TRANSMITTAL Permits Section Air Quality Division Michigan Department of Environmental Quality Constitution Hall, 2nd Floor South 525 West Allegan Street Lansing, MI 48933-1502 Re: December 17, 2014 Permit to Install (PTI) Simple-Cycle CTG Project Alpine Power Plant, Elmira, Michigan Wolverine Power Supply Cooperative, Inc. FOR REVIEW FOR YOUR USE AS REQUESTED COPIES 2 DATE 12/15/2014 Project No. G090066NEW Sent By: John F. Caudell, PE/tc DESCRIPTION PTI Simple-Cycle CTG Project, Alpine Power Plant Elmira, Michigan COMMENTS Attached are two copies of the PTI Application. Also attached is the original signature PTI form, along with three copies of the form. If you have any questions or require additional information, please contact me at 517.887.4024 or [email protected]. By Hand Delivery cc/att: Mr. Brian Warner - Wolverine Power Supply Cooperative, Inc. (By FedEx) Ms. Jacquelyn F. Linck, PE - FTCH (By email) Z:\2009\090066NEW\REC\REPT\PTI_APP\TR_WP_PTI_APP_2014_1217_FNL.DOCX PERMIT TO INSTALL APPLICATION SIMPLE-CYCLE CTG PROJECT ALPINE POWER PLANT ELMIRA, MICHIGAN PREPARED FOR: WOLVERINE POWER SUPPLY COOPERATIVE, INC. CADILLAC, MICHIGAN DECEMBER 15, 2014 PROJECT NO. G090066NEW TABLE OF CONTENTS 1.0 INTRODUCTION ................................................................................................................................ 1 2.0 PROJECT DESCRIPTION ................................................................................................................. 2 3.0 REGULATORY REVIEW ................................................................................................................... 3 3.1 Michigan Regulations .............................................................................................................. 3 3.1.1 Air Pollution Control Rule 201 – PTI Requirements ................................................... 3 3.1.2 Air Pollution Control Rules 224 to 230 – T-BACT Requirement for New and Modified Sources of Air Toxics and Health-Based Screening Level Requirement for New or Modified Sources of Air Toxics.................................................................. 3 3.1.2.1 Air Pollution Control Rule 224 – T-BACT Requirement for New and Modified Source of Air Toxics – Exemptions ............................................... 3 3.1.2.2 Air Pollution Control Rule 225 – Predicted Maximum Impacts of TACs ...... 4 3.1.3 Air Pollution Control Rule 301 – Standards for Density of Emissions ........................ 4 3.1.4 Air Pollution Control Rule 331 – Emission of PM ....................................................... 5 3.1.5 Air Pollution Control Rule 371 – Fugitive Dust Emissions .......................................... 5 3.1.6 Air Pollution Control Rule 401 – Emission of SO2 from Fuel Burning Sources at Power Plants ............................................................................................................... 5 3.1.7 Air Pollution Control Rule 702 – VOC BACT .............................................................. 5 3.1.8 Air Pollution Control Rules 801 thru 834 – Emission of NOX ...................................... 6 3.1.9 Air Pollution Control Rules 901 thru 912..................................................................... 7 3.1.10 Air Pollution Control Rules – Part 18 (PSD) ............................................................... 7 3.2 Federal Regulations ................................................................................................................ 8 3.2.1 NAAQS – Attainment Status Considerations .............................................................. 8 3.2.2 40 CFR 52.21 – PSD .................................................................................................. 8 3.2.3 40 CFR 60 Subparts A, IIII and KKKK – NSPS .......................................................... 9 3.2.4 40 CFR 63 Subparts A, YYYY and ZZZZ – NESHAPs .............................................. 9 3.2.5 Cross-State Air Pollution Rule .................................................................................. 10 4.0 EMISSION CHARACTERISTICS ..................................................................................................... 11 4.1 NSR Regulated Pollutant Emissions ..................................................................................... 11 4.2 TAC and HAP Emissions ...................................................................................................... 12 5.0 CONTROL TECHNOLOGY SUMMARY .......................................................................................... 13 5.1 VOC BACT ............................................................................................................................ 13 5.1.2 New Emergency Generator ...................................................................................... 15 5.2 T-BACT.................................................................................................................................. 16 6.0 AIR QUALITY MODELING AND AIR TOXIC EVALUATION ........................................................... 18 6.1 Model Parameters ................................................................................................................. 18 6.1.1 Model Selection ........................................................................................................ 18 6.1.2 GEP Stack Height Analysis ...................................................................................... 19 6.1.3 Model Input Parameters............................................................................................ 19 6.2 Criteria Pollutant Modeling .................................................................................................... 20 6.2.1 Significant Impact Analysis and Results ................................................................... 20 6.2.2 PSD Increment and NAAQS Analyses ..................................................................... 21 6.3 Secondary PM2.5 Formation .................................................................................................. 22 6.3.1 Emission Profile and USEPA Guidance ................................................................... 22 6.3.2 Qualitative Analysis and Conclusions ....................................................................... 23 6.4 Secondary Ozone Formation ................................................................................................ 24 6.5 TAC Modeling ........................................................................................................................ 25 6.5.1 TAC Emission Rates and Results ............................................................................. 25 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX i TABLE OF CONTENTS 7.0 SUMMARY AND CONCLUSIONS ................................................................................................... 26 7.1 Proposed Emissions Control Technologies .......................................................................... 26 7.2 NESHAP Compliance ............................................................................................................ 26 7.3 NSPS Compliance ................................................................................................................. 26 7.4 Ambient Impacts .................................................................................................................... 27 7.5 Compliance Demonstrations and Monitoring ........................................................................ 27 LIST OF FIGURES Figure 1 Figure 2 Location Map Site Plan LIST OF TABLES Table 1 Table 2 Table 3 Table 4 Table 5 Table 6 Table 7 Table 8 Table 9 Table 10 Table 11 Table 12 Table 13 Table 14 Table 15 Table 16 Table 17 Table 18 Table 19 Table 20 Estimated CTG Potential NSR Regulated Pollutant Emissions Estimated CTG Startup and Shutdown NSR Regulated Pollutant Emissions Emergency RICE NSR Regulated Pollutant Estimated Emissions Estimated NSR Pollutant Emissions from Natural Gas Fired Fuel Heaters Project Related TAC and HAP Emissions Total NSR Regulated Pollutants VOC BACT Economic Calculations for Each CTG VOC BACT Economic Calculations for the Emergency Generator VOC BACT Economic Calculations for the Backup Fire Pump VOC BACT Economic Calculations for Each Fuel Heater Fabric Filter Economic Analysis for Each Fuel Gas Heater Structure Heights Model Input Parameters Hourly Average Stack Parameters per CTG SIL Model Results Summary PSD Increment Model Results Summary NAAQS Model Results Summary Illustrative Analysis of Possible Secondary PM2.5 Impacts Unitized Model Results Maximum PAI LIST OF APPENDICES Appendix 1 Appendix 2 CD Containing Modeling-Related File MDEQ Data Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX ii TABLE OF CONTENTS LIST OF ABBREVIATIONS/ACRONYMS AERMOD AQD BACT CAA CAIR CEMS CFR CH4 CO CO2 CO2e CPM CSAPR CTG EGU ⁰F FTCH GEP GHG GWP HAP HP HRSG hr/yr IRSL ITSL kWe lb/hr lb/MMBtu LRC MACT MDEQ MISO MMBtu/hr MWe MWh NAAQS NESHAP N2O NO2 NOx NSPS NSR O2 O3 PAH Pb PAI PM PM2.5 PM10 ppm ppmvd ppmw PSD American Meteorological Society/Environmental Protection Agency Regulatory Model Air Quality Division (of the Michigan Department of Environmental Quality) Best Available Control Technology Clean Air Act Clean Air Interstate Rule Continuous Emissions Monitoring System Code of Federal Regulations methane (a greenhouse gas) carbon monoxide carbon dioxide (a greenhouse gas) carbon dioxide equivalent (GHG mass emissions including their GWPs) condensable particulate matter Cross-State Air Pollution Rule combustion turbine generator electrical generating unit degrees Farhenheit Fishbeck, Thompson, Carr & Huber, Inc. Good Engineering Practice (as it relates to stack height) greenhouse gas global warming potential of GHGs hazardous air pollutant horsepower heat recovery steam generator hours per year Initial Risk Screening Level Initial Threshold Screening Level kilowatt (electric) pound(s) per hour pound(s) per million British thermal units per hour Lima Refining Company Maximum Achievable Control Technology Michigan Department of Environmental Quality Midcontinent Independent System Operator Million British thermal units per hour Megawatt (electric) Meagawatt hour National Ambient Air Quality Standards National Emission Standards for Hazardous Air Pollutants nitrous oxide (a greenhouse gas) nitrogen dioxide nitrogen oxides New Source Performance Standards New Source Review diatomic oxygen ozone polycyclic aromatic hydrocarbons elemental lead Predicted Ambient Impacts particulate matter Fine Particulate Matter less than 2.5 microns Particulate Matter less than 10 microns part(s) per million part(s) per million, by volume, dry basis part(s) per million, by weight Prevention of Significant Deterioration Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX iii TABLE OF CONTENTS PTE PTI PVMRM RH RICE SCR SER SIL SIP SNCR SO2 SS TAC T-BACT tpy µg/m³ USEPA VE VOC Wolverine potential to emit Permit to Install Plume Volume Molar Ratio Method relative humidity reciprocating internal combustion engine selective catalytic reduction significant emission rate Significant Impact Level State Implementation Plan Selective Noncatalytic Reduction System sulfur dioxide Startup and Shutdown toxic air contaminant Best Available Control Technology for Toxics ton(s) per year microgram(s) per cubic meter United States Environmental Protection Agency visible emissions volatile organic compound(s) Wolverine Power Supply Cooperative, Inc. Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX iv 1.0 INTRODUCTION Fishbeck, Thompson, Carr & Huber, Inc. (FTCH) has been retained by Wolverine Power Supply Cooperative, Inc. (Wolverine) to submit a Permit to Install (PTI) application for two gas-fired, simple-cycle combustion turbine generators (CTGs), a new diesel-fired emergency generator, a new diesel-fueled fire pump, and two new natural gas-fired fuel heaters at a Greenfield site located near Elmira, Michigan (west of the City of Gaylord, Michigan). The plant will generate electricity as required by the Midcontinent Independent System Operator (MISO) primarily during peak electric demand time periods. The new facility will be located near the east corner of M-32 and Flott Road in Elmira Township, Otsego County, Michigan. The site location is identified in Figure 1. This document contains the information necessary to demonstrate compliance with all currently applicable state and federal air quality requirements as they apply to the project. A description of the new project, proposed maximum operating scenarios, proposed emission rates, and all other required information to support this permit application are also included. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 1 2.0 PROJECT DESCRIPTION The project consists of installing the following process equipment (emission units): • Two new simple-cycle CTGs. Each CTG will be rated at a nominal 2,015 Million British thermal units per hour (MMBtu/hr) heat input and nominal 205.3 Megawatt (electric) [MWe] output at 100% load and 59⁰F, and 2,045 MMBtu/hr and 203.3 MWe output at an ambient temperature of 81⁰F. These new CTGs will only be capable of firing natural gas. Air pollution control technology for each CTG includes burner designs and modern combustion controls that will inherently minimize NOX, carbon monoxide (CO), volatile organic compound (VOC), particulate matter (PM), potential organic toxic air contaminants (TACs) and organic hazardous air pollutants (HAPs). Using natural gas fuel also limits potential condensable particulate matter (CPM) and greenhouse gas (GHG) due to the use of low sulfur and lower carbon content fuel. • A new diesel-fired emergency generator rated at 1,500 kilowatt (electric) [kWe] (approximately 2011 horse power [HP]) output for emergency electrical generation. The emergency generator’s annual operation will be limited to 100 hours per year (hr/yr). • A new diesel-fueled reciprocating internal combustion engine (RICE) Fire Pump, rated at 347 HP output for emergency backup operation will be installed in the event the normal electrically driven fire pump(s) be out of service for any reason (such as loss of electrical power). The backup fire pump’s operation will also be limited to 100 hr/yr. • Two new natural gas-fired indirectly heated CTG natural gas fuel heaters (1 per CTG). Each will be rated at a nominal 3.5 MMBtu/hr heat input. A site plan for the facility is presented in Figure 2. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 2 3.0 REGULATORY REVIEW 3.1 MICHIGAN REGULATIONS 3.1.1 AIR POLLUTION CONTROL RULE 201 – PTI REQUIREMENTS Any process or process equipment installed after August 15, 1967, which may emit an air contaminant requires a PTI prior to installation, construction, reconstruction, relocation, or modification, unless specifically exempt. The proposed new process equipment requires a PTI prior to commencement of physical onsite installation. 3.1.2 AIR POLLUTION CONTROL RULES 224 TO 230 – T-BACT REQUIREMENT FOR NEW AND MODIFIED SOURCES OF AIR TOXICS AND HEALTH-BASED SCREENING LEVEL REQUIREMENT FOR NEW OR MODIFIED SOURCES OF AIR TOXICS Rules 224 to 230, effective November 10, 1998, apply to any proposed, new, or modified process or process equipment for which an application for a PTI is required and which emits a TAC. A TAC is defined in Michigan rules as: . . . any air contaminant for which there is no National Ambient Air Quality Standard (NAAQS) and which is or may become harmful to public health or the environment when present in the outdoor atmosphere in sufficient quantities and duration. Rules 224 and 225 require emissions of TACs not exceed the following: ● Rule 224 – The maximum allowable emission rate that results from the application of Best Available Control Technology for Toxics (T-BACT). ● Rule 225 – The maximum allowable emission rate that results in a predicted maximum ambient impact above the Initial Threshold Screening Level (ITSL), the Initial Risk Screening Level (IRSL), or both. Compliance with T-BACT and health-based screening level requirements are presented later in this document. 3.1.2.1 AIR POLLUTION CONTROL RULE 224 – T-BACT REQUIREMENT FOR NEW AND MODIFIED SOURCE OF AIR TOXICS – EXEMPTIONS Pursuant to Rule 224(2)(c), the T-BACT requirements do not apply to emissions of PM and/or VOCs that comply with BACT or the Lowest Achieveable Emission Rate for PM and/or VOCs. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 3 Organic HAPs and TACs, along with CO, will be minimized by the use of modern combustion controls implemented on each new CTG and fuel heater. PM-bound toxics (such as trace metals) will be minimized by the use of natural gas fuel that does not contain trace metals. Each new RICE will have modern combustion technology to minimize the specific heat input rate and will use ultra low sulfur diesel fuel to minimize TACs. A T-BACT analysis is provided in Section 5, which also includes VOC BACT (Rule 702) analyses for all of the proposed emission units. 3.1.2.2 AIR POLLUTION CONTROL RULE 225 – PREDICTED MAXIMUM IMPACTS OF TACS Rule 225 requires the predicted maximum ambient impact from the emission of TACs from new and modified sources not exceed applicable health-based screening levels. The screening level for a TAC is the maximum allowable concentration in the ambient air, outside a reasonable barrier that prevents public access to the source’s property, averaged over a specified period of time (1 hour, 8 hour, 24 hour or annual averaging times). The concentration of a TAC is predicted using an air dispersion modeling computer program. A detailed emission modeling demonstration is included in Section 6.0 of this document and demonstrates compliance with Rule 225. 3.1.3 AIR POLLUTION CONTROL RULE 301 – STANDARDS FOR DENSITY OF EMISSIONS Rule 301 establishes limitations for the visible density of emissions. The proposed CTGs and emergency generator are not expected to have any effect on the ability to comply with the visible emissions (VE) limitations of Rule 301. Rule 301 limits VE as follows: ● A 6-minute average of 20% opacity, except for one 6-minute average per hour of not more than 27% opacity. ● A limit specified by an applicable federal Standard for the Performance of New Source Performance Standards (NSPS). ● A limit specified as a condition of a PTI or Permit to Operate. The use of natural gas fuel and modern combustion controls for each CTG and fuel heaters, and using ultra low sulfur diesel fuel in the emergency generator and backup fire pump as well as modern 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 4 combustion controls in all combustion devices, will assure compliance with the opacity limitations contained in Rule 301. 3.1.4 AIR POLLUTION CONTROL RULE 331 – EMISSION OF PM The estimated PM emissions for the CTGs are provided in Table 1 and demonstrate compliance with the requirements in Rule 331. The PM emissions from the new emergency generator and backup fire pump RICE will comply with the NSPS Subpart IIII requirements. Table 31 of Rule 331 does not include natural gas-fired process equipment or RICE. 3.1.5 AIR POLLUTION CONTROL RULE 371 – FUGITIVE DUST EMISSIONS Pursuant to Rule 371, the Michigan Department of Environmental Quality (MDEQ) may request a Fugitive Dust Control Plan in certain circumstances. No solid fuel handling will be performed onsite, there is infrequent traffic onsite and the main roadway into the plant and vehicle parking areas will be paved. Therefore, a Fugitive Dust Control Plan is not warranted for this project. 3.1.6 AIR POLLUTION CONTROL RULE 401 – EMISSION OF SO2 FROM FUEL BURNING SOURCES AT POWER PLANTS Rule 401 restricts the emissions of sulfur dioxide (SO2) for fuel burning equipment in a power plant. Michigan Air Pollution Control Rule 106(i) defines “fuel burning equipment” as indirect heating where the media being heated does not directly contact the exhaust gases generated from combustion. Rule 401 only applies to solid and liquid fuels. The proposed CTGs and the proposed emergency equipment RICE do not meet the definition of “fuel burning equipment” as contained in R 336.1106(i). Furthermore, the proposed fuel heaters will only use pipeline quality natural gas fuel. Therefore, the requirements of Rule 401 will not apply to the project. 3.1.7 AIR POLLUTION CONTROL RULE 702 – VOC BACT New sources of VOC are subject to Rule 702, which requires an emission limitation based upon the application of BACT. New sources are defined in Rule 701 as: . . . any process or process equipment which is either placed into operation on or after July 1, 1979, or for which an application for a Permit to Install, pursuant to the provision of Part 2 of these rules, is made to the department on or after July 1, 1979, or both, except for any process or process equipment which is defined as an existing source pursuant to R336.1601 (Rule 601). 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 5 Rule 702 requires a new source of VOC to meet all the provisions in the following Subrules: a) The maximum allowable emission rate listed by the department on its own initiative or based upon the application of the best available control technology. b) The maximum allowable emission rate specified by a new source performance standard promulgated by the USEPA under authority enacted by Title I, Part A, Section 111 of the Clean Air Act (CAA), as amended, 42 U.S.C. §7413. c) The maximum allowable emission rate specified as a condition of a permit to install or a permit to operate. d) The maximum allowable emission rate specified in Part 6 of these rules which would otherwise be applicable to the new source except for the date that the process or process equipment was placed into operation or for which an application for a permit to install, under the provisions of Part 2 of these rules, was made to the department. If the Part 6 allowable emission rate provides for a future compliance date, then the future compliance date shall also be applicable to a new source pursuant to this subdivision. Wolverine believes that the use of natural gas fuel with modern, state-of-the-art combustion design meets the intent of Rule 702(a) for VOC BACT. This position is also supported by other very similar Michigan projects that have been approved by the MDEQ Air Quality Division (AQD) for the past several years. 3.1.8 AIR POLLUTION CONTROL RULES 801 THRU 834 – EMISSION OF NOX Part 8 of the Michigan Air Pollution Control Rules limits the emissions of NOX from stationary sources within the State of Michigan. Rules 801 through 822 apply to NOX State Implementation Plan (SIP) Call sources. These sources are required to obtain a NOX Budget Permit. Sources not subject to the NOX Budget Permit requirements must also evaluate whether they are subject to the NOX Ozone Season Trading Program for sources found in Rules 823 through 834. Applicability of the Michigan NOX rules relies upon the applicability criteria found in the federal Clean Air Interstate Rule (CAIR), 40 CFR 97.104 and 40 CFR 97.304. Based upon the promulgation of the Cross-State Air Pollution Control Rule (CSAPR), 76 Fed Reg 48208 (August 8, 2011), federal court decisions related to CSAPR, and the USEPA’s Interim Direct Final Rule of November 21, 2014, 1 all CAIR requirements, including SIPs implementing CAIR, sunset as of December 31, 2014. Accordingly, we do not believe any Part 8 requirements will remain applicable to this project. 1 http://www.epa.gov/crossstaterule/pdfs/CSAPRinterimfinal11_12_14.pdf 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 6 3.1.9 AIR POLLUTION CONTROL RULES 901 THRU 912 The Part 9 Rules are applicable to all sources, including this project. These Rules include: • Rule 901 – General Nuisance (for fugitive emissions and odors). • Rule 910 – Installation and Operation of Emissions Control Equipment. • Rule 911 – Malfunction Abatement Plans. • Rule 912 – Abnormal Conditions, including Startup, Shutdown, Malfunctions, and Reporting of abnormal conditions. The facility will comply with the provisions of these Rules. Fugitive emissions and odors are not inherent to natural gas-fired and diesel-fired emission units. The new power plant will install and maintain all air pollution control technologies associated with the project. Wolverine will prepare a malfunction abatement plan for each emission unit associated with the project. Wolverine will also comply with the requirements of Rule 912. 3.1.10 AIR POLLUTION CONTROL RULES – PART 18 (PSD) As noted previously, the facility will be located in Otesgo County, which currently complies with the NAAQS for PM10, PM2.5, SO2, nitrogen dioxide (NO2), CO, ozone (O3), and elemental lead (Pb). In attainment areas, the federal NSR program is implemented under the Prevention of Significant Deterioration (PSD) program as specified in 40 CFR 52.21. The MDEQ implements the Part 18 PSD program in the state as an approved program from the USEPA. The Part 18 rules incorporate the federal PSD New Source Review (NSR) requirements contained in 40 CFR 52.21 into the state rules. The primary provisions of the PSD requirements are, in part, that proposed new major stationary sources and proposed major modifications to existing major stationary sources be reviewed prior to construction to ensure compliance with the NAAQS, the applicable PSD increments, the requirement to apply BACT on the project’s emissions of air pollutants equal to or greater than their respective major and significance thresholds, and evaluate air contaminants due to secondary growth as a result of a project. A “major stationary source” is any source type belonging to a list of 28 source categories that emits or has the potential to emit (PTE) 100 tons per year (tpy) or more of any NSR regulated pollutant or any other source type that emits or has the PTE any NSR regulated pollutant in amounts equal to, or greater than, 250 tpy. Previously, a major stationary source would have also needed to include any source whose potential GHG emissions are 100,000 tpy, or more, as carbon dioxide equivalent (CO2e), and a major modification would also include a project whose net increase in GHG emissions are 75,000 tpy, or more, as CO2e. However, in June of 2014 the U.S. Supreme Court ruled that GHG emissions should only be 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 7 reviewed if any of the “anyway” pollutants (or traditional NSR regulated pollutants) has triggered the PSD requirements. A stationary source generally includes all pollutant-emitting activities that belong to the same industrial grouping, located on contiguous or adjacent properties, and are under common control. A major modification is generally a physical change or a change in the method of operation of an existing major stationary source that would result in both a significant emissions increase and a significant net emissions increase of any traditional NSR regulated pollutant(s). In determining if a specific project would become subject to the PSD program, the modification must be determined to result in both a significant emissions increase and a significant net emissions increase. Since Wolverine’s project is a new source, a major modification analysis is not applicable. The proposed CTGs are not included in the list of 28 source categories as a plant with fossil fuel-fired boilers (also called steam generating units) with a combined total heat input over 250 MMBtu/hr. Furthermore, the proposed facility will have enforceable provisions that will restrict the annual PTE of each traditional NSR regulated pollutants at a level less than 250 tpy. Therefore, the Part 18 PSD major source program regulations will not apply to the proposed project. 3.2 FEDERAL REGULATIONS 3.2.1 NAAQS – ATTAINMENT STATUS CONSIDERATIONS As noted previously in this document, the facility will be located in Otsego County, which is currently in compliance (attainment) with the NAAQS for PM10, PM2.5, SO2, NO2, CO, O3, and Pb. 3.2.2 40 CFR 52.21 – PSD The federal PSD program applies in geographic areas that are in attainment with the NAAQS. Since the facility is located in Otsego County, the PSD program would apply if the proposed project met or exceeded the applicable major source thresholds. The federal NSR program is implemented pursuant to 40 CFR 52.21. The MDEQ implements the PSD program in Michigan as an approved state from the USEPA. As noted previously, annual allowed NSR regulated pollutant emissions will be below the PSD applicability thresholds and, therefore, the project is not subject to the PSD regulatory requirements. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 8 3.2.3 40 CFR 60 SUBPARTS A, IIII AND KKKK – NSPS Subpart A of the NSPS addresses general requirements that apply to all new stationary sources subject to a specific subpart, such as IIII or KKKK. Subpart A includes general provisions for compliance with applicable emission limits (as specified in a specific subpart for an affected facility), notifications, performance testing, continuous compliance monitoring, recordkeeping and reporting requirements. Some provisions in Subpart A may be “trumped” by a specific NSPS subpart that contains more stringent requirements or exclusion(s) from Subpart A. The proposed CTGs will be subject to the more recent (February 18, 2005) 40 CFR 60 Subparts A and KKKK requirements, not the former Subpart GG requirements, because the date regarding commencement of construction for these new CTGs is well after the effective date for Subpart KKKK. Subpart KKKK currently regulates NOX and SO2 emissions from stationary simple-cycle or combinedcycle combustion turbines. The new diesel-fired emergency RICE will be subject to the NSPS Subpart IIII requirements, since they will be new units that commenced construction (the date an owner/operator places an order for purchasing the RICE from a RICE manufacturer) after April 1, 2006, for non-fire pump RICE, and model year 2009 for fire pump RICE that have a HP range from 175 to 750. The applicable commenced construction dates are contained in 40 CFR 60.4202(a). The proposed, new natural gas-fired CTG fuel heaters are too small to be subject to an NSPS requirement as the lowest NSPS threshold for indirect fired equipment is 10 MMBtu/hr heat input (as contained in NSPS Subpart Dc). The NSPS contains emission limitations, notifications, performance testing (if applicable), continuous compliance monitoring, recordkeeping, and reporting requirements. 3.2.4 40 CFR 63 SUBPARTS A, YYYY AND ZZZZ – NESHAPS Projects of this nature may also be subject to the federal requirements for the control of HAP emissions. The first step to determining applicability is to review the source-specific regulations contained in 40 CFR Part 63. Part 63 is part of the NESHAP with the other being Part 61. Part 61 does not apply since the proposed emission units will not be one of the categories contained in Part 61. A major source of HAPs is defined in Section 112 of the CAA as a stationary source that has a PTE of 10 tpy or more of any individual HAP or 25 tpy of the total combined HAPs subject to regulation under the CAA. Using the design capacity of the new proposed equipment, it has been determined that the total HAPs will be less than the NESHAP major source applicability thresholds (both the 10 tpy and 25 tpy 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 9 thresholds). This is based on HAP emissions data available from stack tests from similar combustion turbine equipment (such as formaldehyde) and use of USEPA AP-42 emission factors. Potential HAP emissions for the entire facility are discussed in Section 4.2 and provided in Table 5. Based on the calculations contained within Table 5, the Wolverine Alpine Power Plant will be a minor (area) source of HAP emissions. NESHAP Subpart YYYY applies to combustion turbines and associated heat recovery equipment that are located at a major source of HAP emissions. Therefore, this NESHAP will not apply to the proposed CTGs. NESHAP Subpart ZZZZ applies to RICE at either a major source or area source of HAPs. The new diesel-fired emergency generator and backup fire pump RICE will comply with the applicable requirements in NESHAP Subparts A and ZZZZ. Pursuant to 40 CFR 63.6590(c)(1), any RICE subject to the requirements of NSPS Subpart IIII (including Subpart JJJJ that applies to spark ignition RICE) “automatically” meets the requirements in NESHAP Subpart ZZZZ. Therefore, the new emergency RICE will comply with the NESHAP ZZZZ via compliance with NSPS IIII. NESHAP JJJJJJ will not apply to the proposed CTGs’ fuel heaters as they will be exclusively fired with natural gas fuel. 3.2.5 CROSS-STATE AIR POLLUTION RULE As indicated in Section 3.1.8, CSAPR’s applicable requirements become effective January 1, 2015. New power plants must acquire CSAPR emission allowances to allow operation of these new sources of SO2 and NOX emissions. The new Wolverine Alpine Power Plant project will be subject to CSAPR and will require SO2 and NOX emission allowances (commonly referred to as a “new source set aside allowance”) equal to its actual annual emissions. Wolverine acknowledges that it will need to hold allowances as required by the CSAPR rule. As acquisition of these allowances occurs well after issuance of this permit and is a function of the Federal Implementation Plan for CSAPR. CSAPR requirements are outside the scope of the PTI review process. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 10 4.0 EMISSION CHARACTERISTICS There will be NSR regulated pollutants, HAP, and TAC emissions associated with the combustion of natural gas fuel in the proposed CTGs and fuel heaters, and combustion of diesel fuel in the emergency RICE. The facility will be an area (minor) source of HAP emissions and a minor source for purposes of the NSR PSD program. 4.1 NSR REGULATED POLLUTANT EMISSIONS The maximum emission rates of all NSR regulated pollutants have been determined. The project’s potential short-term emissions were calculated based on the worst case basis, the maximum capacity of the diesel fuel-fired emergency RICE and the maximum capacity of the fuel heaters. The total annual emissions for the CTGs have been determined based on their maximum, worst case short-term capacity and a combined total operating scenario. The annual PTE for the proposed Alpine Power Plant will be based on total annual (or 12-month rolling time period) fuel use in lieu of any annual (or 12-month rolling) operating schedule (such as a maximum allowed annual hourly operation). The annual emissions for the proposed emergency RICE are based on their short-term maximum capacity and 100 hr/yr (or 12-month rolling time period). The maximum potential emissions as a result of operating the new facility will be less than the applicable major source threshold of 250 tpy for any “traditional” (or “anyway”) NSR regulated pollutant. For this project, the “traditional” NSR regulated pollutants consist of CO, NOX, PM, PM10, PM2.5, SO2, VOC, lead and sulfuric acid mist (idenitifed as “H2SO4”). Based on the June 23, 2014, U.S. Supreme Court’s decision regarding applicability of GHG emissions triggering major NSR review for new stationary sources, GHG emissions from the proposed project being greater than 100,000 tpy will not require major NSR PSD review in and of itself where the “traditional” or “anyway” NSR regulated pollutants will be less than 250 tpy. Wolverine requests that restrictions be placed on the facility’s “traditional” NSR regulated pollutants’ annual (12-month rolling) PTE to remain a minor stationary source for purposes of the major NSR PSD program. Tables 1, 2, 3, 4 and 6 identify the emissions from the CTGs, both new emergency RICE, new fuel heaters and total project emissions, respectively. Table 2 represents an estimate of the Startup and Shutdown (SS) NSR regulated pollutant emissions, based on an assumed total number of events per year. The total annual number of SS events will be determined by MISO and other entities outside the control of Wolverine; therefore, the total number of SS events per year included within this permit application is a best estimate. The emissions that occur during these SS events will be included in the 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 11 total annual (12-month) rolling emission limitations contained within the AQD-issued permit. The estimated SS emissions have been incorporated into Table 1 for the overall NSR regulated pollutant emissions from the CTGs. 4.2 TAC AND HAP EMISSIONS The federally regulated HAP emissions associated from the proposed project will be a subset of the TAC emissions. The TAC and HAP emissions from the project were determined by reviewing currently available emission factors for the proposed equipment and associated fuel. The basis for the emission estimates and methods for calculating TAC and HAP emissions are contained in the tables included in this application describing the emissions. Table 5 describes the TAC and HAP emissions related to the proposed process equipment. The facility will be an area (minor) source of HAPs (less than 10 tpy for a single HAP and less than 25 tpy for all HAPs combined) after the proposed Alpine Power Plant is commissioned. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 12 5.0 CONTROL TECHNOLOGY SUMMARY This project is not subject to the PSD BACT requirements for any NSR regulated pollutant, since the annual potential emissions for any “traditional” NSR regulated pollutant will not equal, or exceed, 250 tpy. Nonetheless, the project will need to demonstrate that the process equipment will comply with the T-BACT and VOC BACT requirements contained in Rules 224 and 702(a), respectively. According to Rule 224(2)(c), for those TACs that are VOC, compliance with VOC BACT meets the requirement for T-BACT. The following are analyses of the T-BACT and VOC BACT requirements proposed for this project, although the use of natural gas for all proposed major combustion sources identified within this permit application should be self evident to demonstrate compliance with the T-BACT and VOC BACT. 5.1 VOC BACT All combustion equipment will generate VOC emissions as a result of incomplete oxidation of the fuel(s). No combustion device achieves 100% complete oxidation of the constituents (primarily carbon and hydrogen) in the fuel. Controlling VOC from combustion equipment primarily includes the following types of technologies: • Design of the combustion technology to achieve as complete (as is possible) oxidation of the carbon and hydrogen in the fuel; and, • Add-on control technology such as a thermal oxidizer or catalytic oxidizer. Catalytic oxidation and thermal oxidation work on the principal of using heat to initiate conversion of the volatile components in the exhaust gas to CO2 and water. Catalytic oxidizers use a bed of precious metal(s), such as platinum, deposited on a substrate to enhance the oxidation reaction that can occur at lower temperatures than thermal oxidizers that do not employ a catalyst. Catalytic oxidizers are generally the add-on VOC control of choice due to their lower cost of operation with reduced fuel use to heat the exhaust gases to the required minimum temperature than is necessary without a catalyst present. The minimum temperature for a catalytic oxidizer to achieve decent VOC control (90% or more) is approximately 550⁰F to 600⁰F. Thermal oxidation does not use a catalyst and relies on a higher temperature to initiate the oxidation reaction of the VOC in the exhaust gas. Thermal oxidation requires more auxiliary fuel use and, therefore, have higher annual operating costs associated with achieving the same level of control efficiency as catalytic oxidizers. The minimum temperature for a thermal oxidizer to achieve decent VOC control (90% or more) is approximately 1,400⁰F to 1,500⁰F. A thermal oxidizer also requires a residence time of 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 13 approximately 0.5 second (or more depending on the turbulence inside the oxidizer) to allow for proper exhaust gas heating and exposure to available oxygen to complete the reaction. Since CO emissions will be minimized as a collateral pollutant, the potential CO emissions have been added to the VOC emissions to properly evaluate whether an add-on control device will reflect the true economic impacts. Furthermore, a negative related environmental impact due to auxiliary fuel use would be additional NOX and GHG emissions generated from the combustion of auxiliary fuel to heat the exhaust gases from the emission unit (if applicable). It has been presumed that any VOC and CO generated from the combustion of the auxiliary fuel will be controlled by an add-on catalytic oxidizer. Note that where a catalytic oxidizer could be implemented on the emergency generator, fire pump and each CTG, there will not be any auxiliary fuel necessary to heat the exhaust gases as the exhaust gases from these emission units have sufficient temperature for proper function of a catalytic oxidizer. Auxiliary fuel will be required for each emission unit using a thermal oxidizer as the exhaust gas temperature from each emission unit is not sufficient for proceeding with the oxidation reaction. The following subsections provide an analysis of VOC BACT for each proposed emission unit. 5.1.1 EACH NEW CTG Each proposed CTG will utilize modern, state-of-the-art combustion technology that reduces the potential for incomplete combustion. With the need to reduce fuel usage per kW of electrical output, including increased energy efficiency, combustion turbine manufacturers are designing turbine combustion systems to meet these requirements. There is a delicate balance between obtaining low VOC emissions with low NOX emissions. Generally, VOC is controlled by providing a hot flame to ensure adequate temperature for oxidation of the carbon and hydrogen in the fuel to reduce the products of incomplete combustion. NOX formation is more probable with higher flame temperatures that breaks down the diatomic nitrogen and oxygen in the combustion air to form NOX. Turbine manufacturers have developed combustion systems that balance lower flame temperature with staged combustion to achieve the desired result of low VOC with collateral low NOX emissions. The following add-on control technologies are technically feasible for each CTG: • Good combustion practices inherent to the design of the turbine; • Catalytic oxidation; 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 14 • Thermal oxidation; and, • A combination of good combustion practices with add-on control technology. All of these control technologies are considered to be technically feasible for each CTG. Good combustion practices will be incorporated into each CTG. The potential VOC emissions will be 4.1 tpy without additional add-on control. Table 7 provides an economic analysis of adding catalytic oxidation and thermal oxidation to each proposed CTG. The minimum economic impact of an oxidizer is over $138,000 per ton of controlled VOC plus CO. This economic impact is greater than typically considered to be economically feasible for VOC emissions and, therefore, is considered to be infeasible for each CTG. Although a catalytic oxidizer would control some of the VOC and CO during startup and shutdown phases of operation, the control efficiency is unknown and is presumed to be negligible. VOC BACT during these modes of CTG operation are considered to be minimizing the amount of time during each startup and shutdown event. Therefore, VOC BACT for each CTG is considered to be implementing good CTG combustion practices with a VOC emission limit of 4.6 tpy during normal (baseload) operation. 