A7 222 Disclaimer—This paper partially fulfills a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering. This paper is a student, not a professional, paper. This paper is based on publicly available information and may not provide complete analyses of all relevant data. If this paper is used for any purpose other than these authors’ partial fulfillment of a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering, the user does so at his or her own risk. TRANSPARENT SOLAR PANELS IN SOLAR WINDOWS AND CELLULAR PHONES Melissa Barbour, [email protected], Mena 3:00, Anthony Jacob, [email protected], Mahboobin 10:00 Abstract—Conventional solar concentrators have limitations. They require great quantities of space, the right position to catch the light, and are aesthetically unpleasing. But a new design seeks to remedy all three problems at once by developing a transparent solar concentration system that can be seamlessly integrated into any building or technological device with transparent surfaces. Professionals have been experimenting with designs for see-through solar panels for some time. But just recently, a team at Michigan State developed solar panels that absorb only light we can not see. By collecting only light from the invisible spectrum, it ensures that to our eyes these solar panels look just like panes of glass. The possible applications of transparent solar panels are numerous. The most widely researched application is known as a “solar window”. However, while the idea is exciting, widespread implementation is practically unlikely as solar panels (no matter their opacity) are most efficient at a specific angle that could not be met when mounted to the sides of building. In addition, they can only be mounted to the south side of a building and they will most likely be shaded by another building. A more practical option for this technology has been suggested by its creator, who sees additional implementation possibilities in mobile devices such as phones or e-readers. Indeed, cell phone companies have already attempted the addition of solar panels behind the touch screen. They have been unsuccessful because opaque solar panels must be placed behind the screen. By the time the light gets to the solar panel, most of it has been absorbed by the display. Transparent panels have been suggested as an obvious solution. They could be placed in front of the display without obstructing the view and thereby be in a better position to power the device. Some speculate that the addition of a transparent solar cell could be enough to keep a device independently powered indefinitely. Key Words— Construction, Energy, Renewable, Solar, Sustainable University of Pittsburgh, Swanson School of Engineering Submission Date: 03.03.2017 1 RELEVANCE Conventional solar concentration systems have many limitations. They require great quantities of space, the right position to catch the sun’s light, and are aesthetically unpleasing. As Margaret Rhodes writes for Wired Magazine, “Standard solar panels live on rooftops, need to tilt at a certain angle, and, most problematically, are an eyesore” [1]. This has hindered implementation in environments with space constraints and kept solar power from living up to its full potential. But a new solar panel design seeks to remedy both problems at once with a transparent solar concentration system that can be seamlessly integrated into any building or technological device with transparent surfaces. THE PROGRESSION OF THE SOLAR PANEL Traditional Solar Panels The history of solar cells dates back to 1876, where a professor and student discovered that when selenium was exposed to light, it produced electricity. A little less than one hundred years later, the silicon solar cell was discovered. The cell produced enough electricity and was efficient enough to run small electrical devices such as alarm clocks. As years went on, these solar cells became available commercially but were still too expensive for everyday people. Slowly, efforts were taken to try and reduce cost. In the 1970s, Exxon Corporation financed research to create solar cells from lower-grade silicon and cheaper materials as an attempt to reduce cost. The federal government also passed several solar friendly bills and created the National Renewable Energy Laboratory in 1974, which is now the United States’ primary lab for renewable energy and energy efficiency research and development [2]. As technology and efficiency of solar cells increased, solar power became more popular. Finally, in 2005, residential and commercial solar panels started becoming more popular. These panels had many benefits and thus were a large step in the right direction. However, these traditional solar panels have many shortcomings. For example, one major problem with the Melissa Barbour Anthony Jacob addition, these panels are beginning to be integrated into consumer products, such as mobile phones [5]. One problem with this technology is efficiency. Solar cell efficiency refers to the portion of energy in the form of sunlight that can be converted via photovoltaics into electricity. The solar conversion efficiency of a standard Luminescent Solar Concentrator (LSC), the technology behind these transparent solar panels, is around one percent. Solar technologies can have efficiencies ranging from eight percent to forty-five percent. A commercial rooftop solar panel has an efficiency of about fifteen percent. Ideally, the efficiency