Stoichiometry Notes Describe the types of relationships indicated by a balanced chemical equation. State the mole ratios from a balanced chemical equation. Particle and Mole Relationships • Stoichiometry is the study of quantitative relationships between the amounts of reactants used and amounts of products formed by a chemical reaction. (It’s the math that figures out how to not have excess) • Chemical reactions stop when one of the reactants is used up. • So based on how much reactant you put in you can calculate how much product you will get out. Particle and Mole Relationships (cont.) • • A mole ratio is a ratio between the numbers of moles of any two substances in a balanced equation. This can only be determined from a balanced chemical equation. • Let practice: What is the mole-to-mole ratio for…… 1. 2C12H22O3 + 32O2 24CO2 + 22H2O 2. CH4 + 2O2 CO2 + 2H2O 3. H2 + O2 H2O Using Stoichiometry All stoichiometry calculations begin with a balanced chemical equation. 4Fe(s) + 3O2(g) 2Fe2O3(s) GramsMoleMole RatioGrams Using Stoichiometry (cont.) Using Stoichiometry (cont.) How many moles of SO3 are formed if you start with 5 moles of Sulfur and have excess Oxygen? __S + __O2 __SO3 Using Stoichiometry (cont.) How many moles of Sulfur do you need to create 45 grams of SO3 if you have excess Oxygen? __S + __O2 __SO3 Using Stoichiometry (cont.) How many grams of Sulfur do you need to create 45 grams of SO3 if you have excess Oxygen? __S + __O2 __SO3 Using Stoichiometry (cont.) How many grams of Na2SO4 will be formed if you start with 200 grams of NaOH and you have an excess of H2SO4? __NaOH + __H2SO4 __H2O + __Na2SO4 Answer the following in your NOTES How many moles of Na2SO4 will be formed if you start with 35 grams of H2SO4 and you have an excess of NaOH? __NaOH + __H2SO4 __H2O + __Na2SO4 How many grams of LiNO3 will be needed to make 250 grams of Li2SO4, assuming that you have enough Pb(SO4)2 to do the reaction? __Pb(SO4)2 + __LiNO3 __Pb(NO3)4 + __Li2SO4 Real Life Application Ingredients •2 1/4 cups all-purpose flour •1 teaspoon baking soda •1 teaspoon salt •1 cup (2 sticks) butter, softened •3/4 cup granulated sugar •3/4 cup packed brown sugar •1 teaspoon vanilla extract •2 large eggs •2 cups (12-oz. pkg.) NESTLÉ® TOLL HOUSE® Semi-Sweet Chocolate Morsels •1 cup chopped nuts Real Life Application • What goes into a cell phone: • – Glass – Plastic – Aluminum – Magnets – Bromine – PVC – Heavy metals like lead, tin, cadmium and chromium Heavy metals, PVC and bromine are all chemicals that we do not want getting into our water and need to be disposed of carefully. We do not want extra amounts of these. Real Life Application • We cannot forget about the law of conservation of mass. • The mass of what we put in must be equal to what we get out. • The excess reactants are all the leftover unused reactants. • (The reactant that’s leftover). Real Life Application • Since we have conservation of mass we also need to take into consideration what limits reactions. • The limiting reactant limits the extent of the reaction and, thereby, determines the amount of product formed. • (The reactant that’s all used up). Real Life Application • Knowing what limiting reagents and excess are we can think about the most cost effective method for producing things. • We do not want a lot of excess so we need to determine what chemical(s) or ingredient(s) to make the limiting reagent • The most expensive chemical is always the limiting reactant. Excess vs. Limiting 2Al(s) + 3CuCl2(aq) → 3Cu(s) + 2AlCl3(aq) If you were an chemical engineer manufacturing aluminum chloride, what would you want to be your excess reagent and why? Compounding Pharmacist • Compounding pharmacy is called when Physician need to prescribe a very specific medication, prepared by a pharmacist, for a patient's individual needs. • A compounding pharmacy is used when: • allergic to a dye or filler in a commercial tablet. • capsule is too large, or the dose is too high, which is common in pediatric cases. Compounding Pharmacist Mortar and Pestle Compounding Pharmacy Situation: I told Mrs. Driebe and Mrs. Lieb that you could: • Predict the products in a double replacement reaction • Balance the equation • Practice stoichiometry Goal: Is to compound 2 grams of calcium carbonate, the active ingredient in Tums for the Mortar and Pestle Compounding Pharmacy using stoichiometry and good lab techniques. Compounding Pharmacist MgCl2 (aq) + 2KCO3 (aq) Mg(CO3)2 (s) + 2KCl (aq) You want to make 2 grams of Mg(CO3)2 how much reactants would you have to mix? Bell Ringer • On average a Pharmacists makes $50 an hour in Arizona. This week you did one job a Pharmacist is trained to do. Could you see yourself as a Pharmacist? Why or why not.
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