int. j. remote sensing, 2002, vol. 23, no. 16, 3229–3249 Quanti cation of surface suspended sediments along a river dominated coast with NOAA AVHRR and SeaWiFS measurements: Louisiana, USA S. W. MYINT Department of Geography, University of Oklahoma, Norman, OK 73019, USA; e-mail: [email protected] and N. D. WALKER Coastal Studies Institute/Dept of Oceanography and Coastal Sciences, Louisiana State University, Baton Rouge, LA 70803, USA; e-mail: [email protected] (Received 22 May 2000; in nal form 8 August 2001) Abstract. The ability to quantify suspended sediment concentrations accurately over both time and space using satellite data has been a goal of many environmental researchers over the past few decades. This study utilizes data acquired by the NOAA Advanced Very High Resolution Radiometer (AVHRR) and the Orbview-2 Sea-viewing wide eld-of-view (SeaWiFS) ocean colour sensor, coupled with eld measurements to develop statistical models for the estimation of nearsurface suspended sediments and suspended solids. ‘Ground truth’ water samples were obtained via helicopter, small boat and automatic water sampler within a few hours of satellite overpasses. The NOAA AVHRR atmospheric correction was modi ed for the high levels of turbidity along the Louisiana coast. Models were developed based on the eld measurements and re ectance/radiance measurements in the visible and near infrared Channels of NOAA-14 and Orbview-2 SeaWiFS. The best models for predicting surface suspended sediment concentrations were obtained with a NOAA AVHRR Channel 1 (580–680 nm) cubic model, Channel 2 (725–1100 nm) linear model and SeaWiFS Channel 6 (660–680 nm) power model. The suspended sediment models developed using SeaWiFS Channel 5 (545–565 nm) were inferior, a result that we attribute mainly to the atmospheric correction technique, the shallow depth of the water samples and absorption eVects from non-sediment water constituents. 1. Introduction Louisiana coastal waters receive inorganic sediments from the Mississippi River, the largest river in North America and sixth largest worldwide in terms of discharge. Annual water and sediment discharges average 18 400 m3 sÕ 1 and 210×106 tons yrÕ 1 (Milliman and Meade 1983). The discharge and sediment load of the Mississippi River enters the northern Gulf of Mexico in two locations, through the Mississippi Internationa l Journal of Remote Sensing ISSN 0143-116 1 print/ISSN 1366-590 1 online © 2002 Taylor & Francis Ltd http://www.tandf.co.uk/journals DOI: 10.1080/01431160110104700 3230 S. W. Myint and N. D. Walker Figure 1. Map of the study region showing where the Mississippi River and Atchafalaya River enter into the northern Gulf of Mexico along the Louisiana coastline. River bird-foot delta and the Atchafalaya River delta, 200 km to the west ( gure 1). The Atchafalaya River (including the Red River ow) carries about 30% of the volume and 50% of the suspended sediment load of that in the Mississippi River (Mossa and Roberts 1990). The low salinity, high turbidity plumes of these two rivers are discharged into very diVerent coastal environmental settings. The main branch of the Mississippi River ows into the Gulf of Mexico through several passes, intersecting a headland that projects about 60 km south of the mainland. The Atchafalaya River water and sediments are discharged through Atchafalaya Bay onto a broad and shallow shelf. The clay and ne silts that remain in suspension are transported seaward onto the inner shelf and alongshore by discharge inertia and wind-driven coastal currents. In this article, we investigate techniques for quantifying suspended sediment concentrations for Louisiana coastal and bay waters using re ectance measurements Quanti cation of suspended sediments from satellite 3231 of NOAA AVHRR and radiance measurements of the Orbview-2 SeaWiFS. Satelliteacquired re ectance measurements can provide valuable information on the distribution of river water and sediments on the continental shelf as well as on the circulation processes aVecting the fate of river-borne material. The development of better techniques for quantifying water constituents using satellite re ectance measurements will lead to major improvements in the understanding and modelling of sediment re-suspension and transport in river-in uenced coastal environments. Many researchers have used optical remote sensing techniques to study the spatial extent and temporal changes in suspended sediments of reservoirs, lakes and rivers and the coastal ocean (e.g. Goldman et al. 1974, Gagliardini et al. 1984, Rouse and Coleman 1976, Curran and Novo 1988, Stumpf 1988, Stumpf and Pennock 1989, Moeller et al. 1993, Wang et al. 1996, Walker 