of these LSCs can be increased by greater than five percent with the introduction of new designs [5]. Researchers at M.I.T. attempted a different approach to solving this efficiency problem by proposing to make a photovoltaic solar cell that would absorb all the energy from the sun except the part that allows us to see. Researchers showed that this design should realistically be able to reach over twelve percent efficiency, a rating comparable to that of existing commercial solar panels [6]. The biggest obstacle between these LSCs and getting them in the commercial market is their longevity. In commercial applications such as window coatings, the solar cells need to continue performing well for years. According to Vladimir Bulović, a professor of electrical engineering at M.I.T., work to extend the lifetime of related products has made good strides. With many industries tackling the same issue, he believes that this engineering problem should be solved in the coming years, and their solar cells should be guaranteed to have a commercially viable lifespan [7]. However, despite these drawbacks, one major benefit to these LSCs is the potential they have in reducing costs of solar technology. Since these LSCs concentrate the energy absorbed into a smaller area, the number of expensive solar cells required dramatically decreases, reducing the overall cost of the module [7]. Besides that, what makes these transparent panels attractive for the near future, is that they can be added to things that are already being deployed, and they won’t require devoting vast new areas to collecting solar energy. With this technology, usable areas already exist in the surfaces surrounding us. traditional solar panel is installation area. Many residential areas and companies would like to utilize solar power, but these solar panels require a large area for the system to be efficient in providing electricity on a constant basis. Another concern with these panels is their cost. The cost of purchasing and installing solar panels always becomes a disadvantage when the topic of solar energy comes up, and these traditional panels support that argument. The panels must also be in the right position to catch the sunlight and absorb its energy, and the weather conditions must be adequate in order for these panels to do their job. Finally, another concern with these panels is that they are aesthetically unpleasing. Solar arrays speak loudly, and many people are reluctant to install a large solar array on their otherwise attractive building. With all these shortcomings, it becomes more difficult for the traditional solar panels to progress successfully. Colored Solar Panels One alternative design for solar panels involves collecting only one color of light and allowing all others to pass through. This gives the panels the appearance of being tinted the same color as the light being collected. These “stained glass” panels are cheaper than the traditional black and nearly match the opaque panels’ efficiency [1]. However, the tinted light that these panels produce has its own aesthetic disadvantages. While every plain window being replaced with stained glass may sound appealing, Richard Lunt, one of the researchers, has found otherwise. “’No one wants to sit behind colored glass. It makes for a very colorful environment, like working in a disco’” [4]. Lunt is on a team at Michigan State that worked to develop a new type of solar panel that collects only the light we can not see. Transparent Solar Panels Transparent panels are a step ahead of the traditional solar panel. Researchers are making transparent solar cells that could turn everyday products such as windows and electronic devices into power generating sources. Introduced around 2014, these panels absorb infrared and ultraviolet light. Because we cannot see ultraviolet or infrared light, these panels appear transparent to the human eye, even while concentrating sunlight. Researches have deposited coatings of their solar cells on various materials and have used them to run electronic displays using surrounding light, all while using simple room temperature methods. One of the biggest advantages of the transparent solar cells is that they can be deposited on any surface without obscuring the look of the underlying material. Coating a skyscraper with these transparent photovoltaic cells is estimated to be able to provide for more than a quarter of the building’s energy without changing the building’s appearance. Not only that, but the cells would block much of the infrared radiation, a large part of the sunlight that heats up the room. This would cut down on air conditioning needs, further reducing energy use and operating costs of the building. In THE TECHNOLOGY BEHIND TRANSPARENT SOLAR PANELS Luminescent Solar Concentrators The main technology behind these transparent panels is the Luminescent Solar Concentrator (LSC). LSCs “collect ambient light from a broad range of angles and concentrate the captured light onto photovoltaic (PV) cells” [8]. The concept for LSCs has been around for over 30 years. However, recent 2 Melissa Barbour Anthony Jacob advances in phosphorescent and fluorescent efficiencies have allowed for an improvement in the LSC’s power conversion efficiency. FIGURE 2 [6] This schematic diagram shows the key components in this transparent photovoltaic device. The main components of this design, pictured above, consist of the plastic or glass, the