Q. J. R. Meteorol. Soc. (2003), 129, pp. 2719–2740 doi: 10.1256/qj.02.180 AIRS channel selection for CO2 and other trace-gas retrievals By CYRIL CREVOISIER¤ , ALAIN CHEDIN and NOELLE A. SCOTT IPSL, Laboratoire de Météorologie Dynamique, Ecole Polytechnique, France (Received 3 September 2002; revised 1 April 2003) S UMMARY New high-resolution infrared sounders, such as the National Aeronautics and Space Administration’s Aqua satellite Atmospheric Infrared Sounder (AIRS) or the European Meteorological Satellite systems, MetOp Infrared Atmospheric Sounding Instrument (IASI), are expected to improve our capability to monitor atmospheric carbon dioxide (CO2 ) and other trace-gas concentrations from space. As they present thousands of channels, the rst problem arising is the selection of a set of channels presenting the best properties to retrieve these concentrations. A new method, the Optimal Sensitivity Pro le (OSP) method, based on the study of the sensitivities of AIRS channels to variations in the vertical of the different atmospheric components, is proposed. It is then compared with two ‘classical’ methods based on the information content and the degrees of freedom for signal of the AIRS channels regarding CO2 . Applying the OSP method to a set of 82 representative atmospheric situations obtained from the 2311 situations of the Thermodynamic Initial Guess Retrieval (TIGR) dataset, divided into three air masses (tropical, temperate and polar), and using simulated AIRS observations, a global set of 43 channels, well covering the whole atmospheric column, is selected for CO2 retrieval. The OSP method is nally used to select channels for retrieval of atmospheric nitrous oxide (N2 O), carbon monoxide (CO) and methane (CH4 ) concentrations. K EYWORDS: Greenhouse-gas sensitivity 1. High-resolution infrared sounders Information content I NTRODUCTION Progress in both basic earth-system science and in managing the carbon cycle to mitigate climate change requires robust and veri able understanding of the current behaviour of the system (Schimel et al. 1995; IGBP 1998). Without knowledge of today’s carbon sources and sinks, including their spatial distribution and their variability in time, theoretical predictions of future levels cannot be veri ed. The atmosphere is a superb integrator of spatially and temporally varying surface uxes (Tans et al. 1990). The distribution of carbon dioxide (CO2 ) in the atmosphere and its time evolution can thus be used to quantify surface uxes (Rayner and O’Brien 2001). The feasibility of using satellite measurements to obtain the temporal and spatial variability of atmospheric CO2 concentration has been proven with existing, low-spectral-resolution instruments (Chédin et al. 2002a,b, and submitted to J. Geophys. Res.), with the National Oceanic and Atmospheric Administration’s Television Infrared Observation Satellite (TIROS-N) Operational Vertical Sounder (TOVS). New satellites such as the National Aeronautics and Space Administration’s (NASA) Terra, launched in December 1999, NASA’s SAGE-3 launched in December 2001, the European Space Agency’s Envisat, launched in March 2002, NASA’s Aqua, launched in May 2002, NASA’s Aura, scheduled for early 2004, or the European Meteorological Satellite systems’ MetOp scheduled for 2005, will y numerous instruments that should improve our capability to monitor CO2 and other trace gases from space. In particular, the advanced infrared sounders, Aqua’s Atmospheric Infrared Sounder (AIRS) and MetOp’s Infrared Atmospheric Sounding Instrument (IASI), will present thousands of channels (respectively 2378 and 8461), covering most of the infrared spectrum. Using all the channels to retrieve CO2 or any other trace gas is of course prohibitive in terms of operational cost and unnecessary as only a small part of these channels is sensitive to the gases. Therefore, the rst problem arising is the ¤ Corresponding author: Laboratoire de Météorologie Dynamique, Ecole Polytechnique, 91128 Palaiseau Cedex, France. e-mail: [email protected] ue.fr c Royal Meteorological Society, 2003. ° 2719 2720 C. CREVOISIER et al. choice of a set of channels presenting the best properties regarding the retrieval of each trace gas. To reach this goal, different methods can be used. First, following Chédin et al. (1999, 2003), we can study the sensitivity of the channels to trace gases and other atmospheric and surface thermodynamic components. This leads to the Optimal Sensitivity Pro le (OSP) method presented here. Another way to select channels is to make a study of the information, de ned by a given gure of merit, brought by each channel. Two gures of merit will be used in the following: the Shannon information content (IC) and the degrees of freedom for signal (DFS), the latter being a measure of the number of statistically independent quantities of any one measurement. Most articles published on the selection of individual channels are based on objective criteria (Rodgers 1996; Lerner et al. 2002; Rabier et al. 2002). However, they all deal with temperature and humidity. We propose here to extend these methods to the study of CO2 and other trace gases. We will use simulated AIRS data computed from a set of representative atmospheric conditions obtained from the Thermodynamic Initial Guess Retrieval (TIGR) climatological dataset (Chédin et al. 1985; Chevallier et al. 1998). Data and models are described in section 2. The three methods used to select channels for CO2 retrieval are presented in section 3 (OSP method) and in section 4 (methods based on information study). Section 5 intercompares the sets of channels obtained. Section 6 presents the channels selected for the retrieval of other trace gases. Section 7 presents the conclusions. 