CHEM 2218 Inorganic Chemistry I Instructor: CHEM 2218 Inorganic Chemistry I (3-1-0:4) Lin Zhenyang (Room 4533; Tel no. x-7379) If organic chemistry is defined as the chemistry of compounds of carbon, primarily those containing hydrogen or halogens plus other elements, inorganic chemistry can be described broadly as the chemistry of “everything else” Teaching Assistants: Name: Email: Cheung, Man Sing [email protected] (x-7406) Lee, Ka Ho [email protected] (x-7406) Shen, Bo [email protected] Shu, Yiwei [email protected] Inorganic chemistry is a vast and thriving discipline that deals with over a hundred elements from many points of view and touches all other branches of science. Course goals Lecture hours: Tutorials: 16:30 – 17:50 am Wednesday and Friday 13:00 – 14:50 am Friday (once every two weeks) Instructors for tutorials: Professors Jia and Leung Chapter 0 Introduction 1 • • • • • • Chapter 0 Introduction 2 Contents Learning Outcomes • This course will provide you with the structure and bonding principles/theories that assist in understanding the behavior of inorganic compounds. On completion of the course, students will be able to, at an introductory level: Demonstrate a comprehensive and well-founded knowledge of structure and bonding theories that are relevant to inorganic molecular compounds. Describe, comprehend and rationalize solid state structures. Explain stability of inorganic compounds using concepts of acids and bases. Classify molecular point groups and recognize the importance of molecular symmetry in the field of chemistry. Describe coordination compounds. Develop a general understanding of periodicity of chemical elements. Chapter 0 Introduction 3 Chapter Topics ILOs 0 Introduction - 1 Atomic structure 1 2 Molecular structure and bonding 1 3 The structures of simple solids 2 4 Acids and bases 3 5 Molecular symmetry 4 6 An introduction to coordination compounds 5 7 Periodic trends in chemical properties 6 Chapter 0 Introduction 4 1 Organic vs. Inorganic Compounds Assessment: Mid-term exam Final exam Assignments 1 & 2 Textbook: Reference books: Course webpage: 44% 48% 4% × 2 Organic Shriver & Atkins Inorganic Chemistry (4th edition) Housecroft & Sharpe Inorganic Chemistry Inorganic Bonding between adjacent atoms σ,π σ,π,δ Bonding with hydrogen terminal C-H terminal M-H, bridging M-H-M Alkyl groups terminal terminal and bridging Coordination numbers 4 max 1, 2,....5,6.... http://home.ust.hk/~chzlin/chem2218/ Chapter 0 Introduction 5 Organic and Inorganic Molecules Chapter 0 Introduction 6 Terminal and Bridging Groups Unusual coordination numbers for H, C Chapter 0 Introduction 7 Chapter 0 Introduction 8 2 Typical geometries of inorganic compounds Chapter 0 Introduction 9 Metal-metal bonds Chapter 0 Introduction Chapter 0 Introduction 10 Sigma-, Pi-, and Delta-bonds 11 Chapter 0 Introduction 12 3
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