The Mechanisms of Formation of W e l d Defects in High-Frequency Electric Resistance W e l d i n g The two kinds of defects associated with previously defined welding phenomena are cold welds comprised of oxide colonies and penetrators consisting of slag inclusions produced when molten slag is drawn into a gapped zone BY H. HAGA, K. AOKI A N D T. SATO ABSTRACT. In order to clarify the mechanisms by which weld defects are formed, welding phenomena were observed using high speed cameras, and weld defects produced in relation to corresponding phenomena were examined. It is found that the possible occurrence of certain kinds of weld defects is determined by the types of phenomena encountered during welding: A possible weld defect accompanied by the 1st type phenomenon is a cold weld; a penetrator is accompanied by 2nd and 3rd types of phenomena. The cold weld is composed of a colony of oxides which are formed on the edge surfaces and remain because they are not squeezed out from between them. The penetrator by nature is a slag inclusion produced when molten slag is drawn into a gapped zone by the action of surface tension and capillary effects in a returning process of the molten bead. Introduction Weld defects of ERW are perpendicular to the plate surface and have planar shapes caused by upsetting in a process of welding. It is reported that these defects have occasionally caused a burst accident in field tests of ERW pipelines. Because of their shape and orientation, it is very hard to find them w i t h NDT, and many efforts have been made to develop an effective NDT method for locating such defects. Very few investigations, however, 104-s I JUNE 1981 Table 1—Chemical Composition of the Materials Used, Wt-% C 0.11 Si Mn Nb 0.25 0.70 0.013 P S AI 0.01 0.01 0.015 have been reported in regard to the cause of the weld defects in ERW; the defects have been simply conceived as certain oxides that form on the surface of strip edges and remain without being squeezed out between them. Macro- and microscopic observations of the weld defects showed that there are t w o kinds of the defects: a cold w e l d and a penetrator. In most cases the former is found over a wide range along the weld line and the latter only intermittently. It is difficult to understand by the past simple explanation why t w o different kinds of defect are generated. The welding phenomena encountered in ERW, as mentioned in a previous report, 1 can be classified into three types according to the periodicity of the welding process and the edge profile between the V-convergency Paper presented at the AWS 60th Meeting held in Detroit, Michigan, April 2-6, 1979. H. HAGA, K. AOKI and ciated with the Products opment Laboratories of Corporation, Sagamihara Annual during T. SATO are assoResearch & Develthe Nippon Steel Kanagawa, lapan. point and the weld point. It is inferred that the type of welding phenomena might determine which kind of the defects will be generated. Experimental results given below show that the inference is almost true. Moreover, observations through high speed photography help identify a phenomenon accompanying the formation of a penetrator. This gives a definite base for correlating the kind of defects to the type of welding phenomena. Experimental Procedure Materials Materials welded in previous work 1 were examined. Chemical compositions of the materials are given in Table 1. Identification of Actual Weld with Photographed One In order to find welding processes accompanying weld defects, it is essential to find how each point along the weld was joined. Each external bead on the weld was identified w i t h the one observed in the high speed photograph as shown in Fig. 7. This method gave an accuracy w i t h i n 1 mm (0.04 in.) to the corresponding position. Examination of Weld Defects Welded pipes were cut into semicylindrical shells and flattened. From the flattened shell dynamic tear (DT) test pieces were prepared. External (a) t e s t 17 (b> t e s t 15 r :c) test 1 1'0 A 2'0 ' 3'0 4>0 ' 5'0 Fig. 1-DT fracture surfaces of the weld representative are contoured beads o n t h e test p i e c e s w e r e p h o t o graphed together w i t h