2. DATA AND MODELS Only two spectral bands are of interest for CO2 study: the band from 650 cm¡1 to 810 cm¡1 (hereafter referred to as the 15 ¹m band) and the band from 2150 cm¡1 to 2450 cm¡1 (hereafter referred to as the 4.3 ¹m band). The 10 ¹m band will not be considered as the CO 2 signal obtained in these regions is too weak and well below the ozone signal. For AIRS, this leads to the study of 775 channels with a spectral resolution of º=±º D 1200 (497 channels in the 15 ¹m band with a spectral resolution of about 0.5 cm¡1 and 278 channels in the 4.3 ¹m band with a resolution of 2 cm¡1 ). In the 15 ¹m band, two other gases are active (water (H2 O) and ozone (O 3 )) while, in the 4.3 ¹m band, three other gases are active (H2 O, nitrous oxide (N2 O) and carbon monoxide (CO)). Our study is based on the 2311 atmospheric situations of the TIGR dataset. These 2311 situations were clustered into 82 classes, the respective means of which are enough to represent the dynamics of the atmospheric variables considered here with a lower computing cost. The 82 resulting situations can nally be classi ed into three types of air mass: tropical (28 situations), temperate (27) and polar (27). Each situation is described by its temperature, water-vapour and ozone atmospheric pro les, the atmosphere being divided into 40 pressure levels, regularly spaced (Chevallier et al. 1998). For each atmospheric situation and for each AIRS channel, we have computed the brightness temperatures which would be seen by AIRS, assuming a cloud-free scene, and the Jacobians (partial derivative of the channel brightness temperature with respect to a layer physical variable such as a gas mixing ratio, a temperature or the emissivity). This was done using the Automatized Atmospheric Absorption Atlas (4A) line-by-line radiative-transfer model (Scott and Chédin 1981) in its latest version 2000 with up-to-date spectroscopy from the ‘Gestion et Etudes des Informations Spectroscopiques Atmospheriques (GEISA): Management and Study of Atmospheric Spectroscopic Information’ (Jacquinet-Husson et al. 1999), with the option of allowing AIRS CHANNEL SELECTION FOR CO2 RETRIEVAL 2721 the Jacobians to be computed analytically (Chéruy et al. 1995). Concentrations of trace gases were assumed to be constant. For CO 2 , N2 O, CO, and CH4 , we assumed concentrations equal to 372 ppmv, 324 ppbv, 100 ppbv and 1800 ppbv, respectively. These are the predicted concentration values for the year 2003 (IPCC 2001). For each situation and each AIRS channel, we have also computed the noise due to the instrument, using the following equation @B .Tref / NE1T fT .º/g D NE1T fTref .º/g @T @B fT .º/g @T (1) where NE1T fT .º/g is the equivalent noise temperature taken at the brightness temperature T .º/ of the channel located at frequency º, and B is the radiance. The reference noise corresponding to a reference temperature Tref of 250 K was provided to us by the AIRS science team. 3. T HE O PTIMAL S ENSITIVITY P ROFILE METHOD To be selected, a channel has to present the best potential to detect CO2 changes from the top-of-the-atmosphere radiance measurements (the ‘signal’) and has to present the lowest possible sensitivity to other gases or thermodynamic variables of the atmosphere (the ‘noise’). Therefore, one way to select channels is to study their sensitivities to different components and then to select the channels presenting the highest ‘signal’to-‘noise’ ratio. (a) Sensitivity studies for AIRS channels The response of a given channel to the perturbation of a relevant atmospheric component (gas, surface characteristics, . . . ) may be obtained by the product, pressure layer by pressure layer, of the component Jacobian and the perturbation pro le. For CO2 we chose to perturb the pro le by half the value of the mean peak-to-peak amplitude of the seasonal CO2 cycle. This is 4 ppmv for tropical situations and 9 ppmv for temperate and polar situations (Conway et al. 1994). The corresponding signal obtained in the CO2 bands is shown in Fig. 1(a) for the 15 ¹m band and in Fig. 2(a) for the 4.3 ¹m band, for a representative tropical pro le. The signal is of the same level in the two bands. It should be noted that IASI measurements will present a higher resolution, under 0.5 cm¡1 unapodized throughout the whole spectrum, in the 4.3 ¹m band (see for example Chédin et al. 2002b). In both bands, some regions present negative signals (around 650 cm¡1 or 2350 cm¡1 ). They are regions where the channels essentially look in the stratosphere. By contrast, channels located in regions presenting a positive signal essentially look in the troposphere. This can be con rmed by the study of the CO2 Jacobians (not shown). Indeed, each channel favours that part of the atmosphere where the corresponding Jacobian is the most important. A channel whose Jacobian is more important in the troposphere (stratosphere) will be referred to as a ‘tropospheric’ (‘stratospheric’) channel. Another difference with IASI is AIRS instrument noise, plotted as dotted line on Figs. 1(a) and 2(a). It has the same level in both bands whereas, for IASI, the noise is greater in the 4.3 ¹m band (results from laboratory experiments). A plot showing the noise at a given temperature can be found on the website of the AIRS team (http://www.airs.jpl.nasa.gov/, April 2003). 2722 C. CREVOISIER et al. (b) 0.8 0.8 0.6 0.6 0.4 TB (K) TB (K) (a) Noise 0.2 H O 0.4 0.2 0 0 CO 0.2 f 650 700 2 750 0.2 f 650 800 1 f 800 1 f (c) (d) 0.8 O 3 0.4 0.2 0.2 0 0 700 Surface T 0.6 TB (K) TB (K) 750 wave number (cm ) 0.4 0.2 f 650 700 wave number (cm ) 0.8 0.6 2 750 800 1 f wave number (cm ) 0.2 f 650 Emissivity 700 750 800 1 f wave number (cm ) Figure 1. Atmospheric Infrared Sounder (AIRS) channel sensitivities to (a) CO2 for a 4 ppmv perturbation, (b) H2 O, (c) O3 , and (d) surface characteristics for the 15 ¹m band and a representative tropical situation. For water vapour, we assume the pro le to be known to within an uncertainty given by the mean error in the background model elds (from a 6-hour forecast) of the European Centre for Medium-Range Weather Forecasts (ECMWF) for each latitude band. This represents the background error assumed in the retrieval/assimilation schemes. These errors were taken from the 1999 version of the ECMWF model analysis system (Derber and Bouttier 1999). It is likely that future developments in data assimilation systems, numerical weather-prediction model formulation, and increased use of satellite data will reduce these errors, so those assumed here are an upper limit. The signal obtained is shown in Figs. 1(b) and 2(b). Surface temperature and emissivity are supposed to be known to within 1 K and 0.01, respectively. These values are the expected retrieval errors (see Chédin et al. 