Selectech Page 1 of 4 [WEBLINK] September 2014 Newsletter Take a Look at the latest image of the Antarctic Ozone Hole Positive Indications from the UN Environment Programme and the World Meteorological Society Report by ScienceDaily Thanks to concerted international efforts, our ozone layer is well on track to recovery. This does not mean that challenges do not remain ahead, but it is good news! Without the Montreal Protocol and associated agreements, atmospheric levels of ozone depleting substances could have increased tenfold by 2050. According to global models, the Protocol will have prevented 2 million cases of skin cancer annually by 2030, averted damage to human eyes and immune systems, and protected wildlife and agriculture, according to UNEP. The phase-out of ozone depleting substances has had a positive spinoff for the global climate because many of these substances are also potent greenhouse gases. The images above show the Antarctic ozone hole on September 16 (the International Day for the Preservation of the Ozone Layer) in the years 1979, 1987, 2006, and 2011. The first two maps are based on data from the Total Ozone Mapping Spectrometer (TOMS) on the Nimbus-7 satellite. The other two maps are made with data from the Ozone Monitoring Instrument on the Aura satellite. Though taken by different instruments, the data sets have all been cross-calibrated and reanalyzed by scientific models. Credit: Images from NASA animation by Robert Simmon, using imagery from the Ozone Hole Watch "On September 23, the UN Secretary General will host Heads of State in New York in an effort to catalyse global action on climate. The Montreal Protocol community, with its tangible achievements, is in a position to provide strong evidence that global cooperation and concerted action are the key ingredients to secure the protection of our global commons," said Achim Steiner of the UNEP. View detail at ScienceDaily Optimise your Chlorification Process Monochloramine as a Secondary Disinfectant Selectech Page 2 of 4 Monochloramine has been used as a water disinfectant since the 1900's and is popular as a secondary disinfectant in water, rather than the only disinfectant. Monochloramine takes longer to disinfect water than does chlorine, so it is seldom used as a primary disinfectant. It's also much less efficient at deactivating pathogens. The stability of monochloramine is what makes it a useful addition. According the the EPA, monochloramine use has expanded recently because of new drinking water regulations that have been developed to limit the amount of disinfection byproducts. What is monochloramine? Monochloramine is formed when chlorine, and then ammonia, is added to water, in sequence. In ammonia, a hydrogen atom is substituted by a chlorine atom to form NH2Cl. It is a less effective disinfectant than chlorine, but is more stable. Monochloramine lasts longer in water systems than chlorine. Advantages: z Mainly used as a second disinfectant in water to provide a longer lasting residual level of disinfectant z Produces fewer potentially harmful disinfection byproducts than Chlorine z Lower decomposition rate makes it useful in killing longer lasting biofilms in pipes, bacteria and the organisms that cause Legionnaire's Disease z Less tendency to react with organics in the water and form taste and odour causing compounds Just like chlorine, high levels of monochloramine in water can be toxic. Levels are strictly regulated by local governing bodies. Free ammonia and monochloramine can both be tested with the Lovibond® MD100 Photometer. Criteria in South Africa: Monochloramine in Drinking water: ≤ 3 mg / litre * SANS 241-1: 2011 Drinking Water Standards Why test for Ammonia? Ammonia is highly soluble in water. One volume of water will dissolve 1 300 volumes of NH3. Ammonia reacts with water to form a weak alkaline. Most Ammonia in the environment comes from fertilizers (sometimes in the form of Ammonium salts such as Sulfate and Nitrate. Large amounts are used in the production of nitric acid, urea and Nitrogen compounds. It is found in ice and refrigerated plants. It is used in household cleaning to remove carbonate from hard water. Since Ammonia is a decomposition product from urea and protein, it is found in wastewater. Many water treatment processes add ammonia to form monochloramine as part of the disinfection process. Aquatic life also contribute to ammonia levels in a stream. NH3 is the principle form of toxic Ammonia. It has been reported toxic to fresh water organisms at Selectech Page 3 of 4 concentrations of 0.53 to 22.8 mg / litre. Toxic levels are both pH and temperature dependent. Toxicity increases as pH decreases and also as temperature decreases. Fish exposed to low levels of Ammonia are more susceptible to bacterial infections, have low growth and are stressed. Tissue changes in their gills, liver and kidneys may also occur. Ammonia is a killer when present in higher concentrations and many unexplained losses have been caused by Ammonia. Toxic concentrations of Ammonia in humans may cause loss of equilibrium, convulsions, coma and death. Ammonia should be tested regularly and corrective measures taken as soon as ammonia is detected, to prevent loss of aquatic life. Criteria in South Africa: Ammonia levels in ponds and fish tanks should be zero. When it is present, the fish in the system should not be fed until the problem is corrected. In small systems, a water change will help and in larger ponds, a 0-20-0 fertilizer may help. Wastewater* 1.0mg / litre for discharge of effluent water to rivers 10.0mg / litre for discharge of effluent water to other areas * DWA – Requirements for the Purification of waste water or effluent, Act No. 991 – 18 May 1984 Drinking water* < 1.5 mg / litre Ammonia as N * SANS 241-1: 2011 Drinking Water Standards Erratum In the article "Lead and Copper in Drinking Water" in the July Newsletter, the Criteria we used for the South African water standards (wastewater and drinking water) were outdated (SANS 2005). I apologise for this error. Thank you to Sarel Pieterse, the Head of the Water Laboratory, Cape Town Municipality, for pointing this out. Lovibond® MD100 CODE: LO276070 These Standards were, in fact, improved on in SANS 241-1: 2011 South African National Standard drinking Water. Here is the correct and updated verion: Criteria in South Africa: Lead Copper Wastewater: Wastewater: 0.1 mg / litre for discharge of effluent water to rivers 0.02 mg / litre for discharge of effluent water to rivers Selectech Page 4 of 4 0.1 mg / litre for discharge of effluent water to other areas 1.0 mg / litre - for discharge of effluent water to other areas Drinking water: Drinking water: Hand-held photometer that is ideal for fast and accurate testing of Free Ammonia and Monochloramine in water. ≤ 10 µg / litre ≤ 2000 µg / litre More detail & specifications More detail about SANS 241:2011 Drinking Water Quality Compliance and 2014 Blue Drop Limits from DWA Postal Address: PO Box 532 Allensnek 1737, South Africa This email was sent to [EMAIL], If you would like to be removed from the mailing list please click on the link below. 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