FACT SHEET ANALYSIS AND The Emission Reduction Benefits of Carbon Capture Utilization and Storage using CO2 Enhanced Oil Recovery Oil Recovery ABOUT THE AUTHORS Deepika Nagabhushan is a CCS Policy Associate at CATF You can reach Deepika at [email protected] or 847-505-4149. Kurt Waltzer is the Managing Director at CATF You can reach Kurt at [email protected] or 617-624-0234, ext. 292 Enhanced Oil Recovery (EOR) using industrial CO2 provides an important way to stimulate the development of the infrastructure needed to capture and store large amounts of CO2 consistent with decarbonizing the energy system. According to the International Energy Agency (IEA), utilizing industrial CO2 Enhanced Oil Recovery for the purposes of Carbon Capture Utilization and Storage (CCUS) results in a net CO2 emissions reduction. Based on IEA’s analysis CCUS-EOR using industrial CO2 can result in a 63% net reduction in CO2 emissions for every barrel of oil produced. If we do not take advantage of CO2 EOR, the oil may be produced by other technologies that do not reduce emissions. AccordingtotheIEA,thereisapotentialtostore140billiontonsofCO2inoilreservoirsaround theworldthroughCO2EOR1-resultinginanetemissionsreductionby88billiontonsofCO2. Thisismorethan40timesthecurrentU.S.powersectoremissions.Thus,undertheright economicconditionstherewouldbealargemarket-basedopportunitytoreduceman-made CO2emissions.Asaresult,enhancedoilrecoveryactivityusingcapturedanthropogenicCO2, couldsignificantlydrivethedeploymentofCCUStechnology&infrastructure,andhelplower technologycostsaroundtheglobe. CanCO2EORprovideanetreductioninCO2emissions? Yes.CCUScombinedwithEORinvolvestheincidentalgeologictrappingorstorageofCO2that occursaspartoftheoilrecoveryprocess.CO2isinjectedintomaturereservoirs,whereitmixes withtheremainingoil,enablingittobemoreeasilyproduced,andasaresultofwhicha portionoftheCO2(usuallyaboutone-thirdtoahalf)isgeologicallytrapped,permanently.The CO2thatisnottrappedisproducedwiththeoil,recaptured,andreinjected–andtheprocess continuesuntilalloftheCO2ispermanentlysequestered. Overthelifeoftheproject,almostalloftheCO2deliveredtothefieldisstoredinthegeologic formation.ButbecauseEORproducesoil,whichwhenprocessedorusedproducesemissions, thestoredvolumeofCO2cannotentirelybecountedasanemissionsreduction.Whenthe volumeofCO2storedundergroundisgreaterthanthoseemittedbytheexcessemissions causedbyEORactivity,thenthedifferencemustbecountedasanetemissionsreduction benefit. ThemostrecentandcomprehensiveassessmentofnetstoragefromCO2EORwasdeveloped bytheIEAin2015.2ThestudyindicatesthatforagivenvolumeofCO2deliveredtoanoilfield orstoragesite,EORcanprovidea63%netemissionsreductionbenefit,underthereasonable assumptionsoutlinedbelow. 2 Figure1:NetReductionsinCO2EmissionsthroughEnhancedOilRecovery(metrictons) Figure1showsthebenefitsofCO2EORintermsofCO2emissionsreduction.Theproduction andconsumptionofatypicalbarrelresultsinabouthalfametrictonofCO2beingemittedto theatmosphere. But,doesn’tEORresultingreateroverallCO2emissionsduetooilproduction? No.ProducingabarrelofoilfromCO2EORisslightlymoreenergyintensivethanaconventional barrelofoil,withemissionsof0.54metrictonsand0.51metrictonsofCO2respectively.But CO2EORhasthebenefitofstoringthe0.30metrictonsofCO2thatwasneededtoproduce1 barrelofoil.Afteraccountingforthisbenefit,theproductionandconsumptionofabarrelofoil