Technische Universität Dresden Peter Krebs Department of Hydro Science, Institute for Urban Water Management Urban Water Systems 11 Wastewater Treatment 11.1 Boundary conditions 11.2 Layout of a wastewater treatment plant (WWTP) 11.3 Mechanical treatment 11.4 Biological treatment 11.5 Final clarification Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 1 11 Wastewater treatment 11.1 Boundary conditions Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 2 Wastewater treatment in Germany In 2000 more than 10‘000 communal WWTPs Class Number Total capacity in mio PE > 100’000 272 83.1 10’000 – 100’000 1’817 56.1 2’000 – 10’000 2’617 12.3 50 – 2’000 5’677 3.2 Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 3 Effluent standards Class COD (mg/l) BOD5 (mg/l) NH4-N (mg/l) N* (mg/l) Ptot (mg/l) 1 < 1000 PE 60 kg BOD5 / d 150 40 - - - 2 < 5000 PE 300 kg BOD5 / d 110 25 - - - 3 < 10000 PE 600 kg BOD5 / d 90 20 10 - - 4 < 100000 PE 6000 kg BOD5 / d 90 20 10 18 2 5 > 100000 PE 6000 kg BOD5 / d 75 15 10 13 1 * N = Sum of NH4+, NO3-, und NO2Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 4 Load variation in WWTP inlet 70 6 NH4-load 50 5 COD-load 40 30 3 Daily average 20 COD and NH4 2 10 0 00:00 4 NH 4-load (kg/h) COD-load (kg/h) 60 7 1 04:00 08:00 12:00 16:00 20:00 0 00:00 Time (hh:mm) Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 5 Wet-weather load of NH4 and TSS from sewer 4 16 NH4 load NH4 load / (Qd·C0) 3 12 TSS load 10 2 8 6 1 4 2 0 0 10:00 12:00 14:00 16:00 18:00 20:00 22:00 Urban Water Systems Q /Q d; TSS load / ( Q d·C 0) 14 Flow rate 11 Wastewater treatment 0:00 2:00 © PK, 2005 – page 6 Flow rate WWTP load with NH4+ at storm event Time Conc., load Load Concentration Time Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 7 11 Wastewater treatment 11.2 Layout of a wastewater treatment plant (WWTP) Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 8 Layout of a WWTP Mechanical treatment Biological treatment precipitation chemical Screen Grid chamber Fat chamber Primary clarifier Activated sludge tank Secondary clarifier River, filtration Sand Fat Primary sludge Return sludge Thickening Secondary sludge Excess sludge Biogas disposal, incineration Use, dewatering, drying, incineration, Disposal Wash, disposal Digestion Urban Water Systems 11 Wastewater treatment Storage © PK, 2005 – page 9 Example: WWTP Chemnitz-Heinersdorf Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 10 Typical residence time in reactors Wastewater HRT (h) Mechanical pre-treatment 0.2 Primary clarifier 1.5 Activated sludge tank Sludge SRT (d) 0.01 1 10 10 5 2 Secondary clarifier Sludge thickener 2 Digester 20 Storage 100 <1d Urban Water Systems 11 Wastewater treatment > 100 d © PK, 2005 – page 11 11 Wastewater treatment 11.3 Mechanical treatment Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 12 Automatically cleaned trash rack Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 13 Sieve Slotted sieve ≥ 0.5 mm Perforated tin ≥ 3 mm Hans Huber AG, Typ Ro9 Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 14 Basics for rack design • Flow velocity: 0,6 v 2,5 m/s • Widen flume to compensate for racks cross section • Consider backwater effect – Hydraulics: d Δh β e 4 3 v2 sinα 2g – + due to clogging lower bottom to compensate for backwater effect • Safety for maintenance (redundant) • Building around racks (Frost, smell) Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 15 Surface load: qA = Q / A (Hazen, 1904) L U U Q Critical case Settling condition H VS L U HRT VS H HRT L H U VS VS U BH Q LB ASC VS qA Independent of H ! Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 16 Grid chamber • In connection with combined systems • Effects of non-organic particles: – Abrasion of steel (e.g. pumps) – Clogging (Sludge hopper, pipes, Pumps) – Sedimentation (activated sludge tank, digester) High maintenance requirements Sludge in sand is hindering Sand in sludge is detrimental for operation ! Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 17 Empirical sedimentation velocities Kalbskopf, 1966 Particle diameter Sedimentation velocity [mm] = 100% [cm/s] = 90% [cm/s] = 85% [cm/s] 0,125 0,160 0,200 0,250 0,315 0,17 0,29 0,46 0,74 1,23 0,26 0,44 0,78 1,25 2,00 0,31 0,56 0,99 1,60 2,35 Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 18 Design rules • Flow velocity: 0,3 m/s • Width extending with height b 5Q h l h • Length: u vs • Sand collector: appr. 0,2 x 0,3 m (not too large!) • Venturi flow measurement after grid chamber Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 19 Aerated grid chamber Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 20 Efficiency of primary clarifier 100 90 settleable solids Efficiency (%) 80 70 TSS 60 50 40 30 BOD5 20 10 0 0 1 2 3 4 5 Residence time HRT (h) Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 21 Effects of primary clarifier on wastewater Unit Inlet TSS g TSS / m3 360 180 0.5 BOD5 COD TKN g O 2 / m3 g O 2 / m3 g N / m3 300 600 60 230 450 56 0.23 0.25 0.067 NH4-N NO2-N NO3-N g N / m3 g N / m3 g N / m3 40 0 1 40 0 1 Compound Ptot g P / m3 Alkalinity mol HCO3- / m3 * Cin Cout Cin Outlet* 0 0 0 10 9 0.1 = f(Drinking water) + NH4-N Short residence time Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 22 Rectangular sedimentation tank Primary / secondary clarifier Flight scraper Effluent weir Inlet Effluent to activated sludge tank or to receiving water Sludge withdrawal Surface: Urban Water Systems Primary clarifier qA = 2 to 6 m/h Secondary clarifier qA = 0.5 to 1.5 m/h 11 Wastewater treatment © PK, 2005 – page 23 11 Wastewater treatment 11.4 Biological treatment Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 24 Biological treatment Suspended biomass Activated sludge system • suspended through turbulence • sludge flocs with 0.1 – 1 mm diameter • degradation related to biomass Increase suspended biomass concentration Sessile biomass Biofilm system • biofilm on carrier • little erosion • degradation related to biofilm surface area Increase of specific surface area Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 25 Important micro-biological processes Growth Implementation of C, N, P in biomass Decay If external nutrients are rare Hydrolysis Heavily easily degradable substances, through encymes Aerobic degradation organic compounds CH2O + O2 CO2 + H2O Nitrification NH4+ + 2 O2 NO3- + H2O + 2 H+ Denitrification 5 CH2O + 4 NO3- + 4 H+ 2 N2 + 5 CO2 + 7 H2O Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 26 Growth of bacteria Doubling time tD 0·tD 1·tD 2·tD 3·tD i·tD ... n·tD 20 21 22 23 2i ... 2n 60 Activated sludge: 50 tD = 6 h X /X 0 40 30 Sludge age = 10 d 20 10 0 0 1 2 3 4 5 6 t /t D Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 27 Growth of bacteria Growth d XB r XB dt Specific growth rate S max S KS XB max S KS = = = = (T-1) Growth is limited through nutrients and oxygen max,2/2 max,1/2 KS,1 KS,2 Substrate, nutrients, O2 Biomass concentration Maximum specific growth rate Substrate concentration Half saturation constant Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 28 Activated sludge system Activated sludge tank Secondary clarifier Air, O2 Sedimentation Inlet Nutrients Effluent Bacteria Return sludge Urban Water Systems 11 Wastewater treatment Excess sludge © PK, 2005 – page 29 Sludge inventory in activated sludge system Activated sludge tank XAST Q Secondary clarifier Q + QRAS Q XAST Xe (QWAS) QRAS = R·Q XRAS (XWAS) Sludge balance in equilibrium X RAS X AST Urban Water Systems 1 R R mit 11 Wastewater treatment QRAS R Q © PK, 2005 – page 30 Flow scheme of activated sludge system Hydraulic wash-out of sludge to secondary clarifier sludge must be returned to activated sludge tank Activated sludge is circled 20 to 50 times sludge concentration in activated sludge tank is maintained Excess sludge is withdrawn from system equivalent to sludge production Through increased hydraulic loading (wet-weather condition) sludge is shifted to secondary clarifier Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 31 Dynamic sludge shift Sludge mass (kg COD) 3000 2500 2000 1500 1000 500 Activated sludge tank 0 0 