dye molecules, and solar cells. The plate consists of multiple layers coated with particles of dye. The thickest layer, at the bottom, is comprised of the plastic, glass, or any other transparent substrate being coated. Near the top, are multiple layers of photovoltaic coating. At the core of this coating are the two active layers. These layers consist of absorptive semiconductor materials that interact once they are excited by the sunlight. They then create an electric field that causes the current to flow. Surrounding those layers are electrodes connected to an external circuit, which carry the current out of the device. Since these electrodes are transparent, an additional layer can be added to the back of the cell to reflect sunlight of selected wavelengths. Miles Barr, president and CTO of Ubiquitous Energy, Inc., says of these transparent panels, “We use a combination of molecular engineering, optical design, and device optimization—a holistic approach to designing the transparent device” [6]. This goes to show that the depth put into this design is what differentiates it significantly from the traditional solar panel. Between the thick plastic/glass layer and the photovoltaic layer is a critically placed gap. This gap allows the solar cell to be transparent to the human eye. However, this also means that the cell does not capture all the incident energy. “We do let the visible photons [light particles] pass through, allowing them to efficiently light the room. But we try to catch all of the photons in the infrared and ultraviolet,” says Bulović. “We try not to let any of those photons get through” [6]. Current versions of this cell transmit more than seventy percent of the visible light, which is within the same range of the tinted glass used in windows of buildings. However, their power conversion efficiency is low. This design should realistically be able to reach twelve percent efficiency. Richard Lunt supports this, mentioning that by simply “stacking” the transparent solar cells, they could reach an efficiency of ten FIGURE 1 [3] Transparent panel containing organic salts that absorbs UV and infrared light and emits infrared so that the panel appears transparent. Basically, these LSCs consist of a glass or plastic plate coated with dyes that absorb sunlight and emit light at longer wavelengths, as pictured above. The LSCs employ novel nanocrystal polymer blends that allow for selective ultraviolet light harvesting that results in a high degree of visible light. A substantial part of the longer wavelength light is trapped by a process called total internal reflection and guided to the edges of the plate, where it is then absorbed by small area PV cells. Total internal reflection is the reflection of the total amount of incident light at the boundary between two media. During this process, as the angle of incidence increases between the light and the plate, more of the light is reflected, thus spreading to the edges of the plate [7]. Previous efforts to construct similar transparent power producing surfaces have focused on, “optically thin photovoltaics that have a significant tinting or limited transmission” or “focusing optic systems using direct light only that requires bulky solar tracking or optics” [7]. These efforts are flawed, leading to significant tinting and limited transmission, defeating the purpose of these transparent panels. This leads to the now more recent technology behind this LSC design, which focuses on selectively absorbing near-infrared photovoltaics and exploiting the excitonic character of molecular semiconductors. Components of the LSC and the Technology 3 Melissa Barbour Anthony Jacob which is going to shade that side of the building’” [9]. The numerous hindrances to implementation create a lot of doubt as to the viability of solar windows. percent while still maintaining the ability to transmit light. They have already demonstrated that an array of transparent cells integrated in series can power the liquid crystal display on a clock, while relying solely on ambient light [6]. The combination of the plastic/glass and the dyes acts as a waveguide. A waveguide is any device that traps light and then moves those light waves along a path to a particular destination. In the case of the LSC, the dyes absorb the light that hit the plastic/glass. The sun’s energy is transferred to the dye, and the electrons in those molecules become excited and jump to a higher energy level. When the electrons fall back to a lower energy level, the dye molecules release that energy into the carrier sheet, where it gets stuck. During total internal reflection, the light bounces around in the material, ultimately making its way to the outer surface. A type of aluminum called tris is added to the mix of dye molecules. These aluminum molecules cause the dyes to emit light waves at a frequency the dyes can't absorb. In this way, no light is lost to re-absorption as it makes its way to the solar cells at the edges of the glass. At the outer surface, the solar cells are waiting to absorb the light and generate electricity. By concentrating the light to the edges, a much smaller amount of photovoltaic material is needed which helps to reduce overall cost of the panel [7]. Solar Phones A more practical option for transparent solar panel technology has been suggested by its creator, who sees possible implementation in “tall buildings with lots of windows or any kind of mobile device