atmosphere Article Indirect Prediction of Welding Fume Diffusion inside a Room Using Computational Fluid Dynamics Sujit Dahal 1,2 , Taehyeung Kim 2, * and Kwangseog Ahn 3 1 2 3 * Department of Eco-Friendly Offshore Plant FEED Engineering, Changwon National University, Changwon 641-773, Korea; [email protected] Department of Environmental Engineering, Changwon National University, Changwon 641-773, Korea Department of Occupational & Environmental Safety & Health, University of Wisconsin-Whitewater, 809 W. Starin Road, Whitewater, WI 53190, USA; [email protected] Correspondence: [email protected]; Tel.: +82-3876-7565 Academic Editor: Robert W. Talbot Received: 13 April 2016; Accepted: 20 May 2016; Published: 25 May 2016 Abstract: Welding is an important and widely used process in the manufacturing and maintenance of various works involving metals and alloys. While welding has broad applications, the welding fume generated during the process has impacts on workers’ health, which needs to be addressed. One of the major steps that can be undertaken to take care of this issue is the use of ventilation, which requires knowledge of characteristics and dispersion of the welding fume in the workers’ breathing zone. It is difficult to assess welding fume dispersion from manual measurement due to numerous welding processes and sufficient data requirement. Numerical prediction of welding fume is dubious due to several errors. This paper considers the use of numerically predicted CO2 concentrations to indirectly predict welding fume distribution in workshops. This is based on the assumption that if the particles are sufficiently small size, they follow the diffusion pattern of gases. Experiments are carried out in a room with an opening and a welding fume generation system for measurement of CO2 and fume diffusion. The results show high possibility of predicting welding fume concentration based on Computational Fluid Dynamics (CFD) simulated CO2 concentration with a correlation coefficient of 0.74. Keywords: CFD; health effects of welding fume; indirect prediction; ventilation; welding fume dispersion 1. Introduction Welding technology is a necessary process in the construction and maintenance of industries, large structures, vehicles, ships, offshore structures, and a number of practices involving metal works [1,2]. Nowadays, some of the welding is operated with the help of machines and robots but most is still carried on manually for precision and quality of work. However, the disadvantage of manual welding is that the fumes produced during the process have a great impact on workers’ health [1]. These fumes consist of powders of different solid substances like Cu, Ni, Zn, etc. with sizes ranging from 1 to 7 µm. Along with the fumes, different gases such as CO2 , CO, NOx , SOx , O3 , etc., and numerous organic pollutants are also produced during the welding process [3]. The gases are formed and emitted due to the presence of extremely high temperature, ultraviolet radiation arising from the arc, and reactions of hot base metal with atmospheric O2 and N2 . However, appearance of CO2 is an exception to those factors because it is generally used as a shielding gas in many welding processes [4]. Shielding gas is used in welding to protect the weld pool from oxidization in ambient air and to reduce fume emission [5]. Some of the examples of welding techniques using shielding gas are gas metal arc welding, electro-gas welding, laser beam welding, plasma arc cutting, etc. Among these techniques, Atmosphere 2016, 7, 74; doi:10.3390/atmos7060074 www.mdpi.com/journal/atmosphere Atmosphere 2016, 7, 74 2 of 10 gas metal arc welding is the most common and widely employed technique for joining metal and a vast range of alloys [6], and it uses Ar, He, O2 , and CO2 as major shielding gases. Ar and He, being inert gases, do not cause major health and environmental risks, and generally produce good-quality welding, but are approximately ten times more expensive then CO2 . For welding of steel structures, either 100% CO2 or combination of CO2 and these inert gases can be used. The additional advantage of using CO2 with other pure gases during welding of metals and alloys is to improve arc stability, minimize undercut, reduce porosity, and improve the appearance of the weld [2]. This kind of gas shielded welding is frequently performed in enclosed compartments and rooms such as in shipbuilding industries where the welder has exposure to a high concentration of fumes [7]. Gomes et al. did assessments of airborne ultrafine particles generated from tungsten inert gas, metal active gas, and friction stir welding, and found that all these processes emitted significant concentrations of ultrafine particles which were deposited