Wastewater Treatment Using IFAS for improved WWTP capacity and performance By Valera Saknenko, Vincent Nazareth, Roberson Gibb, Patrick Devlin and Krista Thomas T he Peterborough Wastewater Treatment Plant (WWTP) in southern Ontario is a Class IV plant discharging to the Otonabee River. As a result of municipal growth, average capacity had to be increased from 60,000 m3/day to 68,200 m3/day, with a simultaneous improvement in effluent quality. This plant re-rating was achieved by full conversion of the existing aeration tanks to a hybrid integrated fixed film activated sludge (IFAS) media system. Concurrent upgrades included improvements to the inlet works, construction of four new primary clarifiers, a sludge dewatering facility and a new septage receiving station. Since September 2011, it has been operating as an IFAS plant, resulting in a number of process benefits, including lower average total ammonia nitrogen (TAN), non-toxic effluent, and greater resiliency of the nitrification process to both organic and hydraulic shock loads. Nitrogen transformation To effectively evaluate the impacts of the IFAS system, it is important to first revisit some chemistry theory to appreciate the transformation process that occurs inside one. The majority of nitrogen enters wastewater in the form of urea and fecal matter, and is then converted through hydrolysis to TAN. TAN (or more correctly TAN-N, which measures only the mass of nitrogen) is the sum of two molecules: NH3 (ammonia or un-ionized ammonia) and NH4+ (ammonium or ionized ammonia). In essentially all solutions, including wastewater, both the ionized (NH4) and un-ionized (NH3) forms are present due to the principles of acid dissociation. The un-ionized form is the compound that is most toxic to fish. Fortunately, for aquatic species, at pH levels in typical wastewater, NH4 is present in much greater concentrations than NH3 (100:1 ratio at pH of 7.4). However, the NH3 percentage rises with increasing 38 | January/February 2015 The Peterborough WWTP. (1) Raw sewage pumping station. (2) Grit tanks. (3) Screen building. (4) Primary clarifiers. (5) Secondary treatment Plant One. (6) Secondary treatment Plant Two. (7) UV disinfection. (8) Digesters. pH and/or sewage temperature. This means that, for identical TAN measurements, warmer effluent results in greater toxicity due to the higher NH3 levels. To limit un-ionized ammonia effluent concentration, TAN must be reduced through a two-step bacteriological conversion process (known as nitrification) during secondary treatment. Ammonia is first converted to nitrite (N02) using Nitrosomonas bacteria. Subsequently, the nitrite is converted to nitrate using Nitrobacter bacteria. The first process (conversion to nitrite) is the rate limiting process, meaning that nitrate is usually present in much greater concentrations. For aquatic species, the rate limiting reaction is critical, since nitrite is toxic at significantly lower concentrations. IFAS overview An IFAS system is capable of improving the resiliency of conversion of TAN to nitrate within a WWTP. The IFAS system comprises fixed or floating media, placed within an activated sludge tank to augment the number of nitrifying bacteria. The IFAS system takes a hybrid approach to nitrification. It uses traditional mixed liquor suspended solids (MLSS) within the aeration tank, as well as biofilm attached to plastic media, to promote the development of additional nitrifying bacteria. A primary advantage of IFAS, versus a traditional activated sludge system, is the ability to create a higher biomass in the aeration tank by providing a surface for bacteria growth to aid the process. This additional biomass is retained in the tanks, thereby maintaining acceptable solids loading to the secondary clarifiers. A significant percentage of the nitrifying bacteria are kept within the aeration tank attached to the biofilm. This contributes to the conversion of ammonia to nitrate, without a proportional increase in MLSS concentrations. The solids retention time (SRT), and, therefore, aeration tank size, can be reduced for a given level of nutrient removal. This makes the IFAS technology attractive for the following retrofit applications: % Increasing plant capacity, while maintaining existing effluent requirements; % Meeting more stringent effluent criteria imposed on a WWTP within the confines of the existing tankage; % Providing biological nitrogen removal (denitrification) by partitioning an existing tank to contain both an IFAS aerobic zone and a separate anaerobic/anoxic zone. The fixed biofilm also provides other Environmental Science & Engineering Magazine Wastewater Treatment inherent benefits to increase the resiliency of the nitrification process. Fixed media provides better nitrification in cold climates, and the biomass population is more resistant to both organic and hydraulic shock loads. Fixed biomass attached to free floating media provides a seeding source to re-populate biomass after a flow surge through secondary treatment. Preliminary and primary treatment at the Peterborough WWTP consists of mechanical screening, aerated grit tanks and primary clarification. Secondary treatment is provided through two parallel IFAS treatment trains and horizontal secondary clarifiers, referred to as Plants One and Two. Prior to discharge into the Otonabee River, secondary effluent is disinfected using UV irradiation. Unit process sizes (bioreactors and secondary clarifiers) in the two plants are marginally different. Primary and waste activated sludge are stabilized in two primary anaerobic digesters (2,444 m3 each) and two secondary digesters (1,445 m3 each) and dewatered using centrifuges. www.esemag.com Table 1: Effluent