CHARACTERISTICS OF PALEO-FLUID AND FLUID FLOW IN THE PENNSYLVANIAN-PERMIAN FOUNTAIN FORMATION Introduction: The Pennsylvanian Fountain Formation is an arkosic sandstone within the Front Range region of Colorado. Bleached white zones extend laterally throughout the formation and have sharp contacts with the surrounding red sandstone. Cross laminae pass through the red and white contacts, indicating that it was bleached after deposition (Hubert, 1960). Features such as these are typically related to zones of migrating reducing fluid (Turner, 1980). The purpose of this project is to determine the nature, behavior, and pathway of the fluid. The first goal is to determine composition of the reducing fluid. The second goal is to determine what conditions were present during fluid movement and associated diagenesis. This includes temperature, pressure, and depth. The third goal is to determine the path of the fluid and what constraints were on the system to cause it to take this particular path. Purpose and importance to the Rocky Mountain region: The purpose of this project is to solve a local geological problem and to provide better understanding of large-scale fluid movements through sandstones. The bleached zones in the Fountain Formation have been noted in several papers but there is no definite conclusion on how they originated. Early work suggested that the bleached zones were a result of a process dependent on flood plain deposition (Hubert, 1960). A later paper states that the bleached zones also occur in marine sediments in the Fountain (Garner, 1963). Hubert’s flood plain origin for the reducing fluid is not plausible when applied to a marine setting. Garner does not propose a solution but merely suggests that more work is needed. Widespread bleached zones are now thought to indicate large-scale fluid flow (Turner, 1980), (Parry, Chan, & Beitler, 2004), (Beitler, 2005). The fact that both marine and continental sediments are bleached over a large geographic range point to a diagenetic event dealing with a large-scale movement of reducing fluid through the Fountain Formation. Understanding fluid flow through sandstones has economic importance for both hydrocarbon exploration and groundwater management. Pathways and factors that control flow are important in exploration. The diagenetic process is very important as well. Fluid inclusions will be used to estimate the temperature, pressure, and depth that the reaction took place at. Once this information is known it will be possible to determine what reactions were actually taking place by analyzing thin sections. Understanding the depth at which certain reactions take place within reservoirs is vital to understanding how these systems operate. Methods: 1. Determine the composition of the reducing fluid: This will be accomplished by analyzing fluid inclusions. Fluid inclusions are pockets of trapped liquid and gas that form during diagenesis (Goldstein, 2003). The inclusions to be considered were trapped in the cement that precipitated during the reduction event and contain the reducing fluid. The inclusions will be observed under fluorescent light to identify hydrocarbons. Hydrocarbon and groundwater inclusions can be analyzed by cooling them on a gas flow temperature stage. The temperature at which they freeze at can be used to determine the fluid’s salinity, which may offer insight into its origin (Goldstein, 2003). Compositional changes can be measured between inclusions from different sites to see how the fluid was changing as it migrated through the sandstone. 2. Determine the conditions that the event took place in: This will be accomplished using fluid inclusions and thin sections. As the fluid inside the inclusion cooled its volume decreased but the volume of the inclusion itself remained the same. This causes a bubble to be present in the inclusion. The temperature that the inclusion was formed at can be determined by heating the inclusion until it reaches its original volume, which is the point at which the bubble disappears. This method can be used to determine what the temperature and pressure was during entrapment (Goldstein, 2003) which can be used to estimate depth. Thin sections will be used in order to look for diagenetic changes between the bleached and non-bleached zones. 3. Determine what controlled the path of fluid flow: This will be accomplished by studying both large-scale features in outcrops and small-scale features in thin sections. Porosity and permeability differences between bleached and non-bleached zones will be studied in outcrops. The lateral continuity as well as other large-scale patterns of the bleached zones will be investigated. Small-scale features will be studied under a polarizing microscope. Thin sections will be made from bleached and non-bleached samples to determine what features are important in controlling the path of fluid flow. Features to be taken into account include the texture and composition of grains, porosity and permeability, clay content, and cement type. Thin sections and doubly polished fluid inclusion sections will be necessary for this project. Four fluid inclusion sections and ten thin sections will be used for each of the seven study sites. Fluid inclusion samples will be taken from adjacent white and red zones. Thin sections will be from samples within white zones, at the boarder of white zones, and in red zones at specific distances from white zones. Samples for fluid inclusion and petrographic analysis will be taken from seven study sites covering 50 miles along the northern Front Range. The southern proposed sampling site is near Lyons, CO and the northern site is near Owl Canyon, 20 miles north of Fort Collins, CO. Five other sampling sites will be located between these two points. The field work will be conducted during Summer 2012, with data acquisition and analysis during the following Fall and Winter, and thesis writing during Spring 2013. Importance of Larimer County Open Spaces: Devil’s Backbone and Horsetooth Mountain have many excellent outcrops of Fountain Formation and are located in the middle section of the study site. Mapping of the white zones can be done fairly easily at these locations because of the large outcrops and continuous exposures. Samples of Fountain Formation sandstone are required to make thin sections and fluid inclusion sections. Ten to fifteen samples are needed from each of the three sample sites. References cited: Beitler, B. (2005). Fingerprints of Fluid Flow: Chemical Diagenetic History of the Jurassic Navajo Sandstone, Southern Utah, U.S.A. Journal of Sedimentary Research, 75(4), 547-561. doi:10.2110/jsr.2005.045 Garner, H. (1963). Fountain Formation, Colorado: A Discussion. New York, (October), 1299-1301. Hubert, J. F. (1960). Syngenetic Bleached Borders on Detrital Red Beds of the Fountain Formation, Front Range, Colorado. Geological Society of America Bulletin, 71(1), 95. doi:10.1130/0016-7606(1960)71[95:SBBODR]2.0.CO;2 Parry, W. T., Chan, M. a, & Beitler, Brenda. (2004). Chemical bleaching indicates episodes of fluid flow in deformation bands in sandstone. AAPG Bulletin, 88(2), 175-191. doi:10.1306/09090303034 Turner, P. Continental Red Beds. New York: Elsevier Scientific Publishing Company. 1980.
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