OXYGEN BLAST FURNACE PROCESS FOR SWEDISH CONDITIONS Linda Bergman1, Mikael Larsson1, Jan-Olov Wikström1, Lena Sundqvist Ökvist1 Guangqing Zuo2, Björn Jansson3 1 MEFOS, Box 812, 971 25 Luleå, Sweden 2 LKAB, Box 952 Luleå, Sweden 3 SSAB, 971 88 Luleå, Sweden Abstract A new blast furnace process with cold oxygen replacing the hot blast, CO2-separation from the top gas and recirculation of the reducing gases to the BF tuyeres and stack is being developed within the joint European ULCOS-project. In this paper the global effects of converting the existing blast furnace at SSAB Luleå Works to the new concept is analysed from a process integration perspective. A study towards minimum cost, energy consumption and environmental effects are analysed and discussed. Introduction Pulverized coal injection (PCI) into the blast furnace (BF) was developed in Japan and Europe during the early 80’s. Initial results indicated that injection rates around 100 kg per tonne of hot metal could be reached quite easily in many blast furnaces, but higher rates were more problematic. The problem was, among other parameters, related to an insufficient combustion of coal in the raceway area. As a way towards much higher injection rates several different concepts for full oxygen blast furnace (OBF) were proposed [1-3]. When the hot blast is replaced with oxygen , the gas volume leaving the raceway area is too small for heating of the burden. The different concepts for OBF showed different solutions to this problem. One concept, that was tested in pilot plant scale, was the NKK process, developed at Keihin Works. A part of the blast furnace off-gas was combusted outside of the blast furnace and the waste gas was injected into the middle part of the shaft. The purpose of the gas injection Top gas was only preheating of the burden. Reduction was still Tail gas CO made by the gas being produced in the raceway. The result removal unit CO2 rich from pilot plant tests were promising and oxygen tuyeres as well as shaft gas burners were also developed and Injection gas demonstrated in full scale on industrial blast furnaces. CO rich Still, no decision for commercial use of the process was taken. 2 900 °C Heater 1000 °C Figure 1 Schematic description of an oxygen blast furnace An OBF process has also been developed and demonstrated in a small industrial BF in Tula, Russia during the late 80’s [4]. CO2 was separated from the BF gas and the remaining reducing gas was preheated to 1100°C and injected into the tuyeres together with pure oxygen. No injection of fossil fuel was applied. In the 90’s, many blast furnaces reached very high pulverised coal injection rates with only a small addition of oxygen, which made the OBF concept less attractive. Nowadays there is a strong focus on emission of green house gases from steel making. Within the joint European project, ULCOS, the OBF is proposed to be one of the possible routes to cut CO2emissions from steel making by 50 %. In the ULCOS-concept, cold oxygen is blown together with pulverised coal via coaxial lances into the tuyeres. CO2 is separated from the BF top gas in a VPSA (vacuum pressure swing adsorption). The remaining reducing gas is preheated and recirculated into the tuyeres (1200 C) and the lower stack (900° C) of the BF, see Figure 1. The process has been demonstrated in the LKAB Experimental BF at MEFOS in Luleå during a seven weeks campaign in 2007. In this paper the integration of a full OBF concept into an existing steel making plant based on the successful trial results from demonstration of the process in pilot scale is considered. A Process integration model is used to evaluate the effects of the new process route with respect to CO2-emission, energy consumption and cost. Description of studied system The SSAB Tunnplåt AB steel plant in Luleå, Sweden, is a BF/BOF route based system. The BF is operated with 100% pellets, and is equipped with pulverised coal injection (PCI). The PCI capacity is in the range of 160-180 kg per tonne of hot metal, depending on production level. A coke plant produces the majority of the coke used in the BF. Since the introduction of olivine pellets from LKAB in the mid 80’s, the slag volume has been low, in the range of 150170 kg per tonne hot metal, and the reductant rate among the lowest in the world. In plant fines are recirculated to the BF as cement bounded briquettes, at a rate of ~50 kg per tonne of hot metal. There are two basic oxygen furnaces (BOF converters) in the system, operated with hot metal from the BF and a small amount of scrap. The crude steel is further treated in the CAS-OB and RH degassing units. Two continuous casters produces slabs that are transported 1000 km by train to the rolling mill located in Borlänge. In 2006 the slab production was 2020 ktonnes. The distribution of process gases is shown in Figure 2. Since the rolling mill for the plant is located