5.1.2 NEW EMERGENCY GENERATOR The new diesel-fired emergency generator will meet the VOC emission requirements contained in NSPS Subpart IIII. The new RICE will use modern combustion control that will minimize the formation of VOC as a result of combustion of the diesel fuel. Additionally, the potential VOC emissions from the new emergency generator will be 0.02 tpy. Table 8 provides an economic analysis of adding catalytic oxidation and thermal oxidation to the proposed emergency generator. The minimum economic impact of an oxidizer is over $791,000 per ton of controlled VOC plus CO. This economic impact is greater than typically considered to be economically feasible for VOC emissions and, therefore, is considered to be infeasible for the emergency generator. We have determined that the use of modern combustion design represents VOC BACT for the new emergency generator. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 15 5.1.3 NEW BACKUP FIRE PUMP The new diesel-fired backup fire pump will meet the VOC emission requirements contained in NSPS Subpart IIII. The new RICE will use modern combustion control that will minimize the formation of VOC as a result of combustion of the diesel fuel. Additionally, the potential VOC emissions from the new backup fire pump are estimated at 0.005 tpy. Table 9 provides an economic analysis of adding catalytic oxidation and thermal oxidation to the proposed backup fire pump. The minimum economic impact of an oxidizer is over $473,000 per ton of controlled VOC plus CO. This economic impact is greater than typically considered to be economically feasible for VOC emissions and, therefore, is considered to be infeasible for the backup fire pump. We have determined that the use of modern combustion design represents VOC BACT for the new backup fire pump. 5.1.4 NEW FUEL HEATERS Table 10 provides an economic analysis of adding catalytic oxidation and thermal oxidation to each proposed fuel heater. The minimum economic impact of an oxidizer is over $38,000 per ton of controlled VOC plus CO. This economic impact is greater than typically considered to be economically feasible for VOC emissions and, therefore, is considered to be infeasible for each proposed fuel heater. 5.2 T-BACT T-BACT for organic-based (or VOC) TAC is the use of VOC BACT as provided in Rule 224(2)(c) and as determined in Section 5.1 for each proposed emission unit. For non-organic TAC, such as metal TACs, an analysis of add-on control technology is presented below. Since the fuel heaters will be the only emission units that have potential non-organic TACs, and will be metal TACs attached to PM, no additional T-BACT is provided for each CTG, emergency generator and backup fire pump. The metal TACs will be associated with PM emissions. The technically feasible PM control technologies for controlling PM from each fuel heater include: • Fabric filter; • Electrostatic precipitator; 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 16 • Wet scrubber; and • Cylcone(s). Since a fabric filter would provide the highest control efficiency of the options above, and the least annual operating costs, a fabric filter has been evaluated for economic feasibility. An ESP and wet scrubber would generally have a higher initial capital cost and annual operating cost than a fabric filter. Cyclone control would not provide for as high a control efficiency due to the particle size of the PM in a fuel heater’s exhaust gas. Particle sizes of PM exiting a combustion device would be 1 micron or less. Cyclones are highly inefficient for PM with a size range this small. Table 11 provides the economic impact as a result of using a fabric filter control device to control PM TACs from each fuel heater. The economic impact would be over $13,000,000 per ton of PM removed and is economically infeasible from each fuel heater. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 17 6.0 AIR QUALITY MODELING AND AIR TOXIC EVALUATION Emissions associated with the proposed project are below major source thresholds with respect to PSD, but exceed the significant emission rates for the following criteria pollutants: NO2, CO, PM10, and PM2.5. Otsego County is attainment for all the listed criteria pollutants. Although the project is not subject to PSD, Wolverine is voluntarily providing a dispersion modeling analysis for criteria pollutants above their individual significant emission rates as part of the PTI application. The criteria pollutant analysis is presented in Section 6.2. In recent PSD permits, the MDEQ and USEPA required that sources address secondary formation of O3 and PM2.5. Although this project in not subject to PSD, the MDEQ has requested that a secondary formation analysis be performed as part of the application. Secondary formation assessments are provided in Sections 6.3 and 6.4. As stated in Rule 225 (R 336.1225) of the Air Pollution Control Commission General Rules, the MDEQ requires that the ambient impact of the TACs released from a rule-subject source be estimated and compared to established air quality standards. An air toxics demonstration is presented in Section 6.5. Model selection and input parameters, used for both criteria pollutant and TAC modeling analyses, are presented in Section 6.1. 6.1 MODEL PARAMETERS The modeling selection and input parameters used for both criteria pollutant modeling and TAC analyses are presented in the following sections. 6.1.1 MODEL SELECTION The model selected for the air dispersion analysis was AERMOD, Version 14134. This model was established as the USEPA-preferred air dispersion model effective December 9, 2005, for steady-state operations. AERMOD is a modeling analysis which incorporates air dispersion based on planetary boundary layer turbulence structure and scaling concepts, including treatment of both surface and elevated sources, and both simple and complex terrain. BEE-line software, which incorporates the USEPA algorithm for the AERMOD program, was used. The software, referred to as “BEEST”, Version 10.13, was developed by a Division of Bowman Environmental Engineering, Inc. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 18 6.1.2 GEP STACK HEIGHT ANALYSIS Prior to running the air dispersion model, the potential for building downwash to affect the stack plume must be evaluated. Building downwash represents the effect that nearby structures have on the air flow near the stack. If the stack is within the area of influence of the building, the swirls and eddies caused by obstruction of the air flow near buildings can affect the plume dispersion characteristics. The GEP analysis was performed using software developed by Bowman Environmental Engineering, Inc. The software includes the USEPA BPIP-Prime Version 04274 code for calculating projected building widths. This analysis was run for all buildings illustrated in Figure 2 greater than 10 feet in height. Structures and equipment less than 10 feet in height were considered insignificant and not included in the assessment. Structure heights for the buildings and equipment considered in the model are provided in Table 12. The highest calculated GEP stack height of any structure was 175 feet (53.3 meters). The stack heights listed in Table 13 are less than the GEP stack height; therefore, direction-specific building effects calculated for each wind direction were entered into the dispersion model as described in the next section. A summary of the results of the GEP analysis are provided electronically in Appendix 1. 6.1.3 MODEL INPUT PARAMETERS The direction-specific building dimensions calculated during the GEP stack height analysis were input into the model. Figure 1 presents the site location. The origin of the grid used in the model is located at the center of the north CTG stack. However, all coordinates are provided in UTM NAD 83 coordinate system. Because the property will be fenced north of M-32, receptors were placed at 25-meter intervals around this portion of the property line. Dense grids of 25-meter and 50-meter intervals surround the property, and a grid of 100 meters and 250 meters covers the outlying areas. Terrain elevations at receptors were obtained using BEE-Line Software’s BEEST program and USGS National Elevation Dataset (NED) 1/3 arc-second data. BEEST implements the AERMAP model (Version 11103), which includes processing routines that extract NED data to determine receptor terrain elevations for air quality model input. The NED data used in the modeling had a resolution of 10 meters (1/3 arc-second) and NAD83 datum. The meteorological data used in the model was 1-minute data from Otsego County Airport, Gaylord, 2009-2013 (Surface Station No. 14854), and Green Bay, 2009-2013 (Upper Air Station No. 4837). The meteorological data was provided by the MDEQ and was processed using AERMET, Version 14134. The model for 1-hr NOX and 24-hr PM2.5 was run using a combined 5-year meteorological dataset to determine the 5-year average impact at each receptor. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 19 All emissions sources included in this analysis will have emissions exhausted from a stack, and were considered point sources in the model. Stack parameters for these sources are provided in Table 13. 6.2 CRITERIA POLLUTANT MODELING A dispersion modeling analysis has been conducted for the criteria pollutants for which emissions are above the significant emission rate criteria. As presented in Table 6, these include NO2, CO, PM10, and PM2.5. If emissions result in impacts that exceed the Significant Impact Levels (SILs), a detailed dispersion modeling impact analysis to demonstrate compliance with the federal PSD increments and NAAQS was conducted as a part of the application, as discussed in Sections 6.2.1 and 6.2.2. Emission rates for the two CTGs were conservatively determined for use in the modeling demonstration. The maximum emission rates for either a start-up hour or a baseload hour were used in the modeling along with the minimum hourly average exhaust flow rate, as summarized in Table 13. Based upon the proposed restriction concerning total annual operating hours, the two units will not often operate simultaneously at their maximum proposed emission rates. However, it was conservatively assumed for modeling purposes that both units will operate simultaneously at their maximum proposed emission rates. Emission rate calculations and associated exhaust flow rates for a start-up hour are provided in Table 14. 6.2.1 SIGNIFICANT IMPACT ANALYSIS AND RESULTS The significant impact analysis is the first step in the modeling study. Emissions for each criteria pollutant with proposed emissions above the significant emission rate are modeled to determine if the impact will exceed the SILs defined in 40 CFR 52.21. Model input parameters for the SIL analysis are provided in Table 13. Maximum hourly emission rates for all sources were used in the model, unless otherwise noted on Table 13. If the impact for a pollutant are above the SIL, PSD increment and NAAQS modeling was performed for the facility. If the impact for a pollutant meets the SIL, no further modeling was conducted. As presented in Table 15, maximum predicted impacts from the project are below the SILs for CO and for annual PM10. Therefore, no further modeling was performed for these specific pollutants and averaging times. Predicted impacts, however, were above the applicable SILs for all other pollutants and averaging times, including the previously promulgated 24-hour SIL for PM2.5. Therefore, PSD increment and NAAQS analyses have been conducted for the remaining pollutants and averaging times, as discussed in Section 6.2.2. A CD containing the electronic model input/output files is provided in Appendix 1 (of the original MDEQ application only). 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 20 6.2.2 PSD INCREMENT AND NAAQS ANALYSES Because predicted ambient impacts from the proposed project are above the various applicable SILs, additional analyses have been performed for the following pollutants and averaging times as follows: ● Annual NO2 (increment and NAAQS) ● 1-hour NO2 (NAAQS only; no increment established) ● Annual and 24-hour PM2.5 (increment and NAAQS) ● 24-hour PM10 (increment and NAAQS) The MDEQ was contacted to obtain background concentration data and to determine what additional sources should be considered in the PSD increment and NAAQS analyses. The MDEQ performed a screening analysis and determined that no additional sources had a significant concentration gradient at the proposed site. Therefore, there are no additional sources that need to be included in the increment or NAAQS modeling. Documentation of current background concentrations and additional source data is provided as Appendix 2. Typically, the first step in the additional analysis is to define the significant impact receptors for the project. (These are the receptors from the SIL analysis where the impacts from the project were determined to be above the SIL.) The significant impact receptors are then usually used for the increment and NAAQS modeling demonstrations. However, because there are no additional sources to include, the full grid was used for the increment and NAAQS modeling. The USEPA revoked the previously promulgated SIL for 24-hour PM2.5. However, USEPA guidance (March 4, 2013) indicates that if the difference between the NAAQS and the background is greater than the SIL, then the USEPA believes it would be sufficient to conclude that the NAAQS would not be violated 3 with an impact below the SIL. As the regional background is 16.8 µg/m , net impacts less than 1.2 µg/m 3 3 (revoked PM2.5 SIL) would not jeopardize the NAAQS (35 µg/m ). In recent, similar recent modeling studies, the MDEQ has not required further refined modeling if the project impact is below the revoked PM2.5 SIL. Because this project’s predicted maximum impacts are above the previous SIL, NAAQS and increment analyses were performed for 24-hour PM2.5 The model was run for the proposed maximum emission rates for each pollutant from each stack, unless otherwise noted on Table 13, with a combined impact from all stacks; therefore, the model PAI is equal to the actual PAI in µg/m³. The results of the PSD increment and NAAQS analyses demonstrate compliance and are presented in Tables 16 and 17, respectively. A CD containing the electronic model input/output files is provided in Appendix 1 (of the original MDEQ application only). 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 21 6.3 SECONDARY PM2.5 FORMATION Project emissions of direct fine particulate (PM2.5) exceed the significant emission rate (SER) of 10 tpy. Project emissions of NOX also exceeds the SER of 40 tpy; NOX is a precursor for secondary formation of PM2.5. Therefore, an assessment of their potential impact on ambient PM2.5 air quality in the area is being provided as part of the permit application process. This analysis represents a qualitative assessment of the potential impact to air quality as a result of secondary PM2.5 formation. This approach is consistent 2 with the guidelines of the USEPA’s March 4, 2013, draft guidance for PM2.5 modeling and is similar to the analysis conducted for the Husky Lima Refinery Crude Oil Flexibility Project recently accepted in Ohio for Lima Refining Company (LRC). This analysis also follows the secondary formation analysis recently submitted and approved for Gerdau MacSteel’s proposed plant expansion at the Monroe, Michigan, facility (PTI No. 102-12A). 