Supplementary Information Evaluation of air quality in a megacity using statistical tools Luciana Maria Baptista Ventura1,2, Fellipe de Oliveira Pinto2, Laiza Molezon Soares2, Aderval S. Luna3, Adriana Gioda1* 1 Pontifical Catholic University of Rio de Janeiro (PUC-Rio), Chemistry Department, Marquês de São Vicente Street, 225, Gávea, Rio de Janeiro-RJ, 22451-900, Brazil 2 Environmental Institute of Rio de Janeiro State (INEA), Air Quality Management 3 Rio de Janeiro State University (UERJ), Chemistry Institute Table s1. Sampling sites with their respective sources of emissions, air basins and geographic coordinates. Sampling sites Downtown Emission Sources Traffic Administrative Area Downtown Copacabana Traffic /marine Jacarepaguá Air basin Latitude Longitude III 22º54'26.67'' 43º11'43.13'' South - 22°58'3.58'' 43°11'15.08'' Traffic West II 22°56'58.34'' 43°21'33.94'' Maracanã Traffic North III 22°54'43.36'' Ramos Industrial Industrial/traffic/ Marine North III 22º50'21.59" 43º15'13.65" West I 22°54'4.59'' 43°43'22.88'' Santa Cruz 43º14'5.02'' Table s2. PM2.5 mean concentration and meteorological mean conditions on the seasons in 2011. Sites Variables Summer Autumn Winter Spring PM2.5 (µg m ³) 12 11 13 8 WS (m.s-1) 0.6 1.0 1.0 1.0 Copacabana T (°C) 29 24 22 24 RH (%) 71 77 73 74 PM2.5 (µg m ³) 17 19 19 13 -1 WS (m.s ) 1.1 1 1.1 1 Downtown T (°C) 27 23 22 23 RH (%) 68 72 68 68 PM2.5 (µg m ³) 31 35 35 27 -1 WS (m.s ) 0.8 1.0 1.0 1.0 Jacarepaguá T (°C) 26 22 21 22 RH (%) 92 87 83 85 PM2.5 (µg m ³) 15 21 17 10 WS (m.s-1) 1.2 1.0 1.0 1.0 Maracanã T (°C) 29 24 22 25 RH (%) 73 79 77 76 PM2.5 (µg m ³) 17 18 20 12 -1 WS (m.s ) 1.1 1.0 1.0 1.0 Ramos T (°C) 33 28 25 28 RH (%) 74 82 77 79 PM2.5 (µg m ³) 9 10 8 7 -1 WS (m.s ) 3 3 3 3 Santa Cruz T (°C) 28 25 25 24 RH (%) 75 80 77 77 Table s3. Loading and Communalities. Loading Variables PC1 Wind Direction -0.290 Wind Speed -0.211 Temperature -0.702 Relative Humidity 0.791 PM 2.5 0.570 PC2 -0.773 0.762 0.174 0.025 0.185 Communalities (%) 68% 63% 52% 63% 36% (a) (c) (e) (b) (d) (f) Figure s1 –Wind rose of the stations: (a) Downtown, (b) Copacabana, (c) Jacarepaguá, (d) Maracanã, (e) Ramos, (f) Santa Cruz. (a) (b) (c) (e) (d) (f) Figure s2 – Box plots of meteorological variables and PM2.5 concentration normalized of the stations (a) Downtown (b) Copacabana (c) Jacarepaguá (d) Maracanã (e) Ramos (f) Santa Cruz. Dots and stars outside the boxes represent possible anomalous values.
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