1 Supplemental material - Literature review 2 3 The meteorological mechanisms leading to aerosol escape have been previously 4 documented for other valleys and basins. Here we present a short summary of 5 selected literature. Whiteman and McKee (1978) published a simple numerical 6 model of pollutant mass entrainment into growing upslope flows during the post- 7 sunrise temperature inversion breakup period. The post-sunrise inversion 8 destruction mechanism was described (Whiteman 1982, 1990; Brehm and Freitag 9 1982) and an analytical thermodynamic model was developed that successfully 10 simulated inversion destruction in Colorado valleys (Whiteman and McKee 1982). 11 Zoumakis and Efstathiou (2006a and 2006b) later extended this thermodynamic 12 model. Bader and McKee (1983, 1985) and Bader and Whiteman (1989) used a full- 13 physics numerical model to demonstrate the mechanism. Two air quality models 14 were developed for the US Environmental Protection Agency to simulate the effects 15 of the mechanism on air quality in valleys (Whiteman and Allwine 1985; Allwine et 16 al. 1997) and its effect on the transport of pollutants from valleys into regional scale 17 flows (Allwine and Whiteman 1983, 1984, 1985, 1988). A sulfur hexafluoride tracer 18 experiment in Colorado's Brush Creek Valley confirmed that tracer material was 19 transported across a north-south valley towards the east-facing sidewall that was 20 heated by the morning sun (Whiteman 1989) and its subsequent fumigation of the 21 slope and transport up the valley sidewall and dispersion into regional flows. Cross- 22 basin flows that occur in Arizona's Meteor Crater basin (Lehner et al. 2011) were 23 successfully simulated with a high-resolution numerical flow model (Lehner and 24 Whiteman 2012, 2014). The removal of nighttime temperature inversions by 25 upslope flows on the heated sidewalls and the role of compensatory sinking over 26 the valley or basin center has been demonstrated in valleys throughout the world 27 (e.g., Müller and Whiteman 1988; Whiteman et al. 2004; Rendòn 2014, 2015). 28 Thermally driven complex terrain flow systems, and basin and valley temperature 29 inversion breakup mechanisms are summarized in textbooks by Stull (1988), 30 Whiteman (2000) and Markowski and Richardson (2010). 31 32 REFERENCES 33 34 Allwine, K. J., and C. D. Whiteman, 1983: Operational Guide to MELSAR-A Mesoscale 35 Complex Terrain Air Quality Model. PNL-4732, Pacific Northwest Laboratory, 36 Richland, Washington, 44 pp. 37 38 Allwine, K. J., and C. D. Whiteman, 1984: Technical Description of MELSAR: A 39 Mesoscale Air Quality Model for Complex Terrain. PNL-5048, Pacific Northwest 40 Laboratory, Richland, Washington, 97 pp. 41 42 Allwine, K. J., and C. D. Whiteman, 1985: MELSAR: A Mesoscale Air Quality Model for 43 Complex Terrain. Volume 1 - Overview, Technical Description and User's Guide and 44 Volume 2 - Appendices. PNL-5460, Pacific Northwest Laboratory, Richland, 45 Washington, 155 and 358 pp. 46 Allwine, K. J., and C. D. Whiteman, 1988: Ventilation of pollutants trapped in valleys: 47 A simple parameterization for regional-scale dispersion models. Atmos. Environ., 22, 48 1839-1845. 49 50 Allwine, K. J., X. Bian, C. D. Whiteman, and H. W. Thistle, 1997: VALDRIFT–A valley 51 atmospheric dispersion model. J. Appl. Meteor., 36, 1076-1087. 52 53 Bader, D. C., and T. B. McKee, 1983: Dynamical model simulation of the morning 54 boundary layer development in deep mountain valleys. J. Climate Appl. Meteor., 22, 55 341-351. 56 57 Bader, D. C., and T. B. McKee, 1985: Effects of shear, stability and valley 58 characteristics on the destruction of temperature inversions. J. Climate Appl. Meteor., 59 24, 822-832. 60 61 Bader, D. C., and C. D. Whiteman, 1989: Numerical simulation of cross-valley plume 62 dispersion during the morning transition period. J. Appl. Meteor., 28, 652-664. 63 64 Brehm, M., and C. Freytag, 1982: Erosion of the night-time thermal circulation in an 65 Alpine valley. Arch. Meteor. Geophys. Bioclimatol., Ser. B, 31, 331-352. 66 67 Lehner, M., and C. D. Whiteman, 2012: The thermally driven cross-basin circulation 68 in idealized basins under varying wind conditions. J. Appl. Meteor. Climatol., 51, 69 1026-1045. 