that demands high aesthetic quality like a phone or e-reader” [4]. Indeed, cell phone companies have already attempted the addition of solar panels. Several years ago, rumors surfaced that the iPhone 6 or 7 would include a “screen with a laminate of film containing solar cells” [5], but these claims never came to fruition. Many cell phone carriers have experimented with the idea of integrating solar panels behind the display screen. However, as Motorola engineer Zili Li explained to New Scientist, they have been unsuccessful “because the LCD [display] absorbs most of the incoming light before it can reach the [opaque] solar cell” [10]. Transparent panels have been suggested as an obvious solution. They could be placed in front of the LCD display without obstructing the view, and thereby be in a better position to power the device. Some speculate that the addition of a transparent solar cell could be enough to keep a device independently powered indefinitely. A constantly charged device would be revolutionary. Nancy Stauffer writes for the MIT Energy Initiative that “Enabling such devices to gather energy from ambient light and recharge their own batteries will provide significant benefits, including added convenience, greater freedom from the power grid, and a better user experience” [6]. However, the implications of this technology reach far beyond the personal inconvenience of having to charge our electronic devices. In many third world countries, mobile phones are the primary device on which people carry out important transactions, like banking. New scientist reports that in developing areas of Asia and Africa farmers use mobile phones to check market prices in many different areas so they know how best to sell their own crops. In Sierra Leone, coffee traders want to cut costs by paying their farmers electronically [11]. But they cannot implement this business practice if there is uncertainty about whether or not any given farmer will have an active phone. In many of these remote areas, the electricity needed to power phones is intermittent at best. “An estimated 500 to 650 million cellphone users are off-grid” [11] according to that same article. This means that these people must walk miles to a charging station and then pay for its use. One company working to solve this problem, Buffalo Grid, reports that “In rural economies, about 50 per cent of the money spent on mobile phones is actually spent on charging them. ... That is some of the most expensive electricity in the world” [11]. Lessening or even eliminating dependence on an unreliable grid or expensive charging stations could simplify the lives of many people and make technology accessible to many more for the first time. APPLICATIONS Solar Windows The possible applications of transparent solar panels are numerous. One expert working to implement colored solar panels in Denmark imagined that “Bus stops, typically made from three to four walls of transparent glass, could easily harvest energy. Park benches could be transformed into colored pieces of furniture and double as charging stations. Outdoor concert stages could catch enough light to then power the restroom and dining facilities” [1]. Many solar technology experts focus on what are called “solar windows”. The implementation involves covering or replacing common glass with transparent solar panels. In this way, almost any building could generate its own electricity. The Journal of Applied Physics notes that “windows, skylights, and greenhouse panels” [8] are all possible targets for this new technology. There are several startups working to scale up to market scale production and integration of solar windows. Theoretically, implementation of enough solar windows could even make a building self-sustaining. However, while the possibility is exciting, such widespread implementation is practically unlikely as solar panels (no matter their opacity) are most efficient under very specific conditions. As reported by Yale Environment 360, “‘The optimal installation for solar is you want it to be facing south, you want a slight tilt to it, and you want good solar access, so you don’t want anything to shade those panels,’ says [MJ] Shiao, of GTM Research. ‘The problem with skyscrapers is suddenly you’re putting them in vertical orientation, there’s only one south side to the building, and chances are that skyscraper is next to another skyscraper, 4 Melissa Barbour Anthony Jacob technology will bring electricity to emerging countries that have not been covered by the grid and lessen the environmental impact of first world energy addicts. After years of progress, the advancements made in photovoltaic technology have made it possible for many see-through surfaces to become energy collectors. Whichever mediums locations are chosen to use transparent solar panel, this could prove to be a very significant step in reducing our dependence on nonrenewable sources of energy. With more remote countries entering the twenty first century and all countries developing sustainable energy for the twenty second, the future is clear. THE FUTURE Making it easier for these farmers to do business with more people will not only improve their standard of living but also decrease the environmental impact of farming. For years, farmers in remote areas have been increasingly resorting to unsustainable farming techniques to increase output. The ability of farmers to instantly check market prices in other