measurements before they were removed. Charpy i m p a c t test p i e c e s w e r e also p r e p a r e d . T h e D T test p i e c e s w e r e s u b j e c t e d t o brittle fracture and Charpy testing. W e l d defects were examined on f r a c t u r e surfaces o f D T a n d C h a r p y test p i e c e s by m i c r o s c o p e a n d s c a n n i n g e l e c t r o n m i c r o s c o p e ( S E M ) , a n d classified according to their m o r p h o l o g y . Figure 1 s h o w s D T f r a c t u r e surfaces of t h e w e l d r e p r e s e n t a t i v e o f t h e 1st, 2nd and 3rd types of w e l d i n g p h e n o m e n a . W e l d d e f e c t s are c o n t o u r e d in t h e p h o t o g r a p h s . E l o n g a t e d b l a c k parts o b s e r v e d near edges o f t h e f r a c t u r e surface are cracks f o r m e d o n e x t e r n a l or internal bead, and not weld defects. In t h e case o f t h e 1st t y p e p h e n o m e n o n , no w e l d defect was observed o n a b r i t t l e f r a c t u r e surface as s h o w n in Fig. 1(a). Large w e l d d e f e c t s , h o w e v e r , are r e v e a l e d o n a d u c t i l e f r a c t u r e surf a c e of t h e C h a r p y test p i e c e p r e p a r e d as s h o w n i n Fig. 2 ( a ) . T h e w e l d d e f e c t o f Fig. 2(a) is c o n s i d e r e d t o b e l o n g t o a cold weld. T h e w e l d d e f e c t s o f Figs. 1 ( b ) , 1 ( c ) , 2 ( b ) a n d 2 ( c ) are c o n s i d e r e d t o b e l o n g to a penetrator. The penetrators were q u i t e s i m i l a r in a p p e a r a n c e b o t h o n the brittle fracture surface and o n t h e ductile one. T h e results o f e x a m i n a t i o n o f w e l d d e f e c t s are s u m m a r i z e d in T a b l e 2. In this e x p e r i m e n t t h e 1st t y p e p h e n o m e n o n always a c c o m p a n i e d a c o l d w e l d w h i c h is f o u n d o v e r a w i d e range along the w e l d line. The c o l d w e l d £fc mm 7'0 &Q A .8?0 ' POO weld defects ? jr.-:?--L • • VA A.A-A^.-AA (a) Results Correlation between the Kind of Weld Defects and the Type of W e l d i n g Phenomena ' of (a) the 1st, (b) the 2nd and (c) the 3rd type phenomena; (b) (c) Fig. 2—Charpy fracture surfaces of the weld representative ot (a) the 1st, (b) the 2nd and (c) the 3rd type phenomena; weld defects are contoured. Test pieces were prepared from the same tests as those in Fig. 7 h a p p e n e d t o b e a c c o m p a n i e d also b y the 2nd type p h e n o m e n o n . Penetrators w e r e a c c o m p a n i e d by 2 n d and 3rd t y p e p h e n o m e n a and never by t h e 1st t y p e . P e n e t r a t o r s w e r e d i s t r i b u t e d n o t u n i f o r m l y , b u t in f r a g ments along the w e l d line. A penetrat o r g e n e r a l l y e x t e n d s in t h e t h r o u g h thickness direction. In t h e 2 n d t y p e p h e n o m e n o n , t h e l e n g t h o f m o s t p e n e t r a t o r s is less t h a n 2 m m (0.08 in.) a n d t h e i r f r e q u e n c y is g e n e r a l l y l o w . In t h e 3 r d t y p e p h e n o m e n o n , p e n e t r a t o r s of v a r i o u s sizes w e r e f o u n d . In tests 1 , 2, 4 a n d 5, in w h i c h the gapped zone had developed long e n o u g h , large p e n e t r a t o r s t h a t w e r e l o n g e r t h a n 5 m m (0.20 in.) w e r e o f t e n f o u n d . The frequency of the penetrat o r is h i g h e r i n t h e 3 r d t y p e t h a n in t h e 2nd type. Fractographic Observation of Weld Defects Weld defects assume different shapes, m i c r o s c o p i c a l l y as w e l l as macroscopically, according to the type of w e l d i n g phenomena. Figure 3 shows a SEM image of cold w e l d on a Table 2—Results of the Examination of the Type and Frequency of Weld Defects Defect Frequency, %* Cold w e l d 10 :£ F 1 S F < 10 F< 1 Penetrator 5 < F < 10 1 S F< 5 F< 1 Test 11,17 14 15 1,2,3,4,5,6 7,9,10,13,16 8,12,15 *Percentage of w e l d defect area to total w e l d area. WELDING RESEARCH SUPPLEMENT 1105-s SEM Mn Fe . •;-y:?yyy?y:: V .'AAA:: ifs m 0. t A o > UJ a o < UJ 50 M t/s UJ cn -*-',.