Past Climate Change and the Ice Ages What we wish to learn Today: 1. What do we mean by "paleoclimate"? 2. What evidence exists for ice ages and ancient climate change? 3. What causes the climate to change? “Recent” climate change and variability… N.H. Temperature (°C) 2 1 0 -1 1000 1200 Mann et al. (1999) GRL 26:759-762 1400 1600 1800 Year 2000 …provides perspective on where we are headed 6 Global Temperature (°C) 4 5 3 N.H. Temperature (°C) 2 1 1 0.5 0 -0.5 1000 1200 1400 1600 1800 2000 0 IPCC Projections to 2100 We KNOW the climate has changed recently 1856 1987 2000 The great Aletsch glacier, Switzerland 1970 2000 Area (km2) Ice on Mt. Kilimanjaro 15 10 5 0 1900 1920 1940 1960 1980 2000 2020 Year L.Thompson, in prep. Glacial Changes since last Ice Age Ice and Trees Percent of Spruce in Total Trees Glacial Europe was treeless in the last ice age Vegetation in present day Europe is dominated by forest, with conifers in the north and deciduous trees in the south. At the glacial maximum, 20 thousand years ago, arctic tundra covered much of Europe south of the ice sheet, and only patches of forests remained near the southern coasts. PreCambrian Paleozoic Mesozoic Cenozoic Ancient Climates • Climate was warm during the Age of the Dinosaurs (the Mesozoic) – Alligators lived in Siberia! – Dinosaurs lived north of the Arctic Circle in Alaska! Methods to establish past climate • Isotopic Geochemical Studies: the study of rock isotopic ratios, ice core bubbles, etc. • Dendochronology: the study of tree rings • Pollen Distribution: the study of plant types and prevalence (e.g., Europe’s vegetation in the last ice age) • Lake Varves: (like dendochronology, but with lake • Coral Bed Rings: (like dendochronology, but with corals) • Fossils: Studies of geological settings, etc. • Historical documents: paintings of glaciers, etc. sediments) Oxygen isotopes and paleoclimate • Oxygen has three stable isotopes: 16O, 17O, and (We only care about • 18O 16O and 18O. 18O) is heavier than 16O (it has 2 extra neutrons). • The amount of 18O compared to 16O is expressed using “delta” notation - the unit is “per mil” (parts per thousand): d18O ‰ = 18O/16O of sample - 18O/16O of standard 1000 18O/16O of standard Fractionation: Natural processes tend to preferentially take up the lighter isotope, and preferentially leave behind the heavier isotope. For most chemistry, the isotopes behave the same. Isotope “fractionation” • Oxygen isotopes are fractionated during evaporation and precipitation of H2O – H216O evaporates more readily than H218O – H218O precipitates more readily than H216O • Oxygen isotopes are also fractionated by marine organisms that secrete CaCO3 shells. The organisms preferentially take up more 16O as temperature increases. Fractionation effects (1) Sea water is heavier than water vapor Precipitation favors H218O (2) cloud water becomes more depleted in H218O as it moves inland or poleward… 16O 18O16O 18O Evaporation favors H216O 18O 16O H218O 18O H218O 16O 16O 16 16O 18O O H216O, 18O 18O H218O 18O 16O 18O 18O 18O 16 O 18O Ocean Ice Land (3) Snow and ice are depleted in H218O relative to sea water. Fractionation effects δ18O = -15 o/oo δ18O = -10 o/oo -11 = 0 o/oo CaCO3 rain o/oo rain -6 δ18O δ18O = -20 o/oo Ocean o/oo Ice Land Carbonate sediments also record the signal of the ocean, and the signal of temperature We can also show that the d18O of precipitation is well correlated with temperature! So, if we know the d18O of water or ice, we know what the air temperature was at that time. (Note that hydrogen isotopes work the same way) Vostok Record The Antarctic Ice Coring operation at Vostok station The Greenland Ice Coring operation at Summit station Ice Core Analyses The ice can be analyzed for its 18O content to estimate temperature The air bubbles trapped in the ice can be analyzed for their carbon dioxide and methane content Ocean Sediment analysis Isotopes of organisms deep-sea foraminifera Growing glaciers Interglacial Ice δ18O = - 30 The “Ice Volume” effect δ18O = 0.0 • Light isotope removed from ocean, locked into large ice sheets Glacial Ice δ18O δ18O = 1.5 = - 35 • Remaining ocean water was +1.5‰ heavier in 18O, as recorded in marine organism shells (CaCO3) • Ocean level was ~120 m lower than today Possible Causes of Climate Change Long-Term 1. Solar Luminosity 2. Shifting Continents 3. Greenhouse gases Medium-Term 1. Orbital parameters 2. Greenhouse gases Short-Term 1. Greenhouse gases 2. Sunspots 3. Ocean currents Power: 4 x 1026 W 2 x 1017 W Evolution of our Sun‘s Luminosity 1.6 Today 1.4 Luminosity . 1.2 1 0.8 0.6 Snowball Earth ? 0 2 4 6 8 Time (billions of years) 10 Shifting land masses (by plate tectonics) may have changed greenhouse gas concentrations, thus affecting climate Today’s configuration Past configurations As the continents shift there is increased subduction and volcanic activity which increases CO2 into the atmosphere That atmospheric CO2 is then consumed in weathering reactions on continents, and eventually returned to the ocean. This is the long-term “weathering” control of climate. Silicate weathering From C. Poulsen’s lecture, 24 Sep ① CO2 + H2O H2CO3 (carbonic acid) ② CaSiO3 + 2H2CO3 Ca2+ + 2HCO3- + SiO2 + H2O (silicate weathering) ③ Ca2+ + 2HCO3- CaCO3 + H2CO3 (carbonate precipitation & burial) Net: CaSiO3 + CO2 CaCO3 + SiO2 Conversion of CO2 gas to limestone! CO2 CO2 H2CO3 Ca2 Ca3SiO3 H2CO3 Ca2 Ca3SiO3 Orbital forcing (Milankovitch) 1879-1958 1. Shape (eccentricity, ~100K and 400K yrs) 2. Tilt (obliquity, ~41,000 yrs = 41K yrs) 3. Wobble (precession, ~23K yrs) Interaction of orbital periods give different patterns of change. The magnitude of shifts in solar insolation are large enough to explain changes in climate Milankovitch Forcing Explains Ice Core Data ~ 23ky 0 -10 Tilt 41ky -20 1000s of years Before Present ( kyr B.P. ) d18O in Chinese caves and insolation Orbital forcing GISP2 Ice Core 1000s of years Before Present ( kyr B.P. ) D. Yuan et al., Science 304, 575 What causes rapid and unpredictable changes in climate? Antarctica -5 order chaos -10 chaos order -5 -10 -15 -20 1000s of years Before Present ( kyr B.P. ) Greenland Causes of Climate change A. Tectonic B. Orbital C. ?? D. ?? Summary 1. Past changes in climate have been dramatic on Earth 2. The longest-term changes (100s Million years, Ma) are driven by shifting continents and interactions with greenhouse gases. 3. At medium time scales (1-10s Ma), changes are triggered by variations in orbital characteristics. Take-home point: “If you don’t like the climate, hang around awhile…”
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