6.3.1 EMISSION PROFILE AND USEPA GUIDANCE This project’s emission profile (i.e., significant emissions for NOX and direct PM2.5) is most consistent with “Case 3” from Table II-1 in USEPA’s March 4, 2013, draft guidance for PM2.5 modeling in that the project is significant for at least one precursor emission (NOX), as well as for direct PM2.5 emissions. For Case 3 projects, USEPA specifies that primary impacts of direct PM2.5 emissions must be addressed. Further, secondary impacts of precursor emissions of NOX and/or SO2 must also be addressed. (SO2 emissions do not need to be addressed for Wolverine, as proposed emissions are below the SER.) The impacts of direct PM2.5 emissions have been included in the modeling analysis presented in Section 6.2 and have been shown to be compliant with PSD increment and NAAQS requirements, satisfying the first requirement presented in Table II-1. The assessment of the secondary impacts due to precursor emissions is the second requirement presented in Table II-1 and is being addressed within this section. The USEPA’s draft guidance for assessing the secondary PM2.5 impacts from the precursor emissions of new or modified sources allows for three possible approaches: the “accounting of the precursor emissions impact on secondary PM2.5 formation may be completely qualitative in nature, may be based on a hybrid of qualitative and quantitative assessments utilizing existing technical work, or may be a full quantitative 3 photochemical grid modeling exercise.” The USEPA has indicated that the last option, photochemical modeling, would only be required in rare circumstances. At present, the March 4, 2013, draft guidance has not been finalized and, therefore, does not represent the USEPA’s final guidance. However, in December 2013, the USEPA notified the MDEQ that a 2 Draft Guidance for PM2.5 Permit Modeling, USEPA, March http://www.epa.gov/ttn/scram/guidance/guide/Draft_Guidance_for_PM25_Permit_Modeling.pdf 3 Draft Guidance for PM2.5 Permit Modeling, USEPA, March 4, 2013, pages 18 and 19. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 4. 2013 22 qualitative assessment may be preferable for addressing the potential secondary impacts due to precursor emissions and provided the LRC analysis as an example. Therefore, the following analysis, which is patterned after the LRC assessment, is consistent with the USEPA’s guidance for conducting a qualitative analysis for the purpose of demonstrating that the secondary formation of PM2.5 from precursors SO2 and NOX for this project will not cause or significantly contribute to a violation of the NAAQS. 6.3.2 QUALITATIVE ANALYSIS AND CONCLUSIONS This analysis details why modeling secondary PM2.5 emissions is not needed in order to determine that emissions of PM2.5 precursors from this project would not cause or contribute significantly to a violation of the annual and 24-hour PM2.5 NAAQS. 1) Background concentrations used in near-field dispersion modeling should represent all current air pollution sources other than those explicitly modeled. The Houghton Lake, Michigan, monitor is the only PM2.5 monitor in the northern lower peninsula of Michigan and has been determined by the MDEQ to be the most representative background data for PM2.5. This area has some of the lowest background concentrations of PM2.5 in the state. The 24-hour average design value (average 3 percentile value of three years, 2011-2013) of 16.8 µg/m is well below the 24-hour PM2.5 NAAQS 3 3 of 35 µg/m . The 3-year annual design value of 5.9 µg/m is also well below the annual PM2.5 3 NAAQS of 12 µg/m . These values leave room under the NAAQS for new source impacts of up to 18.2 µg/m 3 (24-hour) and 6.1 µg/m 3 (annual). As discussed below, the maximum potential Wolverine project secondary PM2.5 impacts are anticipated to be well below these levels. 2) Table 18 documents how insignificant the secondary PM2.5 formation from this project is likely to be. Shown in this table is a screening level assessment of project PM2.5 impacts of precursors based on the described assumption for conversion of NOX to PM2.5 This conversion is based on the preferred/presumptive interpollutant trading ratios originally set forth in the USEPA’s 2008 PM2.5 NSR implementation rule for use for emission offsets in non-attainment area NSR permitting. Although the USEPA no longer supports the use of these offset trading ratios as they are not necessarily representative of the exact precursor conversion in all areas of the country, they do provide perspective as to how insignificant the impacts due to precursor emissions are anticipated 4 to be. It has further been conservatively assumed that the conversion to PM2.5 occurs immediately, and that maximum NOX impacts occur at the same place and time. Based on these assumptions, 4 The USEPA subsequently revised its policy on July 21, 2011 (Revised Policy to Address Reconsideration of Interpollutant Trading Provisions for Fine Particulate (PM2.5)). The revised policy no longer supports the 2008 interpollutant trading ratios as presumptively approvable and instead suggests that any ratio involving PM2.5 precursors adopted by the state for use in the interpollutant offset program must be accompanied by a technical demonstration. This is because the USEPA determined that the 2008 ratios, which were based on analyses of nine urban areas across the country, are not sufficiently representative of conditions in all areas of the country and would need to be considerably more conservative to be presumptively applied nationwide in an offset program. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 23 the secondary impacts of PM2.5 from the project would be significantly below the SIL and would consume no more than 1% of the room under the NAAQS on a 24-hour basis and no more than 0.1% of the room under the NAAQS on an annual basis, as shown in Table 18. Wolverine believes that use of the ratios provides an order-of-magnitude that demonstrates the insignificance of the anticipated impacts due to precursor emissions. 3) Actual NO2 conversion to PM2.5 would need to be considerably greater than the assumptions used in these calculations (as identified in Item 2) for the project to have a significant impact on PM2.5 ambient air quality due to precursor emissions. 4) Secondary formation of PM2.5 from NOX is not instantaneous but occurs over time due to chemical reactions in the atmosphere, generally downwind of the project site. The maximum direct NOX impacts used in the calculations above occur near the facility. At locations close to the original source, there likely would not be adequate time for the conversion of precursor emissions to secondary PM2.5. Therefore, it is expected that secondary PM2.5 impacts near the facility are less than those shown in the table. Generally, the secondary impacts are expected to increase farther from the facility, as there has been more time for the chemical reactions to occur. However, direct emissions and impacts of NOX decrease at further distances from the facility, leaving less precursor emissions to convert to secondary PM2.5. Therefore, the actual impacts of secondary PM2.5 are anticipated to be much lower than those shown in the table. Based on these factors, and consistent with current guidance, Wolverine believes that an adequate assessment has been made to demonstrate that the PM2.5 NAAQS will be protected. This evaluation considered potential contributions due to PM2.5 precursors from the Wolverine project. A further analysis utilizing photochemical modeling is not necessary to demonstrate that the proposed project is not expected to have significant impacts to ambient air quality or to cause or significantly contribute to a violation of the PM2.5 NAAQS. 6.4 SECONDARY OZONE FORMATION Project emissions of VOC are well below the SER of 40 tpy; however, NOX emissions from the project are above the SER of 40 tpy. NOX is considered a precursor for secondary formation of ground-level (tropospheric) ozone. Therefore, an assessment of the potential impact on ambient ozone air quality in the area is also part of the permit application process. Ozone impacts due to direct emissions of VOC are not generally modeled as part of the application process, as ozone modeling is complex and resource-intensive. As such, it is not feasible to quantify impacts of secondary ozone formation via dispersion modeling. Further, many factors impact tropospheric 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 24 ozone development, including temperature, wind speed and direction, and time of day. Therefore, it is not possible to conclusively determine how much of the precursor NOX emissions from the Wolverine project will chemically react in the atmosphere to produce the tropospheric ozone. Conversion of NOX and VOC emissions to tropospheric ozone is not instantaneous, but rather occurs over time, with the rate of conversion highly dependent upon weather conditions. Further, ozone formation is recognized as a regional and long-range transport issue. Studies have even shown that transpacific transport of pollution from Asia influences North America’s air quality, especially during the ozone season. Therefore, it is very unlikely that secondary formation of ozone from NOX emissions attributable to the Wolverine project will have a significant impact on the ozone levels in the area. Otsego County is currently designated as attainment for ozone. Otsego County and surrounding counties are rural with relatively few industrial sources and have low background concentrations of ozone as compared to other areas of the state. Given that secondary formation of ozone is more of long-range transport issue, precursor NOX emissions from the proposed Wolverine project are not expected to have significant impacts to ambient air quality or to cause or significantly contribute to a violation of the ozone NAAQS. 6.5 TAC MODELING In Rule 225 (R 336.1225) of the Air Pollution Control Commission General Rules, the MDEQ requires that the ambient impact of the TACs released from a rule-subject source be estimated and compared to established air quality standards. To estimate the ambient air concentrations, each contaminant concentration is calculated at the stack, assuming peak loading conditions. The contaminant loading from the stack is then subjected to air dispersion modeling to simulate the effect of local meteorological conditions. The ambient concentration at hypothetical ground level receptors is then calculated and compared to the air quality screening levels as developed by the MDEQ. 6.5.1 TAC EMISSION RATES AND RESULTS The input parameter emission rate was a generic 1 lb/hr for each TAC emission source. Therefore, the model output is in units of µg/m³ per lb/hr for each TAC source. The unitized model results are included as Table 19. A summary of the results from the AERMOD model run are presented in Appendix 1. To estimate the actual PAI for each TAC, the model PAI was multiplied by the maximum emission rate in lb/hr, with the contributions from each TAC emission source summed to give a conservative combined impact for that TAC. As presented in Table 20, the PAIs for all TACs from the proposed process are below the applicable air quality screening levels obtained from the MDEQ-AQD List of Screening Levels. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 25 7.0 SUMMARY AND CONCLUSIONS This application submittal represents a minor source NSR PTI application for all “traditional” NSR regulated pollutants and HAPs. The Alpine Power Plant project will help Wolverine meet the growing electrical capacity needs of Wolverine, provide additional grid stability, and partially make up for the loss of Michigan-based electric power generation capacity from the retirements of older fossil fuel-fired EGUs. 7.1 PROPOSED EMISSIONS CONTROL TECHNOLOGIES This project will include VOC BACT and T-BACT emission controls for VOC and TACs emissions (natural gas fuel and proper combustion designs) pursuant to Rules 702(a) and 224, respectively. The CTGs and fuel heaters will incorporate modern combustion controls for all PMs, NOX, CO, and VOC as well as the use of natural gas fuel to minimize SO2, GHG, and CPM emissions. The emergency RICE will also utilize modern combustion controls as well as ultra low sulfur diesel fuel to minimize potential emissions related to combustion. 7.2 NESHAP COMPLIANCE This application demonstrates the project will be an area (minor) source of HAPs, primarily based on the use of emission factors derived from the USEPA AP-42 database and other similar tested combustion turbine units. Therefore, each proposed CTG is not subject to the NESHAP requirements contained in 40 CFR 63 Subparts A and YYYY. The new diesel-fired emergency RICE are subject to the area source requirements of 40 CFR 63 Subparts A and ZZZZ (which is demonstrated via compliance with NSPS Subpart IIII). The small fuel heaters are not subject to the requirements in NESHAP 40 CFR 63 Subpart JJJJJJ due to the exclusive use of natural gas fuel. 7.3 NSPS COMPLIANCE Each proposed CTG will be subject to, and comply with, NSPS Subparts A and KKKK. The new diesel-fired emergency RICE will be subject to, and comply with, the provisions contained within NSPS Subparts A and IIII. The proposed fuel heaters are each less than 10 MMBtu/hr heat input that is the minimum size threshold of NSPS Subpart Dc. Therefore, each fuel heater is not subject to any NSPS requirements. 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 26 7.4 AMBIENT IMPACTS The results of the dispersion modeling analyses demonstrates compliance with all state and federal ambient standards for criteria pollutants and all Michigan TAC ambient health-based screening level requirements. 