1996, Walker and Hammack 2000). Riverine and coastal waters are comprised of a diverse array of living, nonliving and once living material that vary over time and space. The main constituents are suspended inorganic matter, suspended organic matter, phytoplankton , dissolved organic matter and detritus (Kondratyev and Filatov 1999). In the coastal zone of Louisiana, suspended sediments (inorganic matter) are a large component of the in-water substances with sediment loads in the Mississippi and Atchafalaya River typically ranging from 100 to 400 mg lÕ 1 (Mossa 1990, Walker 1996, Allison et al. 2000). Concentrations of suspended inorganic matter due to river discharge as well as from the re-suspension of unconsolidated bottom sediments from wind-waves are relatively high (Huh et al. 1991, Moeller et al. 1993, Huh et al. 1996, Walker 1996, Allison et al. 2000, Walker and Hammack 2000, Huh et al. 2001). The contribution of suspended organic matter may also be relatively high as a result of the high levels of phytoplankto n production (Rabalais et al. 1991) as well as from detritus derived from the extensive marshes. SAIC (1989) showed that a major optical property of the Louisiana shelf waters is the large amount of yellow substances found in the estuarine and river discharges. The determination of suspended sediments or total suspended solids from water re ectance is based on the relationship between the scattering and absorption properties of water and its constituents (Maul 1985). Most of the scattering is caused by suspended sediments whereas the absorption is controlled by chlorophyll a and colored dissolved or particulate matter. The spectral behaviour of sediments is dependant both on the particle size distribution and mineral composition (Maul 1985, Novo et al. 1989). For any given concentration, ne-grained material contains more particles and thus scatters more than would an equal weight of coarse-grained material. Sediment type also eVects the relationship between re ectance and suspended sediment concentration due to the unique re ectance spectra of diVerent sediments. For example, Novo et al. (1989) found that a sample of white clay was four times more re ective at 600 nm than red silt. Moore (1977) demonstrated that the peak in re ectance shifts to longer wavelengths as the suspended sediment concentration increases (Curran and Novo 1988). The absorptive in-water components such as chlorophyll a and CDOM have been shown to lower the re ectance in a substantial way (Curran and Novo 1988). However, the absorptive eVects of CDOM are generally in wavelengths less than 500 nm. Based on these results, it might be surprising to obtain a single model to hold for every synoptic situation as the components of coastal and inland waters change over time. In this article, we use a modi ed version of an atmospheric correction technique developed for NOAA AVHRR satellite data by Stumpf and Pennock (1989) and S. W. Myint and N. D. Walker 3232 later applied by Froidefond et al. (1993) and Walker (1996), among others. The modi cation we present here enables development of statistical models that estimate suspended sediment concentrations in the highly turbid waters of the Atchafalaya River out ow region (Walker and Hammack 2000, Walker 2001). The models are then applied to independent data collected in subsequent years to evaluate the robustness and accuracy of these algorithms under diVerent environmental conditions. Statistical models for estimating suspended sediment concentrations are also developed for the Orbview-2 SeaWiFS, using the standard NASA atmospheric correction formulation (Gordon and Wang, 1994). The primary objectives of this study were: (1) To develop improved techniques for the quanti cation of suspended sediments in turbid coastal environments (Case 2 waters) using visible and near infrared Channels of NOAA AVHRR and Orbview-2 SeaWiFS. (2) To apply these models to independent datasets to evaluate the robustness and accuracy for estimating suspended sediment concentrations under varying environmental conditions. (3) To identify and evaluate the main sources of error in model development. 2. Methodology The main steps undertaken were the (a) collection of ‘ground truth’ measurements coincident with clear-sky satellite overpasses, (b) atmospheric correction of the satellite data to obtain water re ectances, (c) investigation of relationships between the in-situ measurements and the satellite-derived water re ectances, (d) development of statistical models, and (e) application, testing and assessment of the new models on independent datasets. 