at another site, a surplus of process off-gases arises (coke oven gas - COG, Blast furnace gas -BFG and steelmaking gas - BOFG). The BF hot stoves uses BFG with addition of COG as fuel. The coke oven is fired with pure COG. Other usage of the COG is in lime kiln and burners in the steel plant. The recovered BOFG together with the surplus of BFG and COG is used as primary fuel in a near by heat and power plant (CHP). The CHP plant produces hot water for district heating for the community, electricity for the steel plant and the waste gases are used for drying in a wood pellet production facility. Production chain Raw material Gas distribution Raw material Coke oven BF BOF CC Slabs CHP plant Figure 2 A schematic description of gas- and energy distribution within and between the processes Method Process integration Process integration is a generic term for structured methods used in analysis of industrial energy systems. These methods are applied for the design of integrated production systems and treats complex systems with different inner and outer requests. They have special emphasis on the efficient use of energy and reducing environmental effects. The methods can be used in analysis- and decision making to achieve over all solutions that gives more effective industrial systems in environment-, energy- and cost point of view. In the analysis of converting No 3 BF at SSAB Luleå Works to the OBF process mathematical linear programming (MILP) was used. The mathematical programming method refers to a process system modelled with mathematical relationships. The optimisation problem is defined by a mathematic description of the system and an objective function defining the goal to be optimised in the system. The optimisation is defined as maximisation or minimisation of the goal. Model description The process integration model for the SSAB system is based on previous modelling work [5]. The core of the model is a mass- and energy balance for the production chain. Separate subbalances for the main processes provide the possibility to do an over all analysis over the steel plant and calculate the effects of a change in the operation practice for the processes. The driving force of the model is the production of slabs. Each step of the process is linked to the next by the primary product from each process; coke, hot metal and liquid steel. The steel demand in the continuous casting decides the level of production in the BOF, which in turns leads to a certain amount of production in the BF. The electricity demand is included as normalised electricity consumption per tonne of cast product. Coke plant The model calculates the production of coke and by-products (coke oven gas, benzene, sulphur and tar) based on the ingoing coal properties. The rate of production in the coke plant is set to 84 t coke/h. There is a possibility to buy or sell coke if the demand from the BF is higher or lower than the actual production. Blast furnace Ferrous materials and additives are together with coke charged through the top of the BF. Hot blast or oxygen is blown through the tuyeres, where pulverised coal is also injected. The reductants are combusted by oxygen in the hot blast and its main task is to reduce and heat up the descending burden. A need of power, oxygen, COG and steam/heat are included in the description of the process. The chemical reactions in the process are too complex to describe mathematically. A separate BF simulation tool is used to create the different cases of operation to be included in the overall optimisation model. The model divides chemical and thermal reactions in the furnace into different sections, above and below the reserve zone. The off-line BF simulation model has been extended to model also the OBF. Modelling results have been validated by results from OBF operation with top gas recycling at the LKAB Experimental Blast Furnace. The model results were then applied on the SSAB No 3 BF at Luleå Works. The estimated process data are shown in Table 1. Table 1 BF No. 3 reference data and OBF data Parameter Burden Pellet Limestone BOF slag Briquettes Reducing agents Coke PCI Gas inj. tuyeres Temperature Gas inj. shaft Temperature Tuyere parameters Blast volume Oxygen Blast temperature Flame temperature Bosh gas volume Normalised Top gas Volume Temperature CO CO2 H2 N2 ηCO Heat value Shaft efficiency Direct reduction rate a b Unit Ref 2006 OBF kg/tHM kg/tHM kg/tHM kg/tHM 1362 26 46 59 1366 20 42 59 kg/tHM kg/tHM Nm3/tHM °C Nm3/tHM °C 318 142 0 206 170 284 1000 244 900 Nm3/tHM % °C °C Nm3/tHM 976 24 1100 2086 1308 1.0 216a b 100a b 25a b 2283 808 1.7 Nm3/tHM °C % % % % 1471 120 20.5 24.7 3.5 51.3 0.547 2.97 0.97 0.32 1088 100 44.2 40.6 10.5 4.7 0.479 6.7 0.96 0.14 MJ/Nm3 0 based on oxygen flow to blast tuyeres based on total flow to blast tuyeres One difference between the conventional BF and the OBF is the recirculation of reducing