in the lungs of exposed workers [8,9]. Inhalation of these fumes and gases have a great effect on lung function and causes acute as well as chronic diseases like lung cancer, infection, metal fume fever, etc. Hence, it is very essential to protect workers from welding fume exposure [10,11]. Reduction of welding fumes from workers zone is generally achieved by three processes: reduction at the source by changes in process and conditions, use of ventilation and exhausts, and use of a device for personal protection [1]. After reduction at the source, there is still a significant amount of fumes released which should be removed by employing a ventilation method. Welding fume generally consists of ultra-fine and fine particles ranging from a diameter of less than approximately 0.1 to 3 µm [12], which are difficult to remove by natural ventilation because these particles are easily influenced by the complex airflow pattern of the room [13]. The most widely-used ventilation method for control of these contaminants is local exhaust ventilation because it is more effective compared to general ventilation and dilution ventilation [14]. The design of local exhaust ventilation system to efficiently capture most of the fugitive fumes requires knowledge of concentration pattern of the dust near the contaminant source and transport of fumes from their source of origin to exhaust. Transport and concentration of fume is affected by factors like exhaust openings, ambient air currents, momentum of contaminant source, mobility of worker, etc. [15]. It is a difficult task to manually investigate transport pattern and concentration variation through experiments because sufficient numbers of measurements for more than 80 different welding and associated processes are difficult to achieve [16]. Instead of carrying out experiments, numerical methods can be used to predict the concentration of the fume particles, depending on provided conditions and related factors. Based on numerical methods, research has been done for prediction of particle concentration using Computational Fluid Dynamics (CFD) but the simulated results frequently have some divergence from the experimental results. The errors are due to limitations on the predictive methods, which do not take some factors such as particle size distribution and particle rebounding process into consideration [17]. Unlike modeling of particulate matter, CFD has been used in many previous studies with good performance to predict CO2 concentration profile and dispersion in a single room using natural as well as mechanical ventilation [18,19]. Lambert et al. compared the measured and CFD simulated values of CO2 decay in a controlled environment and found that the percent error between computational and experimental data was as low as 5.2% and concluded CFD as an effective tool to study ventilation behaviors [20]. The purpose of this study is to simulate the diffusion of CO2 and find some analogy to support utility of indirect prediction of welding fume concentration. This conjecture is based on the theory that if the particles are in range of sub micrometer level, their motion properties follow the diffusion rules of gases i.e., Brownian diffusion for movement in the air [21,22]. The initial part of the study is conducting measurement of welding fume particle size to find out if the majority of particles belong to sub micrometer range, which is followed by further experiments. The present work is directed towards the comparison of welding fume distribution measured inside the room and CO2 distribution simulated using CFD. If a satisfactory correlation between these two components is achieved, it provides an opportunity to formulate a basis for further studies related to this aspect. Atmosphere 2016, 7, 74 Atmosphere 2016, 2016, 7, 7, 74 74 Atmosphere 3 of 10 of 10 10 33 of 2. Methodology 2. 2. Methodology Methodology 2.1. Experimental Experimental Setup Setup 2.1. The physical physical model model is is aaa room room (L (Lˆ×× W Wˆ H == 2900 2900 mm mm ˆ 2800 mm ˆ 2200 mm) with single The room (L W ×× H ×× 2800 ×× 2200 2800 mm 2200 mm) mm) with with aa single opening (W × H = 600 mm × 800 mm) as shown in Figure 1. The welding apparatus is set up at the opening (W 800 mm) as as shown in in Figure 1. The welding apparatus is set (W ׈HH==600 600mm mm× ˆ 800 mm) shown Figure 1. The welding apparatus is up set at upthe at corner of the the room, andand it consists consists of aaofHIC HIC 500c welder, welding table, base metal (L ××(LB Bˆ×× BH Hˆ== H 400 corner of room, and it of 500c welder, welding table, base metal (L 400 the corner of the room, it consists a HIC 500c welder, welding table, base metal = mm × 400 mm × 18 mm), KS D0062 welding torch, and CO 2 gas