objectives and limits. Effluent Parameter Total Phosphorus Total Ammonia Nitrogen Un-ionized Ammonia Effluent Objective 0.35 mg/l 5 mg/l Winter 2.98 mg/l Summer 0.1 mg/l Effluent Limits 0.39 mg/l n/a Acute Lethality to Rainbow Trout and Daphnia Magna Total Suspended Solids Non-Acute Lethality 10 mg/l 17.5 mg/l CBOD5 10 mg/l 17.5 mg/l Discharge effluent requirements for the Peterborough WWTP are provided in Table 1. TAN reduction is a prescribed effluent objective. There are no total nitrogen or nitrate limits imposed on the effluent, negating any denitrification requirements. Each aeration tank was retrofitted with a non-proprietary IFAS system. One metal cage per plant was installed with a fine perforated metal mesh elevated above the diffusers. This prevents media from settling when the tank is taken out of service. The cages were installed in the front half of the first pass of the three-pass aeration tanks. Air lances were added to assist with media circulation. Approximately 190 m3 of media was added in each aeration tank. The plastic media used was not engineered specifically for IFAS systems, but rather regular packing media with total specific surface area of approximately 210 m2/m3. Although this media may not be as effective as engineered media specifically designed for this type of application, it has proved to be sufficiently effective. Operational results To compare the impact of IFAS on continued overleaf... January/February 2015 | 39 Wastewater Treatment Table 2. Maximum recorded daily peak TAN levels. nitrification at the WWTP, monthly average TAN effluent concentrations were compared for time periods when the plant was operating with and without IFAS. Data indicates that full implementation of the IFAS system at Plants One and Two has had a significant impact on stabilization of the nitrification process. As can be seen from Figure 1, after installation of IFAS, fluctuations in flows did not produce the TAN concentration exceedances observed prior to the retrofit. For example, high flow events in 2005, 2008 and 2011 prior to IFAS resulted in significant wash out of MLSS, including nitrifiers. This resulted in long recovery periods (about six months) before TAN effluent concentration dropped below the effluent objective. After IFAS implementation, similar high flow events in March 2012 and April 2013 did not cause significant effluent TAN spikes. It is noted that a minor spike in TAN occurred in the late summer of 2013, corresponding to the time period when one aeration tank had to be taken out of service. Other effluent indicators also validated performance of the IFAS system. Cross referencing effluent un-ionized ammonia concentrations showed a parallel decrease and stabilization of toxic un-ionized ammonia. This is to be expected since un-ionized ammonia is a direct function of TAN concentration, pH and temperature. Further validation was completed by confirming the increase in effluent nitrate levels after the IFAS implementation. As per the nitrification chemistry described earlier, nitrate levels are expected to increase as nitrification improves. Seasonal aggregates of the average TAN concentrations shown in Figure 1 substantiate the fact that IFAS provides considerable advantages over a conventional suspended biomass process during the coldest seasons. For the period of January through March, effluent total ammonia levels were 30% of the comparative period when the WWTP was operating without IFAS. The impact of IFAS was less during the warmer months, with effluent TAN levels being 70% of pre-IFAS conditions. A review of the annual maximum 40 | January/February 2015 Date Ammonia – N – Effluent Concentration mg/l Full IFAS Maximum Daily TAN Value 11-Sep-13 6.0 mg/l 04-Apr-12 5.4 mg/l Non-IFAS Maximum Daily TAN Value 10-Feb-04 16.0 mg/L 15-Mar-05 17.5 mg/l 20-Feb-08 10.2 mg/l Daily Flow Rate 52.7 MLD 48.5 MLD 50.2 MLD 49.0 MLD 42.9 MLD Figure 1. Seasonal TAN effluent levels. Elevated metal cage. peak daily TAN effluent concentrations gathered from daily samples shows a similar ability of the IFAS system to attenuate peak TAN levels. As shown in Table 2, the maximum recorded TAN levels dropped by 60% after implementation of the full-scale IFAS. Summary Upgrading the Peterborough WWTP with an IFAS system allowed maximum use of the existing infrastructure and increased efficiency by augmenting the total amount of biomass in the system. This approach eliminated the need to build new aeration tanks and secondary clarifiers, saving some $13 million in construction costs. Converting the secondary treatment train to IFAS has lowered average TAN to 1.25 mg/l (37% of original levels) and resulted in a corresponding reduction in un-ionized ammonia. It achieves its greatest efficiency during the coldest winter months. Operators have noted that the ammonia reduction in the “IFAS Zone” has been approximately 80%. The food to micro-organism ratio (F:M Ratio) has changed from 0.4 to 0.28-0.30, leading to a decrease in return activated sludge. Effluent total suspended solids and carbonaceous biochemical oxygen demand have continued to be below effluent limits. Long-term effluent results demonstrate the potential for IFAS to be successfully used in retrofits to increase plant capacity, meet more stringent effluent criteria, or to increase rated capacity to maximize existing tankage volume use within the secondary treatment train. Valera Saknenko, P. Eng., Vincent Nazareth, P. Eng., and Roberson Gibb are with R.V. Anderson Associates Limited. Patrick Devlin, HBSc., and Krista Thomas are with the City of Peterborough. For more information, Email: [email protected] Environmental Science & Engineering Magazine
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