HSC Chemistry 9.4 Chemical Monitoring and Management Section 2 Haber Process 2002 2003 2005 2006 2008 Question 23 (4 marks) Using Le Chatelier’s principle, justify the choice of temperature and pressure conditions used to optimise the yield in the Haber process. ......................................................................................................................................... ......................................................................................................................................... ......................................................................................................................................... ......................................................................................................................................... ......................................................................................................................................... ......................................................................................................................................... ......................................................................................................................................... ......................................................................................................................................... ........................................................................................................................................ Question 23 The better responses included a balanced equation including states, reversible arrows and the negative ΔH. They also identified that the reaction was exothermic as well as identifying the conditions for temperature and pressure used. The better responses explained why the temperature and pressure values are used. The better responses explained the link between pressure and Le Chatelier’s Principle using the moles ratio in gaseous terms as well as temperature and Le Chatelier’s Principle (including rate of reaction as well as yield). The weaker responses referred to pressure as a reactant. Weaker responses included a detailed account of the Haber process but did not answer the question. 2010 9 What types of reaction occur in the Haber process during the production of ammonia? (A) Redox and synthesis (B) Hydration and redox (C) Decomposition and oxidation (D) Reduction and decomposition 2012 Sample answer: Ammonia is important as it is used extensively in many industries. It is a raw material in agriculture for the making of fertilisers to increase crop production. It is used to produce explosives for wartime or construction and mining. Its importance can further be seen in its use in manufacturing synthetic fibres, cleaning products and pharmaceuticals. Question 24 In better responses, candidates effectively linked the properties of ammonia with its uses in industry. In weaker responses, candidates tended to include information about the historical development of the Haber process as a means of producing ammonia, rather than explaining its current industrial uses. In these responses, candidates stated several uses of ammonia, but did not explain why these uses were important.
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