cylinder. The welding system is mm × 400 mmmm × 18ˆmm), KS KS D0062 welding torch, and 2 gas 400 mm ˆ 400 18 mm), D0062 welding torch, andCO CO cylinder.The Thewelding welding system system is 2 gascylinder. automated, and and the the welding welding conditions conditions are are set set as as follows: follows: (1) (1) arc arc voltage voltage = = 38V; 38V; (2) (2) welding welding speed speed = = automated, 0.6 m/min; m/min; (3) wire diameter 1.2 mm; (4) wire speed 7070 mm/s; (5)(5) welding current 350 A; and and (6) 0.6 70 mm/s; (5) welding current == 350 A; (6) m/min;(3) (3)wire wirediameter diameter===1.2 1.2mm; mm;(4) (4)wire wirespeed speed== = mm/s; welding current = 350 A; and shield gas flow = 30 L/min. The configuration of the welding process is shown in Figure 1. Figure shield gasgas flow = 30 L/min. TheThe configuration of of thethe welding (6) shield flow = 30 L/min. configuration weldingprocess processisisshown shownin inFigure Figure 1. 1. Figure Figure 22 displays five points, each at the height of 600 mm (lower part) and 1600 mm (upper part), to imitate displays five points, each at the height of 600 mm (lower part) and 1600 mm (upper part), to imitate the stature stature of of aa welder welder working working in in sitting sitting and and standing standing positions, positions, respectively. respectively. The The placement placement of of the the the measurement points is shown in Figure 3 where four points are in the corners and one point is in the measurement points is shown in Figure 3 where four points are in the corners and one point is in the center of of the the room. room. These These points points are selected to measure size and number of welding fume particles, center points are are selected selected to to measure measure size size and and number number of of welding welding fume fume particles, particles, welding fume concentration and CO 2 concentration. An exhaust fan (Model: MJVF-40, MJ AIRTECH welding fume concentration and CO22 concentration. An exhaust fan (Model: MJVF-40, MJVF-40, MJ AIRTECH CO., Ltd. Ltd. Seoul, Seoul, Korea) Korea) with with maximum maximum flow flow rate rate of of 40 40 m m33/min /min isisused used to ventilate the room. CO., /minis usedto toventilate ventilatethe theroom. room. Figure 1. 1. Schematic Schematic diagram diagram of of welding welding apparatus apparatus setup. setup. Figure Figure 2. 2. Schematic Schematic diagram diagram of of experimental experimental setup setup and and measurement measurement points. Figure points. Atmosphere 2016, 7, 74 Atmosphere 2016, 7, 74 4 of 10 4 of 10 Figure measurement points. points. Figure 3. Top view of the model with measurement 2.2.Field FieldMeasurement Measurement 2.2. Experiments are are carried carried out out to to measure the number and Experiments and size size of of welding weldingfume, fume,concentration concentrationofof welding fume and concentration of CO 2 inside the room. Initially, the number and welding fume and concentration of CO2 inside the room. Initially, the number andsize sizeof ofwelding welding fumeparticles particles is is measured measured using MET ONE fume ONE 237B 237B Portable Portable Air Air Particle ParticleCounter Counter(Hach (HachCompany, Company, Loveland,CO, CO, USA). is welded using an automated welding apparatus with Loveland, USA). TheThe basebase metalmetal is welded using an automated welding apparatus with continuous continuous generation of fumes, and all the measurements are done 10 min after the commencement generation of fumes, and all the measurements are done 10 min after the commencement of the of the apparatus. The particle is operated for at 5 min at arate flow of 2 per Liters per minute apparatus. The particle countercounter is operated for 5 min a flow of rate 2 Liters minute and sixand size six size channels, i.e., 0.3, 0.5, 0.7, 1, 2, and 5 μm are used to measure the number of particles of each channels, i.e., 0.3, 0.5, 0.7, 1, 2, and 5 µm are used to measure the number of particles of each size per size per L of airBefore sample. Beforethe running theinstrument welding instrument and subsequent measurements, 10 L of air10 sample. running welding and subsequent measurements, the particle the particle counter is used to measure initial particle count in each size range inside the room. This counter is used to measure initial particle count in each size range inside the room. This background background measurement of particle count is deducted from the total count of welding fume measurement of particle count is deducted from the total count of welding fume particles in each particles in and eachthe sizeresults range,are andreported. the resultsCO are is reported. CO2atis the measured at the ten measurement size range, measured ten