EOR PERFORMANCE AND MODELING Potential for Additional CO2-Flood Projects in the US Introduction US conventional crude-oil production continues to decline while demand for crude and finished products rises. According to the US Department of Energy Energy Information Administration (US DOE EIA) and shown in Fig. 1, the US demand will be greater than 27 million B/D by 2030, while total production will be less than 10 million B/D. Four factors were identified that will have a significant effect on widespread implementation of CO2 EOR. • Target resource • Technology • Availability of CO2 • Economics Target Resource There are 1,673 reservoirs onshore in the continental US that are canThis article, written by Senior Technology Editor Dennis Denney, contains highlights of paper SPE 113975, “The Potential for Additional Carbon Dioxide Flooding Projects in the United States,” by Hitesh Mohan, SPE, Marshall Carolus, SPE, and Khosrow Biglarbigi, SPE, Intek, prepared for the 2008 SPE Improved Oil Recovery Symposium, Tulsa, 19–23 April. The paper has not been peer reviewed. 30 27.65 25 20 Million B/D There is renewed interest in carbon dioxide enhanced oil recovery (CO2 EOR). Growing concern about climate change and greenhouse gases has increased interest in carbon capture and sequestration. CO2 EOR provides a value-added opportunity to increase crude-oil production while sequestering substantial volumes of industrial CO2. An analysis was conducted to determine the incremental domestic production that could be realized if industrially produced CO2 were available for EOR. Challenges include available volumes of CO2, infrastructure requirements, and prices of the CO2. US Consumption 20.74 Imports 15 12.11 58% includes finished products 10 9.65 8.63 US Production 5 18.00 65% includes finished products (Includes crude, NGLs, and refinery gains) 2004 0 1975 1980 1985 1990 1995 2000 2005 2010 2015 2020 2025 2030 Source: US DOE EIA “Annual Energy Outlook 2006”. Fig. 1—US consumption and demand projections. NGLs = natural-gas liquids. didates for CO2-miscible flooding. Fig. 2 shows the reservoirs that were identified on the basis of the following criteria. • Gravity greater than 22°API • Reservoir pressure greater than the minimum miscibility pressure • Depth greater than 2,500 ft • Oil viscosity less than 10 cp • Current oil saturation greater than 20% • Either sandstone or carbonate rock Technology CO2-EOR technologies have been demonstrated to be profitable in commercial-scale applications for nearly 30 years. As of 2006, 80 CO2-EOR projects in the US had a combined production of 234,000 BOPD. Ten of these projects were started between 2004 and 2006. Of the projects active in 2006, 58 are in the Permian Basin. The reason is partly because of the prevalence of candidate reservoirs in that region, and because of the steady availability of natural CO2. Natural Sources of CO2 The US produces approximately 3 Bcf/D of CO2 from natural sources in the Permian Basin, Colorado, and Mississippi, as well from an ammonia plant in Oklahoma. Of the available CO2, 78% is sent to the Permian Basin. The rest is available in the Gulf Coast of Louisiana, in Colorado, and in Wyoming. The CO2 produced at the Great Plains Coal-Gasification Plant in North Dakota is sold to the Weyburn project in Canada and was not considered for this analysis. Industrial Sources of CO2 Currently, there are a few plants, including a Texas gas plant and an Oklahoma fertilizer plant, that provide CO2 for EOR. These existing sources are listed in the natural-source category. For this study, other existing industrial sources were examined to determine the additional volume of CO2 that could be provided to EOR projects in the US. The primary source of emission data for this analysis was the National For a limited time, the full-length paper is available free to SPE members at www.spe.org/jpt. JPT • JANUARY 2009 55 Fig. 2—US candidate CO2-EOR fields. Ethanol plants Plants >> 50 50 Bcf/yr Bcf/Yr Ethanol plants > 1 Bcf/yr Refineries Ammonia plants Cement plants Hydrogen plants Fossil-fuel power plants Fig. 3—Industrial sources of CO2. Fig. 4—Mapping industrial sources to the candidate fields. 56 Carbon Sequestration Database and Geographic Information System, funded by the National Energy Technology Laboratory and maintained by the Kansas Geological Survey. The database provides source data for 56.5 Tcf of industrial CO2 emissions. Sources considered include fossil-fuel power plants, refineries, cement plants, hydrogen plants, ammonia plants, and ethanol plants. These sources were screened initially according to their proximity to candidate EOR fields. The fossil-fuel power plants were further screened according to the emission volume. Fig. 3 shows the industrial sources considered in the study. Fossil-fuel power plants and refineries represent approximately 90% of the total CO2 emitted. However, CO2 emissions from ethanol plants are expected to grow steadily. Up to 25 Tcf of industrial CO2 can be made available each year through capture from these industrial sources. Determining Wellhead Costs for Industrial CO2 The wellhead cost for industrial sources of CO2 have two main components—capture and transportation. The transportation costs were assumed to be pipeline tariffs and were calculated as follows. (1) Maps of industrial sources and candidate fields were overlaid to define prospective geographic regions. (2) Average distances between the sources and fields were