2002b). The signals are shown in Figs. 1(d) and 2(d). For the three remaining gases, in the same way as for CO2 , the perturbations are assumed to be constant and equal to 20% for O3 , 2% for N2 O and 40% for CO (IPCC 2001). The signals are plotted in Figs. 1(c) and 2(c). In the following, we will not consider the sensitivity of the channels to temperature. Indeed, although the channels sensitive to CO2 are, as any other channel, rst sensitive to temperature, the effect of CO2 variations is likely to be a bias, whereas the signal from the perturbed temperature pro le is in general expected to be randomly distributed over a reasonable time period (about two weeks) and should, therefore, average out when 2723 AIRS CHANNEL SELECTION FOR CO2 RETRIEVAL (a) (b) 0.8 0.8 0.6 Noise B 0.4 T (K) B T (K) 0.6 0.2 H O 2 0.4 0.2 0 0 CO 2 f.2 0 2150 2200 2250 2300 2350 2400 2450 f.2 0 2150 2200 2250 2300 2350 2400 2450 1 f 1 f wave number (cm ) wave number (cm ) (c) (d) CO 0.8 2 B 0.4 0.6 N O T (K) B T (K) 0.6 0.8 0.2 0.2 0 0 f.2 0 2150 2200 2250 2300 2350 2400 2450 1 f wave number (cm ) Surface T 0.4 Emissivity f.2 0 2150 2200 2250 2300 2350 2400 2450 1 f wave number (cm ) Figure 2. Atmospheric Infrared Sounder (AIRS) channel sensitivities to (a) CO2 , (b) H2 O, (c) N2 O and CO, and (d) surface characteristics for the 4.3 ¹m band and for the same representative tropical situation as Fig. 1. a large sample of radiances is considered (Chédin et al. 2002b). However, there are conditions where the temperature errors in the model and CO2 errors may be correlated and this will need to be studied in more detail with in situ data. (b) General scheme of the Optimal Sensitivity Pro le method Figures 1 and 2 show several ‘window’ regions around 700 cm¡1 or 2300 cm¡1 where the CO2 signal is greater than the signals due to other components, these will be called ‘interference’ signals in the following. So the rst criterion for selecting channels is to study the ratio of the CO2 signal to the sum of the interference signals, hereafter referred to as the STI ratio (for signal-to-interference ratio). High STI values, up to 2000, may come from very low interference values, which is the case for the ‘stratospheric’ regions (around 2350 cm¡1 , for example) whereas, in the ‘tropospheric’ regions (around 770 cm¡1 , for example), it can be as low as 0.01. This is due to the fact that either water vapour, surface characteristics, or other gases like N2 O or CO, essentially affect the tropospheric channels. However, low interference values may also result in large STI values even if the CO2 signal is low. As a consequence, a second criterion has to be introduced: the value of the numerator, the CO2 signal, must be greater than a xed threshold, here taken equal to 0.05 K. This value was chosen to avoid selecting too many channels, considering the perturbation values used. 2724 C. CREVOISIER et al. As the STI ratio is a quantity integrating the whole atmospheric column, using it as the only consideration could lead to selecting channels regardless of the region of the atmosphere they are observing. For that reason, a third criterion, using weighting functions (Smith et al. 1979), is introduced. Based on the consideration of the layer observed by each channel (determined by the peak of the CO2 Jacobian associated with the atmosphere considered), it leads to the separate examination of all the channels peaking at a given layer. Summarizing, three criteria are used to select channels: the STI ratio, the signal due to CO2 , and the altitude of the maximum of the Jacobians. For each layer of a given atmosphere, the channels for which the CO 2 Jacobian is maximum are rst selected; then the STI ratio is computed, and the channels for which both the signal due to CO2 and the STI ratio are too low are eliminated; and then the remaining channels are ordered, the rst one being the one which presents the highest STI. Finally, for each layer, channels with an STI ten times as small as the STI of the rst channel selected in the layer are rejected. We applied the method to each of the 82 atmospheres presented in section 2. For each of them, the order of selection of the channels is of course different. To arrive at a single set of channels, to be used whatever the atmospheric situation is, a weight is given to all the channels for each atmosphere, the maximum weight, equal to n if n is the total number of channels, being given to the rst channel selected in each layer. For the second channel selected, the weight is n ¡ 1, and so on. Then, for each layer the channels are ordered by the average of their weights. This can be done for all the situations taken together or divided into three air masses, the latter allowing the study of the differences that may appear between them. (c) Results We rst present the results obtained with the 28 tropical atmospheric situations. The corresponding ‘tropical set’ is made up of 74 channels. Figure 3 shows the spectral location of these channels. Figure 4 illustrates the three criteria of the OSP method for each channel, ordered according to their wave number. The channels are located equally in the two CO2 bands (37 each). In addition, the channels cover both the stratospheric and the tropospheric regions. However, the number of tropospheric channels is more important: 56 channels are tropospheric whereas 18 are stratospheric. To explain this phenomenon, the CO 2 Jacobians of these channels are shown in Fig. 5. Almost all the stratospheric channels observe a large part of the stratosphere, with large overlaps. Their CO2 Jacobians are quite thick: they peak at different pressure levels and extend from about 0.5 hPa to the tropopause (see for example the channels located around 670 cm¡1 , labelled 1 to 6 in Fig. 4). By contrast, the Jacobians of the tropospheric channels are thinner (see for example the channels selected around 2400 cm¡1 , labelled 68 to 74 in Fig. 4). Therefore, more channels are needed to cover the whole troposphere than the whole stratosphere. Moreover, the lower troposphere (roughly below 700 hPa) and the tropopause are out of reach. This is the case for all the channels located in the two CO2 bands. Indeed, for the lower troposphere, an increase of CO2 decreases the emission by the surface and increases the emission by the atmosphere: the two terms compensate one another. On the other hand, a channel peaking around the tropopause generally mixes two parts of the temperature pro le, one with a positive slope and one with a negative slope. Once again, an increase of CO2 gives two signals compensating one another. 