measurement points using 2 points using GrayWolf portable DirectSense IAQ meter (GrayWolf Sensing Solutions, Shelton, GrayWolf portable DirectSense IAQ meter (GrayWolf Sensing Solutions, Shelton, CT, USA) with CT, CO2 USA) with accuracy CO2 measuring accuracy of ±3% rdg which or ±50 displays ppm, which thevalues measured values in measuring of ˘3% rdg or ˘50 ppm, the displays measured in ppm in the ppm in the monitor. Real-time monitoring of CO2 is conducted 10 minutes after kickoff of the monitor. Real-time monitoring of CO2 is conducted 10 minutes after kickoff of the welding apparatus welding apparatus at all 10 measurement points. Gravimetric method is used to measure the weight at all 10 measurement points. Gravimetric method is used to measure the weight of welding fume of welding fume particles at all measurement points, and the measured weight is converted into particles at all measurement points, and the measured weight is converted into concentration at each concentration at each point. The welding fume concentration measuring system is operated at a flow point. The welding fume concentration measuring system is operated at a flow of 2 L/min for an hour of 2 L/min for an hour and consists of a Personal Air Sampler (Model 224-PCXR4, SKC Inc., Eighty and consists of a Personal Air Sampler (Model 224-PCXR4, SKC Inc., Eighty Four, PA, USA), Polyvinyl Four, PA, USA), Polyvinyl Chloride filter paper (pore size = 5 μm, diameter = 37 mm: SKC Inc., Chloride filter paper (pore size = 5 µm, diameter = 37 mm: SKC Inc., Eighty Four, PA, USA), and Eighty Four, PA, USA), and a precision analytical balance (Sartorius R 160 D, Elk Grove, IL, USA). a precision analytical balance (Sartorius R 160 D, Elk Grove, IL, USA). Three separate measurements Three separate measurements are conducted for both welding fume concentration and CO2 are conducted for both welding fume concentration and CO2 concentration, and the average of these concentration, and the average of these measurements is used for comparison with simulated measurements is used for comparison with simulated concentration CO2 . concentration CO2. 2.3. CFD Simulation 2.3. CFD Simulation Commercially available CFD software ANSYS Airpak 3.0.16 (Fluent Inc., Lebanon, NH, USA) Commercially available CFD software ANSYS Airpak 3.0.16 (Fluent Inc., Lebanon, NH, USA) is is used in this study to predict the CO2 concentration distribution in the room. Airpak is one of used in this study to predict the CO2 concentration distribution in the room. Airpak is one of the the most acceptable softwares to simulate indoor air quality which incorporates the powerful solver most acceptable softwares to simulate indoor air quality which incorporates the powerful solver FLUENT [23]. Airpak uses FLUENT to solve turbulent flow equations based on finite volume method. FLUENT [23]. Airpak uses FLUENT to solve turbulent flow equations based on finite volume Equations of conservation of energy, mass and momentum of incompressible air are solved by FLUENT method. Equations of conservation of energy, mass and momentum of incompressible air are solved to find the solution of the model. The two-equation K-ε turbulence model is used to solve turbulent by FLUENT to find the solution of the model. The two-equation K-ε turbulence model is used to flow conditions. There is a presence of mixed convection in the room due to the occurrence of both solve turbulent flow conditions. There is a presence of mixed convection in the room due to the natural and forced convection. Natural convection is caused by buoyancy forces due to density occurrence of both natural and forced convection. Natural convection is caused by buoyancy forces differences in different parts of the room. The density difference is mainly caused by high temperature due to density differences in different parts of the room. The˝density difference is mainly caused by 3 /min, CO flow gas supplied into the building (i.e., CO temperature = 600 C, CO flow = 0.03 m 2 2 high temperature gas supplied into the building (i.e., CO2 temperature = 600 °C, CO2 flow =2 0.03 diameter = 0.2 cm, and CO2 0.2 velocity = 0.33 at welding Density gradient not only m3/min, CO 2 flow diameter = cm, and CO2 m/s velocity = 0.33 m/spoint). at welding point). Densityisgradient caused by temperature gradient, but other factors are also associated with it. But for this study, Atmosphere2016, 2016,7,7,74 74 Atmosphere 5 of 1010 5 of 5 of 10 Atmosphere 2016, 7, 74 is not only caused by temperature gradient, but other factors are also associated with it. But for this is not only caused by temperature gradient, but other factors are also associated with it. But for this density to temperature differences differences from heat sources is only taken