2.1. Satellite data overview The satellite data used in this study were received and analysed at the Earth Scan Laboratory, Coastal Studies Institute, Louisiana State University. Re ectance measurements from the NOAA-14 Advanced Very High Resolution Radiometer (AVHRR) were used as they were obtained with the highest sun angle, in midafternoon. The AVHRR sensor has two Channels appropriate for analysing suspended material, Channel 1 in the red visible portion from 580 to 680 nm, and Channel 2 in the near infrared from 725 to 1100 nm (Table 1). SeaWiFS radiance measurements are obtained in six visible channels and two near infrared channels from 402 to 885 nm (Table 1). The SeaWiFS channels oVer increased radiometric Table 1. NOAA-14 AVHRR and SeaWiFS ocean colour scanner spectral Bands/Channels. Channel/band 1 2 3 4 5 6 7 8 NOAA-14 AVHRR wavelength (nm) SeaWiFS Wavelength (nm) 580–680 725–1100 3550–3930 10 300–11 300 11 500–12 500 – – – 402–422 433–453 480–500 500–520 545–565 660–680 745–785 845–885 Quanti cation of suspended sediments from satellite 3233 sensitivity over NOAA AVHRR visible and near infrared channels (Stumpf 1992) as the sensor’s primary purpose is to estimate chlorophyll a and ocean productivity (O’Reilly et al. 1998). Both sensors have pixel sizes of approximatel y 1.1 km at nadir. 2.2. Field data A crucial step in the quantitative use of remote measurements is the collection of in situ water samples coincident with clear-sky satellite overpasses. It is important that the measurements be made as close together in time as possible. Helicopters provide an eYcient platform for collection of water samples for several reasons. First, one can sample a large area rapidly, enabling the sampling of a range of water types. Second, one can locate areas of uniform colour indicating some homogeneity in the water mass. Third, if clouds are in the eld of view, one can locate cloud-free areas more easily at the elevated altitude. The ‘ground truth’ data used in this study were obtained by helicopter, by high speed boat and by automatic water samplers. For the NOAA AVHRR model development, two helicopter trips were performed over the Atchafalaya region on 26 April 1996 and 21 June 1996, with data collection lasting about four hours, centred on the satellite overpass time. Additional ‘ground truth’ water samples were obtained by automatic water samplers in West Cote Blanche Bay west of Atchafalaya Bay on 26 March and 27 March 1998 within one hour of satellite overpass. On 21 March 2001, additional water samples were collected by a small fast coastal research vessel in Fourleague Bay and on the inner shelf, east of Atchafalaya Bay. Also on 21 March, water samples were collected by a research cruise on the inner shelf near the Mississippi bird-foot delta. The water samples collected on 21 March 2001 were used to test the NOAA AVHRR models. The SeaWiFS ground truth data were obtained on 26 April 2000, west of the Mississippi River delta, in Barataria Bay and on the inner shelf seaward of the Bay. As of yet, additional ‘ground truth’ data have not been obtained to test the SeaWiFS suspended sediment model. The 500 ml water samples, obtained from the top 0.5 m of water, were refrigerated in the dark and processed within a few days of collection. The concentrations of total suspended solids (TSS) were determined by ltering through GF/F glass ber lters following the methods described in USGS (1987). Filters were dryed at 60°C for 12 hours and re-weighed. The inorganic sediment fraction or suspended sediment (SS) was determined by ashing the lters at 500°C for 12 h and re-weighing. For the water samples analysed, the inorganic fraction contributed 80% or more to the total suspended solid (TSS) weight when TSS exceeded 10 mg lÕ 1. At lower TSS concentrations, the organic fraction was as much as 50%. Visual examination of the lter papers before ashing revealed that the organic material was primarly phytoplankto n (Walker and Hammack 2000). 2.3. Atmospheric correction of the data The atmospheric correction of NOAA AVHRR Channel 1 and 2 data were performed using a technique described by Stumpf and Pennock (1989) and Stumpf (1992). This technique incorporates corrections for changes in solar irradiance, aerosols, Rayleigh scattering and sunglint. It is considered valid over approximately 200 km in the east-west direction. Their original ‘bias correction’ method has three main steps. First, corrections are performed to Channels 1 and 2 to compensate for changes in downwelling solar irradiance and transmission changes based on the Rayleigh optical depth and the gaseous absorption optical depth. Subsequently, S. W. Myint and N. D. Walker 3234 Channel 2 re ectances are subtracted from Channel 1 re ectances. The purpose of this step