Advanced Chemistry Mrs. Klingaman Chapter 7: Chemical Formulas & Compounds (Part 2) Name: _______________________________________ Mods: ______________________ Formula Weight Practice Directions: Determine the formula mass as well as the name or formula (respectively) of the compounds below: 1) N2O5 Name: _______________________________________ Formula Mass: 2) FeCO3 Name: _______________________________________ Formula Mass: 3) Ca(C2H3O2)2 Name: _______________________________________ Formula Mass: 4) (NH4)3PO3 Name: _______________________________________ Formula Mass: 5) Phosphoric acid Formula: _______________________________________ Formula Mass: 6) Copper (II) sulfate Formula: _______________________________________ Formula Mass: 7) Disilicon hexabromide Formula: _______________________________________ Formula Mass: In-Class Examples: Percent Composition The percent by mass of an element in a compound is the number of grams of the element divided by the number of grams of the compound, multiplied by 100. Think “part” over “whole”. % by mass A= (atomic mass of element A) (# of atoms of element A) x 100 molar mass of whole compound 1) Magnesium Nitrate % Mg: _____________ 2) Nitrous acid % H: _____________ 3) Aluminum dichromate % Al: _____________ Formula: _______________________ % N: _____________ % O: _____________ Formula: _______________________ % N: _____________ % O: _____________ Formula: _______________________ % Cr: _____________ % O: _____________ Formula Weight and Percent Composition Practice Directions: Calculate the molar mass for the following compounds and find the percent by mass of each element in the compound. 1) FeCrO4 Compound Name: ___________________________________________ % Fe: _____________ 2) CuSO3 % O: _____________ Compound Name: ___________________________________________ % Cu: _____________ 3) KNO3 % Cr: _____________ % S: _____________ % O: _____________ Compound Name: ___________________________________________ % K: _____________ 4) Ca3(PO4)2 % Ca: _____________ % N: _____________ % O: _____________ Compound Name: _____________________________________ % P: _____________ % O: ____________ In-Class Examples: Conversions Using the Mole Example Calculations (with dimensional analysis): 1. Grams Moles How many moles are there in 1.1 grams of iron (III) chloride? Chemical Formula: _____________________________ 2. Moles Grams What is the mass, in grams, of 21.3 moles of dichromic acid? Chemical Formula: _____________________________ 3. Moles Atoms or Molecules Find the number of molecules in 3.2 moles of barium carbonate. Chemical Formula: _____________________________ In-Class Examples: Conversions Using the Mole 4. Atoms or Molecules Moles How many moles are there in a sample of 1.25 x 1023 molecules of beryllium acetate? Chemical Formula: _____________________________ 5. Gram Atoms or Molecules Find the number of molecules in 60 grams of lithium oxalate. Chemical Formula: _____________________________ 6. Atoms or Molecules Grams What is the mass, in grams, of 3.24 x 1023 molecules of xenon hexafluoride? Chemical Formula: _____________________________ Converting Grams Moles: Directions: Find the number of moles in each of the following. 1) 79.2 grams of potassium sulfate Formula: ___________________________ 2) 208 grams of sodium bicarbonate Formula: ___________________________ 3) 111.3 grams of sulfur hexafluoride Formula: ___________________________ Converting Moles Grams: Directions: Find the number of grams in each of the following. 4) 6.5 moles of tin (II) cyanide Formula: ___________________________ 5) 3.8 moles of tricarbon octahydride 6) 9.3 x 10–3 moles of silver Formula: ___________________________ Formula: ___________________________ Converting Moles Atoms or Molecules: Directions: Find the number of atoms or molecules in each of the following. 7) 4.0 moles of phosphorous triiodide 8) 5.9 moles of mercury 9) 1. 2 moles of beryllium dichromate Formula: ___________________________ Formula: ___________________________ Formula: ___________________________ Converting Atoms or Molecules Moles: Directions: Find the number of moles in each of the following. 10) 1.7 x 1023 molecules carbon dioxide 11) 3.3 x 1022 atoms of arsenic 12) 8.6 x 1024 molecules of hydroiodic acid Formula: ___________________________ Formula: ___________________________ Formula: ___________________________ Converting Grams Atoms or Molecules: Directions: Find the number of atoms or molecules in each of the following. 13.) 24 grams of iron (III) fluoride 14) 450 grams of sodium nitrite 15) 122 grams of selenium Formula: ___________________________ Formula: ___________________________ Formula: ___________________________ Converting Atoms or Molecules Grams: Directions: Find the number of grams in each of the following. 16) 7.4 x 1023 molecules of silver nitrate 17) 4.5 x 1022 molecules of lead (II) acetate Formula: ___________________________ 18) 9.2x 1025 molecules of calcium bromate Formula: ___________________________ Formula: ___________________________ Mixed Review of Gram MoleAtom or Molecule Conversions 1) How many grams are there in 3.3 x 1023 molecules of dinitrogen hexoxide? 2) How many molecules are there in 4.23 moles of ammonium hydroxide? 3) How many grams are there in 0.92 moles of boron trichloride? 4) How many moles are there in 4.5 x 1022 molecules of barium nitrite? 5) How many moles are there in 9.34 grams of lithium chloride? 6) How many grams do 4.3 x 1021 molecules of uranium hexafluoride weigh? 7) How many molecules are there in 230 grams of ammonium hydroxide? In-Class Examples: Determining Empirical Formulas Problem #1: An experiment uses a catalyst that is 23.3 % cobalt, 25.3 % molybdenum, and 51.4 % chlorine. What is the empirical formula of this catalyst? Step #1: Percent to mass Assume that you are working with a 100 gram sample, so the % of each element is equal to the mass of each element in grams Step #2: Mass to mole Convert the mass of each element to moles of each element using the molar mass. Step #3: Divide by small Divide each of the mole quantities by the smallest number of moles. Often, this will result in whole or practically whole numbers Step #4: Multiply ‘till whole If step #3 does not result in whole numbers, find the least common multiple that will achieve all whole numbers. These whole numbers represent the subscripts for each element in the empirical formula. The empirical formula for this compound is: ________________________________ Problem #2: What is the empirical formula for a molecule containing 65.5% carbon, 5.5% hydrogen, and 29.0% oxygen? Determining Empirical Formulas 1) Find the empirical formula of a molecule containing 18.7% lithium, 16.3% carbon, and 65% oxygen. 2) The percent composition of acetic acid is 39.9% carbon, 6.7% hydrogen, and 53.4% oxygen. Determine the empirical formula of acetic acid. 3) The compound benzamide is composed of 69.40% carbon, 5.825% hydrogen, 13.21% oxygen, and 11.57% nitrogen. What is the empirical formula of benzamide? 4) Upon analysis, rubbing alcohol (also known as isopropyl alcohol) is found to contain 60.0% carbon and 13.4% hydrogen with the remaining percent due to oxygen. Find the empirical formula of rubbing alcohol. 5) A certain compound is 47.05% potassium, 14.45% carbon, and 38.5% oxygen. What is the empirical formula for this compound? 6) Nitrogen and oxygen form an extensive series of oxides with the general formula N XOY. One of them is a blue solid that comes apart, reversibly, in the gas phase. It contains 36.84% N with the remaining percent coming from O. What is the empirical formula of this oxide?
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