into consideration study, gradient density due gradient due to temperature from heat sources is only taken intoas study, density gradient due to temperature differences from heat sources is only taken into the effects caused by natural convection are far lower than the effects caused by forced convection. consideration as the effects caused by natural convection are far lower than the effects caused consideration as the effects caused by natural convection are far lower than the effects caused byby 3 forced convection. Forced convection occurs due to aai.e., ventilation system, i.e.,an anexhaust exhaust with Forced convection occurs due to a ventilation an exhaust fan with airflow of fan 20fan m /min. forced convection. Forced convection occurs system, due to ventilation system, i.e., with 3/min. A fine mesh of hexa-unstructured geometry is used to discretize the domain. A of 20 m Aairflow fine mesh of hexa-unstructured geometry is used to discretize the domain. A grid independency 3 airflow of 20 m /min. A fine mesh of hexa-unstructured geometry is used to discretize the domain. A grid test isisperformed one and two finer meshes. The finemesh mesh finallyof test is independency performed using one coarse andusing two finer meshes. The fine mesh finally generated consists grid independency test performed using one coarse coarse and two finer meshes. The fine finally generated consists of 1.1 million cells. The 3-D model developed in Airpak with the same geometries 1.1 million cells. The of 3-D in Airpak with the in same geometries and features as the generated consists 1.1model milliondeveloped cells. The 3-D model developed Airpak with the same geometries and features setup 4. and features thephysical physical setup4.isisshown shown in in Figure Figure 4. physical setupas isasthe shown in Figure Figure 4. Model and mesh generation in Airpak. Figure mesh generation generation in inAirpak. Airpak. Figure 4. 4. Model Model and and mesh 3. Results and Discussion 3.3.Results Results and and Discussion Discussion 3.1. Welding Fume Particle Size Distribution 3.1. 3.1.Welding WeldingFume FumeParticle ParticleSize SizeDistribution Distribution Figure 5 shows the variation in welding fume particle size in the room. The respective particle Figure 55shows the in fume particle size size in in the the room. room.The Therespective respectiveparticle particle Figure shows thevariation variation in welding welding fume count at the upper (1600 mm height) and lower (600 particle mm height) sections of the experimental room is count at the upper (1600 mm height) and lower (600 mm height) sections of the experimental roomisis count at the mmcount height) and lower mmS1height) of the experimental room shown in upper Table (1600 S1. The presented in(600 Table is thesections result of deducting background shown in Table S1. The count presented in Table S1 is the result of deducting background measurement shown in Tablefrom S1.the The count presented in Table S1 isFrom the Figure result 5, ofit deducting background measurement total measurement in each size range. is evident that most of from total measurement in each sizeand range. From it isFigure evident most ofthat particles’ measurement from measurement inabout each sizeFigure range. From it is less evident thethe particles’ sizes the are total less than 0.5 μm 99.6% of the 5, particles have5, a that size than 1the μmmost (subof sizes are less than 0.5 µm and about 99.6% of the particles have a size less than 1 µm (sub micrometer), which thethan size that actsand as gases Therefore, reveals a possibility themicrometer), particles’ sizes areisless 0.5 μm aboutduring 99.6% diffusion. of the particles have this a size less than 1 μm (sub which the size that isacts gases during Therefore, this reveals athis possibility thatiswelding fume particles and 2 used as shielding gas emitted at the same point source inwelding this micrometer), which theas size thatCO acts as diffusion. gases during diffusion. Therefore, reveals athat possibility study mightand have similar spread theasemitted room. To explain this theory, a in comparison is made fume particles CO shielding gas at the point this study might have that welding fume particles and COover 2 used shielding gassame emitted at source the same point source in this 2 used as between theover concentrations of welding fume and CO 2 at thethis same points. similar spread the room.spread Toboth explain this aTocomparison is made between the concentrations study might have similar over the theory, room. explain theory, a comparison is made ofbetween both welding fume and CO at thewelding same points. the concentrations of2 both fume and CO2 at the same points. Figure 5. Size distribution of welding fume particles (%). Figure5. 