0,5 1 1,5 2 1,5 2 Time (d) Sludge mass (kg COD) 1400 1200 Sludge bed 1000 800 600 400 200 0 0 0,5 1 Time (d) Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 32 Aeration in an actvated sludge tank Oxygen Bacteria Sludge Organic compounds Effluent, water and sludge Air Inflow from mechanical treatment Return sludge Dimension: communal wastewater treatment 2 m3 wastewater per m3 reactor volume and day Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 33 Dimensioning on sludge loading Sludge loading F/M Q BOD5,in VAST X AST kg BOD5 in kg TSS d BOD5 inlet load is related to sludge mass in activated sludge tank (AST) F/M BOD5 loading related to dry sludge mass (Food/Microorganisms) Q Inflow to WWTP (m3/d) BOD5,in BOD5 concentration in inlet (kg BOD5 / m3) VAST Volume of activated sludge tank (m3) XAST Sludge concentration in activated sludge tank (kg TSS / m3) Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 34 Dimensioning on sludge age VAST X AST 1 Sludge SRT VAST X AST SP ESPBOD Q BOD5,in F / M ESPBOD age Sludge production is related to sludge mass in activated sludge tank SRT Sludge age in (d), 3 – 15 d ESPBOD Specific excess sludge production per BOD5 converted (kg TSS / kg BOD5) SP Sludge production (kg TSS / d) SP ESPBOD Q BOD5,in Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 35 Nutrients demand of micro-organisms Nitrogen Phosphorous iN = 0.04 – 0.05 (g N / g BOD5) iP = 0.01 – 0.02 (g P / g BOD5) Partial elimination of nutrients Wastewater composition in the inlet 300 (g BOD5/m3) 60 (g TKN/m3) 12 (g TP/m3) Effluent concentrations after 100% BOD5 degradation TKNeff = TKNin – iN·BOD5,in = 60 – 0.045·300 = TPeff = TPin – iP·BOD5,in = 12 – 0.015·300 = 46.5 (g N / m3) 7.5 (g P / m3) Enhanced nutrients removal is necessary! Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 36 Nitrification NH4+ NO3- Nitrifying organisms („autotrophic biomass“ XA) have a low growth rate A With production of autotrophic biomass SPA rA VAST A X A,AST VAST and a safety factor SF the necessary sludge age yields SRT SF VAST X A,AST SPA SF VAST X A,AST μ A X A,AST VAST 1 SF μA high sludge age necessary to omit nitrifiers from being washed out of the system Volume of activated sludge tank must be large Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 37 Development of activated sludge system C-Elimination aerobic Nitrification aerobic De-nitrification anoxic aerobic „Bio-P“ anoxic anaerobic Urban Water Systems anoxic aerobic 11 Wastewater treatment © PK, 2005 – page 38 Oxygen consumption Oxygen introduction cs c SOI SOC f cs Introduction Consumption SOC Specific O2-consumption (kg O2 / kg BOD5) cs O2 saturation concentration (g O2 / m3) c O2 concentration (g O2 / m3) f Peak factor for variations (-) SOI Spec. O2 introduction rate to clean water (kg O2 / (m3·h)) Reduction factor for wastewater (0.4) 0.6 – 0.8 The smaller the actual oxygen concentration, the more efficient is the oxygen introduction Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 39 Specific oxygen consumption SOC (kg O2 / kg BOD5) T Sludge age in d (°C) 4 8 10 15 20 25 10 0.85 0.99 1.04 1.13 1.18 1.22 12 0.87 1.02 1.07 1.15 1.21 1.24 15 0.92 1.07 1.12 1.19 1.24 1.27 18 0.96 1.11 1.16 1.23 1.27 1.30 20 0.99 1.14 1.18 1.25 1.29 1.32 1.25 1.20 1.20 1.15 1.10 - 2.00 2.50 1.80 2.00 1.50 1.50 - Peak factors for C und N degradation fC 1.30 fN < 20‘000 PE > 100‘000 PE - Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 40 Design rules Type of biological reactor SRT F/M Without nitrification Nitrification >10°C Denitrification Simultaneous aerobic sludge stabilisation < 20‘000 PE 5 10 12 – 18 25 > 100‘000 PE 4 8 10 – 16 – 0.30 0.15 0.12 0.05 0.9 – 1.2 0.8 – 1.1 0.7 – 1.0 1.0 (kg BOD5 / (kg TS · d)) ESPBOD (kg TS / kg BOD5) Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 41 Concentrations in a plug flow areation tank Qin QRS QES O2 BSB5 NH4+ NO32Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 42 Trickling filter Trickling filter Primary clarification Biofilm grown on internal surface Secondary clarification Recirculation Sludge withdrawal Urban Water Systems Return sludge 11 Wastewater treatment © PK, 2005 – page 43 Dimensioning of trickling filter Surface loading BSu BSu Q BOD5,in a VTF Surface loading (g BOD5 / (m2·d)) without nitrification 4 (g BOD5 / (m2·d)), with nitrifi. 