gases. After cleaning, the top gas enters a CO2 removal unit in order to separate the CO2. In the modelling a VPSA has been used for CO2 separation. After preheating, the injected gas is distributed into the furnace at two levels; the normal tuyeres and a new set of tuyers in the shaft. The specific energy consumption for VPSA, including cryogenics and compression enabling long-range transport and storage of CO2, is included. Aiming for the same production rate for the OBF case as for the reference case will result in lower bosh gas volume. The comparison of the bosh gas volume for the OBF case with the reference case indicates that the production rate could be significantly increased. To avoid low top gas temperatures causing condensation of water in the BF top and at the same time keep the flame temperature below 2300 °C, the blast parameters have to be adjusted. As can be seen from Table 1, a tuyere gas temperature of 1000 °C will result in a top gas temperature of 100°C and a flame temperature of 2280 °C. A decreased tuyere gas temperature decreases the energy demand of the hot stoves. Basic oxygen furnace The hot metal produced in the BF passes the sulphur refining process and enters the BOF. The BOF model is based on a heat and mass balance determining the amount of different ingoing materials. The oxygen demand is calculated on the basis of the total carbon content oxidised and the metals oxidised in the slag. The post combustion ratio defined as the ratio CO2/CO in the BOFG is set to 0.3. Scrap is used as a cooling agent in the converter due to the large amount of energy released. The properties of the slag are controlled by addition of fluxes. The slag basicity practice of CaO/SiO2=4 is used in the calculation. Continuous casting The liquid steel is treated in a secondary metallurgy process before entering the continuous casting. The secondary metallurgy is not considered in the model and the liquid steel is directly introduced to the continuous casting from the BOF shop. A liquid exchange efficiency, ηLS=0.95 is used as a ratio between the liquid steel and the cast product. The recoverable losses are brought back to the BOF shop as cooling agent. The surrounding system and CHP plant The off-gases from the steel plant are collected in gas holders for COG, BOFG and mixed gas (BF-, BOF- and COG). Some of the gas is brought back to the processes as fuel and some is used as the primary fuel in the CHP. The CHP plant has two modes of operation, the pure back-pressure mode or the partly condensing mode. In the 100 % back-pressure mode of operation, the district heating demand of the city of Luleå is used as a heat sink. For this operation the ratio between the power and the heat generation, is set to 0.44. In the completely condensing mode of operation, all the heat is cooled by an external cooling circuit. The steam is expanded further in an extra turbine stage in the steam turbine. This results in extra power generation. The energy efficiency for the electricity generation is set to 0.32. Analysis of CO2 emissions, energy conversion and cost Raw materials and products are analysed with respect to possible CO2- and energy sources in the system. The objective function coefficients for CO2-emissions, energy conversion and costs are shown in Table 2. The costs considered in the model are raw material costs and the main investment costs. The investment cost is estimated from Table 2 Coefficients included in the rebuilding the existing BF. objective function Resource Coking coal PCI coal External coke Pellets Limestone Raw dolomite Dolomite FeSi Scrap Oil Power Credits Power Coke Benzene Sulphur Tar Unit ton ton ton ton ton ton ton ton ton ton MWh MWh ton ton ton ton CO2 objective (tonne/unit) [2.49-3.07] 2.92 3.69 Energy objective (GJ/ unit) [27.0-35.9] 28.2 42.2 0.43 0.47 3.05 0.60 40.2 3.6 -0.60 -3.69 -3.29 -3.6 -42.2 Cost objective (€/unit) [54.7-88.0] 125 271 93 51 31 98 428 266 681 0.043 -0.043 -271 -170 -4 -138 • • • To clean CO2 from the top gas a CO2 removal unit is needed. In the analysis costs for a VPSA unit was considered. The existing silica refractories in the hot stoves have to be replaced with alumina bricks due to carburization. New piping for shaft- and tuyere gas injection has to be installed. The existing oxygen plant is too small to handle the demand of oxygen for the new -3.35 process. The investment cost of a new oxygen plant is not estimated. Instead the unit price of oxygen is included. The estimated cost to rebuild SSAB BF No 3 to an OBF is 1000 MSEK. The investment calculation is made according to an annual repayment according to: r Annual repayment = (1) *G −n 1 − (1 + r ) r = interest n = Economical endurance G = Investment The calculation is made with an interest of 15 % and an economical endurance of 15 years. In the evaluation, the annual repayment cost is converted into an hourly cost based on