Conference Session: A4 Paper #6 Disclaimer—This paper partially fulfills a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering. This paper is a student, not a professional, paper. This paper is based on publicly available information and may not provide complete analyses of all relevant data. If this paper is used for any purpose other than these authors’ partial fulfillment of a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering, the user does so at his or her own risk. THE GRATIFICATION OF GASIFICATION Sydney Anderson [email protected] Mahboobin 10am, Victoria Behne [email protected] Sanchez 5pm Abstract- Plasma gasification is one method to transform garbage into gas, and can be used to solve the global problem of waste accumulation, in a sustainable and ecologically positive way. For example, the Metro Council of Portland, Oregon plans to use plasma gasification to combat the “million tons of garbage” that accumulates there per year. Plasma gasification is a process that transforms waste into reusable energy in the form of syngas, a gas comprised of hydrogen and carbon dioxide, by heating the waste to over 3,000 Celsius with a plasma gasifier. The plasma gasifier is an apparatus that turns waste into useable syngas. This gas is used to generate synthetic chemicals ,for cars that run on synthetic gasoline, steam to turn turbines, electricity to send to residential homes and power heavy machinery in plants. The process replaces outdated waste incinerators that burn waste using coal that release harmful toxins such as carbon monoxide, with an ecological waste-to-energy source. Westinghouse Plasma Corporation, currently uses plasma gasification process to produce energy, and NASA is looking to use the process to replace former methods of trash removal that did not support travel further than earth’s orbit. As current applications, such as those in process at Westinghouse, and future applications, such as those being researched by NASA, show, plasma gasification will continue to reduce the issue of waste accumulation in the future. For this paper, waste is defined as solid material that is no longer of use to a company, building, household, or person. The waste from these different sources end up in landfills, a location to store waste. Unfortunately, at a landfill emissions of toxins such as methane are released. Such air pollution is highly detrimental to human health as methane is more potent that carbon dioxide [1]. Specifically, methane is known stunt growth in children and cause lung and heart disease. Additionally, landfills also release pollution into groundwater sources that pose a threat to animal life, plant life, and humans as this pollution affects drinking water [1]. The process of plasma gasification’s ability to transform waste into syngas must be focused on to completely understand the benefits of using plasma gasification as a method to minimize the waste accumulation on earth. Syngas is a usable substance composed of hydrogen and carbon dioxide, and is an ecological, reusable byproduct of plasma gasification, which in comparison to the former, commercially used method of coal incineration is an improvement (a delineation of how plasma gasification is an improvement will be provided in another section). The focus of transforming waste into energy to solve the worldwide issue of waste accumulation centers around one main problem and its two sub-issues. This main problem is the: increasing trash accumulation across the seven continents and the two sub issues: the lack of environmentally friendly ways to diminish and transform the waste into reusable energy and fuel sources. Finding a solution to this global issue is imperative considering that currently Earth is the only planet that is sustainably inhabitable for humans. The current widely used method of coal incineration is not a sustainable method for creating energy, as it results in multiple toxic byproducts (which will be discussed in more detail in a later section). The key word in these two statements is “sustainable” as that is the crux of this investigation. What exactly are we researching and proving with plasma gasification? The answer was already stated from a current day perspective-to reduce the increasing amount of waste in the world, and from a future perspective, to ecologically do so. The word ecologically is important because it means that plasma gasification will reduce the buildup of waste without harming humans or the planet’s atmosphere. Plasma Key Words- Coal Incinerator, Environmentally friendly/Ecological, Plasma Gasification, Reusable energy, Syngas PLASMA GASIFICATION: WHY IS IT RELEVANT? Waste: Defined The process of plasma gasification is an ecological replacement for the coal incineration waste to energy transformation process. Before the discussion of why plasma gasification is the best replacement for coal incineration, the reason waste should to be changed into gas needs to be addressed. A good way to start this discussion is by asking the question: why and how is waste an issue? 