Dear AP Chemistry Students, I hope you are all have a fun and restful summer! As school gets closer, you will want to review a few chemistry topics in preparation for our first few classes of AP Chemistry. Below, there is a list of suggested topics for review with clickable links to tutorials, videos, and practice problems. Do not feel like you need to go through them all, just perhaps the ones that seem a bit fuzzy to you. You may find these resources helpful to complete the attached problems. The attached problems are due September 8th , the end of the first week of school. Please show work for all problems. Please contact me if you have any questions, or need any additional support for any of these topics! Sincerely, Dr. Brennan [email protected] Topics Units and Math Skills Links http://chemed.chem.purdue.edu/genchem/topicr eview/bp/ch1/units.html Review of periodic table of elements http://www.chem.tamu.edu/class/fyp/mathrev/m r-scnot.html http://www.chem.tamu.edu/class/fyp/mathrev/m r-da.html video: http://www.youtube.com/watch?v=XKCZn5MLKvk https://www.khanacademy.org/science/chemistry /periodic-table/copy-of-periodic-table-ofelements Review of atoms and elements The types of chemical bonds Formulas and Naming https://www.khanacademy.org/science/chemistry /atomic-structure-and-properties/introduction-tothe-atom/v/elements-and-atoms http://www.sciencegeek.net/Chemistry/taters/Un it1AtomicNumbers.htm http://www.youtube.com/watch?v=iih6rJ2S6pk or http://www.mrsmoushon.com/8th/wpcontent/uploads/2011/11/How-to-Draw-BohrDiagrams-and-Lewis-Dot- StructuresPresentation.pdf https://www.khanacademy.org/science/chemistry /chemical-bonds/types-chemical-bonds/v/ioniccovalent-and-metallic-bonds Notes Metric System: you will need to know the prefixes for Giga, Mega, Kilo, Hecto, Deka, Deci, Centi, Milli, Micro, Nano, Angstrom, Pico Scientific Notation Dimensional Analysis On the attached periodic table, label the regions. Also, write down the patterns for ion charges, valence electrons, dot diagrams. This will be checked. All links recommended, if needed Practice problems Bohr Model tips Just this first link http://www.diffen.com/difference/Covalent_Bond s_vs_Ionic_Bonds http://www.kentchemistry.com/links/naming/Na Click on all the green links at the top meCov.htm of the page to learn about naming and formulas for covalent compounds and How to draw dot structures and Lewis Structures Mole Calculations Empirical and Molecular Formulas Balancing Chemical Equations Types of Reactions Stoichiometry Stoichiometry, Limiting Reactant https://www.khanacademy.org/science/chemistry /chemical-bonds/copy-of-dotstructures/v/drawing-dot-structures http://www.sciencegeek.net/Chemistry/taters/Un it2ValenceElectrons.htm http://www.chemteam.info/Mole/Mole.html http://www.chemteam.info/Mole/EmpiricalMolecFormulas.html or http://chemed.chem.purdue.edu/genchem/probs olv/stoichiometry/molecular2/mf2.4.html https://www.khanacademy.org/science/chemistry /chemical-reactions-stoichiome/balancingchemical-equations/v/balancing-chemicalequations-introduction https://www.youtube.com/watch?v=d58UcB_Yb2 Q https://www.khanacademy.org/science/chemistry /chemical-reactions-stoichiome/stoichiometryideal http://misterguch.brinkster.net/pra_equationwor ksheets.html http://www.sciencegeek.net/Activities/GramsGra msStoich.html https://www.khanacademy.org/science/chemistry /chemical-reactions-stoichiome/limiting-reagentstoichiometry http://www.sciencegeek.net/Activities/LimitingRe actant2.html the various types of ionic compounds, as well as acids Just this first link Try just a few of these Lots of helpful how-to articles here All links are helpful. Links to practice problems with answers. If you are interested, check it out All links are helpful. Practice problems with answers Units and Math Skills Units: Units are very important in chemistry. We will be using grams, meters, liters, moles, seconds, volts, and particles (molecules/atoms/ions) throughout the year. You should be comfortable using units in a calculation, including crossing them out and identifying the correct unit used in the answer. You also need to recognize that 1/s is the same as s-1as units in chemistry and will be expressed either way. Make the following conversions, showing proper dimensional analysis work: a. 45 mm = ? m ( 1 m = 103 mm) b. 24 grams = ? cg (1 g = 102 cg) c. 0.025 liters = ? mL (1 Liter = 103 mL) d. 2.4 mol Cu = ? atoms (1 mole = 6.02 x 1023 atoms Periodic Table 1) On the attached periodic table, label the regions. Also, write down the patterns for ion charges, valence electrons, dot diagrams. This will be checked. 