„ iSM , Si 0 Al Fig. 3—SEM and characteristic X-ray images ol cold weld on a tracture surface fracture surface. The cold weld consists of a colony of numerous microdimples, arranged on a flat plane, most of them being less than 1/j in diameter. Inclusions are found in most microdimples. XMA results show that comparatively large inclusions are rich in M n and Si, but most of them are too small to analyze by XMA. Micro-inclusions in the cold weld are found on the cross section of the weld as shown in Fig. 4. Their size is extremely small compared with the diameter of the grains that have grown across the weld. In this case a cleavage fracture is expected to propagate legardless of the presence of cold weld. A ductile fracture, on the other hand, propagates by creating a dimple around an inclusion; consequently, it is considered that ductile fracture can better reveal the cold weld. Figure 5(a) shows a SEM image of the penetrator generally accompanied by the 2nd type phenomenon. D i m ples and inclusions associated with it are much larger than those associated with cold weld. Brittle fracture is thought to propagate the tearing off of inclusions from the base metal. XMA results show that the inclusions are 106-sl JUNE 1981 richer in M n , Si, Al and O and poorer in Fe than is the base metal. Figures 5(b) and (c) show other types of the penetrator. They are accompanied ordinarily by the 3rd type phenomenon and occasionally by the 2nd type. Inclusions associated w i t h these penetrators are larger than those found in Fig. 5(a). XMA results show that the inclusions are also richer in M n , Si, Al and O, and poorer in Fe, than the base metal. ••'UAJ-' A,v-' J ^ A weld Fig. 4—Optical micrograph oi cross section of the cold weld region In the 2nd and the 3rd type phenomena, which did not accompany the cold weld, such extrusions were not observed between the V-convergency point and the weld point. The extrusions disappeared when molten beads were produced before both the edges met. It is considered that the extrusions consist mostly of oxides. The reason for this is that it should not be possible to form such extrusions against strong electromagnetic pressure if the extrusions consist of metal. Thus, the cold weld is a colony of oxides formed on the edge surfaces that remain because they were not squeezed out from between them; this has been conceived to be a mechanism of producing all weld defects in ERW.2-3 If a sufficient amount of molten metal is removed from the edge surfaces by the electromagnetic pressure, oxides formed on the surfaces are also removed and a cold weld will not be produced. But such a condition leads to the 2nd or the 3rd type phenomenon in this experiment.* Penetrators M e c h a n i s m of Formation of W e l d Defects Cold Weld A cold weld occurs uniformly over a wide range along the weld line, and any accidental phenomena are not considered to account for the cold weld. Figure 6 shows the phenomenon (of the 1st type) which accompanied the cold weld. A number of extrusions are observed to be formed on both the edge surfaces approaching to the Vconvergency point. These extrusions were sandwiched between the edges when they were welded. A penetrator is accompanied by 2nd and 3rd type phenomena. Particularly with the 3rd type, a large amount of molten metal is removed, so a penetrator is not considered an oxide residual but a defect different from the cold *According to the theory given in the 1st report, the 1st type phenomenon can be realized depending on the welding rate and V-apex angle even if sufficient molten metal is removed. Therefore, the 1st type phenomenon is not always considered to accompany a cold weld. Inversely, the 2nd type phenomenon will accompany the cold weld ii sufficient molten metal is not removed. SEM Fe Mn Si Al z UJ Q. o > m& UJ o I o a: < LJ Fig. 5-SEM and characteristic X-ray images of penetrator accompanied by (a) the 2nd and (b), (c) the 3rd type phenome weld; the cause producing the penetrator must be found in a certain process peculiar to the 2nd and 3rd types. In the 3rd type phenomenon, a gapped zone develops, removing molten metal out of the gap. The removed molten metal takes the shape of a raindrop resulting from a balance between electromagnetic force and surface tension of molten metal. When both the edges contact at the V-convergency