1 University of Pittsburgh Swanson School of Engineering 31.03.2017 Sydney Anderson Victoria Behne gasification does not produce tar, ash or residual carbon dioxide, unlike coal incineration (combustion). The purpose of coal incineration is to burn coal and use the byproduct to produce electricity. The main deficit to this process is that coal burning releases toxic gases which will be further detailed in a later section that statistically compares plasma gasification to coal incineration. In addition to being a threat to human health, the process of coal incineration is also a danger to the earth’s atmosphere. Coal incineration releases carbon dioxide, which adds to the already increasing amounts of carbon dioxide in the atmosphere. For every million molecules in the air as of 2010, o.o4% was carbon dioxide, though only a fraction of the earth’s atmosphere, this amount alone can trap too much heat into the atmosphere [2]. This effect is more commonly known as global warming, and with the amount of carbon dioxide in the air accelerating upwards annually, coal incineration is not a sustainable method because it poses harm to humans currently, and even more so in the future. To put this in perspective, with 0.00% carbon dioxide in the air, the earth would be frozen solid, so even 0.04% can contain a massive amount of heat and lock it into the atmosphere [2]. Professional Impact: How Plasma Gasification is a Benefit and Improvement on Coal Incineration from Multiple Perspectives Marco Castaldi, associate professor in chemical engineering at The City College of New York, explains that when calculated, the amounts of emission and the type of gas emitted that compare coal incineration to plasma gasification show that “a gasification system makes syngas and converts it to fuel has the possibility to be more efficient than combustion” [3]. Castaldi studies combustion and gasification of solid waste, and as an expert on the subject, this supports our research that will be detailed further in later sections, that gasification is not only an environmentally friendly method to convert waste into gas, but is also an improvement upon the former popular method of coal incineration. Steven Weber, vice president of business development at the solid waste and energy company Covanta, explains that not only is the market “clamoring for non-combustion types of systems” for a more environmentally friendly way convert trash into energy such as plasma gasification, but that the process is also an evolved form of coal incineration [3]. It can be noted that not only does this other expert agree with our claims and those of expert Castaldi, but it also expresses how plasma gasification is a process that is approved of and preferred by many companies. Portland, Oregon: A Trashy Place to Live The metropolitan area of Portland, Oregon is an extreme example of how plasma gasification is the solution to the increasing waste accumulation on the planet. The Metro Council of the city is looking to use plasma gasification as a means to reduce the tons of garbage produced annually [3]. Accounting of the fact that we live in a country promotes recycling, another ecological method for reusing trash can only be a benefit. For an area, such as Portland, Oregon, having exorbitant amounts of trash is an issue because it is detriment to the atmosphere due to methane-emission pollution, as stated in the above section on waste. This is an imposing issue for Portland as such emissions can affect the quality of the air that the areas constituents breath which can cause adverse health effects. The specifics of such health problems will be described in detail in a later section on sustainability and air quality. Using coal incineration would not be beneficial to Portland either because it would also pollute the air, therefore plasma gasification is the only solution to the “millions of tons of garbage that accumulates” in Portland per year [3]. Considering the expert research and opinions discussed in the prior section, the Metro Council wisely plans to begin the use of this process in 2020, as there is FIGURE 1 [1] Graphical representation of linear growth of carbon dioxide amounts in earth’s atmosphere. PLASMA GASIFICATION IN 2017 It is now known how and why plasma gasification is relevant to the world’s population. Another factor that needs to be put into more focus is how it is specifically affecting lives in the present day--2017. The discussion amongst experts and corporate executives from waste to energy companies is important, because it gives a new angle to how plasma gasification can be viewed. This new perspective can range from a scientist’s knowledge on how the process works to a company professional’s knowledge on what is more efficient machinery. Although both perspectives share the same lens of needing the process to be eco-friendly, they simply have a different prescription. 