5. Size Size distribution distribution of Figure of welding welding fume fumeparticles particles(%). (%). Atmosphere 2016, 7, 74 6 of 10 Atmosphere 2016, 7, 74 Atmosphere 2016, 7, 74 3.2. Measured and Simulated Concentration of Welding Fume and CO2 6 of 10 6 of 10 6 of 10 Atmosphere 2016, 7, 74 3.2. Measured and Simulated Concentration of Welding Fume and CO2 The results ofand measured welding measured CO2 , and simulated CO2 at 3.2. Measured Simulated concentration Concentration of of Welding Fumefume, and CO 2 The results measured concentration of welding fume, measured CO2, and simulated CO2 at 3.2. Measured andofSimulated Concentration of Welding Fume and 2 ten measurement points inside the room are shown in Figures 6–8CO respectively. Although the concentration The results ofpoints measured concentration of welding fume, measured CO2, and simulated COthe 2 at ten measurement inside the room are shown in Figures 6–8, respectively. Although units ten for welding fume and CO arethe different,are thewelding similarity of measured pattern among three graphs CO is certainly The results of measured of fume, CO2, and simulated 2 at 2 concentration measurement inside shown in Figures 6–8, respectively. the concentration unitspoints for welding fumeroom and CO2 are different, the similarity of pattern Although among three ten measurement the room are shown in regression Figuressimilarity 6–8,analysis respectively. Although the that evident. Further reasoning ofinside these results done using to find correlation concentration unitspoints for welding fume andisCO 2ofare different, pattern among three graphs is certainly evident. Further reasoning these resultsthe is done usingofregression analysis to concentration for welding fume and CO2of arethese different, pattern among three existsfind between theunits species. graphs is certainly Further reasoning resultsthe is similarity done usingofregression analysis to correlation thatevident. exists between the species. graphs is certainly Furtherthe reasoning find correlation thatevident. exists between species. of these results is done using regression analysis to find correlation that exists between the species. Figure 6. Concentration of measured welding fume at ten measurement points. Figure 6. Concentration of measured welding fume at ten measurement points. Figure 6. Concentration of measured welding fume at ten measurement points. Figure 6. Concentration of measured welding fume at ten measurement points. Figure 7. Concentration of measured CO2 at ten measurement points. Figure 7. Concentration of measured CO2 at ten measurement points. Figure 7. Concentration CO22atatten tenmeasurement measurement points. Figure 7. Concentrationofofmeasured measured CO points. Figure 8. Concentration of simulated CO2 at ten measurement points. Figure 8. Concentration of simulated CO2 at ten measurement points. Figure 8. Concentration of simulated CO2 at ten measurement points. Figure 8. Concentration of simulated CO2 at ten measurement points. Atmosphere 2016, 7, 74 7 of 10 Atmosphere 2016, 7, 74 7 of 10 Atmosphere 2016, 7, 74 7 of 10 3.2.1. Measured Welding Concentrations 3.2.1. Measured WeldingFume Fumevs. vs.Measured MeasuredCO CO22 Concentrations 3.2.1. Measured Welding Fume vs. Measured CO20.96 Concentrations The R2R(coefficient ofofdetermination) measuredCO CO2 2and andmeasured measured welding 2 (coefficient The determination) value value of of 0.96 between between measured welding 2 (coefficient fume concentrations as shown in the regression plot as shown in Figure 9 explains that the concentration The R of determination) value of 0.96 between measured CO 2 and measured welding fume concentrations as shown in the regression plot as shown in Figure 9 explains that the concentration of fume welding fume particles and in room atmosphere similar. other words, this concentrations as shown in the regression plot as shown in Figure 9very explains that the concentration of welding fume particles andCO CO spread in the the atmosphere isisvery similar. InIn other words, this 2 2spread of welding fume particles CO 2 spread in the of room atmosphere is room. very similar. Incorrelation other words, this shows that both the species have similar patterns distribution inthe the room. the is higher, shows that both the speciesand have similar patterns distribution in AsAs the correlation is higher, that bothprediction the speciesishave similar patterns of distribution inprediction the room. As the correlation is higher, theshows error during which contributes betterprediction accuracy. the error during prediction islower, lower, which contributes totobetter accuracy. the error during prediction is lower, which contributes to better prediction accuracy. Figure 9. Correlation of measured welding fume and measured CO2. Figure 9. Correlation of measured welding fume and measured CO2 . Figure 9. Correlation of measured welding fume and measured CO2. 