70 71 Lehner, M., C. D. Whiteman, and S. W. Hoch, 2011: Diurnal cycle of thermally driven 72 cross-basin winds in Arizona's Meteor Crater. J. Appl. Meteor. Climatol., 50, 729-744. 73 74 Lehner, M., and C. D. Whiteman, 2014: Physical mechanisms of the thermally driven 75 cross-basin circulation. Quart. J. Roy. Meteor. Soc., 140, 895-907. 76 77 Markowski, P., and Y. Richardson, 2010: Mesoscale Meteorology in Midlatitudes. 78 Wiley-Blackwell, Chichester, 407pp. 79 80 Müller, H., and C. D. Whiteman, 1988: Breakup of a nocturnal temperature inversion 81 in the Dischma Valley during DISKUS. J. Appl. Meteor., 27, 188-194. 82 83 Rendón, A. M., J. F. Salazar, C. A. Palacio, V. Wirth, and B. Brötz, 2014: Effects of 84 urbanization on the temperature inversion breakup in a mountain valley with 85 implications for air quality. J. Appl. Meteor. Climatol., 53, 840-858. 86 87 Rendón, A. M., J. F. Salazar, C. A. Palacio, and V. Wirth, 2015: Temperature inversion 88 breakup with impacts on air quality in urban valleys influenced by topographic 89 shading. J. Appl. Meteor. Climatol., 54, 302-321. 90 91 Stull, R. B., 1988: An Introduction to Boundary Layer Meteorology. Kluwer Academic 92 Publishers. Dordrecht, Netherlands. 666pp. 93 94 Whiteman, C. D., 1982: Breakup of temperature inversions in deep mountain 95 valleys: Part I. Observations. J. Appl. Meteor., 21, 270-289. 96 97 Whiteman, C. D., 1989: Morning transition tracer experiments in a deep narrow 98 valley. J. Appl. Meteor., 28, 626-635. 99 100 Whiteman, C. D., 1990: Observations of Thermally Developed Wind Systems in 101 Mountainous Terrain. Chapter 2 in Atmospheric Processes Over Complex Terrain, 102 (W. Blumen, Ed.), Meteorological Monographs, 23, no. 45. American Meteorological 103 Society, Boston, Massachusetts, 5-42. 104 105 Whiteman, C. D., 2000: Mountain Meteorology: Fundamentals and Applications. 106 Oxford University Press, New York, 355pp. 107 108 Whiteman, C. D., and K. J. Allwine, 1985: VALMET - A Valley Air Pollution Model. 109 Final Report. PNL-4728, Rev. 1. Pacific Northwest Laboratory, Richland, Washington, 110 176 pp. 111 112 Whiteman, C. D., and T. B. McKee, 1978: Air pollution implications of inversion 113 descent in mountain valleys. Atmos. Environ., 12, 2151-2158. 114 115 Whiteman, C. D., and T. B. McKee, 1982: Breakup of temperature inversions in deep 116 mountain valleys: Part II. Thermodynamic model. J. Appl. Meteor., 21, 290-302. 117 118 Whiteman, C. D., B. Pospichal, S. Eisenbach P. Weihs, C. B. Clements, R. Steinacker, E. 119 Mursch-Radlgruber, and M. Dorninger, 2004: Inversion breakup in small Rocky 120 Mountain and Alpine basins. J. Appl. Meteor., 43, 1069-1082. 121 122 Zoumakis, N. M., and G. A. Efstathiou, 2006a: Parameterization of inversion breakup 123 in idealized valleys. Part I: The adjustable model parameters. J. Appl. Meteor. 124 Climatol., 45, 600-608. 125 126 Zoumakis, N. M., and G. A. Efstathiou, 2006b: Parameterization of inversion breakup 127 in idealized valleys. Part II: Thermodynamic model. J. Appl. Meteor. Climatol., 45, 128 609-623. 129 130 Supplemental material - Figures 131 132 133 134 Figure S1. BCM drainage area and volume as a function of elevation. Data from a 135 detailed topographic map obtained with a planimeter. 136 137 138 139 140 Figure S2. a) Volume weighted PM2.5 aerosol mass, b) wind directions at FWP and 141 SAPP, and c) wind speeds at FWP and SAPP during the 14-day cold-air pool episode. 142 143 144 145 146 Figure S3. a) Relative humidity and b) temperature time series from automatic data 147 loggers co-located with the ceilometers at 8th and 8th (blue, 1309 m MSL) and in 148 the BCM (red, 1457 m MSL). 149 150 151 152 153 Figure S4. View of the BCM looking west from over the SLV. The north-facing slope 154 (left) is snow covered, while the south-facing slope (right) is largely snow free. 155 Copyright, Michael Lynch, used with permission. 156 157 158 159 160 Figure S5. Daily primary emissions of PM2.5 and PM10 for the BCM control volume 161 during the cold-air pool episode. 162 163 Supplemental material - Solar shading model animation of Bingham Copper 164 Mine, 21 January. 165 166 This animation of shadows and insolation in the Bingham Mine and its surroundings 167 for 21 January was produced using a high-resolution topographic model and Earth- 168 sun geometry relationships. 169 170
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