Uddingston Grammar School National 5 Chemistry Metals and Alloys Unit 3 sub-unit a. Homework 1 1. Which of the following diagrams could be used to represent the structure of a metal? 1KU 2. In the cell shown, electrons flow through A. B. C. D. The The The The solution from tin to zinc solution from zinc to tin connecting wire from tin to zinc connecting wire from zinc to tin. 1KU 3. Cu2+ + 2e- Cu 1KU This ion electron equation represents the A. B. C. D. Reduction of copper(II) ions Reduction of copper(I) ions Oxidation of copper(II) ions Oxidation of copper(I) ions 4. Which pair of metals, when connected in a cell, would give the highest voltage and a flow of electrons from X to Y? 1PS You may wish to use the data booklet to help you. A B C D Metal X Magnesium Copper Zinc Tin Metal Y Copper Magnesium Tin Zinc 5. Which of the following metals would react with zinc chloride solution? You may wish to use the data booklet to help you. A. B. C. D. Copper Gold Iron Magnesium 6. Metallic bonding is a force of attraction between A. B. C. D. 1KU Negative ions and positive ions A shared pair of electrons and two nuclei Positive ions and delocalised electrons Negative ions and delocalised electrons. 1KU 7. Four cells were made by joining copper, iron, magnesium and zinc to silver. Which of the following will be the voltage of the cell containing silver joined to copper? You may wish to use the data booklet to help you. 1PS A. B. C. D. 0.5 0.9 1.1 2.7 V V V V 8. In which of the following test tubes will a reaction occur? 1PS 9. The ion-electron equations for the oxidation and reduction steps in the reaction between sulphite ions and iron(III) ions are given below. 1K Oxidation H2O(l) + SO32-(aq) SO42-(aq) + 2H+(aq) + 2e- Reduction Fe3+(aq) + e- Fe2+(aq) The redox equation for the overall reaction is A. B. C. D. H2O(l) H2O(l) SO42-(aq) SO42-(aq) + SO32-(aq) + Fe3+(aq) SO42-(aq) + 2H+(aq) + Fe2+(aq) + e+ SO32-(aq) + 2Fe3+(aq) SO42-(aq) + 2H+(aq) + 2Fe2+(aq) + 2H+(aq) + Fe2+(aq) + e- H2O(l) + SO32-(aq) + Fe3+(aq) + 2H+(aq) + 2Fe2+(aq) H2O(l) + SO32-(aq) + 2Fe3+(aq) 10. Silver jewellery tarnishes in air. This is due to the formation of silver (I) sulphide. The silver (I) sulphide can be converted back to silver using the following apparatus. The equation for the reaction that takes place in the beaker is shown. 3Ag2S(aq) + 2Al(s) 6Ag(s) + Al2S3(aq) Calculate the mass, in grams, of silver produced when 0.135g of aluminium is used up. 3KU 11. Below is a call that contains both a metal and a non-metal electrode. The ion-electron equation for the reaction taking place at the carbon electrode is: I2(aq) + 2e- 2I-(aq) a) State the path and direction of electron flow. 1KU b) What term can be used to describe the reaction taking place at the carbon electrode? 1PS 12. Iron displaces silver (I) nitrate solution. The equation for the reaction is: Fe(s) + 2Ag+(aq) + 2NO3-(aq) Fe2+(aq) + 2Ag(s) + 2NO3-(aq) a) This reaction can be carried out in a cell. A B C State what the three labels, A, B and C should be b) What is the purpose of the ion bridge? 2PS 1KU 13. Chlorine can be produced commercially from concentrated sodium chloride solution in a membrane cell. Only sodium ions can pass through the membrane. These ions move in the direction shown in the diagram. a) Write the ion-electron equation for the change taking place at the positive electrode. You may wish to use the data booklet to help you. 1KU b) Name solution X. 1KU 14. Bauxite contains impurities such as silicon dioxide. Silicon can be extracted from silicon dioxide as shown. SiO2 + 2Mg Si + 2MgO Identify the reducing agent in this reaction. 20 Marks 1PS
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