THE RELATIVE VALUE OF ENERGY DERIVED FROM MUNICIPAL REFUSE ROGER S. HECKLINGER Charles R Velzy Associates, Inc. Elmsford, New York or, in the case of the U.S. Environmental Protec tion Agency, the system sponsor. ABSTRACT Many systems for utilizing the heat energy in municipal refuse are in various stages of develop ment. These systems either use unprocessed solid waste as a fuel or derive a fuel through processing. The fuels produced vary radically in heating value. The energy expended in processing differs from one process to another and the potential end use is not the same for each system. Six representative systems are compared to determine the relative potential value of refuse as a source of energy. SYSTEMS CONSIDERED The six systems considered and the system de velopers whose data were used are tabulated in Table 1. TABLE 1 System Raw Refuse Incineration Developer City of Chicago - Metcalf & Eddy (1) City of Harrisburg - Gannett Fleming Corddry and Carpenter, INTRODUCTION Inc. In recent years, a number of systems have been developed to make use of the energy value of municipal refuse. Many of these systems have been reported in the literature and some have become operational. Not surprisingly, conflicting state ments have been made regarding the relative value of the fuel or energy produced by the various sys tems. Many of the conflicts arise because claims and comparisons are made based on varying raw refuse compositions and at different points along the energy transition path from raw refuse to ultimate use of the energy released. The purpose of this paper is to compare the relative value of refuse as a fuel for six processes beginning with a common raw refuse composition following a similar path through fuel processing, to combustion, heat absorption in steam, and finally to electrical power generation. All data used, except as noted, is taken from literature published by either the system developer (2) Town of Hempstead - Charles R Velzy Associates, Inc. (3) RESCO - Wheelabrator-Frye, Inc. (4) Mechanical Processing City of St. Louis - Horner & Shifrin-Union Electric Co. (5) (6) Thermochemical Processing Liquid Garrett Research and Development Co., Inc. Gas 1 (7) Union Carbide Corporation (9) City of etc. Gas 2 Biochemical Union Carbide Corporation Dynatech RID Company (9) (10) Processing The energy transition path is traced through four phases: Processing Combustion Steam Generation Electrical Generation 133 The first three phases are tabulated in Table 3. The relative potential for recovery of energy as process'or heating steam is tabulated in Table 4. The relative potential for recovery of energy as electrical energy is tabulated in Table 5. Specific comments for the various systems are included in a brief description of each system. Certain general comments pertain to all of the systems compared. 1) All systems receive the same raw refuse as tabulated in Table 2. Note the higher heating value is on a per ton basis as refuse processing plants are normally rated by capacity in tons per day. Both metric tons and short tons (2000 lb) are tabulated. TABLE 2 7) It is assumed that with the proper selection of heat traps, steam generation efficiency is un affected by the pressure or temperature of the steam generated. 8) The energy cost of transporting prepared fuel has not been considered or included for any system. 9) Carbon dioxide in the fuel gases is listed as "noncombustible", in Table 3. 10) For fuel gases, combustion losses are based on the components of the fuel gas listed in the description of the system. The six systems selected for comparison general ly cover the range of systems that have been pro posed in recent years. The specific systems were selected because adequate information was avail able in the literature to permit a meaningful companson. . Raw Refuse Proximate Analysis Moisture 27.0% Volatile 44.0% 7.0% Fixed Carbon 22.0% Noncombustibles Ultimate Analysis H20 27.0% Carbon 25.5% 3.4% Hydrogen 21.5% Oxygen 0.6% Nitrogen 22.0% Noncombustibles Higher Heating Value - 10.50 gigajoules per metric ton (9.00 million Btu's per ton) 2) Electrical power requirements for the Processing Phase have been adjusted from that re ported, where applicable, to exclude power require ments for materials recovery equipment which may be an integral part of the system. 