point in stage 3 mentioned previously, 1 all of the welding current flows through the contacted V-convergency point. Naturally, the electromagnetic force suddenly vanishes in the gapped zone. Only the surface tension acts on the molten bead, and the balance of force is lost. The molten bead then is expected to begin to return to the gapped zone by the action of surface tension. High speed photography revealed that the molten bead in fact returns and fills the gapped zone as shown typically in Fig. 7. Furthermore, it was made clear that the penetrator is produced in such a zone as that filled by the molten beads. In the 3rd type phenomenon, molten beads fill most of the weld. Only a small part of the weld is filled by a molten metal bridge produced at the V-convergency point in stage 3.1 In the 2nd type of phenomenon, molten metal bridges fill most of the weld. But occasionally the returning of molten beads also occurs. A penetrator was found in such a place. In the 1st type phenomenon molten beads cannot return, because the w e l d point coincides with the V-convergency point and the electromagnetic force does not vanish until both the edges are welded; this is the reason why 1st type phenomena are not accompanied by a penetrator. Although a penetrator may be found in the weld filled with molten metal, observation showed that the reverse is not true—that is, the filling of the gap does not always accompany a penetrator. Some accidental process accompanied by the filling process is considered to be the cause of producing the penetrator. Surface Tension Acting on Molten Bead There remains a question to be answered: Is it not surface tension but gravity that forces the molten bead to return to the gapped zone? Gravity, however, is not considered to take any part in the returning process. This is Fig. 6-Phenomenon accompanying cold weld W E L D I N G RESEARCH S U P P L E M E N T 1107-s time (msec) I- zUJ s Q. o —1 UJ 0 2 > UJ Q X ce 1 < UJ </> Ui cc 10 12 Fig. 7—High speed photographs of molten bead action: (a) returning process of molten beads observed in test 1, showing: V-the V-convergency point, M-the molten metal bridge and R-returning bead; A and B of (a) correspond to the A and B of (b), external beads of DT test piece, and to those of (c), DT fracture surface, in which the penetrators are contoured 14 (a) because the process finishes within 10 msec at most, and the gravity-induced falling distance during that time is 0.5 mm (0.02 in.), which is much smaller than the plate thickness. It is possible to estimate the time necessary to fill the gapped zone by capillary effect, if viscosity and internal pressure of the molten bead can be neglected. Let the surface tension be denoted by y and the angle of contact be 0 deg; then the force (per unit length) which draws molten metal is 2y. The equation of motion for the filling process is expressed as follows: Molten bead 2y dt (pbss) 2y • pb (D where p is the density of molten metal, b the w i d t h of the gapped zone and s the height (or the depth) of drawn molten metal, as illustrated in Fig. 8. Equation (1) reduces to: 1 d2 2Y = - P b - ( S 2 ) (2) Solving equation (2) under the initial condition s = S and s = 0 at t = 0, let S approach to 0. Then the solution is given by: The values of v and p are respectively about 1500 d y n / c m and 7.3 g / c m 3 for molten steel. W h e n b is 0.2 mm.: s(mm) = 1.4t(msec) This calculation shows that molten metal fills the gapped zone throughthickness w i t h i n few milliseconds. As is evident from the above, internal as well as external molten beads should be able to return and fill the gapped zone. In fact, occasionally it is possible to observe the trace of return- Table 3—Chemical Compositi on of Penetrator Analyzed by XMA Penetrator, wt-% Base Metal Test -Edge s u r f a c e 15 1 1 3 3 Yokoyama, et a/.4 Fig. 8—Cross-sectional view of the returning process of molten bead 108-s I JUNE 1981 t Mn Si 0.7 0.25 1.4 1.5 1.1 0.17 0.41 0.06 MnO SiO, FeO ALO, 46 44 44 41 42 43 41 42 40 40 7 4 5 5 4 4 3 3 4 3 55 51 82 33 41 3 6 4 13 6 4 2 SIO, Fig. 9—End portion of weld showing the trace of returning of internal bead Fig. 10 (right)—Ternary