2 Sydney Anderson Victoria Behne proof from experts such as Castaldi that plasma gasification is the best method to convert waste into energy. bottom of the main chamber into the collection pan. The slag itself is not highly leachable therefore will not be washed away with water if it is not stored properly. This is beneficial, because if the slag was able to be washed away, it could lead to water and soil contamination damaging water supplies, crops, and eventually make its way into the air we breathe through water cycle [4]. THE BREAKDOWN OF PLASMA GASIFICATION: HOW THE PROCESS OCCURS Plasma gasification is the process of taking ordinary household waste and heating it in a large, lowoxygen gasifier [4]. The plasma gasifier is comprised of: a waste inlet to deposit the trash, a plasma torch to heat the waste, a main chamber that allows the contained movement of several molecules to encourage collisions between the molecules to induce reactions, air feed piping to allow stable gases into the main chamber for gas molecules to react with the plasma generated by the plasma torch, a collection pan for any resulting solid waste, and a syngas outlet for the clean energy to be released [4]. Water Cycle Detailed The water cycle has the potential to bring chemicals from the ground into the air. This cycle of water is the flow of water molecules through different phases and states of matter [6]. For example water can start in a liquid state, go down a mountain, picking up solvents and chemicals from the soil, collect in a lake, then evaporate into water vapor that will later condense and fall back to earth’s surface as precipitation. During the evaporation process, water molecules have the potential to carry other molecules along with them to the atmosphere. The water molecules can “carry” other molecules due to its high polarity difference between in the oxygen and hydrogen molecules. The distinct difference in charges can attract an opposite charge on a poisonous molecule and thus the poisonous molecule would go along with the water molecule to the atmosphere. This distinct difference is why it is important to have the clean, ecologically safe method of plasma gasification to transform trash into energy. Otherwise, contamination due to toxic emissions like those produced from coal incineration could pollute our drinkable water or the water for animals. Breakdown of Plasma Gasification Continued The other major product of the plasma gasification process is syngas. This gas is comprised of any combination of hydrogen gas, carbon monoxide, carbon dioxide, water vapor, methane, and dihydrogen sulfide. The figure below shows the chemical reactions that occur in the main chamber and the resulting gases. FIGURE 2 [5] A plasma gasification unit. Trash enters the waste inlet in a solid state, and once heated to 6,000 degrees Celsius, the matter breaks down into a plasma state. This plasma state is an ionized gas comprised of equal amounts of positive and negatively charged molecules. While in this fourth state of matter, the plasma is mixed with a variety of stable gases including oxygen and nitrogen [4]. The collisions between the ionized molecules and the stable gas molecules result in the production of syngas and a small amount of slag as byproduct [5]. The slag is in a solid state, and has a higher density than the surrounding gases, and subsequently moves to the 3 Sydney Anderson Victoria Behne turn electricity turbines, the gases go through a simple filtration system to remove some particulate, harmful gases and poisonous elements, but the simple filtration system does not harvest parts of the used gases to produce more energy resources. The filtration system also does not filter out all of the harmful gases, thus allows for the remaining harmful gases such as carbon monoxide to be released into the environment where the carbon monoxide can react with ozone molecules, breaking down the ozone layer of the earth [8]. This breakdown of the ozone layer is what results in the earth trapping more heat and causing global warming which is developing into a very prevalent problem. In addition to the breakdown of the ozone layer, there are other concerns surrounding additional harmful gases in the atmosphere. Earlier in this paper is was discussed the health problems associated with methane and carbon dioxide threatening lives belonging to animals, plants, and humans. In contrast, the cooling process of syngas does what the coal incinerators accomplish and provide other resources for energy. Once the syngas is cooled, it is directed to different specialized chambers that complete a variety of tasks including acid gas removal, gas separation, sulfur recovery, methanol synthesis, methanol to gasoline synthesis and others that generate similarly harmless chemicals [9]. Acid gas removal removes the carbon monoxide and other harmful gases from the syngas and directs those harmful gases to other reaction chambers to break them down into harmless gases [9]. The sulfur recovery is for the dihydrogen sulfide that is produced. This gas is also commonly found in natural gas and can supply as an addition energy source once harvested. Methanol conversion allows for the remaining syngas gas to be turned into a middle step for the following chamber of methanol to gasoline synthesis [9]. Producing gasoline is beneficial because this gives another source of the fuel most commonly used with cars. Not only is plasma gasification decreasing the amount of waste accumulation, but it also results in the production of many different useful chemicals that