is to remove contamination from aerosols and sunglint. However, in doing so one assumes that the water re ectance in Channel 2 is zero (Gordon and Morel 1983). Then, a clear-water pixel is identi ed in the area of interest and the re ectance value of this pixel is subtracted from the entire scene. This last step removes contamination due to Rayleigh and aerosol scattering. This technique has been used successfully in studies of Mobile Bay and Delaware Bay (Stumpf 1992) and the Mississippi plume region (Walker 1996). For our study area, the technique required modi cations because the Channel 2 measurements in the Atchafalaya Bay region were non-zero ( gure 2( b)), thus invalidating the assumption that water re ectance in Channel 2 is negligible. This problem was solved by modifying the bias correction technique for use with Channel 1 alone. In short, step 2 was omitted from the above procedure. This modi ed technique was successful in retaining the water re ectance patterns within the Atchafalaya and adjacent bays and on the inner shelf. Three new variables were created in the atmospheric correction process. The variable created by subtracting Channel 2 from Channel 1 is called ‘Ch1-Ch2’. The atmospherically corrected Channel 1 and 2 variables are called ‘Ch1W’ and ‘Ch2W’. Determination of water column re ectance Rd for each Channel was based on the following steps: R # R¾ =R d d c where: C R bias D A(1) A(2) R= *(1/r2)*(1/cosh) c T (1)T (1) T (2)T (2) 0 1 0 1 A(l)=albedo for Channel l, where A=G*C+I (from Kidwell 1998), G and I are calibration coeYcients, and C=count value (0–1023 ), T (l)=exp.{ (t (l)/2+ 0 r t (l))/cosh}, T (l)=exp.{ t (l)/2+t (l)}, (1/r2)={1+0.0167 cos j }2 and j=2 0 1 r 0 (3.1416 ) (D 3)/365, D is the Julian day, cos h=cosine of solar zenith angle at scene centre, t (l)=Rayleigh optical depth for Channel l, t (l)=ozone and water r 0 Figure 2. NOAA-14 AVHRR ( left panel) Ch1W re ectances (%) and (right panel) Ch2W re ectances (%) on 26 April 1996 and the locations of water samples used to develop the suspended sediment/solids models. Quanti cation of suspended sediments from satellite 3235 vapor absorption optical depth for Channel l, R =residual re ectance de ned as bias R for a clear atmosphere over clear water near the area of interest. c The SeaWiFS data were atmospherically corrected using the SeaSpace TerascanTM version of the NASA Goddard SEADAS code based primarily on Gordon and Wang (1994). The NASA atmospheric correction software computes water leaving radiance for channels 1 to 5 and total radiance for 6 to 8. As in the Stumpf and Pennock (1989) technique, the assumption is made that water leaving radiance in the near IR channels is zero and the water leaving radiance in channels 1–5 is lowered accordingly. Throughout the paper, NOAA AVHRR data is presented as re ectance measurements in percent and SeaWiFS data is presented as radiance measurements with units of mW cmÕ 2 mmÕ 1 srÕ 1. These are the standard outputs of our TerascanTM image processing software. The reader is referred to Froidefond et al. (1993) for a discussion of conversion techniques from NOAA AVHRR re ectance to radiance values. 3. Results 3.1. Model development Correlation, linear and nonlinear regression techniques were used to quantify the relationships between the NOAA AVHRR satellite measurements and the in situ measurements of total suspended solids (TSS) and suspended sediments (SS). The SeaWiFS sensor had not been launched at the time of these helicopter over- ights. Linear correlations between TSS, SS and the three variables derived from NOAA AVHRR re ectance data were investigated using the near-simultaneou s measurements of satellite and eld data collected on 26 April 1996 (table 2) and on 21 June 1996 (table 3). The separate correlation analyses provided information on the strength and reliability of the relationships among the variables. Separate analyses for 26 and 27 March 1998 were not performed since only a single measurement was available for each date. Table 2. TSS SS Ch1–Ch2 Ch1W Ch2W NOAA-14 correlation matrix of variables using the 26 April 26 1996 eld data. TSS SS Ch1–Ch2 Ch1W Ch2W 1 0.999 0.677 0.833 0.939 1 0.680 0.836 0.941 1 0.967 0.862 1 0.963 1 Notes: Correlations are all signi cant at the 0.01 level (Pearson Correlation), N=19. Table 3. TSS SS Ch1–Ch2 Ch1W Ch2W NOAA-14 correlation matrix of variables using the 21 June 1996 eld data. TSS SS Ch1–Ch2 Ch1W Ch2W 1 0.996 0.862 0.920 0.952 1 0.863 0.921 0.955 1 0.986 0.862 1 0.935 1 Notes: Correlations are all signi cant at the 0.01 level (Pearson Correlation), N=21. 