3) Combustibles lost in the Processing Phase are those combustibles. that leave the system in a stream other than the fuel stream. For example, in the Mechanical Processing system, a significant amount of combustibles leave the system with the "heavy fraction" from the air classifier. 4) No attempt is made in Table 3 to relate energy from refuse with energy from auxiliary fuel or electrical energy. 5) Electrical power requirements tabulated in the Combustion Phase include energy required to operate the steam generating system. 6) Miscellaneous losses in the Steam Genera tion Phase include radiation loss and boiler blow down loss. RAW R EFUSE INCINE R ATION Raw refuse, as received, is continuously fed onto a grate system for combustion. The products of combustion are used to generate steam in a boiler integral with the grate and combustion sys tem. The steam may be used for heating, process, or electrical power generation. The combustible loss tabulated for the Com bustion Phase is somewhat higher than reported, to be conservative [J ,2,3] Excess air requirements and stack temperatures are higher than for most other systems. Steam conditions selected for electrical generation are lower than for most other processes. [4] MECHANICAL P R OCESSING The system tabulated follows data developed from the demonstration plant operated in St. Louis, Mo., to produce solid fuel for combus tion in utility boilers operated by the Union Elec tric Co. Electric power requirements in the Processing Phase were adjusted from that reported to account for two-stage shredding in a full scale plant and to exclude power requirements for ferrous metal processing. [5] The combustible lost in processing is somewhat better than reported in anticipation of improvements in a full scale plant. [5] Combustible loss in the Combustion Phase as tabulated is a considerable improvement over the losses of 5-40 percent that have been reported. [6] An improvement can be antiCipated for a full scale 134 w Vl ...... ?roduced ENERGY TO ST:::AM Excess Air Stack Te�perature Stack Loss Miscellaneous Loss STEAlo1 GE�E:<.ATION Heat Available 6.63GJ 26GC 1.81GJ 0.35GJ 7.53)113 20KWH 0.27MB 1. 20:-lB 0.99NB 6.11MB 1. lSGJ 7.16GJ 17SC O.72GJ O.21GJ 6.23GJ 5.67MB 5.4SMB 0.44GJ 6.37GJ 0.09MB 3.97MB O.llGJ 4.73GJ O.lSMS 57SF 1.4 S�:3 0.38:13 l7SC 0.38GJ 5.31MB - 0.44!'1B 7.31MB SO% 0.51GJ 8.53GJ - 20KI-/H 300C 1.72GJ 0.36�IB 4.39HB - 0.08GJ 350F 0.33:-\3 10% 0.42GJ 5.12GJ - 0.04GJ 10J.a-IH 4.75MB 0.25 5.54GJ 1.0 0.5 O. 9 4.9 60.9 15.7 9.04GJ 7.75MB 2.58 7.6 33.4 • 1.02MB 1.19GJ 12.8% 60KWH 0.24GJ 4.8 - - 130KWH 5% per Ton 4.1 35.5 30.0% - - - 135K:-IH 2 6.46�:B 0.54:-\3 6.83GJ 0.15GJ 17SC 0.5SGJ - - 15KViH 5.S6:-\3 O. 13:-\3 350F O.47:�3 15% 0.63GJ 7.53GJ - 0.06':;J 0.7 1.3 29.1 7.00:-\B S.16GJ - 0.54GJ Gas (2000 Ibs.) Thermochemical Processing Gas 1 (MB) 57.5% - 0.52GJ Liquid 3S0F 0.62:-\3 30% 0.64GJ 30KWH O. 55�1B 0.12GJ 0.80 18.0 S.9SGJ 7.65MB 23.6 O. 7 500F 1.56MB O. 3O�:B 1:) O\l' 1. 40GJ 8.79GJ Vaporization Loss 0.08GJ 0.31GJ 1.0 0.6 22.0 9.00MB 10.50GJ 3.4 21.5 28.0 3. 7 15% - 30KWH 25.5 - 0.12GJ Mechanical Processing_ 26.0% - - 10KWH (GJ) Based On Raw Refuse Containing per Metric 70n or 9.00 �Iillion Btu's 27.0% - 0.04GJ Power Requirement Corr.bustible Loss CO�!BUSTION Energy in Fuel t Fuel/ t Refuse Nitrogen Noncombustible H20 Carbon Hydrogen Oxygen Fu�l PROCESSII\G Po��r Requirement Auxiliary Fuel Combustible Lost Raw Refuse Incineration 10.50 Gigajoules 3 ENERGY PER TON OF REFUSE Table 3.53GJ O.O S G J l7SC 0.29GJ 5% O.48GJ 3.20GJ - O.O<:GJ . • ... . � .-' ..... ...... � ? _ :).,.. .:l 3.03:-!5 o o .,- �'C' ... :J,J� O.':l!'1S 3.351-13 - 'U 10'" � �.... 