the hourly production set in the system. Results Seasonal variations of the district heating in the CHP plant are defining three cases; an average level of 80 MWh/h as well as a cold winter day and a warm summer day of 140 and 25 MWh/h respectively. In the model oil is set as back up resource if the energy content in the mixed gas is not sufficient for the energy demand in the CHP. Based on the estimated data for the new BF process, the integration of a full OBF was examined in a process integration model for the SSAB Luleå Works. The modelling work was evaluated for three OBF cases as well as a reference case of the SSAB BF No 3 with respect to CO2-emissions, energy conversion and costs. Table 3 Material consumption parameters for the modelled cases OBF Ref. Summer Coke Plant Coke prod. kg/t slabs to BF/OBF kg/t HM deficit / surplus kg/t HM Coke oven gas nm3/t Coke BF/OBF Total HM prod kg/t slabs BF Slag kg/t HM Material consumptions Pellet kg/t HM Coke kg/t HM PCI kg/t HM C kg/t HM Mn ore kg/t HM Lime stone kg/t HM By prod. Briquette kg/t HM BOF slag kg/t HM Injected gas Tuyers nm3/t RJ Shaft nm3/t RJ Oxygen nm3/t RJ Hot blast nm3/t RJ Top gas Volume nm3/t HM Heat value MJ/nm3 VPSA Feed gas nm3/t RJ Inj. Gas nm3/t RJ Tail gas nm3/t RJ CO2 tailgas kg/t HM Excess nm3/t HM Power BF/OBF kWh/t HM BOF shop HM input kg/t LS BOF Slag kg/t LS Total scrap kg/t LS CaO/SiO2 Oxygen nm3/t LS CC Casted slabs Mt/y CHP plant Total Fuel TWh/y Mixed gas TWh/y Oil TWh/y 364 302 -16 433 364 208 95 435 1115 162 1110 150 1362 318 141 400 4 30 59 46 1364 208 170 328 0 17 59 47 --39 931 process In Table 3 the material consumption of the main processes in the modelled system are shown. The reference case OBF OBF Average Winter (Ref.) represents the modelled data of BF No 3 with an average district heat 364 364 208 208 demand of 80 MW. Each of the 95 95 modelled cases for the OBF; OBF 435 435 average, OBF summer and OBF 1110 1110 winter, has a specific hot water 150 150 demand of 80, 25 and 140 MW 1364 1364 respectively. 208 208 and 170 328 0 17 59 47 170 328 0 17 59 47 283 243 211 -- 283 243 211 -- 283 243 211 -- 1446 2.98 1088 6.70 1088 6.70 1088 6.70 ------ 1088 526 503 232 60 1088 526 503 232 60 1088 526 503 232 60 91 116 116 116 936 90 137 4.9 51 932 71 137 4.9 50 932 71 137 4.9 50 932 71 137 4.9 50 2.02 2.02 2.02 2.02 2.278 2.278 0.000 1.193 1.193 0.000 1.254 1.193 0.062 2.095 1.193 0.903 In the reference case, external purchase of coke is needed. For the OBF cases the coke demand from the BF is lower, resulting in an excess of coke. The total demand of reducing agents is lowered from 400 to 328 kg C, in total 18% reduction, in the OBF cases. Furthermore, due to the decreased reductant rate the slag amount is decreased and thus a lower amount of additives are needed. The top gas volume from the OBF is lower than for the BF, but has a higher heat value. Before recycling, the top gas content of CO2 is separated in a tail gas, totally 232 kg. The silicon content of the OBF hot metal is estimated to be reduced from 0.35 to 0.26 %. The reason is the higher partial pressure of carbon monoxide, which will limit the gasification of SiO. This will result in less demand of additives in the BOF, to reach the set point of slag basicity. The BOF slag amount is thus 21 % lower than in the reference case. Depending on seasonal variations, the demand of district heat will vary. In the OBF cases the total amount of fuel gases available within the system is 597 kWh/t slabs. Depending on the district heat demand the need of additional fuel (i.e. oil) will vary. This will also influence the power generation Effects on Energy, CO2 emission and Costs The change from traditional BF operation to OBF will influence the gas distribution within the site and to the external users. The gas- and energy distribution of the reference case is shown in Figure 3. The COG is used internally at the coke plant, BF hot stoves heating, lime kiln and for various burners at the BOF shop. The generated BFG is used together with the COG in the hot stoves. The BOFG is primarily sent together with the surplus of BFG and COG to the CHP. In total, the CHP plant receives 1128 kWh/t slabs while 265 kWh/t slab is flared. No external power is needed to fulfil the requirements of the plant. [kWh/t slabs] Coke plant 122 419 273 1128 1005 Blast Furnace 1' Gas holder CHP plant 2' 3' 42 329 BOF Drying gas Boiler 1' 45 DH 2' 347 Electricity production 3' 299 Electricity from grid 0 265 265 Figure 3 Gas- and energy distribution for the modelled reference case The corresponding gas- and energy distribution of the OBF average case is shown in Figure 4. The internal energy use of the coke oven is the same as in the reference case. The OBF utilises the energy within the system together with some addition of COG to reach the requirement of the hot stove firing. No external BFG is sent to the CHP. [kWh/t slabs] Coke