3236 S. W. Myint and N. D. Walker Signi cant linear correlations (at the 0.01 level ) were determined between the satellite re ectances, TSS and SS. The linear correlations were highest between Ch2W and the TSS/SS on both dates. The correlations were relatively low between the Ch1–Ch2 variable and the TSS/SS measurements. The linear correlations were highest using the eld measurements of 21 June 1996 when the Atchafalaya River discharge was relatively high compared with the April 1996 dataset. River discharge on 21 June was 11 558 m3 sÕ 1 and on 26 April it was 5920 m3 sÕ 1. The ‘ground truth’ measurements of TSS and SS are shown in gure 3 (see gure 2 for locations). TSS ranged from 5–140 mg lÕ 1 and SS ranged from 0 to 120 mg lÕ 1, indicating that inorganic sediments dominated the water constituents. A similar graph was constructed for the satellite re ectance variables ( gure 4). The Ch1W re ectance measurements were higher and exhibited a larger range in values than those of Ch2W, a result that would be expected for this shorter wavelength Channel. By comparing gures 3 and 4, it is evident that the Ch1–Ch2 variable does not follow the curves of TSS and SS above concentrations of about 60 mg lÕ 1. We attribute this result to the failure of the atmospheric correction scheme at the higher levels of TSS and SS. Scatter-plots of satellite re ectances (independent variables) and the eld measurements of suspended sediments (dependant variables) demonstrated that the relationships were non-linear using Ch1W re ectances and linear using Ch2W re ectances ( gure 5). Previous algorithms developed using NOAA AVHRR Ch1 measurements were also non-linear in form (Stumpf 1992, Walker 1996, Walker and Hammack 2000 ). The SPSS software package was used to determine the best predictive models for the estimation of suspended sediments and suspended solids from the re ectance measurements. Both linear and nonlinear regression techniques were investigated. Figure 3. Atchafalaya region eld measurements of total suspended solids (TSS) and suspended sediments (SS): April/June 1996. Sample points 1–21 were obtained in June and 22–44 were obtained in April. Quanti cation of suspended sediments from satellite 3237 Figure 4. Satellite re ectances (%) corresponding to the eld measurements of gure 3. Sample points 1–21 were obtained in June and 22–44 were obtained in April. The nonlinear models that were investigated included logarithmic, inverse, quadratic, cubic, power, compound, S-curve, logistic, growth and exponential. Initially, models were chosen based mainly on the coeYcient of determination (R2) values and Fratios. Table 4 depicts the best model results using Ch1W and Ch2W as independent variables. From the statistical results shown in table 4 and graphical data displays, the most robust models were chosen for the estimation of both suspended sediments (SS) and total suspended solids (TSS) using Ch1W and Ch2W. In gure 6, the predicted concentrations of SS computed from the two diVerent re ectance models are shown. Table 5 corresponds to gure 6, listing summary statistics for the chosen models including R2, the standard error of the estimate (SEE), root mean square error (RMS), F-ratio and the tabled F value. The cubic models (SS1C, TSS1C) yielded the best estimates of suspended sediment and suspended solids using Ch1W (table 5, gure 6). The linear models (TSS2L, SS2L) gave the best results using Ch2W (table 5, gure 6). The equations for the selected predictive models for TSS and SS are given below: TSS= 10.26+(14.8288 Ch1W) SS= 10.746+(12.7179 Ch1W) TSS= 8.1358+(20.0235 Ch2W) SS= 9.3438+(17.3593 Ch2W) (3.1684 (Ch1W)2)+(0.2691 (Ch1W)3) (2.7548 (Ch1W)2)+(0.2353 (Ch1W)3) All of the chosen regression models were highly signi cant as the F-ratio exceeded the tabled F value by a large margin in each case. The model results using Ch1W as input had the lowest SEE values (9.09 and 6.94 for TSS and SS, respectively). Although the summary statistics were impressive for all the models, comparisons of the two panels of gure 6 clearly revealed that the Ch1W model estimations were 3238 S. W. Myint and N. D. Walker Figure 5. Scatter-plot of NOAA AVHRR (top panel ) Ch1W re ectances (%) and (bottom panel ) Ch2W re ectances (%) against suspended sediment (SS) concentrations (mg lÕ 1): April/June 1996. more similar to the eld measurements, particularly at the higher levels of suspended sediment. In gure 7, the spatial distribution of suspended sediments (SS) on 26 April 1996 produced using the Ch1W cubic model and the Ch2W linear model are shown. Model-derived values on the shelf were observed to be similar. DiVerences in the estimated values were detected within and close to the river channels where the Quanti cation of suspended sediments from satellite Table 4. 