11th Nanoscience and Nanotechnology Conference (NanoTR-11)
Ankara, Turkey. 22 -25 June, 2015
Catalytic Application of MOF, Mono/binuclear Manganese Complexes
Esra SU1*, Ibrahim KANI2
1
Department of Chemistry, Istanbul Technical University,
2
Department of Chemistry, Anadolu University,
*
Presenter: [email protected]
1. Introduction
Oxidation of organic compounds processes are
conducted on a large scale for the remediation of
pollutants, production of valuable chemicals, and the
production of energy.[1] Oxidation products, especially
acetophenone and cyclohexenone, which are a versatile
intermediate used in the synthesis of a variety of
chemical products such as pharmaceuticals and
fragrances.[2]
OH
O
O
CH3
2. Abstract
In this study, binuclear Mn(II) complexes with
anthralinic acid and phen/bipy ligands, [Mn2(µ-O2CAr2NH2-ph)2(bipy)2]2(ClO4), (1) and [Mn2(µ-O2CAr2-NH2ph)2(phen)2]2(ClO4)(CH3OH), (2) were synthesized and
characterized by X-ray crystallography, elemental
analysis, IR and UV-vis spectroscopy. The catalytic
oxidation activity on different substrates (ethyl benzene,
styrene, cyclohexene) was studied in optimum media
which was determined with former studies.
Keywords: Complex, crystallography, oxidation.
O
H
Total Conversion (%)
Figure 2 Oxidation pathway of styrene
Figures
100
90
80
70
60
50
40
30
20
10
0
Complex 1
Complex 2
0
100
Time (min.)
200
Figure 3 Conversion curve for cyclohexene
oxidation with complex 1 and 2
Figure 1 Molecular structure of complex 2
3. References
[1]
[2]
Wade, L.G. (2006). Organic Chemistry (6th ed.).
Pearson Prentice Hall. p. 279. ISBN 1-4058-5345X.
Podraze, K.F. Org. Prep. Proced. Int., 1991, 23, p.
217.
This work was supported by the Scientific Research Fund of TUBITAK Project Number: 113Z303 and 1406F390
Associazione Italiana di Tribologia (http://www.aitrib.it/)
2