3.2.2. Measured CO2 vs. Simulated CO2 Concentrations 3.2.2. Measured CO2 vs. Simulated CO2 Concentrations 3.2.2. Measured CO2 vs. Simulated CO2 Concentrations Figure 10 is the regression plot of measured and simulated CO2 with a R2 value of 0.78. This is a 2 value of 0.78. This is Figure 1010isisthe plot of andsimulated simulated CO with 2 of Figure theregression regression plot of measured measured CO 2 with aCO Ra22 R value of 0.78. This is a relatively high coefficient value, which supportsand that the prediction concentration through a relatively high coefficient value, which supports that the prediction of CO concentration through 2 relatively coefficient value, which supports the welding prediction of CO2 concentration through computer high simulation is finely accurate. Hence, inthat an arc workshop, which uses CO 2 as a computer isis finely accurate. Hence,ininananarc arcwelding welding workshop, computer simulation finely accurate. workshop, uses CO 2 CO as 2a as shieldingsimulation gas, it is possible to predict theHence, concentration distribution of CO 2 withwhich thewhich help ofuses computer a shielding gas,it it is possible to predict the concentration distribution of CO with the help of shielding gas, is possible to predict the concentration distribution of CO2 with the 2help of computer simulation. computer simulation. simulation. Figure 10. Correlation of simulated CO2 and measured CO2. Figure 10. Correlation of simulated CO2 and measured CO2. Figure 10. Correlation of simulated CO2 and measured CO2 . 3.3.3. Measured Welding Fume vs. Simulated CO2 Concentrations 3.3.3. Measured Welding Fume vs. Simulated CO2 Concentrations The comparison ofFume measured welding fume and simulated CO2 concentrations portrays a R2 3.2.3. Measured Welding vs. Simulated CO2 Concentrations comparison simulated COthat 2 concentrations portrays 2a Rof2 valueThe of 0.74 as shownofinmeasured Figure 11.welding In other fume wordsand it can be implied change in concentration The comparison of measured welding fume and simulated CO concentrations portrays a R value 2 that change in concentration value of 0.74 as shown in Figure 11.predicted In other words it can be implied of measured welding fume could be through simulated CO 2 with accuracy of around 74%. of measured 0.74 as shown in Figure 11. In other words it can be implied that change in concentration of welding fume could be predicted through simulated CO 2 with accuracy of around 74%. This is also a relatively high value of coefficient of determination, and it supports that there is a measured welding fume could be predicted through simulated COand accuracythat of around 2 with This is also a relatively high value of coefficient of determination, it supports there is 74%. a Atmosphere 2016, 7, 74 8 of 10 Atmosphere 2016, 7, 74 8 of 10 This is also a relatively high value of coefficient of determination, and it supports that there is a possibility possibility of of achieving achievingaameaningful meaningfulprediction predictionofofwelding weldingfume fumeconcentration concentration indirectly through indirectly through CO CO simulatedresults. results. 2 2simulated Figure 11. Correlation of simulated CO2 and measured welding fume. Figure 11. Correlation of simulated CO2 and measured welding fume. 4. Conclusions 4. Conclusions This paper presents a possibility of an alternative method for prediction of welding fume This paper inside presents a possibility an forced alternative methodi.e., for by prediction weldingCO fume concentration a closed room of with ventilation, use of of simulated 2 concentration inside a closed room with forced ventilation, i.e., by use of simulated CO concentration. 2 concentration. The research was conducted by measuring CO2 and welding fume concentration, and The research was conducted measuring CO2 and welding fume concentration, andevaluated comparingusing it with comparing it with predictedbyCO 2 concentration. The extent of their relationship was predicted CO concentration. The extent of their relationship was evaluated using regression analysis. 