Application Note Advantages of Cutting and Perforating Plastics with a 10.2 µm Wavelength CO2 Laser CO2 lasers offer numerous advantages over traditional mechanical methods for cutting, scoring and perforating of the plastic films and other flexible materials widely used in the packaging of food and other consumer goods. While lasers operating at the traditional CO2 wavelength of 10.6 µm are most commonly used for these applications, CO2 lasers with output at 10.2 µm have proven to deliver higher processing speeds and superior results with certain plastic materials, in particular, polypropylene and bi-axially oriented polypropylene (BOPP). This document provides some background and context on laser processing in general, and presents specific applications results for processing at 10.2 µm. Modern Food Packaging Increasing consumer demand for high quality and freshness in packaged foods have led to some very sophisticated packaging techniques based around the use of plastics and plastic films. For example, perishable items and baked goods are often sealed in flexible plastic films, which may themselves consist of multiple layers of different materials. These material combinations are engineered to deliver the optimum combination of physical strength and handling characteristics (to withstand production and transport to the consumer), to provide a barrier to moisture and oxygen (the prime contributors to product spoilage), and to optimize printability (in order to support attractive and eye catching graphics). The single layer films used for wrapping items such as cookies and candy usually consist of polypropylene, typically in the 30 to 100 µm thickness range. Polypropylene is also often a very significant component in multilayer films. Frequently, this material is thermally extruded from a homopolymer, and is then stretched, or “blown,” in two directions, normal to each other, to improve strength even further. This material is known as bi-axially oriented polypropylene (BOPP). BOPP, and the other plastic films, papers and foils used to create packaging, are typically supplied in the form of large rolls. These rolls are mounted onto www.Coherent.com I [email protected] I machines which continuously unroll webs of film and transform them into individual, finished packages. This process often requires that the material be cut, slit, perforated or scored (cut to a finite depth, rather than completely through) while it is moving through the machinery. Laser Processing Advantages Traditionally, mechanical means, such as blades and punches have been employed to perform converting processes such as cutting and perforating. However, lasers are now replacing mechanical tooling for several reasons. First, non-contact laser tools do not wear over time. This eliminates the need to stop machinery in order to replace cutting tools, and also delivers results which are consistent over time. Additionally, laser converting enables high precision control over scoring depth and micro-perforation hole size, both of which are extremely hard to achieve with mechanical tooling. Non-contact laser processing also doesn’t impart any force to the plastic films which could distort or tear them. Laser processing is cleaner than mechanical methods. Specifically, it produces very little dust and debris, and leaves a very clean, processed edge. Cutting debris can be problematic because it settles on other parts of the machinery, and can affect their efficiency. For example, debris which lands on print rollers or pads can degrade graphics reproduction. Another significant advantage of laser processing is its flexibility. Laser cutting parameters are varied simply by changing values in software, making it easy to switch between jobs, or to individualize packaging on the fly. Furthermore, these changes don’t incur any tooling or setup charges. The web processing equipment used for packaging converting often runs at speeds of up to several hundred meters per minute. Laser converting is fast, making it compatible with the speed of existing production lines. In addition, several manufacturers produce laser-based tools that can easily be integrated with existing converting equipment. (800) 527-3786 I (408) 764-4983 1 Why 10.2 µm? In order to accomplish CO2 laser processing, the laser beam is focused down to a small spot on the workpiece. The laser energy is absorbed by the material, causing it to heat up above its melting point. The resulting molten material is then cleared away by either a gas jet or the induced vapor pressure to form the kerf. Galvanometer mirror scanners are used to sweep the laser beam over the surface of the plastic film in order to produce the desired processing pattern. The laser is directly modulated (on/off pulsing) in order to stop and start laser processing as needed, as well as to change overall output power in order to vary the depth of processing when scoring. Most polymer films have an infrared absorption spectrum that consists of numerous sharp peaks. Consequently, small shifts in laser wavelength can have a dramatic impact on absorption efficiency. Since flexible packaging involves very thin films, these films often only absorb a small percentage of the incident laser power, in contrast to applications such as metal cutting where all the laser power is typically utilized. For this reason, increasing the absorption coefficient of the thin film(s) by optimizing the laser wavelength can dramatically increase the processing speed and efficiency for a given laser power level. Polypropylene and BOPP, in particular, have been found to have significantly greater absorption at 10.2 µm, rather than the traditional 10.6 µm output of the CO2 laser, making it sometimes advantageous to work at this shorter wavelength. Absorption of BOPP at 10.2 µm and 10.6 µm Thickness (µm) Absorption (%) P orientation T orientation 58.6 83.7 50 λ = 10.2 µm λ = 10.6 µm 100 18.5 18.5 180 92.4 92.4 50 7.0 14.7 100 28.5 28.5 180 46.2 46.2 Figure 1. The 10.2 µm wavelength delivers