plant 329 419 Oil 30 76 621 0 Oxygen Blast Furnace 1' Gas holder CHP plant 2' 3' 42 2247 BOF 6 268 Figure 4 Energy distributions for the OBF average case Drying gas Boiler 1' 45 DH 2' 347 Electricity production 3' Electricity from grid 153 269 The recovered gas energy sent to the CHP is 597 kWh/t slabs. The decrease is mainly due to the lack of BFG, however the COG available within the system is increasing due to less consumption in the BF hot stoves to heat up the injected gas, compared to the traditional system. The energy requirements in the CHP plant is not fulfilled by steel plant gases, so additional oil is required. The external power increases due to decreased power generation at the CHP plant as a consequence of decreased energy input from the steel plant. Figure 5a shows an evaluation of the energy conversion for the different cases. The energy requirement for the reference case is 20.4 GJ/t slabs. In the three OBF cases the energy conversion is 16.3 GJ/ t slabs within the process. This is a decrease of the energy demand of 20.3 %. External power and oil increases the energy demand for the total system, still resulting in lower energy demand than for the reference case. The total decrease is 8.5 – 15.5% compared to the reference case. Process 25 External power Oil DH Process 2.00 CO2 CCS External 1.80 15 20.41 10 16.27 16.27 16.27 5 t CO2/t slabs GJ/t slabs 20 1.60 0.16 0.17 0.21 1.40 0.26 0.26 0.26 1.20 1.00 1.83 0.80 0.60 1.22 1.22 1.22 Summer Average Winter 0.40 0.20 0 0.00 Summer Average Winter Reference Reference Figure 5 a) Energy conversions for the calculated cases of the total system b) The total CO2-emissions from the modelled system The calculated CO2 emissions for the system are shown in Figure 5b. In the reference case the specific emission within the system is 1.83 ton CO2/ton of slabs. In the OBF cases the calculated emission varies between 1.64-1.69, of which the site emission corresponds to 1.22 t CO2/t slabs. In the winter case with higher district heat demand, more power will be generated in the back pressure operation mode. The relative change in costs for raw material and energy for the average and summer case will decrease 7-8 %, mainly due to less coke demand. However, due to the need for oil in the winter case, the cost will increase with 7 %. The calculated investment cost is increasing the relative costs with 2.7 %, however for the average case still less than for the reference system (4 %). Discussion A process integration model for the material and energy system at SSAB Tunnplåt AB has been used to examine the effects of changing the existing BF to an OBF with regards to material flows, CO2 emissions, energy conversion and costs. Calculation of operational data for converting the BF to an OBF operated on the same raw materials shows that it is possible to decrease the coke consumption with 110 kg/t HM. This is achieved by increasing the PCI rate (+28 kg/t HM) and recirculation of the top gas. The OBF operation has several other positive effects on the system. The generated slag will be less, due to the decreased coke rate in the blast furnace. Furthermore, the reduction of silicon content in the hot metal will influence the production practice in the BOF, thus lower silicon content decreases the chemical energy released from the oxidisation of Si to SiO2. This results in less scrap melting capacity for the converter, and higher amount of hot metal or less iron ore needed for cooling. However from the positive side this also effects the amount of slag additives and the amount of slag generated. The decrease in generated slag (BF and BOF) will be significant (-69.7 kton/y). The decrease in coke rate in the OBF will result in a surplus of coke in the system, 214 kton/y. The excess coke can either be used within the SSAB Company at another site, or be sold on the market. The evaluation has not considered the possibility to decrease the production of coke. The energy system at a steel plant is very complex. The generated off-gases are used as fuel in other processes. In the SSAB case the main user is a power plant supplying the community with district heat as well as producing power for the steel plant. The main idea with the OBF process is to recirculate the off-gas and in that way decreasing the amount of gases out from the system. Today, the BFG stands for 65% of the fuel supplied to the power plant. There is a gas surplus in the system which is seen as flaring of gases (20%). In the OBF case, the fuel to the CHP is decreased significantly as no BFG is available. This results in a demand for an additional fuel, e.g. oil. Depending on seasonal variations the amount is varying. More oil is needed in the winter case than in the summer case. Interestingly to notice is that the amount of available COG will increase and can be used to replace some of the BFG at the CHP. The reason for the increased