Sec 8.3 A Chemical Bonding Pg 165 A. The Electronic Nature of Chemical Bonds 1. Electrostatic Force The force that results from the attraction or repulsion between 2 particles Based on 4 principles 1. opposite charges attract ( protons attract electrons) 2. like charges repel ( electrons repel electrons) 3. the greater the distance between the object the less force 4. the greater the charge on the object the greater the force 2. Atomic Radius As you move across the periodic table the atomic radius decreases - all of the electrons that are being added are added into the same orbital at approximately the same distance from the nucleus. - If 1 electron is added then1 proton is added and the electrostatic forces between the proton and electron will grow and the size of the atom will decrease. - Protons are 2000 times larger and more powerful than electrons. So the addition of 1 proton will greatly increase the electrostatic force in the atom. As you move down the periodic table the atomic radius increases - all of the electrons that are being added are added to different orbitals, so the atomic radius will increase. - Since the electrons are added in different orbitals, the distance between the electrons and protons is increasing and the electrostatic force will decrease. - If a lot of electrons are added in the same orbital, the negative charges of the electron will start to repel each other and the atomic radius will increase. 3. Valence Electrons cont. Open Shell – an orbital that is NOT full. Closed Shell – on orbital that is full. Can also be defined as: - electrons that are able to participate in bonding - electrons that are in OPEN shells - combining capacity If we ignore the transition metals Atom # of valence Electrons valence K 1 Ca 2 Ga 3 Ge 4 As 5 Se 6 Br 7 Kr 8 1 2 3 4 3 2 1 0 Why do you think that Kr has zero? 4. Ionization Energy - the energy required to remove an electron from a neutral atom. The electron removed is always on the outermost orbital. Small atoms will have a LARGE ELECTROSTATIC FORCE and a LARGE IONIZATION ENERGY. Large atoms will have a SMALL ELECTROSTATIC FORCE and a SMALL IONIZATION ENERGY. Sec 8.3 A Chemical Bonding Pg 165 A. The Electronic Nature of Chemical Bonds 1. Electrostatic Force The force that results from the attraction or repulsion between 2 particles Based on 4 principles 1. opposite charges attract ( protons attract electrons) 2. like charges repel ( electrons repel electrons) 3. the greater the distance between the object the less force 4. the greater the charge on the object the greater the force 2. Atomic Radius As you move across the periodic table the atomic radius decreases - all of the electrons that are being added are added into the same orbital at approximately the same distance from the nucleus. - If 1 electron is added then 1 proton is added and the electrostatic forces between the proton and electron will grow and the size of the atom will decrease. - Protons are 2000 times larger and more powerful than electrons. So the addition of 1 proton will greatly increase the electrostatic force in the atom. As you move down the periodic table the atomic radius increases - all of the electrons that are being added are added to different orbitals, so the atomic radius will increase. - Since the electrons are added in different orbitals, the distance between the electrons and protons is increasing and the electrostatic force will decrease. - If a lot of electrons are added in the same orbital, the negative charges of the electron will start to repel each other and the atomic radius will increase. 3. Valence Electrons cont. Open Shell – an orbital that is NOT full. Closed Shell – an orbital that is full. Can also be defined as: - electrons that are able to participate in bonding - electrons that are in OPEN shells - combining capacity If we ignore the transition metals Atom K Ca Ga Ge As Se Br Kr # of valence Electrons 1 2 3 4 5 6 7 8 Why do you think that Kr has zero? 4. Ionization Energy - the energy required to remove an electron from a neutral atom. The electron removed is always on the outermost orbital. Small atoms will have a LARGE ELECTROSTATIC FORCE and a LARGE IONIZATION ENERGY. Large atoms will have a SMALL ELECTROSTATIC FORCE and a SMALL IONIZATION ENERGY.
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