© 2014 HDR © © Architecture, 2014 2014 HDR, HDR,Inc., Inc., Inc.,all all allrights rights rightsreserved. reserved. reserved. COMPARISON OF MBBR AND SUSPENDED GROWTH BNR PERFORMANCE AT THE HRWTF Erika L. Bailey, PE NC AWWA WEA Annual Conference November 16, 2015 © 2014 HDR, Inc., all rights reserved. 01 02 03 04 05 Introduction, Drivers, and Challenges Segregated Treatment Concept MBBR / Suspended Growth Comparison Conclusions Project Status 01 INTRODUCTION, PROJECT DRIVERS, AND CHALLENGES HRWTF IS A PUBLICLY OWNED INDUSTRIAL TREATMENT WORKS Located 20 miles southeast of Richmond, VA 50 mgd capacity, currently treating 28 mgd Small domestic base flow • • • • 23,000 residents LARGE industrial contribution • • 85% of flow High Purity Oxygen (HPO) activated sludge with denitrification • • No nitrification currently HRWTF EXISTING LIQUID TREATMENT PROCESS “HAP” Foul Condensate VAWCO RockTenn Hercules Gravelly Run Industrial Headworks Reaeration Industrial Primary Clarifiers Evonik Honeywell Denit. Basin HPO Aeration Tanks RAS Final Clarifiers HOCl Domestic Domestic Headworks Domestic Primary Clarifiers & Chlorine Contact Tanks 2012 Improvements (Phase 1) PROJECT DRIVERS Nitrogen (TN) Reduction • • • • Chesapeake Bay Nutrient TMDL HRWTF currently purchases TN credits Future market for credit purchases unknown Ammonia (NH3-N) Reduction • • • Current NH3-N limit: 18.9 mg/L 30% - 90% reduction anticipated • Monthly Avg: 2.0 – 14.2 mg/L • Daily max: 3.1 – 21.6 mg/L Total Nutrient Discharge Load by Year (Mlb/yr) HRWTF Waste Load Allocation 2005 2006 2007 2008 2009 2010 2011 TP TN 0.075 1.83 ND ND ND 0.048 0.013 0.028 0.020 1.9 1.55 1.7 1.57 1.88 2.02 1.77 NITROGEN REMOVAL IS CHALLENGE AT HRWTF High influent temperatures exceed 37 ºC • Exceeds upper temperature limit for stable nitrification creates air permitting High concentration • Cooling challenges of VOCs Variable influent wastewater characteristics • Impacts process performance stability nitrification rates Wastewater contains • Slower expected (larger aeration tanks) nitrification inhibitors 02 ADDRESSING BNR CHALLENGES: SEGREGATED TREATMENT CONCEPT PROJECT DEVELOPMENT APPROACH Effectively build upon previous studies • • “Segregated Treatment” alternatives to address key challenges Leverage knowledge from previous testing • • Effectively address nitrification inhibition 2007 Comprehensive Alternatives Evaluation identified Segregated Treatment as preferred alternative UNIQUE “SEGREGATED TREATMENT” APPROACH ADDRESSES TEMPERATURE CHALLENGE Separate high nitrogen and high temperature streams Achieves biological nutrient removal on portion of flow • • • Eliminates need for cooling industrial influent BUT • • Honeywell wastewater contains nitrification inhibitors Domestic Honeywell Total Influent Ashland RockTenn VAWCO Evonik Honeywell Primary Treatment Primary Treatment Biological Nutrient Removal Segregated Stream Combined Influent Secondary Treatment Final Effluent SEGREGATED TREATMENT APPROACH MUST ALSO ADDRESS NITRIFICATION INHIBITION • • Limit Honeywell flow to Segregated Treatment Use MBBR system for biological treatment • • • • • High rate process Concentrated biomass; media provides high surface area to volume environment Biofilm structure Media contained within