availability of COG is mainly due to the fact that less energy is needed to heat up the injection gas compared to heating up conventional hot blast. The injection gas volume is 40 % less than that of conventional blast, furthermore has the injection gas lower temperature. The power demand for the system is increasing due to the fact that the OBF process has a higher specific power demand compared to the conventional BF system. This is an effect of the choice of CO2 removal unit and the increased oxygen demand for the system. With less fuel gas to the CHP, less internal power will be generated and there will be a demand for external electrical power. This will be influenced by the seasonal variations. In the winter case more fuel is supplied and hence more power will be produced. The specific energy use for the steel plant with an OBF will decrease with 15.5%. If the effect of external energy sources is taken into consideration the decrease is 8-15%, depending on the seasonal variations. The main reason for the decreased energy use is the decrease in coke consumption, however the effect of improved gas management, i.e decreased flaring due to gas deficit will also have an impact. From the CO2 emission point of view, the analysis is more complex. If considering the system without storage of the removed CO2 and including the emissions from external power the CO2 emission is decreased by 10% (totally 25%). If CO2 storage could be utilised additional 15% reduction could be achieved. If the emissions from external power or oil are excluded the site emissions would decrease 33% compared to the reference. Thus it is of great importance to be able to store the captured CO2 as well as having a CO2 lean fuel alternative for the CHP. The cost for rebuilding the SSAB BF to an OBF has been estimated to 1000 MSEK. From a cost perspective the OBF will decrease the costs for raw material and energy with 8% manly due to the less demand for coke. Increased coke price on the market will result in even further advantages for the OBF. Penalties for CO2 emissions have not been included in the evaluation. The costs for CO2 permits is varying and is at present 21 €/ton CO2 [6]. Based on the assumption of investment cost, the increase of the relative cost is 3%. The cost for emitting CO2 is likely to increase in the future, however with the level of today’s prices, the benefit from reduced CO2 emissions in the order of 10% would result in reduced cost with 2%. If CO2 could be stored the cost reduction would be as high as 7%. Conclusion The implementation of the OBF concept, with recycling of BF top gas after CO2 removal with a VPSA, has been analysed for SSAB Luleå Works. The analysis is based on successful results from demonstration of the process in pilot scale. Under the assumption that the process can be scaled up successfully to production rate and size of BF No. 3, following will be valid; The coke demand for the system is decreasing when replacing the BF with an OBF. The coke saving from the system is significant and can either be supplied to other sites within the SSAB company, or be sold externally. With increasing coal and coke prices this might be of great importance Integration of the OBF in an existing system is restricted by the existing infra structure and energy users. The fuel for the CHP will be decreased and a need for additional fuels will arise. The potential reduction of CO2 emissions is due to this reason not fully utilized. Acknowledgement We are grateful to Centre for Process Integration in Steelmaking (PRISMA) for the possibility to prepare this paper. PRISMA is an Institute Excellence Centre (IEC) at MEFOS, Metallurgical Research Institute AB, supported by the Swedish Agency for Innovation Systems, The Knowledge Foundation, the Foundation for Strategic Research, and by the industrial participants Luossavaara-Kiirunavaara AB, SSAB Tunnplåt AB and Rautaruukki Oyj. Reference [1] M. Qin Z. Gao G. Wang and Y. Zhang. Blast furnace operation with full oxygen blast. Ironmaking and Steelmaking vol 15 (1988) [2] R. Murai, M. Sato and T. Ariyama. Design of innovative blast furnace for minimizing CO2 emission based on optimization of solid fuel injection and top gas recycling. ISIJ International Vol. 44 (2004) [3] M. Chu, H. Nogami and J. Yagi. Numerical analysis on blast furnace performance under operation with top gas recycling and carbon composite agglomerates charging. ISIJ International Vol. 44 (2004) [4] M. A. Tseitlin, S. E. Lazutkin and G. M. Styopin. A flow-chart for iron making on process oxygen and hot reducing the basis of 100 % usage of gases injection. ISIJ International. Vol. 34 (1994) [5] M.Larsson, J. Dahl. Reduction of the specific energy use in an integrated steel plant- The effect of an optimisation model. ISIJ International vol 43 (2003) [6] Nordpool.com 2008-03-19
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