can then be turned into a variety of synthetic chemicals, steam and electricity. FIGURE 3 [7] Reactions leading to gases that are in syngas. The beginning reactant in most equations is carbon, represented with a ‘C’. The carbon comes the biomass within the trash that is undergoing the plasma gasification process. Other beginning reactants are stable gases that enter the main chamber through the air feed piping as illustrated in Figure 1. Once the reactions are completed, the syngas moves to upper part of the main chamber due to its lighter density that the ionized plasma mass and solid slag. The top of the main chamber has the syngas outlet which is where the syngas exits the reactor and enters a cooling process. When the syngas exits the main chamber, it is above 1000 degrees Celsius [4]. Liquid water is pumped around the tubing that the syngas travels through, out of the reactor. The water takes thermal energy from the syngas, decreasing the temperature of the syngas while also increasing its own temperature. This increase of temperature in water causes the liquid water to turn into water vapor. Because the water vapor is produced in large amounts in order to cool down large amounts of syngas, this steam can be directed to steam turbines that turn to generate electricity [4]. These steam turbines are the same turbines that are used when coal incinerators generate steam to turn turbines. HOW PLASMA GASIFICATION OUSTs COAL INCINERATION Filtration of Gases The process of plasma gasification replaces outdated coal incinerators as an environmentally friendly waste-to-energy source without releasing toxic carbon monoxide gas, while providing more beneficial outputs than coal incineration. Both methods of energy generation are able to create steam for turbines to generate electricity, however each method has a different way of dealing with the left over gases after the steam has been created. The poor filtration that follows the incineration of coal was discussed in the Filtration of Gases section, and For coal incinerators to complete tasks such as generating steam, fossil fuels are burned producing carbon dioxide, carbon monoxide, and water vapor. The combination of these gases exit the coal incineration chamber and turn steam turbines to generate electricity. Electricity is one of only two major uses of the burning of coal. The other major use is heat, however the mass quantities of heat being produced happens through the combustion of the fossil fuels. Once the gases are used to 4 Sydney Anderson Victoria Behne delineated that the practice of energy generation using coal incinerators is outdated. One of the resulting gases in burning fossil fuels such as coal, was carbon monoxide. Coal incinerators are becoming outdated because of the poor filtration system to properly separate harmful gases from what is being released into the environment. the garbage will be reused in an energy generation process that will replace an outdated practice, a practice that does not give as many benefits as plasma gasification. In theory, the process of plasma gasification ensures a future of being able to maintain and continue the world’s extensive use of energy, however there are factors like sustainability and actual production numbers that could make the process of plasma gasification a better in theory than in practice process. The next section takes into account data while comparing plasma gasification to coal incineration with additional supporting explanations as of why plasma gasification is a more favorable, sustainable method of energy production for the future. Carbon monoxide, a poisonous gas, if inhaled, can cause vital parts of the body such as the heart, lungs, and brain, to fail, because carbon monoxide replaces oxygen in the bloodstream, thus depriving the organs of oxygen [10]. In addition to potential asphyxiation, if released into the environment contributes to the greenhouse effect, destroying the ozone layer, and partially causing global warming [11]. ENERGY RELEASE DATA: GASIFICATION VS. INCINERATION One of the sub-issues to the problem is that the waste accumulation solution needs to be ecological. For coal incineration, typically 30% of the emissions must be treated as toxic waste. Conversely, plasma gasification only produces 6% of emissions that is not reusable energy in the form of non-hazardous slag, which can be used as fertilizer [14]. Plasma gasification thus is an ecological replacement for coal incineration looking specifically at the turnout of nontoxic material. Coal incinerators are not only taking away resources from a limited supply, but also not giving back a substantial amount of resources. Plasma gasification goes beyond the actions that coal incineration is used for, and produces natural gas, an additional source of useable energy. Plasma gasification releases, in general cases, roughly 816 kiloWatt per hour per ton of solid waste (kWh/ton MSW) [15] and coal incineration, generally, releases 1,927 kWh/ton [16]. While there is a distinct difference in the amount of energy being produced per ton, plasma gasification may seem more of a cost than a solution. However the source of starting material