calculated for each type of industrial CO2. (3) A pipeline-tariff model was developed and used to calculate the minimum tariff required for each source. Fig. 4 shows the distances between four refineries and a large number of candidate fields in the midcontinent region. In this illustration, the tariff would be for an average distance of 158 miles. This procedure was applied to each geographic region and source of CO2. The capture costs are technology-specific and can vary drastically depending on the plant type. Total Volumes of CO2 Available Up to 26 Tcf of natural and industrial CO2 could be available. Fossil-fuel power plants and refineries represent approximately 90% of the total CO2 available. As a result, the east-coast region has an available CO2 volJPT • JANUARY 2009 1,400 6,000 5,000 1,000 4,000 800 3,000 600 2,000 400 1,000 200 0 2008 CO 2 Injection, MMcf/D Oil Production, million B/D 1,200 0 2012 2016 2020 2024 2028 Year Fig. 5—US onshore Lower-48-States crude-oil production and CO2 sequestration from additional CO2-flood projects. ume of approximately 14 Tcf/yr. The Gulf coast contains a large portion of the nations’ refineries, and thus produces approximately 5.5 Tcf/yr. The 1Tcf/yr of CO2 available in the southwest region comes predominantly from natural sources and Permian Basin refineries. Other significant sources of CO2 are the Rocky Mountains with more than 3 Tcf and the northern Great Plains with 1.2 Tcf. Total costs can be as low as USD 0.92/Mcf for ammonia and hydrogen plants, and as much as USD 3.22/Mcf for fossil-fuel power plants. Costs for ethanol plants can be as low as USD 0.99/Mcf, and CO2 emissions from ethanol plants are expected to grow steadily in the near future. While wellhead costs for all plant types fall within a wide range, technological improvements continue to yield significantly lower capture costs for newly built plants. Technology and market constraints prevent the total volumes of CO2 from becoming available immediately. Development of the CO2 market has three periods: technology R&D, infrastructure construction, and market acceptance. Capture technology is developed during the R&D phase, and no CO2 would be available during that time. During infrastructure development, the required capture equipment, pipelines, and compres- JPT • JANUARY 2009 sors are constructed, and no CO2 would be available. During the market-acceptance phase, the capture technology would be implemented and volumes of CO2 would become available. The maximum volume of CO2 available will be achieved when the maximum percentage of the industry that will adopt the technology does so. This point provides an upper limit on the volume of CO2 that will be available. With these assumptions, the industrial CO2 from more-concentrated sources, such as the ammonia, hydrogen, and ethanol plants, will become fully available after 14 years. The total volumes of CO2 from refineries and fossil-fuel power plants will become available after 21 years. Economics The economics of each project was evaluated with a detailed cash-flow model for all natural and industrial sources of CO2 at oil prices between USD 45/bbl and USD 60/bbl. The economically viable projects then were checked for availability of sufficient CO2 at a regional level. The leastexpensive sources of CO2 were considered first. Projects that could be supplied by a single source of CO2 for the life of the project were aggregated to the regional and national levels to determine the benefits of widespread CO2 EOR. Benefits of Additional CO2-Flooding Projects Fig. 5 shows US incremental-oil production and CO2 sequestration from additional CO2 projects. By 2030, an additional 1.2 million B/D of incremental production could be realized while approximately 5 Bcf/D of CO2 would be sequestered. The sequestered CO2 is the difference between the volume of CO2 injected and the volume of CO2 produced. The “twohump” shape of the CO2 curve is the result of additional CO2 from refineries and power plants becoming available after 2021 for additional projects. Most of the production will come from the southwest. However, additional production could be realized from all other regions, with the midcontinent, the northern Great Plains, and the west coast providing production of approximately 250,000 B/D. Conclusions Widespread use of industrial CO2 for EOR could increase the available volume of CO2 from 3 Bcf/D from natural sources to approximately 70 Bcf/D from a combination of natural and industrial sources. This CO2 would be available for the Permian Basin and for all other parts of the US. By providing a steady source of CO2, at prices between USD 1/Mcf and USD 3/Mcf, more than 200 CO2-EOR projects, with incremental production reaching 1.2 million B/D, could be realized. At the same time, these projects would provide the opportunity to sequester nearly 5 Bcf/D of CO2. Limitations This analysis has important limitations. • The availability of CO2 from industrial sources will depend on industry participation. • The analysis assumes that capture technologies will be successful and available for implementation within 3 to 6 years. • The analysis does not consider the competition between CO2 EOR and other EOR technologies. However, none of these limitations invalidate the results of this analysis if these results are viewed in terms of their intended purpose, which is an estimate of the upside potential of JPT CO2 EOR. 57
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