2725 AIRS CHANNEL SELECTION FOR CO2 RETRIEVAL 0.4 0.3 B T (K) 0.2 0.1 0 0 .1 f 0 .2 f 650 700 750 800 2200 2250 wave number (cm 1f) 2300 2350 2400 2450 Figure 3. Spectral location of the 74 channels of the tropical set obtained with the Optimal Sensitivity Pro le (OSP) method and response to a 4 ppmv perturbation of the CO2 pro le for a representative tropical situation. (a) ©TB(CO 2) (K) 0.4 0.2 0 0.2 0 10 20 30 0 10 20 30 0 10 20 30 (b) 40 50 60 70 40 50 60 70 50 60 70 2 STI 10 0 10 10 2 0 (c) Pressure (hPa) 10 1 10 2 10 3 10 40 channel number Figure 4. Illustration of the three criteria for the 74 channels of the tropical set (28 situations) obtained with the Optimal Sensitivity Pro le (OSP) method: (a) the CO2 signal, (b) the signal-to-noise ratio, (c) the pressure of the maximum of the CO2 Jacobians. 2726 C. CREVOISIER et al. (a) 1f Pressure (hPa) 10 10 0 10 1 10 2 10 3 1 0 800 1 f 750 x 10 2 f 700 3 f 650 4 Normalized CO Jacobians wave number (cm 1 ) f 2 (b) 10 1 f 0 Pressure (hPa) 10 1 10 2 10 3 10 2400 1 0 2350 1 f 2300 2200 wave number (cm f1) Figure 5. 4 2 f 2250 3 f x 10 Normalized CO Jacobians 2 The 74 CO2 Jacobians of the tropical set obtained with the Optimal Sensitivity Pro le (OSP) method for (a) the 15 ¹m band and (b) the 4.3 ¹m band. AIRS CHANNEL SELECTION FOR CO2 RETRIEVAL TABLE 1. AIR MASS 2727 N UMBER OF SELECTED CH ANNELS FO R THE THREE TYPES OF (Tr D TRO PI CAL, Te D TEMPERATE, Po D POLA R ) AND NUMBER OF CH ANNELS IN CO MMON BETWEEN THE THREE SUBSET S Two bands 15 ¹m band 4.3 ¹m band No. of channels Channels in common between the subsets Tr Te Po Tr/Te Tr/Po Te/Po Tr/Te/Po 74 37 37 69 34 35 73 43 30 53 22 31 50 24 26 56 30 26 42 19 23 Figure 4(b) shows the STI ratio, for all the channels selected. As expected, the STI ratio takes higher values for the stratospheric channels, indicating that they are essentially sensitive to CO 2 and not to other atmospheric components. In the troposphere, lower STI values may be compensated for by the selection of more channels in each layer. We now compare the results obtained for the 82 situations clustered into three air masses: tropical, temperate and polar. Table 1 shows that the number of selected channels is about 70 for each ‘air-mass subset’. More 15 ¹m channels are selected for the polar subset whereas channels are selected equally in both CO2 bands for the tropical and temperate subsets. This may be due to the lower tropopause for the polar situations resulting in more stratospheric levels. Now, the channels peaking in the new lower-stratospheric levels are located in the 15 ¹m band, whereas the channels located in the 4.3 ¹m band peak at higher levels. Therefore, more 15 ¹m channels are selected for the polar situations. Table 1 also gives the number of channels in common for two subsets (tropical/temperate, tropical/polar and temperate/polar) and for the three subsets taken together. For each pressure level, the rank of the channels ordered according to the STI is almost the same for the three air masses. The main difference between the three selections comes from the pressure levels seen by the channels. Indeed, as the altitude of the tropopause varies with the air mass, the channels selected for each level may also vary. In conclusion, according to the number of common channels shown in Table 1, a global set of 40–50 channels seems to be enough to characterize well the three types of air mass. 4. S TUDY OF AIRS CHANNELS CO 2 INFORMATION Another way to select channels with the aim of retrieving CO2 from space is based on the study of the information contained in the observations and measured by special gures of merit. Two such quantities are of interest: the CO2 information content (IC) of the channels (in the Shannon sense) and the number of degrees of freedom for CO2 signal (DFS). The information content of a measurement, a concept developed in the context of information theory by Shannon (Shannon and Weaver 1949), can be de ned as the factor by which knowledge of a given state is improved by making the measurement. It is a generalization of the concept of signal-to-noise ratio. The degrees of freedom for a signal in a measurement is the number of useful independent quantities there are in the measurement. Both methods are brie y described in the following. A more detailed description can be found in Rodgers (1996). 2728 C. CREVOISIER et al. (a) Method Let x be the state vector, y the observation vector. These vectors are linked by the radiative-transfer equation yD .x/ C ²M C ²F (2) where ²M and ²F are, respectively, the measurement error and the forward model error. Those errors are assumed to be Gaussian and unbiased with covariance matrices SM and SF . The global error covariance matrix is denoted S² D SM C SF . The prior estimate of x is represented by the background vector xa and its covariance error by Sa . Assuming the radiative-transfer equation to be weakly nonlinear, it can be simpli ed by .x/ D .xa / C H.x ¡ xa / (3) where H is the so-called Jacobian matrix. The retrieval b x in the sense of the posterior estimate of x has a Gaussian probability density function and, assuming that observation and background errors are Gaussian and unbiased, its covariance matrix is given by b S¡1 D S¡1 C HT S¡1 H: (4) a ² Following Rodgers (1996), a sequential approach is used to select the channels. First, the channel which best maximizes the gure of merit from the background state is selected. A new state, represented by a new covariance matrix obtained from that of the background and modi ed by the channel chosen, is then obtained. The next step is to select the channel which maximizes the gure of merit for this new state, and then to iterate the method until the desired number of channels is reached. Let us rst normalize the Jacobian matrix by the error covariance matrix. This gives the new matrix ¡1 K D S² 2 H: (5) Let us suppose i ¡ 1 channels have already