PLEASE Remember to do this in DARK BLUE OR BLACK INK. You may not write over pencil. Answer all analysis questions on your own. If you have questions, please ask me. For any question requiring an explanation, please put it in a complete sentence. Electrolytes Lab Objectives Observe and record the electrical conductivity of water solutions and solid compounds.' Classify substances as strong electrolytes, weak electrolytes or nonelectrolytes using conductivity data. Introduction Electrolytes are compounds that exist as dissolved ions in water solutions. A distinguishing macroscopic property of electrolyte solutions is that they conduct electricity. Molten electrolytes also conduct electricity. The submicroscopic interpretation is that the ions are free to move about in the liquid, and these charged particles carry the electrical current. Purpose In this experiment you will investigate water solutions of chemicals by testing them for conductivity. . You will interpret your results in terms of the submicroscopic behavior of atoms and molecules. Finally, you will test various solutions to determine their relative tendencies to conduct electricity, and again interpret you results based on what the electrons, atoms, and molecules are doing. You will classify solutions as strong electrolytes (those that readily conduct electricity); weak electrolytes (those that conduct electricity only weakly); and nonelectrolytes (those that do not conduct electricity). When the two leads are immersed in a drop of solution or in a solid that conducts electricity, the light emitting diode (LED) will glow. Safety Wear your safety goggles Use only full small-scale pipettes on for the carefully controlled delivery of liquids. Do not drop the pipette on the bulb; it could cause the chemical to splash. If you are using acetone, be aware that it will remove nail polish. Materials Small-scale pipettes of the following solutions and solids: Solutions: methanol (CH3OH) water ethanol 2-propanol hydrogen peroxide(CH3CH2OH) or (CH3CHOHCH3) Solids and solutions sodium chloride sodium carbonate potassium iodide potassium chloride Acetone CH3COCH3 calcium chloride sucrose PLEASE Remember to do this in DARK BLUE OR BLACK INK. You may not write over pencil. Answer all analysis questions on your own. If you have questions, please ask me. For any question requiring an explanation, please put it in a complete sentence. Equipment: Small-scale reaction surface conductivity apparatus small cup with distilled water for rinsing electrodes EXPERIMENT Wear your goggles. Wear an apron. Follow all safety rules. Record your observations on the sheet that says EXPERIMENTAL DATA. Part A. Conductivity of Ionic Compounds 1. To test the compound dry, place 1 grain of each solid in the indicated place on the reaction surface and test each for conductivity. To test the compound wet, use the DROPPER that says “distilled water”; not your rinsing water. Add 1 drop of distilled water to each compound and test the “wet” mixture. - Write ALL your observations on the “Experimental Data” page. 1) Did the light go on and if so 2) was it strong or weak? 3) Did anything else happen? NaCl(s) KCl(s) KI(s) CaCl2 (s) Na2CO3(s) C12H22O11 (s) salt “lite” salt un-iodized salt ice-melter washing soda table sugar Part B. Conductivity of Liquids 2. Place 1 drop of each indicated chemical solutions bellow on the plastic sheet in the designated place and test each drop for conductivity with the conductivity apparatus. Be sure to clean and dry the conductivity leads after each test. 1) Did the light go on and if so 2) was it strong or weak? 3) Did anything else happen? H2O (l) water CH3CH2OH (l) Or CH3COCH3 CH3CHOHCH3(l) ethanol (grain) or acetone 2-propanol rubbing alcohol CH3OH (l) methanol (wood) alcohol H2O2 (l) hydrogen peroxide a disinfectant Cleaning up Avoid contamination by cleaning up in a way that protects you and the environment. Careful clean the reaction surface with a damp paper towel and dry the surface. Dispose of the paper towels in a trash BAG, not in the trash can. You will be instructed to wash your hands. Put them completely under the running water and rub them together. You do not need to use soap. Turn In From this point to the end. Do not turn in the 1st 2 pages. Name ______________________________________ Per ____________ Name_______________________________________ Name ______________________________________ Name ______________________________________ EXPERIMENTAL DATA PART A Write your, record your results for the tests done on the previous page. YOU MUST HAVE ANSWER FOR AT LEAST 1 & 3. 1 & 2 can be just one word. 3 can be abbreviated if it is understandable (Give a key). 1) Did the light go on and if so 2) was it strongly or weakly? 3) Did anything else happen? NaCl(s) KCl(s) KI(s) CaCl2 (s) Na2CO3(s) C12H22O11 (s) salt “lite” salt un-iodized salt ice-melter washing soda table sugar 1. Observations dry 2. 3. Observations “wet” PART B H2O (l) CH3CH2OH (l) or CH3COCH3 CH3CHOHCH3(l) ethanol (grain) or acetone 2-propanol rubbing alcohol CH3OH (l) H2O2 (l) Observations water methanol (wood) alcohol hydrogen peroxide a disinfectant Remember to do this in DARK BLUE OR BLACK INK. You may not write over pencil. Answer all analysis questions on your own. If you have questions, please ask me. For any question requiring an explanation, please put it in a complete sentence. PLEASE Questions for Analysis Use what you learned in your observations to answer the following questions: Answer any question that requires a written response (not a picture) in a complete sentence. For these answers a weak glow is NOT a positive result – it does not conduct electricity. Describe how the electrolyte tester works including why it works on electrolytes and not on non-electrolytes. (Include how the electricity travels, what is happening to the circuit when the light goes on and when it goes off. What makes the electricity flow?) A. Which of the solids (no water added) in any part of this experiment conducted electricity? B. What must be added to the solids before it will conduct electricity? C. Does adding water make the substance conduct electricity every time? What substance(s) didn’t? You can picture solid sodium chloride as a regular ordered arrangement of atoms called an ionic lattice. Solid KCl and KI are similar to NaCl. Draw them and explain the result of the conductivity test of the solid versus when water was added in terms of your drawing. In other words, explain why the same compound gave a different result when tested as a solid and as a liquid using the drawing. Using the drawings AND explain in words why electricity flowed in the aqueous forms but not in the solid forms. Use the drawings you did in the boxes to the left and this space to explain in words. Solid NaCl liquid NaCl Solid KCl liquid KCl Solid KI Liquid KI Remember to do this in DARK BLUE OR BLACK INK. You may not write over pencil. Answer all analysis questions on your own. If you have questions, please ask me. For any question requiring an explanation, please put it in a complete sentence. PLEASE 3. You know that solutions that conduct electricity do so because they contain ions that are free to move about in solution. The picture below is an example of a solution of aqueous sodium chloride. Draw pictures to represent the solutions of KI and KCl. Use another piece of paper if you do not have enough room. 4. Which of the liquids in Part B conducted electricity? This is a list and does not need to be in a sentence. ___________________________________________________________________________ ___________________________________________________________________________ 5. Make a list of the formulas for all the substances dissolved in water or liquids used in this lab that electrolytes. (This does NOT need to be in a sentence.) _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ were 6. Make a list of the formulas for all of the non-electrolytes use in this lab. (This does NOT need to be in a sentence.) _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ 7. Why is pure water (distilled) considered a non-electrolyte? ___________________________ ___________________________________________________________________________ ___________________________________________________________________________ 8. Predict what will happen if you test tap water for conductivity and explain why. ___________ ____________________________________________________________________________ ____________________________________________________________________________ 9. What is the characteristic of an electrolyte solution that allows it to conduct electricity? ___________________________________________________________________________ ___________________________________________________________________________ 10. Describe characteristic of the structure of the non-electrolytes that prevents them from conducting electricity? _________________________________________________________________ ___________________________________________________________________________ __________________________________________________________________________
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