Effect of room air change rate and room configuration on airborne and surface concentration of pesticides released from vaporisers devices C J Saunders, P Johnson, J Wheeler, M Coldwell Health and Safety Laboratory [email protected] ISO 9001:2000 www.hsl.gov.uk an agency of the Health & Safety Executive Outline of presentation • • • • • Background Reasons for the study Objective Type of pesticide vaporiser devices Measurements of ventilation rates in hotel rooms • Measurements of pesticide concentration in a test room • Emission rates and air concentration prediction • Conclusions Background • Malaria is present in over 100 countries • Affects 100 million people worldwide • Resulting in approximately 2 million deaths each and every year • Consequently a lot of effort has been put into effective methods of killing the mosquito Why carry out the study? • In the UK use of non-agricultural and amateur pesticide products comes under the remit of HSE Biocides Unit • Approval by HSE leads to a ‘product license’ • To approve a license HSE needs to consider efficacy, toxicological, environment and human exposure • For the plug in devices HSE had no exposure data • Data available based on models - no experimental data in published literature Main objective • Investigate the effect of various parameters on the airborne and deposition concentrations of pesticide typically generated from mosquito devices • Not the intention to look at the risk from pesticides Pesticides for indoor use • Two types of electric plug in devices – Impregnated mat – Liquid system • Both use pyrethroid insecticide – Relatively low toxicity, when compared to other pesticides Types of pesticide devices • Impregnated mat (Bioallerathrin 40 mg on each mat) • Mat slots under grill • 6 W heater • Measured interface temp ~ 130oC • Lasts 8 –10 hours Types of pesticide devices • Liquid (Prallerthrin, 0.87 % pesticide in a liquid suspension) • Liquid is wicked by capillary action • 7 W heater • Measured interface temperature ~ 170oC • Lasts up to 45 nights • But use for only 12 hours per day Ventilation rates in Hotels rooms • Two international hotel chains approached • One hotel from each chain selected • 3 rooms selected in each hotel • Measured air change rates using tracer gas technique Ventilation rates in Hotels rooms Hotel A B Test room Room dimensions LxWxH (m) Approximate room volume (m3) Measured air change rate 6.3 x 3.3 x 2.3 48 1.3 5.6 x 3.5 x 2.3 45 2.2 6.3 x 3.3 x 2.3 48 0.8 7.1 x 3.5 x 2.5 61 1.0 7.0 x 3.8 x 2.5 67 0.4 Complex geometry 55 4 x 4 x 2.7 43.2 1.3 4.4* 0.05, 0.5, 3 * Window open View of actual room Device Different furniture configurations Table Bed Chair Supply Supply Extract Chair Extract Bed Room configuration 2 Device Table Device Table Room configuration 1 Room configuration 3 Chair Bed Supply Device Extract Test programme Test 1 Room configuration 1 Air change rate 0.05 2 2 0.05 3 3 0.05 4 1 0.5 5 2 0.5 6 3 0.5 7 1 3 8 2 3 9 3 3 Study design Device Effect of air change rate on deposition (Liquid) Prallethrin Surface Deposition air change 0.05 air change 0.5 air change 3.0 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 Position Average Floor 4.1 Floor 3.1 Floor 2.1 Floor 1.1 Average Table 3.1 Table 2.1 Table 1.1 Average Bed 3.1 Bed 2.1 0.0 Bed 1.1 Ave Concentraion ng cm-2 4.5 Air concentration for different room configuration (Liquid) Prallethrin Concentration ( µ g m-3) 8.0 6.0 1 2 4.0 3 2.0 0.0 Bed Table Static (seated) Static (Head) Position Air concentration at different BZ heights (Liquid) Prallerthrin Concentration ( µ g m-3) 14 12 10 0.05 ach 8 0.5 ach 6 3 ach 4 2 0 0.84 (Bed) 1.15 (Seated) Height (metres) 1.6 (Standing) Prediction of airborne concentration • Airborne concentration independent of room position • This means that the pesticide over the period of the test is uniformly distributed • To predict airborne concentration we need emission rate measurements Emission rate for the liquid device Prallerthrin Weight loss of pesticide (mg) 8 7 6 5 4 3 2 Emission rate 0.85 mg h-1 1 0 0 2 4 Time (hours) 6 8 Predicted concentrations for liquid device Prallerthrin 0.05 ach 0.5 ach 3 ach -3 Concentration (µg m ) 150 100 50 Emission rate 0.85 mg h-1 0 0 1 2 3 4 Time (hours) 5 6 7 8 Applying a correction factor ach Mean Predicted airborne conc. airborne conc. (µg.m-3) (µg.m-3) 35 ng.cm-2 74 157 0.5 4.1 29.7 Correction factor of 0.138 ach Mean Cor. Predicted airborne airborne conc. conc.(µg.m-3) (µg.m-3) 0.05 11 9.6 0.5 4.1 4.1 1 0.9 3 85 9.6 Device Main conclusions • Air change rate significantly affects the concentration of pesticides, both in the air and on surfaces • No significant difference in airborne concentration of pesticide with height - both devices • Surface conc. on the bed and table similar and higher that floor – both devices • Possible to use emission rate (with a correction factor) to predict pesticide air concentration for other air change rates – but not room sizes Thank you for listening
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