been selected. The covariance matrix for this step is denoted b Si¡1 . Following Eq. (4), the new covariance matrix obtained for step i by selecting channel j is b S¡1 D b S¡1 C kj kT (6) i i¡1 j where kj is the vector linked to the j th channel, i.e. the j th row of K. To initiate the selection, the covariance matrix b S0 is the background one. The gain in information content is then given by Ij D 12 ln.jb Si¡1 j/ ¡ 12 ln.jb Si j/ (7) where jj stands for determinant, and the degrees of freedom for signal by dj D tr.b Si¡1 / ¡ tr.b Si /; (8) where tr./ stands for trace. These equations can be simpli ed as ln.1 C kTj b Si¡1 kj / .b Si¡1 ki /T .b Si¡1 ki / dj D : T b .1 C kj Si¡1 kj / Ij D 1 2 (9) (10) The channel selected at this step is the one that maximizes Ij (IC) or dj (DFS), j varying over all the channels not yet selected. AIRS CHANNEL SELECTION FOR CO2 RETRIEVAL 2729 (b) Study context x is now the atmospheric CO2 pro le. Water vapour, trace gases and surface characteristics are supposed to be known within some residual indetermination as we have seen in section 3. These are taken into account in the measurement error. We still restrict our study to the channels of the two CO 2 bands. The method is applied to the 82 atmospheric situations used in section 3. We assume the covariance matrix S² to be diagonal. The matrix SM takes into account the instrument noise and the interference. For each channel, the instrument noise is computed for the atmospheric situation studied. The ‘noise’ due to the residual indetermination of water vapour, trace gases and surface characteristics, is de ned as the root mean square of the perturbations in brightness temperature described in section 3. The forward-model error variance in SF is taken constant and equal to .0:2/2 K2 for all the channels. This representation of forward model noise is not realistic and attention needs to be paid to improving our knowledge of this error. Nevertheless, this value has been used in most publications (Rodgers 1996; Prunet et al. 1998). Unfortunately, the prior knowledge of CO2 is quite poor due to the scarcity of measurements that, however, indicate relatively constant values for CO 2 concentration in the troposphere and in the stratosphere. Therefore, we assume that the prior covariance matrix Sa has a constant variance taken equal to 102 ppmv2 for the stratosphere and the boundary layer, and equal to 82 ppmv2 for the troposphere. Larger values were taken for the stratosphere and the boundary layer, as CO2 concentration in these two parts of the atmosphere is expected to be harder to retrieve than in the troposphere. A correlation between the stratosphere and the troposphere, and between the troposphere and the boundary layer, is assumed, using a Gaussian correlation function with a scale length of about 10 km. This choice is discussed in section 5. These assumptions will be improved in the future with the rst results obtained from ongoing studies (aircraft campaigns, analysis of NOAA TOVS and AIRS data, etc.). We have checked that the values of the variances themselves did not affect the order of the selection. (c) Results (i) CO2 Shannon information content. Figure 6 shows the spectral location of the 775 channels and their rank in the IC selection, for a representative tropical situation chosen from among the 28. Among them, the channel labelled 1 in the ordinate and located at 2258.03 cm¡1 is the rst to be selected: it is the one which presents the largest gain in information from the background. After the selection of this channel, the covariance matrix is updated and then the IC of the remaining channels relative to this new state are computed. Selecting, for example, ten channels consists of retaining the rst ten highest vertical bars. This is very different from the OSP method. Now, channels are ordered by their IC, stratospheric and tropospheric channels mixed together. But the idea of ordering the channels level by level is lost. Creating a set of channels presenting the best properties regarding CO 2 retrieval is via the study of the gain in information from the background due to the selection of a few channels. Following the selection of, for example, ten channels, a new information spectrum can be computed. To see the gain in information, Fig. 7 plots the difference between the initial information spectrum and the spectrum obtained after the selection, normalized by the initial spectrum (starred line). A gain equal to 1 for a channel means that all the information content of the channel has been assimilated by the selection. The other curves show the gain in information obtained for the selection of 50 and 90 channels. The gain in information obtained with the rst 50 channels selected is 2730 C. CREVOISIER et al. 1 100 150 200 250 300 350 400 450 500 550 600 650 700 750 775 650 700 750 800 2200 2250 2300 2350 2400 2450 1 wave number (cm ) Figure 6. Rank of Atmospheric Infrared Sounder (AIRS) channels in the information-content selection for the tropical set. 1 0.9 0.8 Gain in information 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 650 700 750 800 2200 2250 wave number (cm 1) 2300 2350 2400 2450 Figure 7. Gain in information for a representative tropical atmospheric situation after the selection of 10 channels (starred line), 50 channels (dashed line) and 90 channels (solid line) using the information-content method. 2731 AIRS CHANNEL SELECTION FOR CO2 RETRIEVAL Pressure (hPa) 10 1 f 10 0 10 1 10 2 10 3 3 f 2 f.5 2 f 1.5 1 0.5 f f f Normalized CO Jacobians 2 Figure 8. 