3239 Linear and nonlinear estimations for TSS and SS using Ch1W and Ch2W. TSS Ch1W SS Ch1W TSS Ch2W SS Ch2W R2 F-ratio R2 F-ratio R2 F-ratio R2 F-ratio LIN QUA CUB EXP POW 0.71 96.97 0.70 94.86 0.91 379.52 0.90 349.14 0.92 213.63 0.92 217.05 0.91 207.56 0.91 189.80 0.95 218.03 0.95 224.38 0.95 224.77 0.95 233.48 0.91 393.54 0.83 194.13 0.83 193.92 0.71 96.92 0.83 192.99 0.78 140.13 0.87 268.53 0.76 129.12 Notes: LIN=Linear model; QUA=Quadratic model; CUB=Cubic model; EXP= Exponential model; and POW=Power model. sediment levels were highest. The Ch2W model yielded higher levels of SS in these regions. This was also observed in the actual Ch2 re ectance measurements ( gure 2). It is most likely that the diVerence may be attributed to diVerential absorption by non-sediment water constituents including gelbstoVe, marsh detrital material and phytoplankto n (Wang et al. 1996). Absorption eVects would have impacted Ch1 more than Ch2, lowering re ectance values in Ch1. Additional information on water constituents will be needed to clarify the observed diVerences between re ectance patterns of the two channels. 3.2. Application and testing of the models Water samples were obtained on 21 March 2001 in the Atchafalaya Bay region and in the Mississippi River plume, coincident with a clear sky NOAA AVHRR image. The Atchafalaya and Mississippi Rivers were in ood with discharges of 10 214 m3 sÕ 1 and 24 209 m3 sÕ 1 ( http://www.mvn.usace.army.mil), respectively. Twelve surface samples were collected in the Atchafalaya region and six in the Missisissippi Plume region (Locations, gures 8 and 9). The satellite re ectance values were extracted from individual pixels closest to the location of the water samples. The models developed in previous secions were then applied to this independent set of data. The estimates of SS and TSS from the Ch1W and Ch2W models were better than expected. RMS errors were lowest using the Ch2W linear algorithm and ranged from 5.8–7.2 mg lÕ 1 (table 6). The Ch1W cubic algorithm produced concentration estimates with RMS values of 10.6–10.9 mg lÕ 1. Bias values were negative using Ch1W ( 22 to 24 mg lÕ 1) and positive using Ch2W (13–21 mg lÕ 1). The relatively high bias values are attributable to the larger range of SS and TSS encountered on 21 March 2001. The spatial distribution of surface suspended sediments hindcast using the NOAA AVHRR re ectance models are shown for the Atchafalaya region ( gure 8) and for the Mississippi delta region ( gure 9). The two diVerent algorithms yielded similar values in Atchafalaya Bay and on the inner shelf. However, the estimated values diverged in the river channels (Atchafalaya River and Wax Lake, west of the River), as was also observed in gure 7. The estimates were also diVerent in the far western bay. A water sample obtained mid-stream in the Atchafalaya River in March 2001 3240 S. W. Myint and N. D. Walker Figure 6. Model estimates of SS concentrations (mg lÕ 1) using the NOAA AVHRR (top panel ) Ch1W cubic model and ( bottom panel ) Ch2W linear model, compared with eld measurements of SS. ‘SS1C’ and ‘SS2L’ refer to the suspended sediment predictions using the Ch1W cubic model and the Ch2W linear model, respectively. of 317 mg lÕ 1 indicates that the higher suspended sediment concentrations hindcast with Ch2W re ectances were more representative of eld measurements. The data suggest that Ch1W re ectances were too low, perhaps due to absorption from organic sources such as marsh detritus, phytoplankton or yellow substances. Quanti cation of suspended sediments from satellite Table 5. Variable Ch1W Ch2W 3241 Summary statistics for the non linear cubic regression model using NOAA AVHRR Ch1W and the linear regression model using NOAA AVHRR Ch2W data. Models R2 SEE RMS F-ratio Tabled F 0.05 TSS SS TSS SS 0.95 0.95 0.91 0.90 9.09 6.94 10.38 9.38 7.69 6.60 10.14 9.16 218.03 224.38 379.52 349.14 4.08 4.08 4.08 4.08 Figure 7. Model-estimated regional SS concentrations (mg lÕ 1) on 26 April 1996 using ( left panel ) the Ch1W cubic model and (right panel ) the Ch2W linear model. Contour intervals of 10, 25, 50 and 100 mg lÕ 1 are shown. Figure 8. Model-estimated regional SS concentrations (mg lÕ 1) for the Atchafalaya region on 21 March 2001 using ( left panel ) the Ch1W cubic model and (right panel ) the Ch2W linear model. Contour intervals of 10, 25, 50 and 100 mg lÕ 1 are shown. The region in which ‘ground truth’ data was obtained is denoted by a box. S. W. Myint and N. D. Walker 3242 Figure 9. Model-estimated regional SS concentrations (mg lÕ 1) for the Mississippi delta region on 21 March 2001 using (left panel ) the Ch1W cubic model and (right panel ) the Ch2W linear model. Contour intervals