separate cells Self-regulating system (do not manage SRT) MBBR: Moving Bed Biofilm Reactor Anoxic Cell BOD Removal Cell Nitrification Cells PILOT TESTING CONDUCTED TO CONFIRM DESIGN BASIS Side-by-side comparison of suspended growth and MBBR processes Both processes fed with the same influent flow stream • • • • Domestic primary effluent Gradually increased levels of Honeywell flow 03 COMPARISON OF MBBR / SUSPENDED GROWTH PERFORMANCE PILOT TESTING CONFIGURATION PILOT TESTING CONDITIONS Scenario Description 1 2 3 40% HW @ Design Avg 70% HW @ Design Avg 100% HW @ Design Avg Influent % Honeywell 19% 29% 37% 95.0% 90.0% SG 85.0% MBBR 80.0% 75.0% 70.0% 3/17 3/24 3/31 4/7 4/14 4/21 TN Removal SG MBBR MBBR Recycle 100.0% 200% 80.0% 160% 60.0% 120% 40.0% 80% 20.0% 40% 0.0% 0% 3/17 3/24 3/31 4/7 4/14 4/21 MBBR Internal Recycle (%) • TN removal in MBBR dropped when internal recycle was temporarily stopped. TN removal quickly increased to the same levels as the Suspended Growth system once the recycle stream resumed. NH3-N Removal (%) • 100.0% TN Removal (%) SCENARIO 1 – 40% HONEYWELL Ammonia-N Removal Ammonia reduction • • Both systems achieved <1.0 mg/L NH3 for 85% of the time. Effluent Ammonia-N (mg/L) SCENARIO 1 – 40% HONEYWELL • MBBR DAF unit provided greater and more consistent solids removal. Polymer was not needed. 40% 60% 1.0 0.1 0.0 0% 20% 80% 100% Percent Values Less Than or Equal to Indicated Value Suspended Growth MBBR 100.0 Effluent TSS (mg/L) • MBBR 10.0 Solids removal • Suspended Growth 10.0 1.0 0% 20% 40% 60% 80% Percent Values Less Than or Equal to Indicated Value 100% MBBR • • More stable removal of ammonia and TN 100.0% NH3-N Removal (%) SCENARIO 2 – 70% HONEYWELL Ammonia-N Removal 95.0% MBBR 85.0% 80.0% Suspended Growth • 4/21 4/28 5/5 5/12 5/19 5/26 TN Removal Drop in nitrification performance due to an unexplained loss of biomass 90.0% 80.0% 70.0% TN Removal (%) • SG 90.0% 60.0% 50.0% SG 40.0% MBBR 30.0% 20.0% 10.0% 0.0% 4/21 4/28 5/5 5/12 5/19 5/26 • Decrease in SRT and MLSS SRT may have reached as low as 9 days (7 day aerobic SRT). Nitrifier washout not expected (at 18 °C) • • But continuous nitrification inhibition experienced in the Suspended Growth system would make it more sensitive to the low SRT impacts. 5,000 80 4,000 60 3,000 40 2,000 20 1,000 0 0 4/21 4/28 5/5 Eff. TSS TSS (mg/L) • 100 5/12 5/19 5/26 Total SRT 100.0 50 90.0 45 80.0 40 70.0 35 60.0 30 50.0 25 40.0 20 30.0 15 20.0 10 10.0 5 0.0 0 4/21 4/28 5/5 5/12 5/19 5/26 SRT (days) Sudden increase in effluent TSS from the Suspended Growth system • TSS (mg/L) SCENARIO 2 – 70% HONEYWELL MLSS MLSS (mg/L) Eff. TSS • • Suspended Growth system achieved <1.0 mg/L NH3 about 70% of the time. MBBR achieved <1.0 mg/L NH3 for almost 100% of the time. Solids removal: • • • MBBR DAF unit provided greater and more consistent solids removal. Polymer was not needed. Effluent Ammonia-N (mg/L) Ammonia Removal • MBBR 40% 60% 10.0 1.0 0.1 0.0 0% 20% 80% 100% Percent Values Less Than or Equal to Indicated Value Suspended Growth MBBR 100.0 Effluent TSS (mg/L) SCENARIO 2 – 70% HONEYWELL Suspended Growth 10.0 1.0 0% 20% 40% 60% 80% Percent Values Less Than or Equal to Indicated Value 100% MBBR provides more stable performance in terms of ammonia and TN removal. NH3-N