0.1 12.6 4.38GJ 3.76:-\3 - - 21.9 65.5\ - 0.22GJ 5 SKIlH 0.66GJ 0.57:-1B 45% Bioc�e:::ical P!"ocessina W 0\ Refuse Based on Steam Generation at 80% Efficiency 1.00 (Base) 4.83MB 0.89 5.67GJ 0.48MB ** Based on 42.5\ Turbine Eff. (8000 Btu/KwH Turbine Heat Rate) * Relative Value 5.43MB 0.56GJ 2.8SMB 1.12MB 0.53 3.41GJ 1. 32GJ 1 3.99MB 0.64MB 80KWH 0.82MB 5.4SMB 0.74 4.67GJ 0.75GJ 6.35GJ 6.37GJ Net Refuse Energy To Steam 0.24MB 140KWH 3.97:1B Gas 0.28GJ 0.56GJ 4.73GJ per Ton 4. 661-'.B 1.20MB lSOKWH 5.86MB 0.85 5.42GJ 1.41GJ 0.60GJ 6.93GJ 2 Ibs.) Gas (2000 Ther�ocheffiical Processing Less Steam Equivalent Electrical Energy ** Of 60KWH 5.31MB Liouid (MB) 0.32GJ 0.24GJ 6.23GJ Mec�anical Processinq Btu's Containing )Iillion 0.12GJ 30KWH· Raw Total Electrical Energy Required 5.67MB Based On per Mecric Ton or 9.00 0.95GJ 6.63GJ (GJ) Less Auxiliary Fuel @ 80\ Eft.* Energy To Steam I n c i n e ra c i on Raw Refuse 10.50 Gigajoules ENERGY PER TON OF REFUSE Table 4 2.05MB 0.521-'.B 6SK:m 0.46:1B 3.03z.<.B 0.38 2.39GJ 0.61GJ 0.26GJ 0.S3GJ 3.53GJ P:-c::essi:1o Bioc�e:cical W -J .... ** * (1800 psi), 540/540C 470C(875F) B - 605KWH 60KWH 665KWH 5.31MB 1.09 2.41GJ 0.24GJ 2.65GJ 6.23GJ Pro�essing Mechanical 356KWH l40KWH 496KWH 3.97MB (9750 Btu/KWH) 0.65 1.45GJ 0.56GJ 2.01GJ B 4.73GJ Liauid per Ton 378KWH 80X\<IH l02KWH 560K\<IH 5.45MB 0.68 1.56GJ 0.32GJ 0.35GJ 2.23GJ A 6.73GJ Gas 1 B 5B4KWH l50KWH 734KWH 5.86)013 1.06 2.30GJ - 0.60GJ - 2.90GJ 6.83GJ Ga s 2 (2000 lbs.) �hermochemic3l Processi�g (MB) (lOOO/lOOOF) Turbine Heat Rate 2.35 (8000 Btu/KWH) Turbine Heat Rate 2.86 1.00 (Base) 553KIYH 30KWH 583KWH 5.67MB (GJ) Electrical Equivalent Based on Plant Heat Rate of 3.4 (10,000 Btu/KWH) B-12.40 MPa A- 4. 50 MFa ( 650 psi), Relative Value 2.21GJ - Net Electrical Energy From Refuse 2.33GJ A 0.12GJ * 6.63GJ Less Electric"al Energy Less Electrical Equivalent of Auxiliary Fuel ** Electrical Output Steam Conditions Energy to Steam Raw Refuse Incineration 10.50 Gigajoules Based On Raw Refuse Containi�g per Metric 70n or 9.00 Hillion Btu's ENERGY PER TON OF REFUSE Table 5 257hl.H 65h....'H 57KHH 379KHH 3.03MB .46 1.04GJ 0.26GJ 0.20GJ 1.50GJ B 3.53GJ . Bioc�e�ical Processina by volume: plant due to two-stage shredding, a more effective injection point, and, if necessary, installation of a burn-out grate at the bottom of the furnace. CO H2 CO2 CO. C2Hx N2 THE R MOCHEMICAL P R OCESSING - LIQUID Raw refuse is shredded in two stages to 0.4 mm (0.015 in.) size and pyrolized under controlled conditions to produce a liquid fuel. Power requirements for the Processing Phase have been adjusted to exclude power requirements for materials reclamation features of the system. [7] The pyrolysis process also produces a com bustible gas and carbonaceous char. The gas is used for drying purposes and to sustain the process. The char is unsuitable for use as a fuel. The liquid fuel could be burned in most con ventional steam generators. Higher heating value at standard conditions is 11.2 MJ/m' (300 Btu/ft'). Pure oxygen is introduced into the bottom of the vertical pyrolyzing chamber. The oxygen com bines with some of the carbon in the refuse to produce the heat of pyrolyzation. There is no residue char. Electrical power requirements have been ad justed from that reported to account for the power requirements of the shredder. [9] The fuel produced can be burned in most con ventional steam generators. The gas clean-up system is assumed to produce a dry gas. , • THER MOCHEMICAL P R OCESSING - GAS I Raw refuse is coarsely shredded and pyrolyzed in an oxygen starved atmosphere to produce a fuel gas composed of the following by volume: H20 N2 CO2 CO H2 CH. C2 H. O2 47% 33% 14% 4% 1% 1% BIOCHEMICAL P R OCESSING Raw refuse is shredded and introduced into a liquid environment where microorganisms convert the cellulose in the refuse into methane and carbon dioxide. Most noncellulosic hydrocarbons are un affected by the microorganisms and thus are lost to the process. In addition, cellulose is lost in the continuous bleed of effluent from the digestor. Auxiliary fuel is required to support the process. [10] Methane is separated from the bulk of the carbon dioxide by absorption with mono ethanolamine to produce a fuel gas composed of the following by volume: CH. 95% CO2 5% The fuel gas can be burned in any boiler where natural gas can be burned. 