Weekly Plan 7 Covalent bonding Student book links Specification links Link to GCSE specification Suggested time allowed: Five hours 1.2.8–10 1.2.16 1.2.2 (e)–(j) 1.2.2 (q)–(s) Covalent bonding Properties of simple covalent compounds Suggested teaching order 1. 2. Learning outcomes Define covalent bonding including multiple bonds. Draw dot-and-cross diagrams for simple molecules – e.g. H2, Cl2, HCl, H2O, NH3, CH4, O2, N2, CO2. Dative covalent bonding as in the ammonium ion Dot-and-cross diagrams for some molecules that do not obey the octet rule – e.g. BF3 and SF6 Electron pair repulsion theory The shapes and bond angles in some simple molecules and ions Students should be able to: Describe a covalent bond as a shared pair of electrons. Describe single and multiple covalent bonding. Use dot-and-cross diagrams to represent covalent bonding. Describe dative covalent bonding. Describe examples of compounds that do not obey the octet rule. Explain how the shape of a simple molecule is determined. State that lone pairs of electrons repel more than bonding pairs. Explain and predict the shapes of – and bond angles in – molecules and ions. Describe the structures of simple covalent molecules. Explain the physical properties of simple covalent compounds. 3. 4. Key words How science works Coordinate bond Covalent bond Dative covalent Lone pair Learning styles (S = Starter activities, M = Main activities, P = Plenary activities) Kinaesthetic Activities M1–M3 Activities P1–P3 Interpersonal Activity S1 Activities M1–M3 Activities P1&P3 5. 6. Giant covalent lattice Simple molecular lattice Molecule Auditory Activities S1&S2 Activity P1 Lesson time allocated: HSW 3D molecular shapes HSW 1 Use models to develop and modify scientific explanations. ICT activities Visual Activity S3 Activities M1–M3 Activity P3 Research other dative covalent molecules. PowerPoint presentations to show atoms coming together to form covalent molecules Wikipedia: Read about covalent bonding © Pearson Education Ltd 2008 This document may have been altered from the original 1 Weekly Plan 7 Suggested starter activities Equipment Teacher notes 1. Brainstorm how two atoms that both need to gain electrons can achieve stability. Ascertain how much the students remember from GCSE. 2. Having talked about discrete, simple molecules, ask the students to predict melting points, solubility and conduction of electricity. This will also revise the same properties for giant ionic structures. 3. Do a quick demonstration of the sublimation of iodine – a simple covalent molecule. Two or three crystals of iodine in a large flask Risk assessment. This demonstrates that very few iodine crystals produce lots of iodine vapour. Suggested main activities Equipment Teacher notes 1. Having introduced the topic and studied the first few dotand-cross diagrams, ask the students (in pairs) to draw other examples of covalent bonding. The students will probably need some help before going on to multiple bonds. 2. Practical Activity 10: Investigating the relationships between bonding, structure and physical properties in substances See practical activity worksheet. 3. Let them make the molecular shapes using one of the various molecular model kits (or balloons!). Molecular model kits or balloons The students can even estimate bond angles and suggest names for the shapes. Larger balloons could represent lone pairs. Suggested plenary activities Equipment Teacher notes 1. Let them chose two s- or p-block elements at random and suggest the name, formula and type of bonding. Element cards Be aware of the students drawing two metals – the students have not studied metallic bonding yet, but will probably accept alloys. 2. Let them try the non-octet examples by themselves. At some stage you will need to tell them that they do not have to obey the octet rule. 3. Develop a cartoon molecule to demonstrate the nature of covalent bonding and its properties. © Pearson Education Ltd 2008 This document may have been altered from the original 2 Weekly Plan 7 Homework suggestions Questions at the end of the double page spreads Try dot-and-cross diagrams and shapes of analogous molecules such as PH 3, H2S, etc. Cross-curriculum links Technology – properties of materials Extension ideas Dot-and-cross diagrams for more difficult compounds, e.g. C2H4, NaOH, H2O2 etc. The shapes of more complicated molecules, e.g. PCl5, C2H4, H2O2 etc. Find the structure of three simple covalent molecules that contain an odd number of electrons in total. Draw the structures of other dative covalently-bonded molecules such as Al2Cl6 and NH3BF3. Potential misconceptions Students often think that boiling simple covalent molecules involves breaking the covalent bonds. Covalent bonds are intramolecular whereas boiling breaks intermolecular forces. They also think that all molecules obey the octet rule – they will meet examples where the octet rule is not adhered to here. Notes The web links referred to here are some that the author has found personally helpful but are not intended to be a comprehensive list, many other good resources exist. © Pearson Education Ltd 2008 This document may have been altered from the original 3
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