2 2 regression analysis. The squared correlation coefficient (R ) of the experimental CO2 and welding 2 ) of the experimental CO and welding fume concentration is The squared correlation coefficient 2 fume concentration is very high (R2(R = 0.96), which means the behaviors of welding fume and the CO2 very high (R2 = 0.96), means the behaviors ofthe welding fume and the CO2 used asrelationship shielding gas used as shielding gaswhich are very similarly spread in atmosphere. Comparison of the are very similarly spread in the atmosphere. Comparison of the relationshipshows between predicted CO2 between predicted CO2 with measured CO2 and welding fume concentration R2 values of 0.77 2 values of 0.77 and 0.74 respectively, with CO2 and welding fume concentration shows andmeasured 0.74 respectively, which are also relatively high values andRback a meaningful prediction. Based on theare results, it can be established numerical simulations are sufficiently to indirectly which also relatively high valuesthat andthe back a meaningful prediction. Based onuseful the results, it can be calculate appropriate welding simulations fume emissions in the case that proper measurement technique and established that the numerical are sufficiently useful to indirectly calculate appropriate instrument is unavailable for direct measurement. It is possible to explain this compatibility. The welding fume emissions in the case that proper measurement technique and instrument is unavailable diffusion of fume particles and other gases is comparable as measurement of particle size showed for direct measurement. It is possible to explain this compatibility. The diffusion of fume particles thatother moregases than is 99.5% of fume as particle size is below 1 μm and they that tendmore to follow diffusion and comparable measurement of particle size that showed thanthe 99.5% of fume pattern of gases. As this study was not aimed in developing a model for prediction of welding fume, particle size is below 1 µm and that they tend to follow the diffusion pattern of gases. As this study butnot to aimed determine the possibility of indirect prediction based fume, on diffusion characteristics, future was in developing a model for prediction of welding but to determine the possibility research should be directed towards unearthing the relationship of these two species by changing of indirect prediction based on diffusion characteristics, future research should be directed towards model parameters and verifying it byspecies usingbyadequate of measurements. Further unearthing the relationship of these two changingnumbers model parameters and verifying it by experiment and simulation can also be applied with complex building setup to illustrate the using adequate numbers of measurements. Further experiment and simulation can also be applied significance of this method in more realistic conditions. with complex building setup to illustrate the significance of this method in more realistic conditions. Supplementary Material: The following is available online at http://www.mdpi.com/2073-4433/7/6/74/s1. Supplementary Materials: The following is fume available online at http://www.mdpi.com/2073-4433/7/6/74/s1. Table S1: Number and diameter of welding particles. Table S1: Number and diameter of welding fume particles. Acknowledgments: This research was financially supported by Changwon National University, South Korea in Acknowledgments: This research was financially supported by Changwon National University, South Korea in 2014–2015.The Theauthors research waswish partially supported by Brain Korea 21 Plus, and Ventech Corp., South Korea. The 2014–2015. also to thank the editor and anonymous reviewers for valuable suggestions. authors also wish to thank the editor and anonymous reviewers for valuable suggestions. Author Contributions: Sujit Dahal was involved in literature review experimental works, conduction of CFD simulation, analysis of the results, and writing thein manuscript. Kwangseog Ahn contributed to the concept and Author Contributions: Sujit Dahal was involved literature review experimental works, conduction of CFD methodology of the research and assisted in reviewing and editing the manuscript. Taehyeung Kimconcept designed simulation, analysis of the results, and writing the manuscript. Kwangseog Ahn contributed to the andthe concept and methodology of the research, theand experimental and analysis of results assisted methodology of the research and assistedsupervised in reviewing editing theworks manuscript. Taehyeung Kimand designed in reviewing and editing the manuscript. All authors have read and approved the final manuscript. the concept and methodology of the research, supervised the experimental works and analysis of results and Conflicts Interest: The no conflict interest. assisted of in reviewing andauthors editing declare the manuscript. Allof authors have read and approved the final manuscript. Conflicts of Interest: The authors declare no conflict of interest. Atmosphere 2016, 7, 74 9 of 10 References 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. Escala, S.; Nooij, M.; Quintino, L. Economically welding in a healthy way. 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