0 0.5 1 4 x 10 CO2 Jacobians of the rst 40 channels selected with the information-content method for a representative tropical situation. important. But the increase in information when going from 50 (dashed line) to 90 (solid line) channels is smaller. Thus, selecting a reduced set of channels is enough to get most of the information content of the whole set of channels. The rst channels selected are located in the two CO 2 bands and, more precisely, in three restrictive domains: one centred at 2380 cm¡1 , the second at 2250 cm¡1 and the third at 700 cm¡1 (see Fig. 6). These three regions correspond to tropospheric channels. So, if we stop the selection at ten channels, information from the stratosphere will not be taken into account. This is con rmed by Fig. 7 (starred line): when only ten channels are selected, the gain in information in the stratospheric parts of the spectrum is nil. The selection of the rst stratospheric channel occurs after 11 iterations. Then, the channels next selected are of both kinds. Therefore, according to the IC method, few stratospheric channels are needed to get most of the information from the stratosphere, whereas more tropospheric channels are needed for the troposphere. To see which part of the atmosphere is seen by the rst 40 selected channels, their CO2 Jacobians are plotted in Fig. 8 for the representative tropical atmosphere. As already pointed out with the OSP method, almost all the atmosphere is seen with two exceptions, the lower part of the troposphere (from 700 hPa to the surface) and the tropopause. The Jacobians of the rst selected channels are the lowest, thinnest ones. The stratospheric ones cover almost the same large part of the stratosphere, with large overlaps, and peak at the same level. The results given above hold for the three air masses (tropical, temperate and polar). However, as for the OSP method (see section 3(c)), more 15 ¹m channels are selected rst for the polar situations. 2732 C. CREVOISIER et al. Pressure (hPa) 10 1 f 10 0 10 1 10 2 10 3 3 f 2 f.5 2 f 1.5 1 0.5 f f f Normalized CO Jacobians 0 0.5 2 Figure 9. 1 4 x 10 CO2 Jacobians of the rst 40 channels selected with the degrees of freedom for signal (DFS) method for the representative tropical situation. (ii) Degrees of freedom for CO2 signal. Once again, the rst channels selected are located in the two CO2 bands, in restricted domains close to the ones obtained with the IC method. The main difference comes from the channels selected in the stratospheric regions: the channels located around 2300 cm¡1 and, to a lesser extent, around 675 cm¡1 are part of the rst channels selected. Now, if we stop the selection at ten channels, information from the stratosphere is taken into account via three channels. This is con rmed by the study of the CO2 Jacobians of the rst 40 selected channels which are shown in Fig. 9 for the representative tropical situation. As expected, they cover the whole atmosphere better than the IC method, especially the stratosphere with channels peaking at different levels. This better coverage of the levels is due to the gure of merit considered here. The method is constructed to measure the number of degrees of freedom existing per level and then to nd the number of useful independent quantities there are per level in the measurement made with each channel. Hence, this method is closer to the OSP method, whose aim is to select the optimal channel for each level, compared with the IC method whose aim is to maximize the total information content regardless of the levels. 5. C OMPARISON BETWEEN THE OSP AND DFS METHODS To compare the OSP and the DFS methods for AIRS channel selection, they are now applied to each atmospheric situation divided into three air masses, providing six subsets of channels (two tropical, two temperate and two polar) which are now compared. The comparison is essentially made between the OSP method and the DFS method as we have seen that they are the closest ones in principle. 2733 AIRS CHANNEL SELECTION FOR CO2 RETRIEVAL 0 10 1 Pressure (hPa) 10 2 10 3 10 10 3 10 2 1 10 STI/STI(OSP) 0 10 1 10 Figure 10. Pressure layers covered by the Atmospheric Infrared Sounder (AIRS) channels (dashed lines). Also shown is the highest signal-to-interference (STI) ratio reached in each level divided by the highest STI ratio that can be reached, for an 18-channel Optimal Sensitivity Pro le (OSP) selection (open circles) and an 18-channel degrees of freedom for signal (DFS) selection (stars). First, the sets obtained by the two methods present similar characteristics. They are made of channels selected in the two CO2 bands. For the tropical and temperate subsets, the number of channels selected in each band is almost the same. For the polar subset, more stratospheric channels are selected in the 15 ¹m band than in the 4.3 ¹m band. However, a major difference concerns the way each method covers the atmospheric column. Figure 10 shows the 18 pressure levels seen by the channels (dashed lines). The rst 18 OSP selected channels cover these 18 pressure levels, one channel per level, and present the best STI that can be reached (dashed lines with open circles). By contrast, the 18 rst channels selected by the DFS method only cover nine levels, shown by the starred dashed lines. The stratosphere is not well covered by these channels (three levels covered out of six) and some levels are lacking in the troposphere. The position of the star gives, for each level covered by the rst 18 DFS channels, the value of the highest STI ratio reached by these channels divided by the highest STI ratio that can be reached (given, by de nition, by the OSP method). For ve levels (two stratospheric and three tropospheric), the STI are equal, showing that the same channels have been selected by the two methods. But elsewhere, the STI ratios are not optimal for the channels selected by the DFS method, a low STI ratio indicating that the channel is more sensitive to other signals (H2 O, N2 O, etc.). This is the case for the IC method too, with even fewer levels covered in the stratosphere, as seen in Fig. 8. The lack of stratospheric channels resulting from the IC method could be due to the background covariance matrix Sa used. Indeed, the actual correlation between the stratosphere and the troposphere is unknown. Even if the order of the selection of 2734 C. CREVOISIER et al. the tropospheric channels taken alone and of the stratospheric channels taken alone is not affected by this correlation, the rank of the rst stratospheric channel selected may change. For example, when assuming a diagonal covariance matrix, the rst stratospheric channel is selected after 25 iterations whereas, with the covariance used in section 4, the same rst stratospheric channel is selected after only 11 iterations. Another point is the error covariance matrix S² used. A change in the correlation would change the selection for the tropospheric channels which are the only ones sensitive to