18.5% 56.8% 9.3% 5.4% 5.2% 2.1% 1.4% 1.3% This wet analysis by volume and the individual losses were derived from the dry analysis and overall heat balance that have been reported. Higher heating value calculates to roughly 1.1 MJ/m' at 650C (30 Btu/ft' @ 1200 F). Auxiliary fuel is required to sustain the process. The losses tabulated have been adjusted from those reported to suit the Raw Refuse analysis. [8] Because of the volume of fuel produced and the sensible heat in the fuel, combustion must take place in close proximity to the point of pyrolysis. A specially designed combustion chamber and boiler are required. The steam conditions used for raw refuse incineration are also tabulated for this system. DISCUSSION It should be emphasized that all data for the Processing Phase of energy transition has been taken from the published references and adjusted only as noted. Combustible losses in the Combus tion Phase have also been based on published data as noted. Power Requirements in the Combustion Phase and Miscellaneous Losses in the Steam Generation Phase are either taken from the refer ences or are assumed based on experience with similar equipment. Vaporization Losses and Stack THE R MOCHEMICAL P ROCESSING - GAS 2 Raw refuse is coarsely shredded and pyrolyzed to produce a fuel gas composed of the following 138 Losses are either straightforward calculations CONCLUSIONS using established procedures or have been taken from the references. See Appendix for sample calculations of Vaporization -Loss and Stack Loss. One should understand, however, that none of the systems are presently operating as tabulated to the end point of Electrical Generation. Two general observations can be made. First, a great deal of energy can be lost in the Processing Phase. The fact that this happens is expressed as the Second Law of Thermodynamics. Second, the more complex (and thus less efficient) Processing Phases tend to produce a fuel that can be com busted relatively more efficiently. Therefore, in two of the systems tabulated, Mechanical Proces sing and Thermochemical Processing - Gas 2, Electrical Generation is more efficient than for Raw Refuse Incineration. ]n all other cases, Raw 1) None of the processing �stems tabulated is inherently more efficient than Raw Refuse In cineration as a means of utilizing the energy in refuse. 2) As a source of energy for process or heating steam, Raw Refuse Incineration is more energy efficient than all other processing systems tabulated. 3) Two of the processing systems tabulated, Mechanical Processing and Thermochemical Processing-Gas 2, can be more efficient for Elec trical Generation than Raw Refuse Incineration. 4) A careful study is required to determine if there are other benefits derived from a process to offset the inherent reduction in available energy that results from processing. Refuse Incineration is the most efficient system REFERENCES for utilizing the energy in refuse. Based on the data tabulated, the Raw Refuse Incineration system appears to have a potential for improvement that is not available to the other systems. For example, 10 percent more Steam [1] Stabenow, G., "Performance of the New Chicago Northwest Incinerator," Proceedings of 1972 National Incinerator Conference, ASME, New York, N.Y., 1972, pp. 178-200. [21 Pepperman, C. M., "The Harrisburg Incinerator: Generation energy or Electrical Generation energy A Systems Approach," Resource Recovery Thru Incinera could be realized if stack temperature could be tion, ASME, New York, N. Y., 1974, pp. 247-266. reduced from 260C (500F) to I 75C (350F). This