of 10, 25, 50 and 100 mg lÕ 1 are shown. The location of ‘ground truth’ data collection is depicted using dots. Table 6. RMS and bias values for the estimation of TSS and SS from NOAA-14 AVHRR Ch1W and Ch2W re ectance data on 21 March 2001. RMS TSS SS TSS SS Ch1W Ch1W Ch2W Ch2W 10.94 10.57 7.18 5.81 Bias 22.19 24.02 21.07 13.44 Extensive chlorophyll blooms have been previously observed in Vermilion Bay during eld sampling, however, water samples were only obtained from Fourleague Bay in March 2001. In the Mississippi delta region ( gure 9), the surface sediment distribution patterns were similar, but somewhat higher using the Ch2W linear algorithm. The Ch2W re ectance data and predictions were observed to contain more noise and more atmospheric contamination in the 21 March 2001 image, compared with those of 1996. The March 2001 data set provided the opportunity to improve the SS algorithms due to the larger range of sediment concentrations encountered in the eld (maximum ‘ground truth’ data was 209 mg lÕ 1 in March 2001). Scatter-plots of Ch1W and Ch2W re ectances with SS are shown in gure 10. The summary statistics for the new SS regression models, developed by combining eld and satellite measurements from 1996 and 2001, are summarized in table 7. The cubic model using Ch1W yielded a coeYcient of determination (R2) of 0.9. The linear model using Ch2W yielded a coeYcient of determination of 0.93. The equations for these new models for SS is given below. SS= 22.49+(22.76 Ch1W) (5.36 (Ch1W)2)+(0.42 (Ch1W)3) SS= 11.32+(16.78 Ch2W) Quanti cation of suspended sediments from satellite 3243 Figure 10. Scatter-plot of NOAA AVHRR (top panel ) Ch1W re ectances (%) and ( bottom panel ) Ch2W re ectances (%) against SS concentrations (mg lÕ 1) using all eld measurements: 1996 –2001. 3.2. Development of suspended sediment models using SeaW iFS A dedicated ‘ground truth’ collection survey was conducted on 26 April 2000 for the Orbview-2 SeaWiFS sensor. This eld experiment was undertaken in Barataria Bay, west of the Mississippi River bird-foot delta and the adjacent coastal ocean. Twenty-two water samples were obtained along a line that ran from 10 km oVshore S. W. Myint and N. D. Walker 3244 Table 7. Ch1W Ch2W Summary statistics of suspended sediment regression models using all eld data with NOAA AVHRR Ch1W and Ch2W variables. R2 F-ratio R2 F-ratio LIN QUA CUB EXP POW 0.64 104.07 0.93 816.15 0.88 206.39 0.94 436.11 0.90 174.15 0.94 285.79 0.81 242.18 0.66 110.22 0.73 154.56 0.73 156.55 Notes: LIN=Linear model; QUA=Quadratic model; CUB=Cubic model; EXP= Exponential model; and POW=Power model. to the interior of the bay ( gure 11). Two additional samples were obtained to the east of the line within the central bay region. The samples in the vicinity of the tidal pass were excluded from the analysis as they were too close to land to be valid with the nominal 1.1 km pixels of SeaWiFS. The correlation matrix obtained for the radiance values, SS and TSS is shown in table 8. The concentration of suspended sediments (SS) and total suspended solids (TSS) were found to be highly correlated (0.998). Channel 6 (670 nm) was more highly correlated with SS and TSS than was Channel 5 (555 nm). Correlation coeYcients between Ch 6 radiances, TSS and SS were 0.85 (table 8). Correlation coeYcients between the Ch 5 and TSS/SS were only 0.46–0.47. The relatively high correlations with Channel 6 were not unexpected as Figure 11. Orbview-2 SeaWiFS image of 26 April 2000 showing the normalized water leaving radiance at ( left panel) 555 nm and (right panel ) normalized radiance at 670 nm (mW cmÕ 2*steradianÕ 1*micrometerÕ 1) with ‘ground truth’ station locations superimposed. Quanti cation of suspended sediments from satellite Table 8. 3245 Correlation matrix showing the relationship between TSS, SS, SeaWiFS 555 nm and SeaWiFS 670 nm radiances on 26 April 2000. TSS SS SeaWiFS-555 SeaWiFS-670 TSS SS SeaWiFS-555 SeaWiFS-670 1 0.998** 0.456* 0.845** 1 0.468* 0.853** 1 0.552* 1 Notes: ** Correlation is signi cant at the 0.01 level (Pearson Correlation), N=20. *Correlation is signi cant at the 0.05 level (Pearson Correlation), N=20. it is most similar to NOAA AVHRR Ch1 measurements. The relatively poor performance of Channel 5 may be partially attributed to over-correction for the atmosphere by the standard NASA algorithm, although SS concentrations were not as high as in the Atchafalaya region (maximum of 48 mg lÕ 1). Another source of error may have been the use of water samples from the upper 0.5 m of the water column, if the Ch5 radiances represented an integration over a deeper water column. Statistical models were then developed using the radiance values of the 555 nm and 670 nm Channels (table 9). For estimation of SS, the power model out-performed other models. Only the model using the 670 nm Channel is considered a reasonable approximation of the surface suspended sediment levels ( gure 12). The modelestimates of suspended sediment concentrations are compared with actual values in gure 13. The RMS error for this model was 8.24 mg lÕ 1. 