2) Indicate the formal family name to which each of the indicated elements belong: iodine _______________________ potassium _____________________ argon _______________________ strontium ______________________ tellurium _______________________ 3) Of the elements listed in question 3: (list them by their chemical symbols) a. which elements are metals? _____________________________________ b. which elements are nonmetals? ___________________________________ c. which elements are metalloids? ___________________________________ Atoms and Elements 4) Complete the chart below about the particles that make up the atom: Proton Neutron Electron Relative Mass Charge Location in atom 5) Complete the chart below: (only mass #s are given, you must look up the atomic #s) # of # of # of protons neutrons electrons 28 Si 60 Ni 195 Pt 238 U 6) From the data below, determine the average atomic mass of the given element: Isotope (Mass #) 203.97302 204.97444 206.97587 207.97663 Abundance by % 1.40000% 24.10000% 22.10000% 52.40000% Average atomic mass:____________ 7) Bohr Model: a. How can you use the periodic table to determine the number of energy levels an atom has? b. What are valence electrons? How can you tell how many valence electrons an atom will have? c. Draw the Bohr model for Neon-20 d. Draw the Bohr model for Potassium – 39 Ionic & Covalent Compounds 8) a. When metals form ions, they tend to gain/lose electrons and become +/- charged. b. When non-metals form ions, they tend to gain/lose electrons and become +/- charged. c. Which group of elements do not form ions? why? d. Based on its location in the periodic table, what is the most stable ion for: Al _______ Ca _______ S ________ I _________ Cs ______ 9) a. Ionic compounds transfer / share electrons between two metals / metal and a nonmetal / two nonmetals. b. Covalent compounds transfer / share electrons between two metals / metal and a nonmetal / two nonmetals. 10) Based on their locations in the periodic table, write the formula of the ionic compounds formed between: a. gallium and fluorine ____________ b. lithium and iodine ____________ c. aluminum and oxygen ____________ d. magnesium and nitrogen ___________ 11) Name the following ionic compounds. Use a polyatomic ion list from the internet if needed. a. AlF3 _______________________________ b. Fe(OH)2 ________________________________ c. Cu(NO3)2 ____________________________ d. Ba(ClO4)2 ______________________________ e. Li3PO4 _______________________________ f. Cr2(CO3)3 ______________________________ 12) Write the formulas for the following ionic compounds. Use a polyatomic ion list from the internet if needed. a. potassium chromate ___________________ b. magnesium chlorate __________________ c. iron (III) carbonate ___________________ d. tin (IV) sulfate ____________________ e. lead (IV) arsenate ____________________ f. silver sulfide _______________________ 13) Write the formulas of the following binary covalent compounds: a. tetraphosphorus decoxide ______________ b. dinitrogen tetroxide __________________ c. sulfur trioxide _____________________ d. trinitrogen monoxide _________________ 14) Write the names of the following binary covalent compounds: a. SCl6 _____________________________ b. IBr5 _______________________________ c. XeF4 _____________________________ d. NO _______________________________ 15)Draw the best Lewis Structure for the following Covalent Compounds or Polyatomic Ions: CO2 NH3 BF3 NH4+1 C2H2 H2CO3 Chemical Reactions 16) Write the following as a chemical equation. Predict products if needed and include phases: a. Sulfur solid reacts with iron solid to form solid iron(III) sulfide. b. Magnesium fluoride solid and hydrochloric acid react to in a double replacement to form two products. 17)Balance the following equations and indicate the type of reaction taking place: a. ____ Ca(OH)2 + ____ Al2(SO4)3 ____ CaSO4 + ____ Al(OH)3 Type of reaction: _________________ b. ____ Mg + ____ Fe2O3 ____ Fe + ____ MgO Type of reaction: _________________ c. ____ C2H4 + ____ O2 ____ CO2 + ____ H2O Type of reaction: _________________ d. ____ PbSO4 ____ PbSO3 + ____ O2 Type of reaction: _________________ e. ____ H2O + ____ SO3 ____ H2SO4 Type of reaction: _________________ Formulas and Moles, Stoichiometry 18) A compound has two boron atoms and six hydrogen atoms. a. What is its molecular formula? ________________ b. What is its empirical formula? ___________________ 19) Write the empirical formula for: a. Al2Br6 _____________ b. C8H10 _____________ 20) Determine the molar mass of: a. H2S _____________________ c. C4H8O2 _______________ b. Sb2(S2O3)5 ______________________ 21) If you have 5.8 x 10 22 molecules of hydrogen sulfide, how much would it weigh? 22) 500 grams of sodium hydroxide would contain how many formula units (particles)? 23) Calculate the percentage (by mass) of oxygen in: a. sulfur dioxide ________________ b. aluminum nitrate ________________ 24) Determine the empirical formula of a compound that contains 11.66 g of iron and 5.01 g of oxygen: 25) Determine the empirical and molecular formula of a compound that contains: 49.5 % carbon, 5.15% hydrogen, 28.9% nitrogen and 16.5 % oxygen with a molar mass of 195 g/mol. Empirical formula = ___________________ Molecular Formula = _______________________ 26) Given the reaction: ___ Na2SiO3 + ___ HF ____ H2SiF6 + ____ NaF + _____ H2O a. How many grams of NaF form when .500 mol of HF are completely consumed? _________________ b. How many grams of water form if 125 g of NaF formed? ______________________ 27) Given the reaction: ____ C6H14 + ____ O2 ____ CO2 + ____ H2O a. 42.0 grams of hexane (C6H14) are combined with 80.0 of oxygen. What is the limiting reagent (reactant)? b. What mass of the excess reagent is left over? ________________ c. What mass of water vapor is produced? _________________ d. If the actual yield of water vapor is 20.6 grams, then what is the percent yield? _____________
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