for each energy generation method have different futures. With expected lifespan until the year 2090, coal incineration sources are not reliable in the long term [12]. Since plasma gasification runs off of material solid waste of already disposed garbage, there is a continuous supply while garbage is being produced. With earth’s population growing, there is no foreseeable shortage of garbage. There are even overflowing landfills that could be a starting main source of garbage for plasma gasification. This abundance of available starting material for plasma gasification allows for the lesser amount of energy output per ton of starting material. This promotes a cycle of use and reuse of materials with the process of plasma gasification, which is another benefit of the process. How companies of today are taking advantage of many benefits of this process will be discussed in the next sub-section. FIGURE 4 A short paragraph on the harmful effects of carbon monoxide. The process of plasma gasification has a multi-step system to separate and handle most, if not all the gases produced in the main chamber of the reactors. In the gas filtration section, there was an explanation of the filtration system following the gasification of the solid waste. This multiple step filtration system was able to pull out the poisonous gases and react those gases with other molecules, making the gases no longer harmful. Other steps included those that turned gases into methanol and later that methanol into gasoline, thus proving that plasma gasification causing the production of more beneficial outputs than coal incineration. The generation of syngas and the detailed filtration steps to handle syngas is a more fruitful energy generation process than coal incineration, because of the variety of resourceful products that are created from syngas. With the average size of a landfill being around 2500 acres, plasma gasification is able to decrease the volume and hopefully decrease the amount of land covered by municipal solid waste (MSW) [13]. While sitting in a landfill, waste releases gases, like previously mentioned carbon dioxide and methane, that contribute to air pollution [13]. By implementing the process of plasma gasification, the amount of stagnant waste producing pollutants will decrease. In addition to removing the mass quantities of waste, the waste is turned into a useable energy source that can complete the same actions as coal incineration in terms of turning turbines to generate electricity. But plasma gasification does not stop there with the products after the turbines. Plasma gasification plants have a cooling and filtration system in place to fully reap the benefits, from the syngas produced. Having less garbage laying around on the earth’s surface will yield less air pollution, more living space, and 5 Sydney Anderson Victoria Behne Advanced Plasma Power Limited (APP) Westinghouse Plasma Corporation Advanced Plasma Power is another leader in plasma gasification. They have innovated their own method of plasma gasification called Gasplasma. Gasplasma is a very similar process to the one described in the earlier sections, the only difference is that this company uses a patented reactor, hence it has a different name. The company also releases syngas just as Westinghouse and Air Products does to generate electricity for gas engines, turbines, or fuel cells. Although, in addition to these uses, APP also produces Plasmarok, an inert (non-reactive) byproduct of plasma gasification that can be used in construction material similar to the slag produced in the general process [20]. This idea of ecologically turning waste into energy reinforces the idea of a cycle of use and reuse that guarantees the demise of trash landfills and garbage loaded oceans. The Westinghouse Plasma Corporation, specifically, uses the plasma gasification process in this facet, and has introduced the process to the United States, United Kingdom, India, and China. Westinghouse uses the clean, reusable energy that is a resulting product of the process to power both homes and energy plants [17]. Westinghouse aims to be the “leading technology platform for converting the world’s waste into clean energy for a healthier planet” [17]. This is of great import, as in the first section of this paper how both waste accumulation itself and coal incineration is a detriment to human health and the atmosphere. Westinghouse tackles both issues by dominating the world with some of the most leading plasma gasification technology to create electricity, ethanol (liquid fuel), steam and syngas for industrial use [17]. This company is efficient on top of being environmentally friendly, as Westinghouse facilities can boast “renewable energy production from post-consumer waste streams that would normally have to be land filled, while [also] providing state-of-the-art emission control of” the toxins [18]. Additionally, at Westinghouse, the entire process of plasma gasification of 1 ton of solid waste, for example, has the capability of creating 1000 kWh of power in comparison to the 500-650kW of power that could be created by coal incineration per ton of waste [17]. Westinghouse