significantly higher cut speeds with polypropylene for film thicknesses below 100 µm. Cut speed (m/s) Polypropylene Cut Speed 6.0 4.0 Applications Results The Coherent applications laboratory has investigated the processing of plastic films at 10.2 µm under a variety of process conditions. Some of the most significant results are presented in this section. Hole drilling in 30 µm thick BOPP film The production of large numbers of small diameter (~50 µm) through-holes is critical to packaging techniques such as micro-perforating for fresh produce. In this case, the small holes yield a breathable package that avoids the build-up of anaerobic conditions leading to product spoilage. Precise control of hole size is necessary in order to provide the precise oxygen transmission rate (OTR) for a specific application. This study compared hole diameters that can be readily achieved using 10.2 µm and 10.6 µm CO2 lasers (both from the Coherent GEM series). Specifically, a series of single shot drilling trials were performed with both lasers on 30 µm thick BOPP film. For the 10.2 µm laser, it was possible to fully perforate the film and create a 45 µm diameter hole with a 15 µs pulse, having a pulse energy of 150 µJ. In contrast, the smallest hole that could be achieved using a 10.6 µm laser and similar optics was 60 µm in diameter. And, this required a pulse energy of 1.7 mJ, a tenfold increase in pulse energy. The ability to completely pierce through the film with a short duration pulse is essential in this application because of the high web speeds. For example, at a web speed of 5 m/s, a 50 µm hole drilled in 20 µs becomes an ellipse that is 100 µm long. This increase in area can raise OTR’s to unacceptably high levels. Hence, shorter pulsewidths enable the production of smaller diameter holes or ellipses without the need for complex scanning systems to compensate for web movement. The 10.2 µm drilled holes produced in this testing were very clean, with some re-melted reinforcement of the hole. Plus, the pulse duration necessary to drill these small holes is short enough such that, at normal web speeds, no significant ‘stretching’ of the hole occurs along the direction of travel. 10.2 µm 10.6 µm 2.0 0.0 25 75 125 Film thickness* (microns) www.Coherent.com I 175 [email protected] *only <50 µm film oriented I (800) 527-3786 I (408) 764-4983 2 Cutting 4 in x 2 in labels from 95 µm thick, white polypropylene film The goal of this test was to prove that a CO2 laser operating at 10.2 µm can cut 95 µm thick polypropylene film at a high speed and with a clean edge. Processing parameter summary Material Polypropylene Film Material Thickness Laser 0.95 µm Coherent C-40 CO2 Wavelength To explore this, the beam from a Coherent C-40 10.2 μm CO2 laser was directed into a 3.3X telescope, and then delivered a distance of 1.5 meters to a Scanlab HurryScan II galvanometer scanner equipped with a 200 mm focal length meniscus scan lens. The theoretical focused spot diameter for this configuration is 220 μm. The scanner was controlled by SCAPS SAM Lite software. 10.2 µm Average power 12 W 24 W Pulse Repetition Rate 10 kHz 20 kHz 30 µs 40 µs Pulse Width Pulse energy 1.2 mJ 1.2 mJ Pulse spacing 33 µm 30 µm Theoretical spot size 220 µm 220 µm 325 mm/sec 600 mm/sec 85 % 86 % Scan speed Pulse overlap . Figure 3. Magnified edge detail of a 95 µm thick polypropylene film cut with a 10.2 µm CO2 laser operating at 12 W. A plate with a 4 in x 2 in rectangular aperture was set beneath the scanner so that its upper surface was in the focal plane of the scan lens. A sheet of 95 µm thick, white polypropylene film was set on the plate and held down with metal bars. Circular cuts were made at a variety of scan speeds, laser pulse repetition rate and laser pulse durations. The cuts were examined under a binocular microscope. Results showed that the material could be cleanly cut at a speed of 325 mm/sec using 12W of laser power. Cutting could also be accomplished at a speed of 650 mm/sec using 24W of power. The cut edge had some taper but was clean www.Coherent.com I [email protected] I Perforation of 0.0018 in (45 µm) thick laminated polypropylene film This experiment was conducted to prove that a CO2 laser operating at 10.2 µm can cleanly perforate 45 µm thick, laminated polypropylene film at a processing speed of 600 feet/min. To assess this, the beam from a Coherent C-40 10.2 μm CO2 laser was passed through a ScanLab HurryScan 14 galvanometer scanner equipped with a 100 mm focal length, flat field lens, to yield a nominal working spot diameter of 125 µm. The scanner was controlled by Scaps Samlite software, which also commanded laser pulsing. The pulse repetition rate was set at 1250 Hz in order to achieve the desired perforation length and spacing at the scanning speed of 500 to 600 feet/min. The photo shows that clean perforations were obtained under these conditions. (800) 527-3786 I (408) 764-4983 3 Conclusion Compact, sealed CO2 lasers offer an ideal combination of low cost, high reliability and small footprint for converting applications such as cutting, scoring and perforating of plastic films. For polypropylene and BOPP, in particular, increased processing speed and improved results can be obtained with lasers operating at 10.2 µm, making these even more attractive tools for systems integrators and converters alike. And, since Coherent offers the highest output power lasers available at 10.2 µm, these products are the ideal solution for high efficiency converting applications. Figure 4. Perforations produced in 0.018 in thick polypropylene film with a 25W, 10.2 µm CO2 laser. Processing parameter summary Material Polypropylene Film Material Thickness 45 µm Laser Coherent C-40 CO2 Wavelength 10.2 µm Average power 24.9 W Pulse Repetition Rate 1250 Hz Pulse Width 500 µs Pulse energy 20 mJ Pulse spacing 250 µm Theoretical spot size 125 µm Scan speed www.Coherent.com 600 ft/min I [email protected] I (800) 527-3786 I (408) 764-4983 4
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