2 (g BOD5 / (m2·d)) Q Inflow to trickling filter (m3/d) BOD5,in BOD5 inlet concentration (kg BOD5 / m3) VTF Volume of trickling filter (m3) a Specific biofilm surface per volume of trickling filter (m2 / m3 TF) 100 – 140 – 180 (m2 / m3 TF) Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 44 Degradation in trickling filter Concentration BOD5 Trickling filter NH4+ N03- C-degradation and nitrification are separated in space Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 45 11 Wastewater treatment 11.5 Final clarification Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 46 Functions of final clarifiers Separation of sludge and cleaned wastewater through Sedimentation Clarification Low effluent concentration Storage of sludge shifted from actibated sludge tank, namely under wet-weather conditions Thickening High return sludge concentration Geometry • Circular, flow from centre to periphery • Rectangular, longitudinal flow • Rectangular, lateral flow • Vertical, upward flow Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 47 Sedimentation Primary clarifier Concentration low Free settling Final clarifier, separation zone Flocculating settling Hindered settling Thickening high none Final clarifier, sludge bed Final clarifier, bottom flocculating Particle-Interaction Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 48 Sludge volume index SVI SVI is an indicator for volume of sludge flocs and their settling characteristics 0.5 h Sludge volume hS (ml/l) SV V H X0 H V SVI SV X0 (ml / g TSS) hS Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 49 Final clarifier, idealised functions Inlet zone Effective zone Clear water layer Separation layer Storage layer >3m Thickening layer ATV A131 (2000) Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 50 Dimensioning of surface Q qSV qSV AFC SV X AST SVI Surface overflow rate qA Sludge overflow rate qSV q A X AST SVI Limit values qA qSV (m/h) (l/(m2·h) Horizontal flow tanks 1.6 500 Vertical flow tanks 2.0 650 ATV A131 (2000) Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 51 Dimensioning of water depth Clear water layer h1 0.5 m Separation layer 0.5 q A 1 R h2 1 SV 1000 Storage layer 1.5 0.3 qSV 1 R h3 500 Thickening layer X AST q A 1 R tth h4 X BS XBS Sludge concentration at bottom tth Thickening time Urban Water Systems 1.5 – 2.0 h without nitrification 1.0 – 1.5 h with nitrification 2.0 – (2.5) h with denitrification 11 Wastewater treatment X BS 1000 1 3 tth SVI ATV A131 (2000) © PK, 2005 – page 52 Calculation procedure (plant without nitrogen elimination) • • • • • • • • • • • • estimate or measure inflow load choose system estimate sludge volume index choose thickening time calculate concentration of bottom sludge calculate return sludge concentration choose recycle ratio estimate XAST calculate surface of secondary clarifier calculate h1, h2, h3, h4 of secondary clarifier check thickening time calculate volume of activated sludge tank is balance between AST and SC optimised? Urban Water Systems 11 Wastewater treatment Variation XAST © PK, 2005 – page 53 Circular tank Scum skimmer Flocculation chamber Sludge scraper Inlet With scraper or suction removal device Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 54 Rectangular tank, longitudinal flow, flight scraper system Chain motor Water level Effluent launder Effluent Inlet Sludge Sludge hopper Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 55 Rectangular tank, lateral flow, suction system Inlet channel Removal bridge Scum skimmer Inlet baffle Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 56 Vertical flow tank Effluent launder Effluent Inlet Filter Pump Return sludge Thickening Return sludge Urban Water Systems 11 Wastewater treatment © PK, 2005 – page 57
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