fromEORcontributesanetof0.24metrictonsofCO2totheatmosphere. IfanEORbarrelreplacedabarrelofconventionallyproducedoilinthemarket,thenthere wouldanemissionsreductionof0.27metrictonsofCO2perbarrel(thedifferencebetween conventionaloilemissionsandEORbarrelemissions).Inrealitythough,allelsebeingequal,this 1to1displacementdoesnotoccur.Thenewoilsupplywilllowerthemarketpriceofoiland thusincreasethedemandforoil.TheIEAestimatesthatforevery10barrelsofoilproduced 3 throughCO2EOR,only8barrelsofexistingoilaredisplacedand2barrelsareadditional.The displacementofthe8barrels(or80%ofexistingsupply)providesanemissionsreduction benefitof0.23tonsperEORbarrel.3But,theincreaseinconsumptionoftheadditional2EOR barrels(20%ofexistingsupply)increasesemissionsby0.04tonsperEORbarrel.4Thesemarket effectsresultinanetemissionsreductionbenefitto0.19metrictonsofCO2perEORbarrel,on average. ConsideringtheCO2usedforEORisanthropogenic,i.e.capturedfromthepowerorindustrial sectorsandwhichwouldotherwisebereleasedintotheatmosphere,thenetreductionofCO2 is63%perbarrelofoilproducedorper0.3tonsinjected(or,peranyothervolumeofCO2 injected). ThetypeofoilproductionthatisassumedtobereplacedbyEORisalsoakeyfactorin determiningthenetreductioninemissions.TheIEAanalysisfoundthatnetemissionreductions couldrangefrom47%to150%dependingonthecarboncontentoftheoilthatisassumedto beoffset.5Whilea20%increaseinoilconsumptiondrivenbyCO2EORoilproductiondelivers netemissionsreduction,eveniftheconsumptionincreasedby50%ofabarrel,therewouldstill beanetemissionsreductionbenefit. ArethereanyotheremissionsthatmightaffectEOR'sbenefit? Yes,emissionsupstreamfromtheCO2EORprocesscanalsoaffecttheCO2emissionsreduction benefitsfromusinganthropogenicCO2.But,itisimportanttonotethattheupstreamemissions affectanysequestrationmethodthesameexactway.Inotherwords,upstreamemissions affectbothEORandstorageindeepsalinegeologicreservoirsequally.Hence,itisonly downstreamemissionsthatprovidethecrucial“applestoapples”netemissionsreductions benefitcomparison. Upstreamemissionsincludethosefromcoalandnaturalgasproduction,transportationoffuel, combustionandtransportationofcapturedCO2.But,thekeyemissionsimpactisdrivenby 4 capturetechnologyandconfiguration(new/retrofit/fullorpartialcapture)usedattheemitting source.Forexample,ifweweretoincludeinourupstreamcalculationsa90%capturefroma retrofitonanexistingcoalplantusingcurrentconventionalcapturetechnology,thenitwould reducetheemissionsreductionbenefitfromCO2EORby25%,duetoprocessenergypenalties andcapturerates.6Alternatively,ifweweretoconsideranadvancedcarboncapture technologysuchasonebasedontheAllamCycle,whichcouldreach100%capturelevels, bringingtheenergypenaltytominimallevels,thenthereductioninthebenefitfrom downstreamCO2EORwouldbeminimal.7 WouldtheoilfromdepletedoilfieldsbeproducedanywaywithoutCO2EOR? Likely.ThesameoilthatistargetedforCO2EOR,canbeproducedbyothertechnologiesand willonlyresultinincreasedemissions.Oilfromdepletedwellswillberecoveredusingthebest availablemethod,evenifitisnotCO2injection,iftheoilpricessodictate.CO2EORiseffectively incompetitionwithotherEORoptionsoutlinedbelow.Theseoptionsdonotprovideany climatebenefit,butinsteadonlypermitandleadtoincreasedCO2emissions. Geologically-sourcedCO2hasbeeninuseforseveraldecadesforCO2EOR.75%oftheCO2 currentlyusedforEORisproducedfromnaturalgeologicdeposits.NationalEnergyTechnology