equilibrium system FeO-MnO-Si02 ing of the internal bead as shown in Fig. 9. Metallurgical Considerations in Penetrator Formation The molten bead contains the oxide removed from the edge surface. New oxide is further produced on the surface of the molten bead exposed to the air. At the interface between the oxide layer and the molten bead, the following reactions should occur: (FeO) + [ M n ] ^ ± [Fe] + ( M n O ) 2(FeO) + [Si] ^ ± 2[Fe] + (Si0 2 ) where [ ] is the concentration in the molten iron and ( ) the free oxide content of the slag. A part of M n O , Si0 2 and FeO is free or forms silicate, and exists as a liquid phase. The rest exist as a solid phase. The proportion of free oxides depends on the solubility of the oxides. In order to examine w h i c h phase of slag becomes a penetrator, the chemical composition of the penetrator is analyzed quantitatively by XMA. Results of the present analysis are given in Table 3 together w i t h results of available past analyses.4 In this experiment, the contents of M n O , S i 0 2 and FeO in penetrators are 35 ~ 50%, 35 ~ 50% and 3 ~ 10%, respectively, regardless of the type of welding phenomena. A ternary phase diagram (Fig. 10) shows this component of M n O Si0 2 -FeO exists as a liquid phase at 1500°C (2732°F). Other results also show that most of the penetrators exist as a liquid phase at 1500°C (2732°F). The temperature of the molten bead cannot exceed the melting point of FeO MnO steel too far; this is because most of welding current flows along the edge surfaces due to a high frequencyinduced proximity effect. Therefore, it is considered that a part of the molten slag on the molten bead changes into a penetrator. The molten slag covers the surface of the molten bead, because the density of the former is about half that of the latter. It is concluded that the penetrators are produced when molten slag is drawn into the gapped zone in the returning process of the molten bead. convergency point and the electromagnetic force vanishes in the gapped zone. 5. It is the surface tension and the resultant capillary effect that force the molten beads to return into the gapped zone. The internal bead as well as the external one is able to return. 6. The penetrator by nature is a slag inclusion that is produced when molten slag is drawn into the gapped zone in the returning process of the molten beads. Ac/cnow/ec/gmen( Conclusions 1. There are two kinds of weld defects in ERW: the cold weld and the penetrator. 2. The type of welding phenomena determine which kinds of weld defects are produced. A possible weld defect accompanied by the 1st type phenomenon is the cold weld. The 2nd type phenomena accompanies a small penetrator, or the cold weld if sufficient molten metal is not removed from the edge surfaces. The 3rd type phenomenon frequently accompanies the penetrator. 3. The cold weld is composed of a colony of oxides which are formed on the edge surfaces and remain because they are not squeezed out from between them. 4. In 2nd and 3rd type phenomena, molten beads, which have been removed from the edge surfaces, return and fill the gapped zone when both the edges contact at the V- The authors wish to express their appreciation to Dr. T. Ikeno, the director, and Dr. S. Kanazawa, the deputy director of the laboratories, for their proposal of these successive studies, and to Mr. H. Imai, Dr. H. Mimura and Mr. M. lino for their helpful discussions. The contributions of Mr. K. Sakurai and Mr. M. Yamada are also appreciated. References 1. Haga, H., Aoki, K„ and Sato, T. 1980. Welding phenomena and welding mechanisms in high-frequency electric resistance welding—1st report. Welding lournal 59(7): pp. 208-s to 212-s. 2. Martin, D.C. High-frequency resistance welding. Welding Research Council Bulletin 160. 3. Hasebe, S., Kyogoku, T., Takahashi, S., Yamura, T. and Okazawa, T. 1972. Development of ERW high-test line pipe for arctic service. Sumitomo Metals 24(2): pp. 67-90. 4. Yokoyama, E., Yamagata, M., Kanou, T. and Watanabe, S. 1977. ). Iron & Steel Inst. lapan 63(11): p. S650. WELDING RESEARCH SUPPLEMENT 1109-s O tx < Ul CO Ul cc
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