Chemistry Unit Notes Almost everything you can think of is “matter” -- meaning it’s made of something that has a mass and volume that can be measured. Fire and light are not matter, they’re energy. All matter is made of atoms of elements. Elements are pure substances that are made of only one kind of atom. Atoms have 2 basic regions: the nucleus and the electron cloud. The nucleus is made up of protons and neutrons while electrons constantly orbit around the nucleus in different energy levels of the electron cloud. Subatomic particles: A proton carries a positive charge. A neutron carries no charge. An electron carries a negative charge. A proton and a neutron have about the same mass (1 amu) but an electron’s mass is so small that it contributes very little to the overall mass of the atom. Therefore, we generalize and say that the mass of the atom is in its nucleus. Every proton in the world is exactly like every other proton; every neutron is exactly like every other neutron; every electron is exactly like every other electron. What makes the elements different is not the KIND of particles that make them up but the NUMBER of them. An element is identified by the number of protons its atoms contain, and they are arranged in order on the Periodic Table of Elements: There is a lot of information about an atom located on the period table: The atomic number is also the number of protons. Since we’re dealing with neutral atoms (with no charge), the number of protons and electrons will be equal. The atomic mass is the mass of the nucleus which contains both protons and neutrons (each with a mass of 1.0) so to calculate the number of neutrons you simply subtract the atomic number from the atomic mass. Example: Atomic number: 5 Atomic mass (rounded): 11 Number of protons: 5 (the same as the atomic number) Number of electrons: 5 (the same as the number of protons) Number of neutrons: 6 (the atomic mass minus the atomic number) So one atom of Boron looks like this: Elements are identified based on the number of protons…..every atom of boron has 5 protons. If it didn’t, it wouldn’t be boron. The number of neutrons, however, can vary, and this does not affect the identity of the element but it does affect its mass. Perhaps some boron atoms contain 4 neutrons, some 5, some 6, some 8. Different atoms of the same element but with different numbers of neutrons are called isotopes. Because the number of neutrons can vary, the atomic mass on the periodic table is an average mass. While the protons and neutrons are located together in the nucleus, the electrons orbit the nucleus in specific energy levels or “shells.” Only 2 electrons can be in the first level, up to 8 electrons can be in the second and third level. Some elements are more reactive than others, meaning they combine with other elements easily to form new substances. This is mostly due to the number of electrons in the outermost shell of the atom. The elements are also arranged in the Periodic Table so that the left side is almost completely metals, the few on the right are non-metals, and those along the diagonal line from Boron are metalloids. Properties of Metals They tend to be shiny They are ductile: they can be stretch and pulled into thin wires They are malleable: they can be pounded into thin sheets They’re usually good conductors: heat and energy can easily flow through them They tend to react with oxygen and water to corrode (break down) [Rust is how iron corrodes; the green color of the Statue of Liberty is due to the corrosion of copper] Properties of Nonmetals They are dull They are brittle (break easily) The are insulators (heat and energy do not flow easily through them) Metalloids have varying properties, sometimes like a metal and sometimes like a non-metal. REALLY, REALLY SIMPLIFIED CHEMISTRY Each element has its own characteristics. If you simply mix two elements together, they will usually keep their own characteristics. In order for a new substance to form, a chemical reaction has to take place where the atoms are actually bonded together. For example, sodium is a soft, shiny metal that will sizzle and flame in water. Chlorine is a green, poisonous gas. If you simply put some sodium (Na) in a bottle of chlorine (Cl), you will still have a soft, shiny metal in some green, poisonous gas. However, if you chemically combine them in a chemical reaction, they will form NaCl (table salt) which is white, solid, not explosive in water, and necessary for your survival. When two or more atoms combine, they make a molecule. Molecules are shown with a chemical formula. If the atoms of the molecule are different, they form a compound. Example: When two oxygen atoms combine, they make oxygen gas, a molecule. Chemical formula: O2 When three oxygen atoms combine, they make ozone, a molecule. Chemical formula: O3 If two oxygen atoms combine with one carbon atom, they make a molecule of carbon dioxide, which is also a compound because the atoms are different. CO2 Subscripts are small numbers written below and after an element to tell us how many atoms of that element are present in the molecule. Example: There are two hydrogen atoms and one oxygen atom in a molecule of water, so the “2” goes after the hydrogen. When only one atom is present, no number is written. H2O The difference between carbon monoxide (CO) and carbon dioxide (CO2) is the number of oxygen atoms in the molecule. And this makes a completely different compound with very different properties. carbon monoxide carbon dioxide = hydrogen peroxide H2O2 (very different from water) There are seven elements that exist as diatomic molecules, meaning two atoms are bonded together: H2, Br2, I2, N2, O2, Cl2, F2 When you have more than one molecule, a coefficient (large number) is placed in front of the entire molecule. For example, three molecules of water would be written: 3 H2O In 3 molecules of water, there are 6 hydrogen atoms and 3 oxygen atoms. New substances are formed in a chemical reaction and it is shown by writing a chemical equation. In a chemical equation, the reactants are located on the left of the arrow and the products are located on the right of the arrow. During a chemical reaction, bonds are broken between existing molecules and the atoms are rearranged to form new substances. For example, hydrogen and oxygen can combine to form water. But it is important to realize that in order to make a new product you can only use the atoms you start with in the reactants. Hydrogen and oxygen are both diatomic elements so they can only be written as H2 and O2. But if we complete the reaction correctly using the same amount of atoms on both sides, we don’t end up with water as the product. (Hydrogen peroxide is a different product.) H2 + O2 H2O2 To make water with the correct ratio of two hydrogen atoms to every one oxygen atom, we would have to balance the chemical equation so that the same number of each atom is on both sides of the arrow. 2 H2 4 hydrogen atoms + O2 2 oxygen atoms 2 H2O 4 hydrogen atoms 2 oxygen atoms The Law of Conservation of Mass states that the atoms that go into a reaction must be the same as those that come out, even if they are rearranged differently. You cannot create atoms or destroy atoms in a chemical reaction. This is why to show the proper reaction, the equation must be balanced. Substances that are combined physically but not chemically are called mixtures. Types of Mixtures Homogenous mixture -- the substances are mixed so well that it looks the same throughout (you can’t see the individual substances in it). This is also called a solution. In a solution, the solute (usually a solid) is dissolved in the solvent (usually a liquid). Examples: saltwater, blood, coffee, wine, orange juice (without pulp), Kool-Aid, shampoo When making a solution, solutes dissolve faster with 1) higher temperature 2) stirring Heterogeneous mixture -- the substances are NOT mixed well and you can often see the individual substances that make it up. These also tend to be easier to separate. Examples: soil, Italian salad dressing, orange juice (with pulp), cider, chicken soup Physical vs. Chemical changes Physical changes are those that may change the way a substance looks but the substance is still the same (same chemical formula). Examples of physical changes: Breaking or sharpening a pencil Cracking an egg Freezing water* Pounding bread dough Bending steel *It’s important to note that phase changes are physical changes: if you boil water, you are simply changing liquid to gas but it’s still H2O Chemical changes are those that change the actual chemical makeup of the substance (a new chemical formula) and can only occur if a chemical reaction takes place. Examples of chemical changes: Burning a pencil Cooking an egg Baking bread dough Milk souring Steel rusting
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