other trace gases as can be seen when plotting their Jacobians (see section 6(b)). For the DFS method, the impact of the covariance is less important, as the selection tries to cover all the levels. For two 40-channel DFS selections, one with the correlation length used in section 4 and the other with a doubled length, 35 channels are in common and the rank of the channels selected is almost the same. The ve remaining channels are both tropospheric (three) and stratospheric (two). Finally, both IC and DFS methods more or less depend on the a priori information given by the background covariance matrix and the error covariance matrix. This information, which in uences the selection made, is not available for CO2 and the other trace gases. The OSP method only uses the known values of the typical variations of CO2 (to derive the sensitivities), and we have checked that these values are not at all critical for the selection. The OSP method considers each level individually and rejects channels looking in the troposphere and in the stratosphere at the same time (as such a case would result in a low CO2 signal). 6. A GLOBAL SET OF CHANNELS FOR CO2 AND OTHER TRACE - GAS RETRIEVALS OBTAINED USING THE OSP METHOD (a) A global set of channels for CO2 retrieval To create a single global set of AIRS channels that may be used for CO 2 atmospheric concentration retrieval, whatever the atmospheric situation is, we now use the three air-mass subsets obtained with the OSP method. From them, the channels presenting a high STI ratio simultaneously for the three types of air mass are kept. However, if, for a given level, a channel presenting a high STI ratio for only one type of air mass misses, it is added to the set, allowing some particularities of each air mass to be taken into account. The global set thus obtained is made up of 43 channels that are detailed in Table 2. Twenty-one are located in the 15 ¹m band and 22 in the 4.3 ¹m band. Thirty-three are tropospheric channels and ten stratospheric channels. Table 3 presents the number of channels, among the 43, taken into each air-mass subset. Twenty-seven channels are common to the three air-mass subsets. Other channels are associated with only one or two air masses (for example, channel 308 was only selected in the tropical set whereas channel 190 comes from the temperate and polar sets). Table 3 also gives the number of channels in common between the OSP subsets and the subsets provided by a 40-channel DFS selection. Because the OSP method selects channels that cover the stratosphere and the troposphere better, only 20 DFS channels are in the global set. The CO2 Jacobians of the 43 channels of the global set are shown in Fig. 11 for a representative tropical situation. They cover most of the atmosphere, with the exception of the boundary layer and the tropopause (see section 3). More CO2 channels could of course be selected by the OSP method to increase the signal (which only reaches a few tenths of a kelvin), but this could also lead to an increase in the noise, in particular spectroscopic, due to the increasing ‘pollution’ of the additional channels by other gases (H 2 O, O3 , etc.). The 43 channels of the global set are 2735 AIRS CHANNEL SELECTION FOR CO2 RETRIEVAL TABLE 2. T HE 43 ATMOSPH ERI C I NFRARED S OUNDER (AIRS) CHA NNELS OF THE GLOBA L SET PROV IDED BY THE O PTI MAL S ENSITIVITY P ROFILE ME THOD FOR CO 2 ATMOSPHERI C CON CENTRATION RETRI EVAL AIRS channel no. 62 77 79 151 156 172 173 175 180 185 190 193 213 218 239 248 250 251 308 309 318 Wave number (cm¡1 ) 664.43894 668.21233 668.71887 692.95488 694.32529 698.74834 699.02671 699.58412 700.98165 702.38492 703.79396 704.64216 710.35068 711.79259 717.91418 720.57056 721.16357 721.46045 738.08281 738.39350 741.20138 AIRS channel no. (s) (s) (s) (t) (t) (t) (t) (t) (t) (t) (t) (t) (t) (t) (t) (s) (t) (t) (t) (t) (t) Wave number (cm¡1 ) 1938 1939 1946 1947 1948 1958 1971 1973 1988 1995 2084 2085 2097 2098 2106 2107 2108 2109 2110 2111 2112 2113 2249.3488 2250.3105 2257.0651 2258.0332 2259.0022 2268.7365 2281.5134 2283.4915 2298.4335 2305.4713 2363.7251 2364.6821 2376.2284 2377.1958 2384.9638 2385.9384 2386.9139 2387.8901 2388.8672 2389.8451 2390.8238 2391.8033 (t) (t) (t) (t) (t) (t) (t) (t) (s) (s) (s) (s) (s) (s) (t) (t) (t) (t) (t) (t) (t) (t) (t) indicates a tropospheric channel and (s) a stratospheric channel. TABLE 3. O RIG IN OF THE 43 ATMO S PHERI C I NFRARED S OUNDER (AIRS) CH AN NELS OF THE GLOBA L SET Total 15 ¹m/4.3 ¹m Tropo/Strato In common Tr Te Po 37 16/21 27/10 34 14/20 26/8 33 14/19 24/9 26 22 28 The channels come from the tropical (Tr), temperate (Te) or Polar (Po) subsets, from the 15 ¹m or 4.3 ¹m bands, and peak in the troposphere (Tropo) or stratosphere (Strato). The last line gives the number of channels in common in the two subsets provided by the Optimal Sensitivity Pro le (OSP) and degrees of freedom for signal (DFS) methods. the most important channels that should be used in a retrieval procedure, according to the OSP method. These channels have recently been added to the National Environmental Satellite, Data, and Information System (NESDIS) restricted list of distributed AIRS channels. (b) OSP channel selection for other trace-gas retrievals The OSP method may also be used to select channels for the retrieval of other trace gases. We now focus particularly on N2 O, CO and CH4 . The best signals for N2 O can be found in the 4.3 ¹m band. In this region, CO is also active. The sensitivities of the corresponding AIRS channels are shown in Fig. 2(c), for a 2% perturbation of the N2 O pro le and for a 40% perturbation of the 2736 C. CREVOISIER et al. 10 1 f 0 Pressure (hPa) 10 1 10 2 10 3 10 3 f 2 f.5 2 f 1 1 0 f.5 f f.5 Normalized CO Jacobians 0 0.5 Figure 11. 