg(OH)2 + 2HCl MgCl2 + 2H2O AgCl(s) + 2NH3(aq) Ag(NH3)2+ + Cl- return Sound Oxidation of sugar Fireworks return Explosion Dynamite Building Demolition Whale Removal return Odor Certain molecules, especially those containing sulfur or nitrogen, have distinctive odors. return Electrical Conductivity Ba(OH)2 + H2SO4 return Density/Volume Sugar + H2SO4 return pH Change return Magnetic Properties Fe + S8 return Generate Electricity Chemical reaction in the battery return Lab- How do we know what gas is being produced? Demo- Gas Collection by Water Displacement Minimum of two trials of each reaction Work as pairs within your groups While others are testing draw apparatus and write the general procedures Lab- How do we know what gas is being produced? Experiment 1 Zinc metal reacts with hydrochloric acid to produce hydrogen gas and zinc (II) chloride. Experiment 2 Dihydrogen dioxide in the presence of the catalyst sodium iodide decomposes to produce oxygen gas and liquid water. Lab- How do we know what gas is being produced? Experiment 3 Calcium Carbonate reacts with hydrochloric acid to produce a gas. What gas is it? Design an experiment to identify the gas produced. Include predictions. Get it signed off before you begin If…and…then… If(hypothesis) and(test) then(prediction) If all chemistry students have memorized the element names and symbols and they are asked to the name or symbol for any element then every student will answer every question correctly. Lab- How do we know what gas is being produced? What did you learn from Experiment 3? What gas is being produced? Lab- How do we know what gas is being produced? Experiment 4 Can we confirm this some other way? Group Quiz 1. 2. 3. 4. Hydrogen gas reacts with oxygen gas to produce water Carbon monoxide gas reacts with oxygen gas to yield carbon dioxide gas. Liquid dihydrogen dioxide decomposes to produce water and oxygen gas. A calcium hydroxide solution reacts with a hydrogen sulfate solution to produce a calcium sulfate solution and water. What do all Chemical Reactions have in Common? All Chemical Reactions obey the Law of Conservation of Matter Nothing can be created or destroyed. (What goes in must come out.) 4 main types of chemical reactions Synthesis or Combination Decomposition Single Displacement Double Displacement Types of Chemical Reactions Combination reaction • • A + B AB Ex. metal + oxygen metal oxide 2 Mg (s) + O2 (g) 2 MgO (s) Decomposition Reaction AB A + B Ex. salt metal + nonmetal 2 NaCl (s) 2 Na (s) + Cl2 (g) Single-Displacement Reaction A + BC B + AC or A + BC C + BA Ex. metal + acid hydrogen + salt • Zn (s) + 2 HCl (aq) H2 (g) + ZnCl2 (aq) Ex. metal + salt metal + salt • Fe (s) + CuSO4 (aq) Cu (s) + FeSO4 (aq) • Double-Displacement Reaction AB + CD AD + CB Ex. acid + base salt + water • HCl (aq) + NaOH (aq) NaCl (aq) + H2O (l) Can you Classify the following picture reactions? 1 2 3 4 4 Types of Reactions Synthesis Decomposition Single Displacement Double Displacement Some Practice Write as many chemical reactions as you can think of using the following atoms and molecules as reactants. Practice Word Equations and reaction types identification Classification of Chemical reactions Individual Classify each type of reaction Group Quiz Work as a group to write word equations for each of the reactions Classification of Chemical Reactions Examples 1. 2H2 + O2 2H2O Hydrogen reacts with oxygen to produce water. 2. 2H2O 2H2 + O2 Water decomposes to produce hydrogen and oxygen Balancing Equations Coefficient – the whole number out front of the formula- tells you how many of each molecule Subscript – small number to the bottom right of an element- tells you how many atoms of that element are in the molecule. Balancing Chemical Equations 1. 2. 3. 4. Write a formula equation with correct symbols and formulas. Count the number of atoms of each element on each side of the arrow. Balance atoms by using coefficients. Check your work by counting atoms of each element. Balancing Chemical Equations Practice Problems Sodium hydroxide decomposes to produce sodium oxide and water. Iron reacts with oxygen to produce iron(III) oxide. Round Table – Balancing Chemical Equations 1. 2. Balance the Equation Write a complete sentence for each reaction including (atom/molecule) references to the coefficients. Team Iron can be obtained by reacting the naturally occurring ore hematite, Fe2O3, with carbon. The carbon is converted to CO2. Write a balanced chemical equation for this reaction. Helpful info Sulfuric Acid- H2SO4 Ammonia- NH3 Carbonic Acid - H2CO3 Hydrofluoric Acid – HF Phosphoric Acid – H3PO4 Law of Conservation of Mass Balancing synthesis and Decomposition Reactions Counting atom amu– atomic mass unit Predicting Products Identify the type of reaction Write the products of the reaction Balance the equation Example. 1. Cl2 + KI 2. FeCl3 + NaOH Single Displacement: Cu + AgNO3 Lab – Types of Reactions 9 experiments Work at an open station Demo Copper and Silver Nitrate Predicting Products Being able to write a chemical equation does not necessarily mean that the reaction will take place. There is a way to predict whether a reaction will occur and what the products will be. The Activity Series of Metals Predicting Products The Activity Series Matter tends to react in such a way that more reactive substances form less reactive substances. Activity series: a list of metals organized according to their tendency to react. Activity Series The higher the metal on the activity series, the more active that metal. The more active elements tend to be more stable in a compound than in elemental form Predict whether a reaction occurs Practice Pb + MgCl2 Al + Cu(NO3)2 Group Quiz Na + H2O Ca + Fe(NO3)2 Ag + Mg(NO3)2 Zn + Cu(NO3)2 Objectives Students will review types of chemical reactions. Students will investigate the law of conservation of matter and its effect on chemical equations. Students will learn to balance chemical equations
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