SunCoal Industries CarboREN® Plants Biomass-to-Biocoal Technology Using Organic Waste to Produce Green Energy The CarboREN® Plant SunCoal Industries offers its customers facilities that refine organic waste into SunCoal® biocoal with the patented CarboREN technology, for use in generating bio-energy. The CarboREN plant, based on the principles of hydrothermal carbonization, utilizes green waste from municipalities (grass, leaves, etc.) or other organic waste from industrial processes (wood chips, bagasse, empty fruit bunches, etc.) to produce dry and solid SunCoal biofuel, which has similar characteristics to dry brown coal. The CarboREN technology is unique in that very damp organic waste can be used at a high energy efficiency to produce completely dry biocoal. The resulting biocoal has a very high quality in comparison the raw material used (reduced ash, chlorine, nitrous oxide and sulfur content and a high ash melting temperature). The only resulting material from the process besides the biocoal is wastewater, that can be redirected to a water treatment facility. In the case of impure organic waste (for example, with high sand content), the separated impurities can be forwarded to composting. SunCoal biocoal can be used in existing power plants to generate heat and power, or can be further processed to produce syngas and its secondary products. Example of a CarboREN Plant for Industrial Supply Input Material 375,000 Tons p.a. Produced SunCoal 150,000 Tons p.a. CO2-Savings Through Coal Substitution 270,000 Tons CO2-Eq. p.a. Process Duration Plant Surface 6–12 Hours 25,000 m2 Energy Yield 790 MM kWh p.a. Equivalent Power Produced by Co-Firing 300 MM kWh p.a. (ca. 110,000 2-Person-Households) Equivalent Syngas Produced 232 MM Nm3 p.a. Equivalent BtL-Fuel Produced Wastewater 49 MM l p.a. 150,000 m3 p.a. Typical Input > Bagasse > Grass cuttings > Fallen leaves > Landscape management waste > Rice husks > Shrub cuttings and branches > Straw > Waste from fruit juice mills > Waste from palm oil mills (empty fruit bunches) > Wood chips SunCoal® Biofuel Typical Fuel Characteristics of SunCoal Derived from Wood Chips Lower Heating Valueca. 20 MJ/kg (ca. 5.7 kWh/kg) Potential Syngas Yieldca. 1,550 Nm3/t Potential BtL-Fuel Yieldca. 325 l/t Bulk Density SunCoal Powder400 kg/m3 Bulk Density SunCoal Pellets650 kg/m3 Water Contentca. 5 % Ash Content< 1.5 % Chlorineca. 0.07 w % Sulfuric Acidca. 0.2 w % Nitrateca. 0.7 w % Ash Melting Temperature> 1,100 °C SunCoal® Biofuel Advantages >A homogenous biofuel is created from damp organic waste with heterogeneous characteristics > During refinement, impurities (sand, stones, glass, metal) and unwanted elements (sulfur, chlorine, nitrogen, potassium) are removed or reduced > Because of the high product quality achieved during refinement, organic waste can be used in all types of power plants as biofuel >The dry and hygienic SunCoal biofuel can be stored at length, and the high energy density allows it to be easily transported > The energy use is CO2-neutral, since the CO2 that is released when used is the same amount that is absorbed during biomass growth via photosynthesis > The lower heating value (LHV) of SunCoal is much higher than that of the untreated biomass > The production of SunCoal biofuel does not impact the production of foodstuffs, since the only organic waste used would otherwise rot or be composted > SunCoal powder is ideal for use in entrained flow gasifiers CarboREN®-Technology The patented CarboREN technology from SunCoal Industries homogenizes biomass to biocoal, which is then dried. Using this process, damp biomass with up to 80 % water content and a low heating value is converted to biocoal, which has similar characteristics to fossil coal. The CarboREN technology is the most effective technoloügy available for biomass-tofuel production from damp organic waste. The efficient process requires only a minimal amount of energy use (7 % of the energy of the produced biocoal) and is designed according to customer needs. Additionally, a wide variety of organic waste materials can be used. 1. Receiving and Storage Before being treated, delivered organic waste is stored depending on composition. Storage in the SunCoal Industries CarbonREN plant is designed for automatic loading on nights or weekends. 2. Controlled Crushing and Filtering The biomass is crushed and reduced to a grain size of <60 mm and sieved to remove impurities such as sand, stones, metal or plastic. Accumulated waste can either be processed later or disposed of. 3. Washing During this phase the reduced biomass is separated from inorganic material such as sand and stones. The resulting reduced and washed biomass is then fed into the hydrothermal carbonization. 