1 4 x 10 2 CO2 Jacobians of the 43 Atmospheric Infrared Sounder (AIRS) channels of the global set. TABLE 4. ATMOSPH ERI C I NFRA RED S OUNDER (AIRS) CHA NNELS PROV IDED BY THE O PTI MAL S ENSI TIVITY P RO FI LE METHOD FOR N2 O, CO AND CH4 ATMOSPHERI C CON CENTRATION RETRIEVALS AIRS channel no. Wave number (cm ¡1 ) Gas AIRS channel no. Wave number (cm¡1 ) Gas 1883 1884 1897 1901 1917 1921 1923 1924 2197.91 2198.83 2210.85 2214.57 2229.59 2233.38 2235.27 2236.22 N2 O N2 O N2 O N2 O N2 O N2 O N2 O N2 O 1867 1869 1875 1877 1400 1401 1402 1403 2183.30 2185.12 2190.58 2192.41 1302.03 1302.61 1303.19 1303.77 CO CO CO CO CH4 CH4 CH4 CH4 CO pro le. Unfortunately, very few channels are sensitive to CO variations. Indeed, CO is essentially active around 2150 cm¡1 , which is at the limit of the 4.3 ¹m band covered by AIRS channels. However, despite their small number, the channels present a high sensitivity to N2 O and CO variations: the CO signal can be ve times as large as the CO2 one, due to the three sharp absorption lines that can be seen in Fig. 2, and may allow good retrievals. Applying the OSP method to the same set of atmospheric situations used for CO2 gives the eight channels for N2 O and four channels for CO that are detailed in Table 4. They are only tropospheric as shown by their corresponding Jacobians plotted in Figs. 12(a) and 12(b). IASI, which will cover the whole infrared spectrum, should in principle allow the most interesting channels for CO retrieval to be selected, but with a higher noise. 2737 10 1 10 2 (a) Pressure (hPa) Pressure (hPa) AIRS CHANNEL SELECTION FOR CO2 RETRIEVAL 3 10 2.5 f f 2 1.5 f 1 f 0.5 f 0 Normalized N2O Jacobians 0.5 x 10 10 1 10 2 10 3 (c) 3 2.5 1 10 2 10 3 5 x 10 6 (d) 2 1.5 1 CH 4 0.5 0 N2 O 1250 1300 1350 1400 Pressure (hPa) TB (K) 10 f5 1 10 f 5 f 0 Normalized CO Jacobians H O 2 f.5 0 1200 2 f0 7 (b) 1 f0 1 f wave number (cm ) 8 f 6 f 4 f 2 f Normalized CH Jacobians 4 0 x 10 6 Figure 12. For the representative tropical situation: (a) N2 O Jacobians for the eight channels selected in the 4.3 ¹m band by the Optimal Sensitivity Pro le (OSP) method, (b) same as (a) for CO, (c) Atmospheric Infrared Sounder (AIRS) channel sensitivities to CH4 , H2 O and N2 O in the 7 ¹m band, (d) CH4 Jacobians for the four channels selected in the 7 ¹m by the OSP method. The best signal for methane can be found in two parts of the infrared spectrum, the 7 ¹m and 3.3 ¹m bands. Only the rst region is covered by AIRS channels. The response of AIRS channels to a 10% perturbation of CH 4 is shown in Fig. 12(c), as are the responses to the perturbations of the H 2 O and N2 O pro les used in section 2. For most of the channels, the CH4 signal is below the H2 O signal. Thus, only four channels, detailed in Table 4, are selected by the OSP method. They are tropospheric as shown by their corresponding Jacobians plotted in Fig. 12(d). 7. C ONCLUSIONS In this paper, three methods for selecting AIRS channels with the purpose of retrieving CO2 concentration were presented. The new Optimal Sensitivity Pro le (OSP) method relies on the study, pressure level by pressure level, of the sensitivity of each channel to the variations of CO 2 atmospheric concentration compared with the sensitivities to other atmospheric components (gases, surface characteristics). The other two methods select channels by their information content or their degrees of freedom for signal, the latter being closer to the OSP method. These two methods assume a Gaussian behaviour of the variables and rely on the knowledge, unfortunately presently 2738 C. CREVOISIER et al. very limited, of the background and observation error covariance matrices. The OSP method only uses the known values of the typical range of variation of the gases. Concerning CO2 retrieval, all methods select channels in the two CO2 bands, centred at 15 ¹m and 4.3 ¹m. These channels cover the troposphere and stratosphere, with the exception of the tropopause and the lower troposphere. The OSP method provides channels that cover the stratosphere and the troposphere better, by selecting channels peaking at different levels. Applying the method to a set of representative atmospheric situations leads to the selection of a global set of 43 AIRS channels, well distributed along the atmospheric column, with a reduced sensitivity to other atmospheric components, that should be used to retrieve CO2 atmospheric concentration. A recent CO2 data assimilation study performed at ECMWF and based on the ECMWF background covariance with simulated AIRS data has indicated that the use of the 43 channels given by the OSP method indeed improved the CO2 retrieval compared with other channel selections carried out with respect to the information content of temperature, water vapour, and CO2 together. Such channel selections tend to favour the rst two variables, which have a much larger sensitivity signal in the observed radiances (R. J. Engelen, personal communication). The OSP method was extended to other trace gases (N2 O, CO and CH 4 ). As the 43 channels selected for CO2 retrieval, the resulting 16 channels have been added to the NESDIS restricted set of distributed AIRS channels. The OSP method can be applied to other high-resolution infrared sounders, such as the MetOp IASI instrument which will present more than 1500 channels in the two CO 2 bands. However, the results should be different because of the spectral resolution which is larger for IASI and the noise which is higher in the 4.3 ¹m band than the AIRS one. An important point, not taken into account in our study, is the role of clouds. All the atmospheric situations studied here were assumed to be cloud free. Nevertheless, well known techniques exist to detect clouds, making it possible to work under clear-sky conditions at the precise time of the satellite pass. However, in particular for low clouds, due to the relative sharpness of the CO2 Jacobians of the tropospheric channels and their good distribution within the troposphere, it should be possible to get information above the clouds. Another issue is the non-Local Thermodynamic Equilibrium (LTE) effects clearly identi ed on AIRS measurements in a number of 4.3 ¹m channels, which precludes the use of them during daytime. ACKNOWLEDGEMENTS This work was partly supported by the European project on measuring CO2 from space exploiting planned missions 2002–2004 (known as COCO). Calculations were performed using the resources of the Institut du Développement et des Ressources en Informatique Scienti que computing centre. The authors thank L. L. Strow for providing them with AIRS characteristics (spectral response function and noise), and ECMWF for data from their background model elds. 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