Laboratory(NETL)estimatesthatthereareanadditional3.9billionmetrictonsofgeologicallysourcedCO2intheUSthatcouldbeproducedeconomicallyforuseinEOR.8Becausethe natural-sourcedCO2wasalreadygeologicallytrapped,itdoesnotdeliveraclimatebenefit whenusedforCO2EOR,unlikeindustrial-sourcedCO2. Theuseofsurfactants,polymers,anddetergentsforchemicalfloodinginreservoirsisanother formofenhancedoilrecovery.Advancesindrillingsuchasinfielddrilling,horizontaldrilling andfrackingcouldalsobeusedtoextracttheoilfromreservoirs,whichwouldotherwisebe targetsforCO2injection. 5 MethanereactsinoilfieldsinamannersimilartoCO2.TheNorwegianoilcompanyStatoilhas beeninjectingmethaneintotheNorthSeaforoilrecovery(64millionmetrictons/year)in amountsthataresimilartothoseofCO2injectedintothePermianBasininTexasforEOR.9 MethaneisalsoregularlyinjectedintotheNorthSlopeformationalsoforEOR.AlthoughEORis typicallynotthewaytoextractthemosteconomicvalueoutofmethane,itisstillusedinsome regionswhereeitherCO2isnotavailableoroil-gaspricearbitragedrivesapreferencefor methaneinjectiontoproduceadditionaloil. Conclusion EnhancedOilRecoveryusingcapturedindustrialCO2canprovideanetCO2emissionsreduction of63%relativetotheCO2stored,takingintoaccountemissionsfromoilconsumption.The combinationoftheexistingandprojecteddemandforEORandtheavailabilityofindustrialCO2 offersthepotentialfordevelopingtheneededinfrastructuretomorewidelydeployCCUS technologyatasignificantscaleandtostorelargeamountsofCO2.WithoutCO2EORusing capturedindustrial(anthropogenic)CO2,theoilwilllikelybeproducedanyway,usingother methodsofextractionthatdonotprovideemissionsreductionbenefits. 1 IEA Greenhouse Gas R&D Programme (IEA, GHG), “CO2 Storage in Depleted Oilfields: Global Application Criteria for Carbon Dioxide Enhanced Oil Recovery, 2009/12, December 2009.” 2 International Energy Agency, “Storing CO2 through Enhanced Oil Recovery, combining EOR with CO2 storage (EOR+) for profit,” 2015. 3 The more precise IEA displacement estimate is 84%. Multiplying that with the difference between conventional oil and EOR oil (0.27 metric tons per bbl) results in a net benefit of 0.23 metric tons per bbl. 4 The more precise IEA displacement estimate is 16%. Multiplying that with the emissions from one barrel of EOR oil (0.24 metric tons per bbl) results in a net increase of 0.04 metric tons per bbl. 5 International Energy Agency, “Storing CO2 through Enhanced Oil Recovery, combining EOR with CO2 storage (EOR+) for profit,” 2015. 6 Calculated from spreadsheet model developed for Azzolina, et al., “How green is my oil? A detailed look at greenhouse gas accounting for CO2-enhanced oil recovery (CO2-EOR) sites.” International Journal of Greenhouse Gas Control 51 (2016) pp. 369-379. Considering coal plant retrofit with 90% capture level, 30% energy penalty and make up power from NGCC without carbon capture (no displacement of electricity grid mix). 7 NETPower briefing to USEA, May 25, 2016. 8 National Energy Technology Laboratory, “Subsurface Sources of CO2 in the Contiguous United States Volume 1: Discovered Reservoirs,” March 4, 2015, DOE/NETL-2014/1637. 9 Cavanagh, Ringrose, Statoil, ASA “Improving oil recovery and enabling CCS: a comparison of offshore gasrecycling in Europe to CCUS in North America”, GHGT-12, Energy Procedia 63 (2014) 7677 – 7684. 6
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