4. Hydrothermal Carbonization (HTC) In just a few hours, temperatures of 200°C and pressure of 20 bars completely breaks down the structure of the biomass and separates out water. The resulting HTC-slurry is continuously removed from the cooker, „de-stressed“ through ambient pressure and cooled. 5. Mechanical Dehydration During mechanical dehydration the water content of the HTC-slurry is reduced to 40-50 % by a press. The separated water is mostly reused in the process. 6. Thermal Drying The resulting HTC-cake is dried, reducing the water content to less than 5 %. Surplus heat from existing plants or existing local or district heating can further increase the economic feasibility. Wastewater produced by the process can either be directed to a wastewater treatment plant or treated in the CarboREN plant itself. Preparation The resulting biocoal can be processed into SunCoal® powder, SunCoal granulate or SunCoal pellets, according to customer specification, for storage, further refined (for example, into syngas), or used directly as fuel. A. SunCoal® Granulate The powder-free SunCoal® granulate is the simplest biocoal form and can be burned in biomass firings or power plants. B. SunCoal Powder SunCoal® powder is similar to dry brown coal powder and can be used for coal powder firings or in entrained flow gasifiers. C. SunCoal Pellets SunCoal pellets have an especially high energy density and can be used in pellet firings for heat generation, or co-fired in a power plant. Because of the high abrasion resistance and the hydrophobic characteristics, the pellets can be optimally stored and transported, similar to fossil coal. SunCoal Biocoal Uses Biocoal produced from organic waste with the SunCoal Industries CarboREN® technology can be used in a variety of applications: 7. Decentralized Heat & Power Generation SunCoal biocoal can be efficiently used for decentralized heat and power generation in existing plants in a typical capacity range from 100 kW to 20 MW. The composition and characteristics of SunCoal biocoal are similar to that of dry brown coal, allowing its use in all types of firing facilities, including grate, fluidized bed and powder firings. As an alternative to direct combustion, biocoal can also be used in gasifiers. 8. Production of Biomass-to-Liquid Fuels (BtL) The current biofuel market is limited to first generation biofules, such as bio-ethanol, which are (for example) produced in Brazil from sugar cane, and shipped abroad. The future of this space is the use of the whole plant (second generation biofuels) and the use of organic waste. Biocoal can effectively be refined to syngas through established coal gasification technologies, and then in synthesis (for example Fischer-Tropsch-Synthesis) processed into energy-dense biofuel (BtL-fuel). 9. Centralized Power Generation SunCoal biocoal can serve as an efficient and environmentally friendly alternative to fossil coal in large power plants via co-firing. As the demand for co-firing biomass requires significant tonnages, a shipment of biocoal as pellets from abroad is advantageous. HTC Biomass Processing Organic Waste 1. Receiving and Storage 2. Controlled Crushing and Filtering Washed HTC CarboREN® Technology 4. Hydrothermal Carbonization 5. Mechanical Dehydration Fernwärme Possible Types of Biocoal Preparation A. Granulate B. Powder Processing / Transport Biomass Firing Raffinerie - bio Bio-Refinery (Gasification and Synthesis) Fernwärme Typical Uses Fernwärme 7. Decentralized Heat & Power Generation 8. Automobiles Inert Material and Unfiltered Organic Material Composting or Disposal 3. Washing (optional) and Crushed Biomass Wastewater 6. Thermal Drying SunCoal® C. Pellet Bulk Freight Ship Fernwärme 9. Power Generation in Power Plant Sewage Treatment Plant SunCoal Industries Ser vices Feasibility studies, including tests with customer samples in pilot plant Project development Engineering and approvals Turnkey construction Commissioning, test operations, optimization After-sales service Training and maintenance Berlin SunCoal Ludwigsfelde We look forward to hearing from you! SunCoal Industries GmbH phone +49-(0)3378-88122-10 Rudolf-Diesel-Straße 15 fax D-14974 Ludwigsfelde mail [email protected] Germany +49-(0)3378-88122-19 www.suncoal.com
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