Removal (%) • 100.0% 98.0% 96.0% SG 94.0% MBBR 92.0% 90.0% 5/19 5/26 6/2 6/9 6/16 TN Removal 100.0% 90.0% 80.0% TN Removal (%) SCENARIO 3 – 100% HONEYWELL Ammonia-N Removal 70.0% 60.0% 50.0% SG 40.0% MBBR 30.0% 20.0% 10.0% 0.0% 5/19 5/26 6/2 6/9 6/16 • • • Both systems achieved <1.0 mg/L NH3 about almost 100% of the time. MBBR achieved effluent ammonia < 0.1 mg/L 75% of the time Suspended Growth achieved effluent ammonia < 0.1 mg/L 55% of the time Solids removal: • • • MBBR DAF unit provided greater and more consistent solids removal. Polymer was not needed. Effluent Ammonia-N (mg/L) Ammonia Removal • MBBR 40% 60% 10.0 1.0 0.1 0.0 0% 20% 80% 100% Percent Values Less Than or Equal to Indicated Value Suspended Growth MBBR 100.0 Effluent TSS (mg/L) SCENARIO 3 – 100% HONEYWELL Suspended Growth 10.0 1.0 0% 20% 40% 60% 80% Percent Values Less Than or Equal to Indicated Value 100% SUSPENDED GROWTH PERFORMANCE OVERVIEW Kinetic Parameter (from reactor Specific Nitrification Rate profiles) Normalized to 20 (from batch Deg C testing) μmax at 20 Deg C Denitrification Rate (normalized to 14.7 Deg C) PER Estimate (at 40% HW) % Honeywell based on Pilot Testing Scenario 1, Scenario 2, Scenario 3, 40% 70% 100% 2.22 2.47 2.84 mg NOx-N/g MLVSS*hr 3.43 4.13 4.12 mg NOx-N/g MLVSS*hr 0.7 0.78 0.57 0.49 day-1 0.21 0.1112 0.18 0.19 lb NOx-N/lb MLVSS*day 0.53 0.59 0.41 0.57 (#/day VSS produced)/ (#/day influent cBOD) 0.23 0.25 0.16 0.18 (#/day VSS produced)/ (#/day influent COD) 0.11 0.08 0.02 0.015 0.11 0.09 0.02 0.02 0.09 0.08 0.01 0.01 0.11 0.09 0.02 0.01 # TKN/# VSS # TKN/# TSS # TP/# VSS # TP/# TSS 2.1 Observed Yield Nitrogen Uptake Rate Phosphorus Uptake Rate Units MBBR PERFORMANCE OVERVIEW Rate Denitrification BOD-Removal COD-Removal Nitrification (in BOD-removal zone) (from reactor profiles) Nitrification (in nitrification zone) (from batch testing) % Honeywell based on Pilot Testing PER Estimate Scenario 1, Scenario 2, Scenario 3, (at 40% HW) 40% 70% 100% 0.56 0.25 0.30 0.25 4.51 1 9.23 7.01 7.33 2.7 0.27 0.56 0.49 Phosphorus Uptake Rate g NOx-N/m2-day g BOD/m2-day g COD/m2-day g NH4-N/m2-day 0.48 0.25 0.04 g NH4-N/m2-day 0.84 0.69 0.35 g NH4-N/m2-day 0.61 0.54 0.49 0.73 (#/day VSS produced)/ (#/day influent cBOD) 0.27 0.23 0.20 0.24 0.11 0.08 0.02 0.015 0.10 0.08 0.02 0.02 0.10 0.09 0.03 0.02 0.11 0.09 0.03 0.02 0.63 Observed Yield Nitrogen Uptake Rate Units (#/day VSS produced)/ (#/day influent COD) # TKN/# VSS # TKN/# TSS # TP/# VSS # TP/# TSS 04 CONCLUSIONS PILOT TESTING CONFIRMS SELECTION OF MBBR SYSTEM Typically outperformed Suspended Growth system More stable • • • • • During loading condition transitions At higher fractions of Honeywell in the combined influent Better solids separation/control PLANNED SEGREGATED TREATMENT PROCESS UPGRADES Segregated Treatment to Solids Handling Screen MBBR Honeywell NaOH Domestic Wastewater Screen Screen Industrial Wastewater Grit Removal Domestic PCs Grit Removal Industrial PCs WAS DAFT SBS CCT Denit Basin RAS to Solids Handling Aeration Tanks (HPO) Secondary Clarifiers Post Aeration Gravelly Run 05 PROJECT STATUS © 2014 HDR © © Architecture, 2014 2014 HDR, HDR,Inc., Inc., Inc.,all all allrights rights rightsreserved. reserved. reserved.
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