does this while also staying far below the gas emissions allowances set by the United States Environmental Protection Agency. For example, the US EPA allows for 205 parts per million (ppmvd) of nitrogen oxide to be released and Westinghouse only releases 36 ppmvd in comparison to 110-205 ppmvd from incineration facilities in the United States [17]. FUTURE APPLICATIONS A solution is not successful unless it is sustainable. It has been noted that currently plasma gasification can solve the issue of waste accumulation in use with companies or even cities such as Portland, Oregon, however plasma gasification cannot be deemed a successful solution unless it can be continually applied for a prolonged period of years, even decades. National Aeronautics and Space Administration (NASA) The issue of waste accumulation is not one that is limited to earth; it also extends to space. NASA is looking to use the process to replace former methods of trash removal during space travel, that require reactors that are borderline too large for the shuttle, as it presently does not support travel further than earth’s orbit [21]. In contrast with Westinghouse, NASA hopes to create smaller scale plasma gasification reactors that are small enough to be kept on a space shuttle. This can not only be used to create alternative fuel sources as mentioned in prior sections, but it can also be expanded to many different settings, not just on a space shuttle. The small scale plasma gasification reactor that NASA is developing, is of interest to the United States military for its potential to be used in “remote locations to save on fuel shipping costs” [21]. Additionally, it could provide remote villages and inhabitants of third world nations the ability to remove their waste and also gain the benefits of another source for fuel and energy. NASA expects to have a model ready for space travel in 2018. Air Products Air Products is another global energy corporation. This company has locations in the United States, Canada, India, Mexico, Colombia, Malaysia, and many others. Air products uses plasma gasification to generate nearly 50 mega-watts (MW) of electricity per plant which is enough to power over 100,000 homes. They also divert over 350,000 tons of non-recyclable waste from landfills annually. Like Westinghouse, this is an improvement upon coal incineration methods, as a MW is 1000 times larger than a kW [19]. Expansion for Westinghouse Plasma Corporation Westinghouse already is an innovator for waste to energy conversion through plasma gasification, but they 6 Sydney Anderson Victoria Behne plan to continue to develop their technology to produce more forms of reusable energy. The company is looking to produce additional biofuels that can power machinery such as automobiles such as fischer-tropsch liquids and propanol in addition to the ethanol that they already produce. Also, Westinghouse is looking to develop plasma gasification for hydrogen separation. Hydrogen separation is a process that purifies hydrogen and leaves nontoxic water as its only byproduct [22]. Hydrogen separation can be used for fuel cells, refinery, and in vehicles. All of which of course are improvements to the more common, nonreusable fuel source for cars--gasoline. If Westinghouse is able to commercialize fuel cells, then the cost of using them for cars could potentially decrease exponentially as the current cost of a fuel cell car is minimum of $50,000 climbing more towards $100,000 due to their limited availability [23]. Considering that about 80% of the world’s energy demands are met by using non-reusable fossil fuels, the prospective future for Westinghouse is not only sustainable, but would continue to improve the world’s energy resources [22]. This fact shows that Westinghouse will continue to use plasma gasification in such a way that satisfies the main problem and two sub-issues of this investigation into plasma gasification. National Center for Biotechnology reports that “pathological lung damage was measured in terms of increases in lung permeability” as a result of the ash and other toxins such as carbon dioxide released into the air as a byproduct of coal incineration [25]. This is a problem because continued exposure over time can cause illnesses such as interstitial lung disease, as it can be caused by coal dust [26]. Illnesses like interstitial lung disease can cause minor problems such as shortness of upon exercising, or more dangerous problems such as respiratory failure which can lead to heart failure due to lack of oxygen in the blood-essentially death in extreme cases [26]. In comparison, plasma gasification does not release any toxins, as was discussed earlier, in fact the process does not even use coal at all! Henceforth, such worries are unnecessary in discussions concerning plasma gasification. The sustainability aspect in this case is the increased longevity of human lives. Coal incineration exposes humans in areas near the plants to dangerous toxins and could lead to preventable illnesses. Whereas, plasma gasification produces energy without affecting the health of humans in nearby areas to the plasma gasification plants (factories). SUSTAINABILITY: A FUTURE WITH PLASMA GASIFICATION A topic that ends evaluation is how jobs will fare with a larger-scale (more than currently used, as mentioned in prior sections) transition to plasma gasification. Executing the plasma gasification process requires people to collect municipal solid waste, transportation of that waste, workers to watch the machinery, and more educated workers to watch the quality of inputs and evaluate output values. By eliminating coal incineration, people that mine, transport, put the coal into the incinerators, and those that oversee the incineration, will lose their jobs. Generally, the start of both processes begins with harvesting and transportation, so a job lost in one portion of the process could easily transfer over to another with little additional training. Looking at the more educated workers, the position in evaluating coal incineration would be similar in positions in plasma gasification, thus having an easy transfer of workers. However, there would be additional education needed to learn how plasma gasification works and what to look for when evaluating outputs. Due to the multi-step filtration system plasma gasification uses, there is the possibility that plasma gasification will require more people than coal incineration, because more individual people would be required to watch over each step in the plasma gasification filtration system to ensure that each step in functioning at maximum potential. Henceforth, the likelihood for job creation outweighs the smaller chance of job loss. Economy: Creation and Loss of Jobs Air Quality: Atmosphere Throughout this paper, the main factor that made plasma gasification more favorable than coal incineration, was that plasma gasification is environmentally friendly. Although, on top of being environmentally friendly by eliminating garbage from landfills, plasma gasification is also able to yield multiple sources of energy that were previously generated by coal incineration, thus plasma gasification is preserving fossil fuels. As was mentioned in an earlier section, the elimination of garbage and the reduction of coal incineration will lead to improved quality of life, because there will be significantly less pollutants, released from solid waste and burning fossil fuels, entering the atmosphere. According to the National Center for Biotechnology, the implementation of coal incineration practices cause global warming, acidification, and toxification to soil [24]. Air Quality: Human Health Previously, how pollution affected air quality in relation to the earth’s atmosphere was discussed. On a smaller scale, pollution from coal incineration has adverse effects on animal and human health as well. Again, the 7 Sydney Anderson Victoria Behne [6] “Summary of the Water Cycle.” UGUS. Accessed 2.27.2017. https://water.usgs.gov/edu/watercyclesummary.htm [7]”Gasification the Waste to Energy Solution.” Naresh Bhatt. Climate CoLab. 2016. Accessed 2.27.2017. https://climatecolab.org/contests/2016/wastemanagement/c/proposal/1329507 [8] “Coal generates 44% of our electricity, and is the single biggest air polluter in the U.S..” Union of Concerned Scientist. Accessed 2.27.2017. http://www.ucsusa.org/clean_energy/coalvswind/c01.html #.WLXcvDvytPY [9] “Syngas Contaminant Removal and Conditioning.” National Energy Technology Laboratory. Accessed 2.27.2017. https://www.netl.doe.gov/research/coal/energysystems/gasification/gasifipedia/cleanupl [10] “Carbon Monoxide Poisoning.” U.S. Department of Labor Occupational Safety and Health Administration. 2002. Accessed 2.9.2017. https://www.osha.gov/OshDoc/data_General_Facts/carbon monoxide-factsheet.pdf [11]“Carbon Monoxide.” Scottish Environment Protection Agency. Accessed 2.9.2017. http://apps.sepa.org.uk/spripa/Pages/SubstanceInformation .as [12] “The End of Fossil Fuels.” Ecotricity. Accessed 2.27.2017. https://www.ecotricity.co.uk/our-green-energy/energyindependence/the-end-of-fossil-fuels [13] “Solid Waste Management.” Florida Department of Environmental protection. Accessed 2.27.2017. http://www.dep.state.fl.us/waste/quick_topics/publications/ shw/recycling/swm_99/chapters/landfill.pdfpx?pid=4 [14] J. Bowyer, K. Fernholz. “Plasma Gasification: An Examination of the Health, Safety, and Environmental Records of Established Facilities.” Dovetail Incorporated. 14.02.2014. Accessed 6.2.2017. http://www.dovetailinc.org/workshop_materials/plasma_g asification_presentation.pdf [15] “Plasma Gasification.” Clean the Air News Blog. 1.13.2015. Accessed 2.27.2017. http://news.cleartheair.org.hk/?cat=63 [16] “Frequently Asked Questions.” US Energy Information Administration. Accessed 2.27.2017. https://www.eia.gov/tools/faqs/faq.cfm?id=667&t=2 [17] “Westinghouse Plasma Gasification is the Next Generation of Energy from Waste Technology.” Westinghouse Plasma Corporation. 5.30.2013. Accessed 1.8.2017. https://www.usea.org/sites/default/files/event/Westinghouse_Walter_Howard.pdf [18] “Summary of Qualifications: Alter NRG Plasma Gasification Solution.”Westinghouse Plasma Corporation. 