areas will keep the companies who buy their produce honest. Fair wages will reduce the desperation felt by small farmers. It is likely that this could, in turn, slow the spread of environmentally unconscious practices like slash and burn farming. It is important for all engineering endeavors to take sustainability into account. Merriam-Webster defines sustainability as “of, relating to, or being a method of harvesting or using a resource so that the resource is not depleted or permanently damaged” [12]. Experts have concluded that non-renewable energies, such as fossil fuels, do not meet that definition and are, therefore, unsustainable. A 2012 BBC study estimated that if consumption of these resources continued at the current rate, the last fossil fuel reserves would be empty by 2054 [13]. This highlights the importance of innovative renewable energy technologies. New designs, such as the transparent solar cell, that increase the viability of renewable energy will play an important role in powering our world going forward. The increased implementation possibilities of the seethrough solar panel are an important contribution to the expansion of sustainable energy. Making renewable energy available to more people could greatly slow the depletion of non-renewable energy sources. Reducing our dependence on these sources is vitally important as we near the point where relying on them will no longer be possible. Furthermore, increased implementation potential is not the only advantage of clear solar panels when it comes to sustainability. Detractors of current solar technology cite the environmental risks of a potential leak. Toxic substances such as Cadmium, lead, and sulfuric acid, have the potential to harm the environment if accidentally released [3]. Many of these pollutants will still be present with the transparent technology as they are not found in the panel but in the battery bank. However, transparent solar technology does not include cadmium sealed inside the panel, and thereby poses less of a threat to the environment than the opaque design. Because of the increased implementation possibilities and the lack of toxic material in the panel, the clear solar cell holds a lot of potential as far as sustainability efforts are concerned. It and technologies like it are likely to receive more attention in coming years as necessity forces us towards sustainability. SOURCES [1] M. Rhodes. “Clear Solar Panels Double as Highway Sound Barriers.” Wired. 08.04.15. Accessed 1.10.17. https://www.wired.com/2015/08/clear-solar-panels-doublehighway-sound-barriers/ [2] “A History of Solar Cells: How Technology has Evolved.” Solar Power Authority. 07.13.16. Accessed 03.01.17. https://www.solarpowerauthority.com/a-history-of-solar-cells/ [3] N. Gromicko. “Disadvantages of Solar Energy.” InterNACHI. 2017. Accessed 03.01.17. https://www.nachi.org/disadvantages-solar-energy.htm [4] J. Wallace. “Solar Concentrators: Colorless dopants make luminescent solar concentrator transparent as a window.” Laser Focus World. 10.02.14. Accessed 1.10.17. http://www.laserfocusworld.com/articles/print/volume50/issue-10/world-news/solar-concentrators-colorlessdopants-make-luminescent-solar-concentrator-transparent-asa-window.html [5] K. Boehrer. “Researchers Develop Transparent Solar Concentrator That Could Cover Windows, Electronics.” The Huffington Post. 08.24.14. Accessed 1.10.17. http://www.huffingtonpost.com/2014/08/24/transparent-solarconcentrator_n_5700544.html [6] N. Stauffer. “Transparent Solar Cells.” MITe. 06.20.13. Accessed 03.01.17. http://energy.mit.edu/news/transparent-solar-cells/ [7] R. Lunt. “Transparent Luminescent Solar Concentrators for Large- Area Solar Windows Enabled by Massive Stokes-Shift Nanocluster Phosphors.” Advanced Energy Materials. 04.25.13. Accessed 1.10.17. https://www.deepdyve.com/lp/wiley/transparent-luminescentsolar-concentrators-for-large-area-solar-dYZXF06GWo [8] S. Leow. “Analyzing luminescent solar concentrators with front-facing photovoltaic cells using weighted Monte Carlo ray tracing.” Journal of Applied Physics. 06.07.13. Accessed 03.01.17. http://aip.scitation.org/doi/full/10.1063/1.4807413 [9] D. Levitan. “Will Solar Windows Transform Buildings to Energy Producers?” Yale Environment 360. 05.03.12. Accessed 1.10.17. LASTING IMPLICATIONS In conclusion, the transparent solar panel is poised to make renewable energy more accessible than ever. This 5 Melissa Barbour Anthony Jacob http://e360.yale.edu/feature/will_solar_windows_transform_b uildings_to_energy_producers/2524/ [10] P. Marks. “Self-Powered Displays Keep Gadgets Live.” New Scientist. 05.05.07. Accessed 1.10.17. https://www.newscientist.com/article/mg19426026-100-selfpowered-displays-keep-gadgets-alive/ [11] A. Ananthaswamy. “Send a Text Message to Charge Your Cellphone.” New Scientist. 03.06.13. Accessed 1.11.17 https://www.newscientist.com/article/mg21729075.500-senda-text-message-to-charge-your-cellphone/ [12] “Sustainability.” Merriam Webster. Accessed 3.22.17 https://www.merriam-webster.com/dictionary/sustainability [13] D. Swain. “Stock Check.” BBC. 06.12. Accessed 3.24.17 http://www.bbc.com/future/bespoke/BBCF_infoData_stock_c heck.pdf ACKNOWLEDGEMENTS We would like to thank our writing instructor Rachel McTernan for helping with our specificity. We would also like to thank the dedicated professionals who work to make our lives more sustainable every day. 6
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