Algal-Sludge Granules as a Novel Technique for Wastewater Treatment Ahmed S. Abouhend1,2 1 Civil & Env. Eng. Dep., Umass Amherst, USA 2 Marine Pollution Lab., NIOF, Egypt The Northeast Residuals And Biosolids Symposium, Oct. 19, 2015 Civil & Environmental Engineering Background ! Conventional Wastewater Treatment Process Cost (Energy): https://www.britannica.com/technology/wastewater-treatment/images-videos Civil & Environmental Engineering " 3-4 % of US Electricity 2 Secondary Treatment ! Activated Sludge System Cost (Energy): " 25-60% of costs http://www.ewisa.co.za/misc/wastewater/defaultas1.htm https://www.lakelandgov.net/water/education/plant-tours/water-reclamation-plant/tour-stop-no-5 Civil & Environmental Engineering 3 Wastewater as a Significant Energy Source " Chemical energy in wastewater ! Based on COD; 1 m3 = 6-8 MJ " Energy used for treatment ! 1 m3 = 0.6 kW h = 2.16 MJ Wastewater holds about 2-5 times the energy used to treat it. ! The Question: How to Recover This Energy? Civil & Environmental Engineering 4 Alternative Technologies ! Algal-based Wastewater Treatment Technologies " Most wastewater treatment lagoons in the U.S. do not harvest algae biomass. http://algaebiogas.eu/algal_bacterial_wwt Civil & Environmental Engineering 5 The Novel Technology: Algae-Sludge Granules Algae Bacteria Civil & Environmental Engineering 6 How the opportunity was identified? Granules Seed Granule 10 mm Wastewater Treated Seed Granules water Biomass Reactor Granules Settling Civil & Environmental Engineering Granules 2-4 mm 7 Application: Sequenced Batch Reactors # 2 SBRs (1.5 L each) by 4- 6 hrs cycles/day. R1 # The WW is the primary effluent of AWWTP. # 150 days of operation. # 2 Light sequences were studied; R1: 3.5 hr l- 2.5 h d R2: 2.5 hr d- 3.5 h l R2 # HRT: 1 day 0.75 46 1 17 47 0.5 8 64 72 0.75 day 79 150 Days of Operation Civil & Environmental Engineering 8 Potential Impact of Treatment Process Influent WW Cycling and Mixing Civil & Environmental Engineering After 15 min Settling 9 Effluent Quality ! COD Removal Conentration (mg/L) 250 TCOD 200 150 Inf 100 R1 R2 50 0 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 Days of Operation Civil & Environmental Engineering 10 Effluent Quality ! Total Nitrogen (TN) TN Conentration (mg/L) 50 40 Inf 30 R1 20 R2 10 0 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 Days of Operation Civil & Environmental Engineering 11 Effluent Quality ! Ammonia (NH3) 50 NH3 45 Conentration (mg/L) 40 35 Io 30 G1 25 G2 20 15 10 5 0 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 Days of Operation Civil & Environmental Engineering 12 Effluent Quality ! Phosphate (PO4) 10 Conentration (mg/L) PO4 8 C5H7O2NP0.1 Io 6 G1 G2 4 2 0 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 Days of Operation Civil & Environmental Engineering 13 Self Aeration : Natural Oxygenation O2 Production Rate 14 O2 Production DO (mg/l) 12 Specific Oxygen Production Rate: 10 y = 0.2011x + 1.7461 R² = 0.96267 8 6 8.0 (mg/gVSS)/hr 4 2 0 0 10 20 30 40 Time (Min) Civil & Environmental Engineering 50 60 14 Biomass Separation and Energy Production ! Algal-sludge granules settled with an average settling velocity of Biofeed 12 m/h.Stock Energy Generation 0 min 1/2 min 1 min Fermentation 5 min 15 min Anaerobic Digestion Transesterification << 99% Biomass Separation Efficiency Civil & Environmental Engineering 15 The Yield (Biomass-Energy Conversion) ! The biomass yields were up to 400% higher than typical activated sludge: 1 g COD Consumed 1.41 g COD (Biomass) Algal Granules Civil & Environmental Engineering 0.34 g COD (Biomass) Activated Sludge 16 Conclusion Algae-Sludge Granules Technology ! Demonstrated wastewater treatment without external aeration. ! Allows for recovery of energy laden in WW in the form of harvestable biomass and leads to substantial cost reduction in WW treatment. ! Achieves environmental benefits reducing the green house gases emitted into the atmosphere ! The successful application could provide an alternative to the activated sludge process. Civil & Environmental Engineering 17 Current and Future Research ! Operating a pilot ASG unit at AWWTP: * Now; 30 L reactor as SBR * Our goal: 1000-2000 L System ! Investigation on several others $ Pathogens $ Heavy metals ! Anaerobic digestion of ASG biogranules. Civil & Environmental Engineering 18 Acknowledgement # Park Lab Group # NIOF, Egypt $ Chul Park, Ph.D. $ Khalid El-Moselhy, Ph.D. $ Jeongmi Seo $ Christopher Watt $ Adam McNair Funding Civil & Environmental Engineering 19 Civil & Environmental Engineering 20
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