7.5 COMPLIANCE DEMONSTRATIONS AND MONITORING Wolverine is proposing to utilize parametric NOx monitoring for each CTG in accordance with 40 CFR 97 Subpart H (which includes reference to 40 CFR 75 Appendix E) to verify compliance with the permitted emission rates. A 40 CFR 75 NOx monitoring plan will be developed prior to operation in accordance with the Federal Monitoring Plan requirements and schedule (this Plan will also address 40 CFR 60 monitoring requirements). Onsite performance testing will begin within 180 days of the proposed power plant’s commissioning to demonstrate compliance with emission limits. Should either CTG at the Alpine Power Plant exceed an annual capacity factor of 20% for any 1 calendar year or an average of 10% for 3 consecutive calendar years, Alpine Power Plant will install a certified NOX continuous emission monitoring system (CEMS) by December 31 of the following calendar year for the affected CTG. This is consistent with the current CSAPR regulations and allows a source a reasonable amount of time to select, install and certify a NOX CEMS. The following language is proposed as Special Conditions for each CTG to enforce this requirement: Permittee shall install, certify and operate no later than December 31 of the following calendar year a NOX CEMS for monitoring actual NOX emissions from EU-CTG1 if the capacity factor during any calendar year is greater than 20% or if the 3-calendar year average capacity factor is greater than 10%. Capacity factor is the actual utilization (as MWh) of EU-CTG1 divided by its potential capacity (as MWh) based on 8,760 hours per calendar year multiplied by 100. (40 CFR 97.70, 40 CFR 75.12(d)(2)) Permittee shall install, certify and operate no later than December 31 of the following calendar year a NOX CEMS for monitoring actual NOX emissions from EU-CTG2 if the capacity factor during any calendar year is greater than 20% or if the 3-calendar year average capacity factor is greater than 10%. Capacity factor is the actual utilization (as MWh) of EU-CTG2 divided by its potential capacity (as MWh) based on 8,760 hours per calendar year multiplied by 100. (40 CFR 97.70, 40 CFR 75.12(d)(2)) 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 27 A parametric monitoring plan will also be developed for other NSR regulated pollutants, which will likely be based on performance (emission) testing results and using appropriate surrogate pollutants wherever possible (such as VOC or CO for organic HAP emissions). Compliance with the emission requirements for the new emergency RICE will be based on the RICE manufacturer’s certification that the emissions will meet the emission limits (if available). 12/15/2014 Z:\2009\090066NEW\REC\REPT\PTI_APP\WP_PTI_APP_2014_1215_FNL.DOCX 28 Figures VICINITY MAP MICHIGAN engineers scientists _ ^ architects constructors ELMIRA OTSEGO COUNTY fishbeck, thompson, carr & huber, inc. Hard copy is intended to be 11"x17" when plotted. Scale(s) indicated and graphic quality may not be accurate for any other size. PLOT INFO: Z:\2009\090066NEW\CAD\GIS\MAP_DOC\Alpine\FIG02_SITE PLAN.mxd Date: 12/3/2014 11:32:47 AM User: acs LEGEND Property Boundary LOCATION MAP NORTH 0 500 FEET 1,000 Source: Esri, DigitalGlobe, GeoEye, i-cubed, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and the GIS User Community, Esri, HERE, DeLorme, MapmyIndia, © OpenStreetMap contributors, Esri, HERE, DeLorme, TomTom, MapmyIndia, © OpenStreetMap contributors, and the GIS user community Air Permit Application Wolverine Power Alpine Power Plant, Elmira, Otsego County, Michigan LOCATION OF SITE PROJECT NO. G090066NEW 1 FIGURE NO. ©Copyright 2014 All Rights Reserved Tables Page 1 of 1 Table 1 - NSR Regulated Pollutant Emissions From CTGs Air Permit to Install Application Alpine Power Plant, Elmira, Michigan 203.3 Maximum CTG Generator Capacity (1 CTG) = MWe at 81 °F and 100% load 2,045 MMBtu/hr at 81°F and 100% load (HHV Basis) One CTG 100% Load Heat Input Rate = 72.8% (represents total annual operation for both CTGs divided by 8,760 hr/yr) Annual Capacity Factor = 6,380 hr/yr (represents total, combined annual operation for both CTGs at 100% load) Annual Operation = Total Annual Heat Input Rate = 13,044,676 MMBtu/yr and represents baseload operation at 100% load only for both CTGs (HHV basis) Annual Natural Gas Usage Rate = 12,714.1 MMCF/yr at 1,026 Btu/CF natural gas and represents baseload operation only at 100% load for both CTGs (HHV basis) Total Annual Natural Gas Usage Rate = 12,850.3 MMCF/yr at 1,026 Btu/CF natural gas (HHV basis), and includes baseload at 100% load + startup and shutdown events Emission Factor (Baseload Operation) (See Footnotes for Emission Factor Basis) Short-Term Emissions per CTG (Baseload Operation) (lb/hr) Short-Term Emissions Both CTGs Combined (Baseload Operation) (lb/hr)7 Annual Emissions Both CTGs Combined (Baseload Operation) (tpy) Startup and Shutdown Emissions 1 (tpy) Total Annual Emissions 2 (tpy) CO 3 2.0000E-02 lb/MMBtu NOX 3 3.2652E-02 lb/MMBtu 40.9 81.8 130.4 82.0 212.4 66.8 133.5 213.0 6.9 PM (Filterable Only) 4 219.8 6.6E-03 lb/MMBtu 13.5 27.0 43.0 1.4 44.4 PM10 (Filterable + Condensable)4 6.6E-03 lb/MMBtu 13.5 27.0 43.0 1.4 44.4 PM2.5 (Filterable + Condensable)4 6.6E-03 lb/MMBtu 13.5 27.0 43.0 1.4 44.4 SO2 3 2.1666E-03 lb/MMBtu 4.4 8.9 14.1 0.2 14.3 VOC 3 1.4025E-03 lb/MMBtu 2.9 5.7 9.1 14.9 24.0 2.12E-05 lb/MMBtu 0.04 0.1 0.14 0.001 0.14 770,530 14.5 NSR Regulated Pollutant H2SO4 5 CO2 3 238,983 477,966 762,356 8,174 CH4 6 2.20E-03 lb/MMBtu 4.5 9.0 14.4 0.15 N 2O 6 2.20E-04 lb/MMBtu 0.5 0.9 1.4 0.02 1.5 239,230 478,460 763,144 8,182 771,327 CO2e 6 ---- ---- 1 Based on Table 2 at 250 startup/shutdown events per 12-month rolling time period. 2 Represents the sum of 100% load and startup/shutdown events. See Table 2 for emissions related to startup/shutdown events. 3 Emission factors based on CTG manufacturer, except for CO. CO emission rate is based on 13 ppmv at 12% CO2, which is an approximate 50% increase over vendor provided emission information. CO2 mass emission rate provided by CTG manufacturer is in units of lb/hr. 4 PM/PM10/PM2.5 emission factor from AP-42 Table 3.1-2a. To be conservative, PM emissions have been estimated to be equivalent to PM 10 and PM2.5, even though PM is only to include filterable portion (PM determined from performance testing using USEPA Methods 5 or 17 of 40 CFR 60 Appendix A). 5 The H2SO4 emission factor presumes approximately 0.8% of the SO2 is emitted as SO3 and then converts to H2SO4 in the presence of moisture. This is then multiplied by the ratio of the molecular weight of H2SO4 to SO3 (which is 98/80). 6 Based on GWP and emission factors obtained from 40 CFR 98 Subparts A and C, respectively, for natural gas fuel. A factor of 2.20462 is used to convert kg/MMBtu to lb/MMBtu. 7 Emissions for 2 CTGs are twice the Short-Term Emissions per CTG (Baseload Operation) . Table 1.1 Emission Calculation Methods E ST = C ST X EF E A = E ST X Annual Operation at 100% Load / 2,000 lb/ton where: E ST = Short Term Emissions (lb/hr); E A = Annual Maximum Emissions (tpy); C ST = CTG Heat Input Capacity (MMBtu/hr); and EF = emission factor (lb/MMBtu) Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 1 of 1 Table 2 - Estimated CTG Startup and Shutdown NSR Regulated Pollutant Emissions Air Permit to Install Application Alpine Power Plant, Elmira, Michigan 250 Estimated Total 12-month Rolling Startup and Shutdown Events Estimated Startup and Shutdown Emissions, Single CTG Mode of Operation Cold Start Shutdown Fuel MMBtu/Event 292 267 NOx lb/Event 30 25 CO lb/Event 320 336 VOC lb/Event 49 70 PM10/PM2.5 SO2 H2SO4 lb/Event 5.8 5.3 lb/Event 0.63 0.58 lb/event 0.006 0.006 GHG lb/event 34,193 31,265 Duration Minutes 8 8 Hours 0.13 0.13 Notes: 1. NOX, CO and VOC emission rates provided by CTG manufacturer. 2. Conservatively estimated that PM10 and PM2.5 are emitted at a rate of 0.02 lb/MMBtu (to account for less efficient combustion of carbon in fuel) and SO 2 is 0.0022 lb/MMBtu during startup and shutdown events. 3. For H2SO4 emissions, see footnote 4 related to Table 1.1. 4. GHG emissions based on 40 CFR 98 Subparts A and C for GWP and Emission Factors, respectively, for natural gas fuel. A factor of 2.20462 is used to convert kg/MMBtu to lb/MMBtu. 5. Duration in minutes provided by potential CTG manufacturer. 12-Month Rolling Time Period Heat Input and Emissions Due to Startup and Shutdown Events Fuel (MMBtu/yr) 139,750 NOx (tpy) 6.9 CO (tpy) 82.0 VOC (tpy) 14.9 Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx PM10/PM2.5 (tpy) 1.4 SO2 (tpy) 0.2 H2SO4 (tpy) 0.001 GHG (tpy) 8,182 Duration Minutes 4,000 Hours 66.67 12/4/2014 Page 1 of 2 Table 3 - Emergency RICE NSR Regulated Pollutant Estimated Emissions Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Table 3.1 - NSR Regulated Pollutant Emissions from Diesel Fired Emergency Generator Nominal RICE Rating = Nominal Generator Rating = Nominal RICE Heat Input = Annual Operating Hours = NSR Regulated Pollutant Emission Factor (See Notes) 1 CO NOx 1 1 2,011 1,500 13.44 100 0.44 g/HP-hr 4.08 g/HP-hr HP kW MMBtu/hr hr/yr Hourly Emissions Annual Emissions (lb/hr) (tpy) 2.0 18.1 0.1 0.9 0.1 0.2 0.007 0.01 PM PM10 2 0.03 g/HP-hr 1.76E-02 lb/MMBtu PM2.5 2 1.76E-02 lb/MMBtu 0.2 0.01 SO2 3 1.52E-03 lb/MMBtu 0.02 0.001 0.11 g/HP-hr 163.6 lb/MMBtu 0.5 2,199 0.02 110 1 VOC CO2e 4 1 Emission factors are based on potential engine manufacturer for emergency generators and are less than the requirements contained in NSPS Subpart IIII, 40 CFR 60.4202(a)(2) which refers to Table 1 of 40 CFR 89.112 for emission limits. 2 PM10 and PM2.5 emission factor is from the vendor provided PM rate (as g/HP-hr and converted to lb/MMBtu) plus the condensable PM (as lb/MMBtu) from USEPA AP-42, Chapter 3.4, Table 3.4-2. 3 SO2 emissions are based on USEPA AP-42, Chapter 3.4, Table 3.4-1. Sulfur content of diesel fiel is 0.0015%. 4 CO2e global warming potential and emission factors obtained from 40 CFR 98 Subparts A and C, respectively. The global warming potential for CH 4 (25) and N2O (298) are consistent with the USEPA published changes on November 29, 2013. A factor of 2.20462 is used to convert kg/MMBtu to lb/MMBtu. Table 3.1 Emission Calculation Methods Using lb/MMBtu Emission Factors E ST = C HI X EF E A = E ST X Annual Operating Hours / 2,000 lb/ton where: E ST = Short Term Emissions (lb/hr); E A = Annual Maximum Emissions (tpy); C HI = RICE Heat Input Capacity (MMBtu/hr); and EF = emission factor (lb/MMBtu) Using g/kW-hr Emission Factors E ST = C kW X EF / 453.59 g/lb E A = E ST X Annual Operating Hours / 2,000 lb/ton where: E ST = Short Term Emissions (lb/hr); E A = Annual Maximum Emissions (tpy); C kW = RICE Power Output Capacity (kW); and EF = emission factor (g/kW-hr) Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 2 of 2 Table 3 - Emergency RICE NSR Regulated Pollutant Estimated Emissions Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Table 3.2 - NSR Regulated Pollutant Emissions from Diesel Fired Back Up Fire Pump Nominal RICE Rating (Each) = Each RICE Nominal Heat Input = Annual Operating Hours = NSR Regulated Pollutant Emission Factor (See Notes) 1 CO 1 NOx 1 347 2.3 100 HP MMBtu/hr hr/yr Hourly Emissions Annual Emissions (lb/hr) (tpy) 1.4 g/HP-hr 1.1 2.2 g/HP-hr 1.7 0.1 0.1 PM 2 PM10 1.18E-01 g/HP-hr 4.67E-02 lb/MMBtu 0.1 0.00 0.1 0.01 2 4.67E-02 lb/MMBtu 0.1 0.01 1.52E-03 lb/MMBtu 0.004 0.0002 0.1 g/HP-hr 0.1 0.00 163.6 lb/MMBtu 378 19 PM2.5 SO2 3 1 VOC CO2e 4 1 Emission factors are based on potential engine manufacturer and are less than the requirements contained in NSPS Subpart IIII, 40 CFR 60.4202(d) for emergency fire pumps, which refers to Table 4 of NSPS Subpart IIII for emission limits. 2 PM10 and PM2.5 emission factor is from the vendor provided PM rate (as g/HP-hr and converted to lb/MMBtu) plus the condensable PM (as lb/MMBtu) from USEPA AP-42, Chapter 3.4, Table 3.4-2. AP-42 Chapter 3.3 does not provide condensable PM. Thus, the condensable PM is from Chapter 3.4. 3 SO2 emissions are based on USEPA AP-42, Chapter 3.4, Table 3.4-1. Sulfur content of diesel fiel is 0.0015%. Emission factor is lb/MMBtu (HHV). 4 CO2e global warming potential and emission factors obtained from 40 CFR 98 Subparts A and C, respectively. Emission factor is lb/MMBtu (HHV). The global warming potential for CH4 (25) and N2O (298) are consistent with the changes made by the USEPA on November 29, 2013. Table 3.2 Emission Calculation Methods Using lb/MMBtu Emission Factors E ST = C HI X EF E A = E ST X Annual Operating Hours / 2,000 lb/ton where: E ST = Short Term Emissions (lb/hr); E A = Annual Maximum Emissions (tpy); C HI = RICE Heat Input Capacity (MMBtu/hr); and EF = emission factor (lb/MMBtu) Using g/HP-hr Emission Factors E ST = C HP X EF / 453.59 g/lb E A = E ST X Annual Operating Hours / 2,000 lb/ton where: E ST = Short Term Emissions (lb/hr); E A = Annual Maximum Emissions (tpy); C HP = RICE Power Output Capacity (HP); and EF = emission factor (g/HP-hr) Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 1 of 1 Table 4 - Estimated NSR Pollutant Emissions from Natural Gas Fired Fuel Heaters Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Heat Input Capacity = Natural Gas HHV = Equivalent Annual Fuel Usage Rate per Fuel Heater = Equivalent Annual Fuel Usage Rate per Fuel Heater = Total Annual Heat Input Limit or Capacity = Annual Operation = 1 1 NOX MMBtu/hr Btu/CF 3.41E-03 MMCF/hr 21.8 MMCF/yr 22,330 MMBtu/yr 6,380 hr/yr 0.09 lb/MMBtu Short-Term Emissions per Fuel Heater (lb/hr) 0.3 0.12 lb/MMBtu 0.4 1.3 Emission Factor (See Notes) NSR Regulated Pollutant CO 3.5 1,026 2 Total Annual Emissions (tpy) 1.0 1.9 lb/MMCf 0.01 0.02 PM10 (Filterable + Condensable) 1 0.023 lb/MMBtu 0.1 0.3 PM2.5 (Filterable + Condensable) 1 0.023 lb/MMBtu 0.1 0.3 0.6 lb/MMCf 0.002 0.007 PM (Filterable) SO2 2 VOC 1 Lead 2 0.1 0.2 5.00E-04 lb/MMCf 1.71E-06 5.44E-06 2.18E-02 lb/MMCf 7.43E-05 2.37E-04 0.017 lb/MMBtu H2SO4 3 CO2 4 117 lb/MMBtu 409 1,306 CH4 4 2.20E-03 lb/MMBtu 0.01 0.02 N2 O 4 2.20E-04 lb/MMBtu 0.0008 0.002 410 1,307 GHG as CO2e 4 117 lb/MMBtu 1 Emission factors for CO, NOX, PM10, PM2.5, and VOC are based on vendor data. 2 Emission factors are based on USEPA AP-42 Chapter 1.4, Tables 1.4-1 and 1.4-2. 3 The H2SO4 emission factor assumes approximately 0.8% of the SO2 is emitted as SO3 and then converts to H2SO4 in the presence of moisture. This is then multiplied by the ratio of the molecular weight of H2SO4 to SO3 (which is 98/80). 