is not an unreasonably low temperature to con sider. Or, 10 percent more Electrical Generation ings of (I 000 F) turbine. This has been done in Duessel forf, Germany, for over ten years. It may come as a surprise that combustible loss in the Combustion Phase is less for Raw Refuse Incineration than for Mechanical Processing. This may not be so surprising, if one understands that in Raw Refuse Incineration, unshredded refuse is ex posed to the combustion process for upwards of one hour, whereas in the Mechanical Processing [4] course factors other than time bear on combustible loss. The Tabulated loss for Raw Refuse Incinera tion is somewhat greater than reported [1,2,3], and MacAdam, W. K., Design and Pollution Control Features of the Saugus, Massachusetts, Stream Generating and Refuse-Energy Plant, APCA, Pittsburgh, Pa., 1974, Paper #74-95. [5] Shannon, L. J., Fiscus, D. E., and Gorman, P. G., St. Louis Refuse Processing Plant: Equipment, Facility, and Environmental Evaluations, U. S. Environmental Pro tection Agency, Washington, D. C., 1975, EPA-650/275-044. [6] Shannon, L. J., et aI., St. Louis/Union Electric Refuse Firing Demonstration Air Pol/ution Test Report, U. S. Environmental Protection Agency, Washington, D. C., 1974, EPA-650/2-74-073. system, processed refuse is exposed to the com bustion process for approximately one second. Of 1968 National Incinerator Conference, ASME, New York, N. Y., 1968, pp. 142-153. energy could be realized if steam could be generated for a 8.60 MPa (1250 psi), 540C Kaiser, E. R., Zeit, C. D., and McCaffery, J. B., [3] "Municipal Incinerator Refuse and Residue," Proceed [7] Mallen, G. M., and Titlow, E. I., "Energy and Resource Recovery From Solid Wastes," Garrett Research and Development Company, I nc., La Verne, California, 1975. [8] Sussman, D. B., Baltimore Demonstrates Gas Pyrolysis: The Energy Recovery Solid Waste Facility in the tabulated loss for Mechanical Processing is Baltimore, Maryland, U. S. Environmental Protection somewhat less than reported [6] . Agency, Washington, D. C., 1974, EPA/530, sw-75d.i. It must be understood that the tabulated data does not recognize such potentially significant [9] Anon, "Solid Waste Disposal Resource Recovery," Union Carbide, New York, N. Y., 1974, F-3698. [10] Kispert, R. G., et aI., "Fuel Gas Preparation from factors as economics, size, capacity, or by-product Solid Waste: Final Report," Dynatech R/D Company, benefits of a particular system. Cambridge, Mass., 1975, NSF/RANN/SE/C·827/PR/74/5. 139 APPENDIX Sample calculations of Vaporization Loss and Stack Loss for Mechanical Processing System. Theoretical Air ® . @ + @ =3.23 + 0.24=3.47 tons air/ton fuel Analysis of Processed Fuel ffi CD 8) 0) @ (j) Moisture 0.260 Carbon 0.280 Hydrogen Excess Air @ ® 0.037 Oxygen 0.236 Nitrogen 0.007 Noncombustible 0.180 Tons fuel per ton of refuse 0.80 @ @+ @ Fuel to Stack Gas @ H.O/ton fuel 1040 Btu/lb. x 2000 Ib./ton x Stack Temperature @ @.;- @ =0.592';-5.32=.112 tonsH.O/ 350F ton stack gas Air Requirements for Combustion of Carbon 11.52 tons air/ton carbon x CD = SpecificHeat of Stack Gas @ 11.52 x 0.28= 3.23 tons air/ton fuel dW g,n x 34.56 x (.037 ;7 - (0 - 0.24 x (1.0 - @ ) + 0.48 x @ 0.24 (I .0-.112) = 0.48 x .112=0.267 Btu/lb.-oF Air Requirements for Combustion of Hydrogen 3 + 0.81=5.32 tons stack Moisture in Stack Gases 0.30 34.56 ton"i'/to = 4.51 gas/ton fuel refuse @ -( @ @+ @ ® x (j) = 1040 x 2000 x 0.593 x 0.8= 990;000 Btu/ton @ ® + 0.05 x CD ) = 1.0 - (0.18 + 0.01)= 0.81 tons gas/ton fuel 1.0 Total Stack Gas Weight Vaporization Loss per Ton of Refuse Excess Air = 3.47 + 1.04=4.51 tons air/ton fuel ® CD+ ( CD x 9)=0.26 + (0.037x9)=0.593 tons @ @ @ = 3.47 x 0.30=1.04 tOIlS air/ton Total Air H. O,per Ton of Fuel ® x fuel <p) = Stack Loss per Ton of Refuse @ @ x ® -x ( @ - 80F) x (j) x 2000 Ib./ton= 5.32 x 0.267 x (350-80) x 0.8 x 8)=0.24 tons air/ton fuel. 2000=620,000 Btu/ton of refuse 140
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