6.2016. Accessed 3.1.2017. file:///C:/Users/Sydney%20Anderson/Downloads/SoQ_Jun e_2016%20(1).pdf PLASMA GASIFICATION PAST, PRESENT AND FUTURE The initial intent of this investigation into the benefits of the use of plasma gasification as a waste to energy alternative to coal incineration was to discover how and why it is an improvement upon the former. The team proposed that plasma gasification is the better method, and the results of the investigation, as described throughout the paper show that we were correct in our proposal. Plasma gasification has not only proven to be a cleaner method of waste to energy conversion, but is also more efficient and more useful. It was proven to be cleaner as its byproducts are harmless in comparison to coal incineration, which produces multiple toxic gases. Additionally, plasma gasification produces about twice as much kilowatts of energy that can be used for electricity than incineration, as well as producing a myriad of other useful byproducts such as ethanol and steam. Along with the statistical scientific data to support the success of this investigation, there is also the factor that plasma gasification has a sustainable future whereas incineration does not. Not only will gasification reduce the detrimental effects to the earth’s atmosphere and human health that are a result of the use of incineration, but it will also propel many leading companies of the world into an even more environmentally friendly and efficient world of waste to energy conversion that can be applied to daily use or even to aid third world nations. Henceforth, plasma gasification has surpassed its predecessor, coal incineration, and is the best method of waste to energy conversion for the present and the future. SOURCES [1]“Landfill Problems.” We Green USA. Accessed 2.28.2017. http://www.wegreen-usa.org/landfill-problems.html [2] R. Harris. “Dangerous Territory': Carbon Dioxide Levels Reach Milestone.” NPR. 5.10.2013. Accessed 2.28.2017. http://www.npr.org/2013/05/10/182029983/dangerousterritory-carbon-dioxide-levels-reach-iconic-high [3] J. Garber-Simon. “Plasma gasification one option for the Portland region's trash.” 5.4.2015. Accessed 1.8.2017. http://www.oregonmetro.gov/news/plasma-gasificationone-option-portland-regions-trash [4] “Waste to Energy.” Westinghouse. 2017. Accessed 1.8.2017. http://westinghouse.com/story-waste-to-energy/ [5] “Plasma Gasification.” National Energy Technology Laboratory. Accessed 1.8.2017. https://www.netl.doe.gov/research/Coal/energysystems/gasification/gasifipedia/westinghouse 8 Sydney Anderson Victoria Behne [19] “Tees Valley Renewable Energy Facilities.” Air Products. Accessed 2.28.2017. http://www.airproducts.co.uk/microsite/uk/teesvalley/techn ology.htm [20] “About Us.” Advanced Plasma Power. 2017. Accessed 2.28.2017. http://advancedplasmapower.com/about-us/our-company/ [21] S. Siceloff. “Reactor Makes Trash a Power Source.” NASA. 12.3.2012. Accessed 1.7.2017. https://www.nasa.gov/centers/kennedy/about/sustainability /trashtogas.html [22] S. Adhikari, S. Fernando. “Hydrogen Membrane Separation Techniques.”American Chemical Society Publications. 1.7.2006. Accessed 2.28.2017. http://pubs.acs.org/doi/abs/10.1021/ie050644l [23]K. Bullis. “How Toyota Will Be First With a Fuel-Cell Car.” MIT Technology Review. 11.15.2015. Accessed 2.28.2017 https://www.technologyreview.com/s/521616/how-toyotawill-be-first-with-a-fuel-cell-car/ [24] Zhao Y, Xing W, Lu W, Zhang X, Christensen TH. “Environmental impact assessment of the incineration of municipal solid waste with auxiliary coal in China.” PebMed. 06.08.2012. Accessed 03.39.2017. https://www.ncbi.nlm.nih.gov/pubmed/22683228 [25] Fernandez A, Wendt JO, Wolski, Hein KR, Wang S, Witten ML. “Inhalation Health Effects of Fine Particles from the Co-Combustion of Coal and Refuse Derived Fuel.” PubMed. 06.2003. Accessed 03.29.2017. https://www.ncbi.nlm.nih.gov/pubmed/12718979 [26] Mayo Clinic Staff. “Interstitial Lung Disease.” Mayo Clinic. 06.11.2017. Accessed 03.29.2017. http://www.mayoclinic.org/diseases-conditions/interstitiallung-disease/basics/causes/con-20024481 ACKNOWLEDGEMENTS Kal Bhojak, business analyst for Alter NRG Corp, for responding and providing information when we contacted Westinghouse. Mark Jeffrey, our conference chair, for providing insightful guidance for the direction of the final paper. Iman Basha, our conference co-chair, for providing feedback on the flow and progression of abstract to final paper. ADDITIONAL SOURCES “Emerging Waste-to-Energy Technologies: Solid Waste Solution or Dead End?” EHP. 6.2016. Accessed 1.8.2017. https://ehp.niehs.nih.gov/124-a106/ “Gasification vs. Incineration.” Gasification and Syngas Technologies Council. Accessed 6.2.2017. http://www.gasificationsyngas.org/applications/gasification-vs-incineration/ M. Gerber, C. Valkenburg, C. Walton et. al. “Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 1: Availability of Feedstock and Technology.” 12. 2008. Accessed 1.8.2017. http://www.pnl.gov/main/publications/external/technical_r eports/PNNL-18144.pdf T. Onabanjo. Et. al. “Energy recovery from human faeces via gasification: A thermodynamic equilibrium modelling approach.” NCBI. 7.15.2016. Accessed 1.8.2017. https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4892428/ 9
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