4. Discussion and conclusions The technique of ‘ground truthing’ satellite data via helicopter and high speed boat proved very eVective for obtaining water samples close in time to the satellite re ectance measurements. This is of great importance in coastal regions where re ectance patterns change rapidly as a result of water movements due to tidal and wind-driven currents, mixing and re-suspension processes. The near simultaneous acquisition of eld measurements and regional synoptic satellite data enabled the development and testing of statistical models for estimating near-surface total suspended solids (TSS) and suspended sediments (SS) in surface Table 9. Summary statistics of the selected regression models using SeaWiFS 555 and 670 nm Channel data. TSS 555 nm SS 555 nm TSS 670 nm SS 670 nm R2 F-ratio R2 F-ratio R2 F-ratio R2 F-ratio LIN QUA CUB EXP POW 0.21 4.73 0.22 5.04 0.72 45.05 0.73 48.28 0.56 10.73 0.56 10.98 0.72 21.77 0.73 22.97 0.56 6.91 0.57 7.14 0.72 21.77 0.73 22.97 0.37 10.49 0.42 13.01 0.79 66.86 0.80 70.08 0.52 19.42 0.58 24.90 0.83 89.34 0.84 97.24 Notes: LIN=linear model; QUA=Quadratic model; CUB=Cubic model; EXP= Exponential model; and POW=Power model. 3246 S. W. Myint and N. D. Walker Figure 12. Scatter-plot of satellite-derived normalized radiances (670 nm) and SS concentrations (mg lÕ 1) along transect line shown in gure 11. Figure 13. Model estimates of SS concentrations (mg lÕ 1) using the SeaWiFS 670 nm power model compared with eld measurements of SS. waters along the river-in uenced Louisiana coastline. The high levels of suspended sediments in near-shore regions required the development of a new atmospheric correction technique for use with the NOAA AVHRR re ectance measurements. The improved atmospheric correction enabled development of a robust algorithm Quanti cation of suspended sediments from satellite 3247 for estimating suspended sediments that was applicable to imagery acquired several years later. The NOAA AVHRR Ch1W non-linear model and the Ch2W linear model yielded R2 values from 0.9–0.95 for SS and TSS. Subsequent testing with an independent dataset yielded acceptable RMS values (<10 mg lÕ 1) in a region where sediments ranged from near 0 to over 200 mg lÕ 1. The combination of all eld measurements enabled development of a more comprehensive SS model with R2 values for Ch1W and Ch2W of 0.9 and greater. These results indicate that the main contributor to re ectance was backscatter from inorganic suspended sediment in the water column. The close t between the eld measurements and the model-estimates of TSS and SS suggest that light attenuation from gelbstoVe, detritus, phytoplankton pigments, etc. were minimal in the regions sampled. The regional model estimates of SS using the Ch1W and Ch2W models were found to be similar over large portions of the Atchafalaya and Mississippi plume region. However, they did diVer in the Atchafalaya River and in an interior bay where the near-IR Channel re ectances were higher and appeared to be more representative of suspended sediment levels, based on the eld data. The Ch1 re ectances may have been lowered by absorption due to the presence of non-sediment constituents in the water in these regions. The suspended sediment models developed using SeaWiFS Channel 5 were not as good as those developed using SeaWiFS Channel 6 or NOAA AVHRR Channels 1 and 2. SeaWiFS Channel 6 (670 nm) radiances were well correlated with SS and TSS (R2 of 0.84 ). The superiority of Channel 6 may be attributed to its longer wavelength and reduced eVects from pigments associated with organic substances (CDOM or pigments from phytoplankto n species). The relatively low correlations between Channel 5 radiances and the eld measurements may have resulted from over-correction for aerosols in the atmosphere, the shallow depth of the water samples (<0.5 m), and absorption eVects from other pigments. Important questions have arisen in the course of this study that merit further investigation. ‘What is the ideal depth for the ‘‘ground truth’’ water sample?’ The depth of the water sample may be critical to the relationships developed. It would be informative to obtain water samples from several depths to improve attempts to quantify suspended sediment concentrations. 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