4 Based on GWP and emission factors obtained from 40 CFR 98 Subparts A and C, respectively, for natural gas fuel. A factor of 2.20462 is used to convert kg/MMBtu to lb/MMBtu. Emission Calculation Methods E ST = C ST X EF / HHV E A = C A X EF / HHV / 2,000 lb/ton where: E ST = Short Term Emissions (lb/hr); E A = Annual Maximum Emissions (tpy); C ST = Total Heat Input Capacity (MMBtu/hr); C A = Annual Maximum Heat Input Capacity based on 6,380 hours/yr of operation (MMBtu/yr); EF = emission factor (lb/MMBtu); and HHV = Natural Gas Higher Heating Value (Btu/CF) Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 1 of 4 Table 5 - Project Related TAC and HAP Emissions Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Total Potential HAP Emissions = 2.7 tpy (Since the total HAPs are less than 10 tpy, the project is, by default, minor for a single HAP.) Table 5.1 - Short-Term and Annual TAC and HAP Emission Rates for CTGs Maximum Heat Input Rate = Annual Operation = TAC / HAP 1,3-Butadiene Acetaldehyde Acrolein Benzene Ethylbenzene Formaldehyde 3 Naphthalene PAH 4 Propylene Oxide Toluene Xylenes 1 2,045 MMBtu/hr 6,380 hr/yr CAS Number 106-99-0 75-07-0 107-02-8 71-43-2 100-41-4 50-00-0 91-20-3 ---75-56-9 108-88-3 1330-20-7 Potential HAPs Emission Factor 1 Emission Rates 2 (lb/hr) (tpy) 8.79E-04 2.80E-03 8.18E-02 2.61E-01 1.31E-02 4.17E-02 2.45E-02 7.83E-02 6.54E-02 2.09E-01 (lb/MMBtu) 4.30E-07 4.00E-05 6.40E-06 1.20E-05 3.20E-05 9.00E-05 1.30E-06 1.84E-01 2.66E-03 5.87E-01 8.48E-03 2.20E-06 2.90E-05 1.30E-04 6.40E-05 4.50E-03 5.93E-02 2.66E-01 1.31E-01 Total CTG HAPs = 1.43E-02 1.89E-01 8.48E-01 4.17E-01 2.7 HAP? (Yes or No) Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Except for formaldehyde, the HAP emission factors are based upon the emissions factors of AP-42 Chapter 3.1, Table 3.1-3. 2 The short-term emissions are based on the hourly maximum heat input rate and the annual emissions are based on the annual operation at 100% capacity. Annual emissions reflect the potential for both CTGs. 3 4 Formaldehyde emission factor is based on a GE 7FA turbine from the June 2007 stack test for Zeeland Power Company, Zeeland, Michigan. "PAH" consists of a grouping of sixteen HAP polycyclic aromatic hydrocarbons. Table 5.1 Emission Calculation Methods E ST = C ST X EF E A = E ST X Annual Operation / 2,000 lb/ton where: E ST = Short Term Emissions (lb/hr); E A = Annual Maximum Emissions (tpy); C ST = Total Heat Input Capacity (MMBtu/hr); and EF = emission factor (lb/MMBtu) Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 2 of 4 Table 5 - Project Related TAC and HAP Emissions Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Table 5.2 - Short-Term and Annual TAC and HAP Emission Rates for One Emergency Generator Mechanical Power = Equivalent Heat Input Rate = Annual Operation = TAC / HAP Acenaphthene Acenaphthylene Acetaldehyde Acrolein Anthracene Benzene Benzo (a) anthracene Benzo (b) fluoranthene Benzo (a) pyrene Benzo (g,h,i) perylene Benzo (k) fluoranthene Chrysene Dibenz(a,h)anthracene Fluoranthene Fluorene Formaldehyde Indeno(1,2,3-c,d)pyrene Naphthalene PAH 4 Phenanthrene Propylene Pyrene Toluene Xylenes 6 2,011 13.44 100 CAS Number 83-32-9 208-96-8 75-07-0 107-02-8 120-12-7 71-43-2 56-55-3 205-99-2 50-32-8 191-24-2 207-08-9 218-01-9 53-70-3 206-44-0 86-73-7 50-00-0 193-39-5 91-20-3 ---85-01-8 115-07-1 129-00-0 108-88-3 1330-20-7 HP MMBtu/hr hr/yr Emission Factor 6 (lb/MMBtu) Short-term Emission Rate (lb/hr) Annual Emission Rate (tpy) 4.68E-06 9.23E-06 2.52E-05 7.88E-06 1.23E-06 7.76E-04 6.22E-07 1.11E-06 2.57E-07 5.56E-07 2.18E-07 1.53E-06 3.46E-07 4.03E-06 1.28E-05 7.89E-05 4.14E-07 1.30E-04 6.29E-05 1.24E-04 3.39E-04 1.06E-04 1.65E-05 1.04E-02 8.36E-06 1.49E-05 3.45E-06 7.47E-06 2.93E-06 2.06E-05 4.65E-06 5.42E-05 1.72E-04 1.06E-03 5.56E-06 1.75E-03 3.14E-06 6.20E-06 1.69E-05 5.30E-06 8.27E-07 5.21E-04 4.18E-07 7.46E-07 1.73E-07 3.74E-07 1.46E-07 1.03E-06 2.33E-07 2.71E-06 8.60E-06 5.30E-05 2.78E-07 8.74E-05 2.12E-04 2.85E-03 4.08E-05 5.48E-04 2.79E-03 3.75E-02 3.71E-06 4.99E-05 2.81E-04 3.78E-03 1.93E-04 2.59E-03 Total Emergency Generator HAPs = 1.42E-04 2.74E-05 1.87E-03 2.49E-06 1.89E-04 1.30E-04 0.001 HAP? (Yes or No) No No Yes Yes No Yes Yes Yes Yes Yes Yes Yes Yes No No Yes Yes Yes Yes No No No Yes Yes Emission factors obtained from USEPA AP-42, Chapter 3.4, Tables 3.4-3 and 3.4-4. Table 5.3 Emission Calculation Methods E ST = C ST X EF E A = E ST X Annual Operation / 2,000 lb/ton where: E ST = Short Term Emissions (lb/hr); E A = Annual Maximum Emissions (tpy); C ST = Total Heat Input Capacity (MMBtu/hr); and EF = emission factor; (lb/MMBtu) Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 3 of 4 Table 5 - Project Related TAC and HAP Emissions Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Table 5.3 - Short-Term and Annual TAC and HAP Emission Rates for One Backup Fire Pump Mechanical Power = Equivalent Heat Input Rate = Annual Operation = TAC / HAP 1,3-Butadiene Acenaphthene Acenaphthylene Acetaldehyde Acrolein Anthracene Benzene Benzo (a) anthracene Benzo (b) fluoranthene Benzo (a) pyrene Benzo (g,h,i) perylene Benzo (k) fluoranthene Chrysene Dibenz(a,h)anthracene Fluoranthene Fluorene Formaldehyde Indeno(1,2,3-c,d)pyrene Naphthalene PAH 4 Phenanthrene Propylene Pyrene Toluene Xylenes 7 347 2.31 100 HP MMBtu/hr hr/yr CAS Number 106-99-0 83-32-9 208-96-8 75-07-0 107-02-8 120-12-7 71-43-2 56-55-3 205-99-2 50-32-8 191-24-2 207-08-9 218-01-9 53-70-3 206-44-0 86-73-7 50-00-0 193-39-5 91-20-3 ---85-01-8 115-07-1 129-00-0 108-88-3 1330-20-7 Emission Factor 7 (lb/MMBtu) 3.91E-05 1.42E-06 5.06E-06 7.67E-04 9.25E-05 1.87E-06 9.33E-04 1.68E-06 9.91E-08 1.88E-07 4.89E-07 1.55E-07 3.53E-07 5.83E-07 7.61E-06 2.92E-05 1.18E-03 3.75E-07 8.48E-05 Short-term Emission Rate (lb/hr) Annual Emission Rate (tpy) HAP? (Yes or No) 9.04E-05 4.52E-06 Yes 3.28E-06 1.17E-05 1.77E-03 2.14E-04 4.32E-06 2.16E-03 3.89E-06 2.29E-07 4.35E-07 1.13E-06 3.58E-07 8.16E-07 1.35E-06 1.76E-05 6.75E-05 2.73E-03 8.67E-07 1.96E-04 3.89E-04 6.80E-05 5.97E-03 1.11E-05 9.46E-04 6.59E-04 1.64E-07 5.85E-07 8.87E-05 1.07E-05 2.16E-07 1.08E-04 1.94E-07 1.15E-08 2.17E-08 5.65E-08 1.79E-08 4.08E-08 6.74E-08 8.80E-07 3.38E-06 1.36E-04 4.34E-08 9.81E-06 1.94E-05 3.40E-06 2.98E-04 5.53E-07 4.73E-05 3.30E-05 0.0005 No No Yes Yes No Yes Yes Yes Yes Yes Yes Yes Yes No No Yes Yes Yes Yes No No No Yes Yes 1.68E-04 2.94E-05 2.58E-03 4.78E-06 4.09E-04 2.85E-04 Total Backup Fire Pump HAPs = Emission factors obtained from USEPA AP-42, Chapter 3.3, Table 3.3-2. Table 5.3 Emission Calculation Methods E ST = C ST X EF E A = E ST X Annual Operation / 2,000 lb/ton where: E ST = Short Term Emissions (lb/hr); E A = Annual Maximum Emissions (tpy); C ST = Total Heat Input Capacity (MMBtu/hr); and, EF = emission factor; (lb/MMBtu) Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 4 of 4 Table 5 - Project Related TAC and HAP Emissions Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Table 5.4 - Short-Term and Annual TAC and HAP Emissions From Two Fuel Heaters Heat Input Capacity = Annual Heat Input = Natural Gas HHV = TAC / HAP Metals Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Manganese Mercury Molybdenum Nickel Selenium Vanadium Zinc Organics 2-Methyl Naphthalene 3-Methylcholanthrene Acenaphthene Acenaphthylene Anthracene Benzene Benzo (a) anthracene Benzo (a) pyrene Benzo (b) fluoranthene Benzo (g,h,i) perylene Benzo (k) fluoranthene Chrysene Dibenzo(a,h) anthracene Dichlorobenzene, mixed isomers Dimethylbenz(a)anthracene Fluoranthene Fluorene Formaldehyde Indeno(1,2,3-cd)pyrene Naphthalene n-Butane N-Hexane N-Pentane Phenanthrene Pyrene Toluene Total Fuel Heaters HAPs = 8 7.0 61,320 1,026 MMBtu/hr (2 Heaters at 3.5 MMBtu/hr Each) MMBtu/yr Btu/CF Emission Factor Units Short-Term Emissions per Fuel Heater (lb/hr) Combined ShortTerm Emissions (lb/hr) 2.00E-04 4.40E-03 1.20E-05 1.10E-03 1.40E-03 8.40E-05 8.50E-04 3.80E-04 2.60E-04 1.10E-03 2.10E-03 2.40E-05 2.30E-03 2.90E-02 lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF 6.82E-07 1.50E-05 4.09E-08 3.75E-06 4.78E-06 2.87E-07 2.90E-06 1.30E-06 8.87E-07 3.75E-06 7.16E-06 8.19E-08 7.85E-06 9.89E-05 1.36E-06 3.00E-05 8.19E-08 7.50E-06 9.55E-06 5.73E-07 5.80E-06 2.59E-06 1.77E-06 7.50E-06 1.43E-05 1.64E-07 1.57E-05 1.98E-04 2.40E-05 1.80E-06 1.80E-06 1.80E-06 2.40E-06 2.10E-03 1.80E-06 1.20E-06 1.80E-06 1.20E-06 1.80E-06 1.80E-06 1.20E-06 1.20E-03 1.60E-05 3.00E-06 2.80E-06 7.50E-02 1.80E-06 6.10E-04 2.10E+00 1.80E+00 2.60E+00 1.70E-05 5.00E-06 3.40E-03 lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF lb/MMCF 8.19E-08 6.14E-09 6.14E-09 6.14E-09 8.19E-09 7.16E-06 6.14E-09 4.09E-09 6.14E-09 4.09E-09 6.14E-09 6.14E-09 4.09E-09 4.09E-06 5.46E-08 1.02E-08 9.55E-09 2.56E-04 6.14E-09 2.08E-06 7.16E-03 6.14E-03 8.87E-03 5.80E-08 1.71E-08 1.16E-05 1.64E-07 1.23E-08 1.23E-08 1.23E-08 1.64E-08 1.43E-05 1.23E-08 8.19E-09 1.23E-08 8.19E-09 1.23E-08 1.23E-08 8.19E-09 8.19E-06 1.09E-07 2.05E-08 1.91E-08 5.12E-04 1.23E-08 4.16E-06 1.43E-02 1.23E-02 1.77E-02 1.16E-07 3.41E-08 2.32E-05 Emission Factor Value 8 (lb/MMCF) 7440-38-2 7440-39-3 7440-41-7 7440-43-9 18540-29-9 7440-48-4 7440-50-8 7439-96-5 7439-97-6 7439-98-7 7440-02-0 7782-49-2 7440-62-2 7440-66-6 91-57-6 56-49-5 83-32-9 208-96-8 120-12-7 71-43-2 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 218-01-9 53-70-3 25321-22-6 57-97-6 206-44-0 86-73-7 50-00-0 193-39-5 91-20-3 106-97-8 110-54-3 109-66-0 85-01-8 129-00-0 108-88-3 CAS No. Emission factors obtained from USEPA AP-42, Chapter 1.4, Tables 1.4-3 and 1.4-4. Table 5.4 Emission Calculation Methods E ST = C ST X EF / HHV E A = C A X EF / HHV / 2,000 lb/ton where: E ST = Short Term Emissions (lb/hr); E A = Annual Maximum Emissions (tpy); C ST = Total Heat Input Capacity (MMBtu/hr); C A = Annual Maximum Heat Input Capacity based on 8,760 hours/yr of operation (MMBtu/yr); EF = emission factor (lb/MMCF); and, HHV = Natural Gas Higher Heating Value (Btu/CF) Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 1 of 1 Table 6 - Total Annual Project NSR Regulated Pollutant Emissions Summary Air Permit to Install Application Alpine Power Plant, Elmira, Michigan NSR Regulated Pollutant CTG 1 Emergency Generator Backup Fire Pump Fuel Heaters Total Cumulative Emissions Major Source Threshold Major Source? Significance Threshold Significant Emissions? (tpy) 0.1 0.9 0.007 0.01 (tpy) 0.1 0.1 0.00 0.005 (tpy) 1.0 1.3 0.021 0.257 (tpy) 213.6 222.2 44.5 44.7 (tpy) 250 250 250 250 (Yes or No) No No No No (tpy) 100 40 25 15 (Yes or No) Yes Yes Yes Yes PM PM10 (tpy) 212.4 219.8 44.4 44.4 PM2.5 44.4 0.01 0.005 0.257 44.7 250 No 10 Yes SO2 14.3 24.0 ---0.14 0.001 0.02 ------- 1.75E-04 0.00 ------- 0.007 0.2 0.00001 0.0002 14.3 24.2 0.00001 0.1 250 250 250 250 No No No No 40 40 0.6 7 No No No No 771,327 110 19 1,307 772,763 NA CO NOX VOC Lead H2SO4 GHG (as CO2e) 1 2 NA 2 NA 2 NA 2 CTG emissions are total for both CTGs and includes startup and shutdown emissions. 2 Based on the June 23, 2014 US Supreme Court decision, GHG emissions do not trigger a major source requirement in and of itself. At least one of the "traditional" ("anyway" or "conventional") NSR regulated pollutants would need to trigger a major source requirement before GHG emissions are evaluated pursuant to the major NSR PSD program. Since none of the "traditional" NSR regulated pollutants are major, the major and significant thresholds are NA (not applicable) for GHG emissions. Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 1 of 1 Table 7 – VOC BACT Economic Calculations for Each CTG Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Parameters Assumptions Heat Recovery Operating Temperature Oxidation efficiency Capital Cost Components Equipment Costs: -- Basic Equipment, e.g., Incinerator: -- Other (auxiliary equipment, etc.): Total Equipment Cost--base: Total Equipment Cost --escalated: Purchased Equipment Cost : Total Capital Investment (1995 $): Total Capital Investment (1998 $): Annualized Cost Components Direct Operating Costs: Operating labor Supervisory labor Maintenance labor Maintenance materials Natural gas Electricity Catalyst replacement Recuperative Combustion 0,35,50 or 70 Total Annualized Cost($): Tons of VOCs Controlled (TPY): Cost Effectiveness: ($/ton Controlled) 956,150 1138 50.7 0 40 44 0.067 3.49 0.07 0.824404522 Operating hours (hours/year) 3,190 Regenerative Combustion 70% 85 or 95 1,400 99% $13,362,784.82 $0.00 $13,362,784.82 $17,817,164.10 $21,024,253.64 $33,849,048.36 $41,058,785.41 Sub total Indirect Operating Costs: Overhead Taxes, insurance, administrative Capital recovery Input Parameters Waste stream flow rate (scfm) Waste stream temperature (deg F) Annual VOC + CO emission (tpy) Gross heat of combustion (btu/lb, toluene) Operating Labor Rate ($/hr) Maintenance Labor Rate ($/hr, OLR*1.1) Electricity Price ($/kwh) Natural Gas Price ($/mmBtu or $/mscf) Annual interest rate (fraction): Means CPI (1995 to 2014) Catalytic Combustion 95% 0,35,50 or 70 1,400 99% $26,076,857.01 $31,631,142.62 0% 600 99% $11,134,066.99 $0.00 $11,134,066.99 $12,938,353.99 $15,267,257.71 $24,580,284.91 $29,815,805.54 $7,975.00 $1,196.25 $8,772.50 $8,772.50 $2,950,066.04 $2,263,683.14 $0.00 $5,240,465.42 Sub total $7,975.00 $1,196.25 $2,288.00 $2,288.00 $457,937.99 $797,567.55 $0.00 $1,269,252.80 Sub total $16,029.75 $1,642,351.42 $5,845,847.33 $8,248.35 $1,265,245.70 $4,503,563.09 $16,029.75 $1,192,632.22 $4,060,443.62 $12,744,693.92 50.2 $253,913.77 $7,046,309.95 50.2 $140,384.32 $6,976,522.62 50.2 $138,993.94 Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\TBL 7_VOC BACT_CTG_2014_1113.xlsx $7,975.00 $1,196.25 $8,772.50 $8,772.50 -$1,468,215.14 $2,484,719.94 $664,195.97 $1,707,417.03 12/4/2014 Page 1 of 1 Table 8 – VOC BACT Economic Calculations for the Emergency Generator Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Parameters Assumptions Heat Recovery Operating Temperature Oxidation efficiency Capital Cost Components Equipment Costs: -- Basic Equipment, e.g., Incinerator: -- Other (auxiliary equipment, etc.): Total Equipment Cost--base: Total Equipment Cost --escalated: Purchased Equipment Cost : Total Capital Investment (1995 $): Total Capital Investment (1998 $): Annualized Cost Components Direct Operating Costs: Operating labor Supervisory labor Maintenance labor Maintenance materials Natural gas Electricity Catalyst replacement Recuperative Combustion 0,35,50 or 70 Total Annualized Cost($): Tons of VOCs Controlled (TPY): Cost Effectiveness: ($/ton Controlled) 4,743 759 0.12 0 40 44 0.067 3.49 0.07 0.824404522 Operating hours (hours/year) 3,190 Regenerative Combustion 70% 85 or 95 1,400 99% $177,426.51 $0.00 $177,426.51 $236,570.24 $255,495.86 $319,369.83 $387,394.56 Sub total Indirect Operating Costs: Overhead Taxes, insurance, administrative Capital recovery Input Parameters Waste stream flow rate (scfm) Waste stream temperature (deg F) Annual VOC + CO emission (tpy) Gross heat of combustion (btu/lb, toluene) Operating Labor Rate ($/hr) Maintenance Labor Rate ($/hr, OLR*1.1) Electricity Price ($/kwh) Natural Gas Price ($/mmBtu or $/mscf) Annual interest rate (fraction): Means CPI (1995 to 2014) $0.00 $0.00 $8,772.50 $8,772.50 $22,523.44 $8,587.14 $0.00 $48,655.58 Sub total Catalytic Combustion 95% 0,35,50 or 70 1,400 99% $763,644.76 $926,298.61 $0.00 $0.00 $2,288.00 $2,288.00 $3,108.46 $3,957.43 $0.00 $11,641.89 Sub total 0% 600 99% $155,255.27 $0.00 $155,255.27 $180,414.55 $194,847.71 $243,559.64 $295,437.05 $0.00 $0.00 $8,772.50 $8,772.50 $307.08 $9,424.90 $3,302.70 $30,579.68 $10,527.00 $15,495.78 $55,156.27 $2,745.60 $37,051.94 $131,884.08 $10,527.00 $11,817.48 $41,145.39 $129,834.63 0.1188 $1,092,884.12 $183,323.52 0 $1,543,127.24 $94,069.56 0.1188 $791,831.28 Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\TBL 8_VOC BACT_Emer Gen_2014_1113.xlsx 12/4/2014 Page 1 of 1 Table 9 – VOC BACT Economic Calculations for the Backup Fire Pump Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Parameters Assumptions Heat Recovery Operating Temperature Oxidation efficiency Capital Cost Components Equipment Costs: -- Basic Equipment, e.g., Incinerator: -- Other (auxiliary equipment, etc.): Total Equipment Cost--base: Total Equipment Cost --escalated: Purchased Equipment Cost : Total Capital Investment (1995 $): Total Capital Investment (1998 $): Annualized Cost Components Direct Operating Costs: Operating labor Supervisory labor Maintenance labor Maintenance materials Natural gas Electricity Catalyst replacement Recuperative Combustion 0,35,50 or 70 Total Annualized Cost($): Tons of VOCs Controlled (TPY): Cost Effectiveness: ($/ton Controlled) 759 961 0.14 0 40 44 0.067 3.49 0.07 0.824404522 Operating hours (hours/year) 3,190 Regenerative Combustion 70% 85 or 95 1,400 99% $112,195.63 $0.00 $112,195.63 $149,595.17 $161,562.78 $201,953.47 $244,968.91 Sub total Indirect Operating Costs: Overhead Taxes, insurance, administrative Capital recovery Input Parameters Waste stream flow rate (scfm) Waste stream temperature (deg F) Annual VOC + CO emission (tpy) Gross heat of combustion (btu/lb, toluene) Operating Labor Rate ($/hr) Maintenance Labor Rate ($/hr, OLR*1.1) Electricity Price ($/kwh) Natural Gas Price ($/mmBtu or $/mscf) Annual interest rate (fraction): Means CPI (1995 to 2014) $0.00 $0.00 $8,772.50 $8,772.50 $2,932.87 $1,600.55 $0.00 $22,078.42 Sub total Catalytic Combustion 95% 0,35,50 or 70 1,400 99% $658,785.24 $799,104.35 $0.00 $0.00 $2,288.00 $2,288.00 $387.56 $633.46 $0.00 $5,597.02 Sub total 0% 600 99% $56,365.44 $0.00 $56,365.44 $65,499.52 $70,739.49 $88,424.36 $107,258.46 $0.00 $0.00 $8,772.50 $8,772.50 -$598.53 $1,756.77 $528.10 $19,231.34 $10,527.00 $9,798.76 $34,878.06 $2,745.60 $31,964.17 $113,774.48 $10,527.00 $4,290.34 $15,124.37 $77,282.23 0.1386 $557,591.88 $154,081.28 0 $1,111,697.52 $49,173.05 0.1386 $354,783.91 Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\TBL 9_VOC BACT_Fire Pump_2014_1113.xlsx 12/4/2014 Page 1 of 1 Table 10 – VOC BACT Economic Calculations for Each Fuel Heater Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Parameters Assumptions Heat Recovery Operating Temperature Oxidation efficiency Capital Cost Components Equipment Costs: -- Basic Equipment, e.g., Incinerator: -- Other (auxiliary equipment, etc.): Total Equipment Cost--base: Total Equipment Cost --escalated: Purchased Equipment Cost : Total Capital Investment (1995 $): Total Capital Investment (1998 $): Annualized Cost Components Direct Operating Costs: Operating labor Supervisory labor Maintenance labor Maintenance materials Natural gas Electricity Catalyst replacement Recuperative Combustion 0,35,50 or 70 Total Annualized Cost($): Tons of VOCs Controlled (TPY): Cost Effectiveness: ($/ton Controlled) 529 441 1.2 0 40 44 0.067 3.49 0.07 0.824404522 Operating hours (hours/year) 3,190 Regenerative Combustion 70% 85 or 95 1,400 99% $102,607.16 $0.00 $102,607.16 $136,810.44 $147,755.28 $184,694.10 $224,033.34 Sub total Indirect Operating Costs: Overhead Taxes, insurance, administrative Capital recovery Input Parameters Waste stream flow rate (scfm) Waste stream temperature (deg F) Annual VOC + CO emission (tpy) Gross heat of combustion (btu/lb, toluene) Operating Labor Rate ($/hr) Maintenance Labor Rate ($/hr, OLR*1.1) Electricity Price ($/kwh) Natural Gas Price ($/mmBtu or $/mscf) Annual interest rate (fraction): Means CPI (1995 to 2014) $0.00 $0.00 $8,772.50 $8,772.50 $3,252.91 $709.91 $0.00 $21,507.82 Sub total Catalytic Combustion 95% 0,35,50 or 70 1,400 99% $652,741.23 $791,772.98 $0.00 $0.00 $2,288.00 $2,288.00 $467.11 $441.87 $0.00 $5,484.98 Sub total 0% 600 99% $46,260.71 $0.00 $46,260.71 $53,757.30 $58,057.89 $72,572.36 $88,030.04 $0.00 $0.00 $8,772.50 $8,772.50 $745.13 $779.12 $369.38 $19,438.64 $10,527.00 $8,961.33 $31,897.31 $2,745.60 $31,670.92 $112,730.66 $10,527.00 $3,521.20 $12,430.80 $72,893.47 1.188 $61,358.14 $152,632.16 1 $128,478.25 $45,917.64 1.188 $38,651.21 Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\TBL 10_VOC BACT_Fuel Heater_2014_1113.xlsx 12/4/2014 Page 1 of 2 Table 11 - Fabric Filter Economic Analysis for Each Fuel Gas Heater Air Permit to Install Application Alpine Power Plant, Elmira, Michigan CAPITAL COSTS Direct Costs Purchased Equipment Costs Control Device $74,288 Based on vendor estimate and adjusted for exhaust gas flow rate from fuel heater using an algorithm called the "Six Tenths Rule" for estimating capital costs. Instrumentation Freight Purchased Equipment Cost, PEC (B) 10% of control device cost (A) 5% of control device cost (A) 21% $7,429 $3,714 $85,431 EPA Air Pollution Control Cost Manual 6th Edition EPA Air Pollution Control Cost Manual 6th Edition Direct Installation Costs Foundations & supports Handling & erection Electrical Piping Insulation Painting Direct Installation Costs 4% 50% 8% 1% 7% 4% 74% $3,417 $42,715 $6,834 $854 $5,980 $3,417 $63,219 EPA Air Pollution Control Cost Manual 6th Edition EPA Air Pollution Control Cost Manual 6th Edition EPA Air Pollution Control Cost Manual 6th Edition EPA Air Pollution Control Cost Manual 6th Edition EPA Air Pollution Control Cost Manual 6th Edition EPA Air Pollution Control Cost Manual 6th Edition Retrofit Cost of purchased equip cost (B) of purchased equip cost (B) of purchased equip cost (B) of purchased equip cost (B) of purchased equip cost (B) of purchased equip cost (B) 30% Site Specific $22,286 Site Specific $0 Buildings, as required Total Direct Costs, DC Indirect Costs Engineering Construction and field expenses Contractor fees Start-up Performance test Contingencies Total Indirect Costs, IC Total Capital Investment = DC + IC Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\TBL 11_Metal TAC_BACT BH (PM) Fuel Heater Cost Estimate 2014_1114.xls EPA Cost Manual 6th Edition for Retrofit on Existing Process Assumed not necessary. $170,936 10% 20% 10% 1% 1% 3% 35% of purchased equip cost (B) of purchased equip cost (B) of purchased equip cost (B) of purchased equip cost (B) of purchased equip cost (B) of purchased equip cost (B) $8,543 $17,086 $8,543 $854 $854 $2,563 $29,901 EPA Air Pollution Control Cost Manual 6th Edition EPA Air Pollution Control Cost Manual 6th Edition EPA Air Pollution Control Cost Manual 6th Edition EPA Air Pollution Control Cost Manual 6th Edition EPA Air Pollution Control Cost Manual 6th Edition EPA Air Pollution Control Cost Manual 6th Edition $200,837 12/4/2014 Page 2 of 2 ANNUAL COSTS Direct Annual Costs, DC Operating Labor Operator Supervisor Operating Materials Bag replacement Electricity for Fan, 7" pressure drop (water), 92,970 acfm Maintenance Labor Materials 2.00 hr/shift, 3 shifts/day, 342 days/yr 15% of operator 965,903 KwH 1.00 hr/shift, 3 shifts/day, 342 days/yr 100% of maintenance labor Total Direct Annual Costs, DC Indirect Annual Costs Overhead Administrative Charges Property tax Insurance Capital Recovery 8.72% for a 20 - year equipment life and a 6% interest rate Total Indirect Annual Costs, IC $61,560 $9,234 Effort required to operate the baghouse Effort required to operate the baghouse $19,000 EPA Air Pollution Control Cost Manual 6th Edition $64,715 EPA Air Pollution Control Cost Manual 6th Edition $30,780 $30,780 Effort required to maintain the baghouse Effort required to maintain the baghouse $151,354 60% 2% 1% 1% 8.72% Total Annual Costs = DC + IC Pollutant Removed (tons/yr) Cost per Ton of PM Removed of total labor and material costs of Total Capital Investment of Total Capital Investment of Total Capital Investment $90,812 $4,017 $0 $2,008 $17,513 $114,350 EPA Air Pollution Control Cost Manual 6th Edition EPA Air Pollution Control Cost Manual 6th Edition Property taxes are exempt in Michigan. EPA Air Pollution Control Cost Manual 6th Edition $265,704 0.02 See Note $13,419,419 NOTE - Based on PM removal of 99%. Uncontrolled PM emissions from one fuel heater is 0.02 tpy. Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\TBL 11_Metal TAC_BACT BH (PM) Fuel Heater Cost Estimate 2014_1114.xls 12/4/2014 Page 1 of 1 Table 12 – Structure Heights Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Structure CTG North Unit CTG South Unit 1 1 ID on Figure 2 Base Air Intake Unit#1 Base Air Intake Unit#2 Generator Pumphouse Warehouse2 Administration Building Water Tank 2 Maximum Structure Height (feet) 47 70 21 25 47 70 12 14 26 25 26 24 15 38 1 Individual portions of CTGs listed separately in legend of Figure 2. The portions of the CTGs considered as structures in the model include IDs 1, 6 and 30. Each CTG was conservatively modeled as a structure with two tier heights: the base of the entire structure was modeled at 47 ft, while the air intake was modeled at a height of 70 ft. Actual structure heights may be lower. 2 The warehouse and administration building are both shown as ID #26 on Figure 2. The warehouse (25 ft) is the west portion of the structure; the administration building (15 ft) is the east portion of the structure. Note: This table represents the structures for which a stack is located within the downwash area of the structure ("5L"). Note that the blocks shown on the diagram for the fuel gas metering and conditioning areas represent area designations and not buildings. Note: Structures and equipment less than 10 feet in height were considered insignificant and not included in the assessment. Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 1 of 1 Table 13 – Model Input Parameters Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Source CTG North Unit1 CTG South Unit1 Fuel Gas Heater North Fuel Gas Heater South Emergency Generator 2 Fire Pump 2 Model Name NAD 83 UTM Coordinates Base (m) Elevation Easting Northing (feet) Stack Height (feet) Stack Diameter (feet) Exhaust Temperature (deg F) Exhaust Flow Rate (acfm) Exit Velocity (fps) NOx CO Emission PM10/PM2.5 Emission Rate Emission Rate (lbs/hr) Rate (lbs/hr) (lbs/hr) CTGN 671,105 4,992,377 1,313.5 85 22 1,093 2,482,731 108.9 87.9 13.5 371.4 CTGS FGHN FGHS 671,107 671,199 671,199 4,992,336 4,992,301 4,992,297 1,313.5 1,313.5 1,313.5 85 16 16 22 0.83 0.83 1,093 441 441 2,482,731 900 900 108.9 27.5 27.5 87.9 0.42 0.42 13.5 0.081 0.081 371.4 0.32 0.32 EMGEN 671,093 4,992,321 1,313.5 14 1 759 10,909 231.5 0.21 0.24 2.0 FIREPUMP 671,109 4,992,286 1,313.5 16 0.67 1076 1,900 90.7 0.019 0.11 1.1 1 The maximum emission rates for either a start-up hour or a baseload hour was used in the modeling along with the hourly average exhaust flow rate. Details are provided in Table 14. The annual average hourly emission rates from the Fire Pump and Emergency Generator (based on 100 hours/year operation) were utilized for NO2 modeling. The maximum hourly emission rates were utilized for all other pollutants. 2 Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 1 of 1 Table 14 – Hourly Average Stack Parameters per CTG during Startup/Shutdown Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Maximum Startup/Shutdown NOx Emissions1 (lbs/event) Maximum Startup/Shutdown Duration (mins) NOx Baseload Emissions (lbs/hr/stack) NOx Baseload Emissions (lbs/min/stack) Duration of Baseload Operation During Startup/Shutdown Hour (mins) Baseload Emissions During Startup/Shutdown Hour (lbs) Total NOx Emissions for Startup/Shutdown2 (lbs/hr/stack) 30 8 66.76 1.11 52 57.86 87.9 Maximum Startup/Shutdown CO Emissions1 (lbs/event) Maximum Startup/Shutdown Duration (mins) CO Baseload Emissions (lbs/hr/stack) CO Baseload Emissions (lbs/min/stack) Duration of Baseload Operation During Startup/Shutdown Hour (mins) Baseload Emissions During Startup/Shutdown Hour (lbs) Total CO Emissions for Startup/Shutdown2 (lbs/hr/stack) 336 8 40.9 0.68 52 35.44 371.4 Duration of Baseload Operation During Startup/Shutdown Hour (mins) 52 Baseload Emissions During Startup/Shutdown Hour (lbs) 0.01 Total PM10/PM2.5 Emissions for Startup/Shutdown2 (lbs/hr/stack) 5.8 Maximum Startup/Shutdown PM10/PM2.5 Emissions1 (lbs/event) 5.84 Maximum Startup Exhaust Flow Rate (acfm)3 332,830 1 Maximum Startup/Shutdown Duration (mins) 8 PM10/PM2.5 Baseload PM10/PM2.5 Baseload Emissions Emissions (lbs/hr/stack) (lbs/min/stack) 6.60E-03 1.10E-04 Startup Exhaust Temp Startup Exhaust Flow (deg F) Rate (scfm) 800 140,000 Duration of Startup (mins) Baseload Exhaust Flow Rate (acfm) Baseload Exhaust Temp (deg F) Baseload Exhaust Flow Rate (scfm) Baseload Duration during Startup Hour (mins) 8 2,882,883 1,138 956,150 52 Hourly Average Exhaust Flow Rate Hourly Average Hourly Average During Startup Hour Temperature Exhaust Flow (scfm) (deg F) Rate (acfm) 847,330 1,093 2,482,731 Both startup and shutdown emissions (per event) were considered and the higher emission rate was selected. 2 This emission rate represents the total worst-case emission rate during a startup or shutdown hour. Manufacturer data indicated an exhaust flow rate of 175 pounds per second at the midpoint of the start-up operations. This was converted to an acfm based on an exhaust flow temperature of 800 degrees Fahrenheit. Shutdown exhaust flow rates were assumed to be proportional to startup. 3 Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 1 of 1 Table 15 – SIL Model Results Summary Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Maximum Predicted Impacts SIL 2011 2012 2013 Maximum Pollutant (µg/m3) CO 142.1 141.6 151.0 151.0 2000 CO 71.0 81.3 82.2 98.8 500 NO2 0.9 1.1 1.1 1.2 1 NO2 37.0 37.0 7.6 PM25 0.4 0.5 0.4 0.5 0.4 0.5 0.3 PM25 3.5 3.5 1.2 PM10 0.4 0.5 0.4 0.5 0.4 0.5 1 PM10 5.4 3.8 4.0 4.3 3.7 5.4 5 Note: The impact for 1-hour NO2 represents Tier 1, where 100% of NOx is conservatively assumed to be NO2. 2009 147.8 98.8 0.9 2010 139.1 80.7 1.2 Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx SIL Averaging Period 1-hr 8-hr Annual 1-hr Annual 24-hr Annual 24-hr Exceeds SIL No No Yes Yes Yes Yes No Yes 12/4/2014 Page 1 of 1 Table 16 – PSD Increment Model Results Summary Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Maximum Predicted Impacts Increment 2009 2010 2011 2012 2013 Maximum Pollutant (µg/m3) NO2 0.9 1.2 0.9 1.1 1.1 1.2 25 PM25 0.4 0.5 0.4 0.5 0.4 0.5 4 PM25 5.4 3.8 4.0 4.3 3.7 5.4 9 PM10 5.4 3.8 4.0 4.3 3.7 5.4 30 Note: The impact for 1-hour NO2 represents Tier 1, where 100% of NOx is conservatively assumed to be NO2. Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx Increment Averaging Period Annual Annual 24-hr 24-hr Exceeds Increment No No No No 12/4/2014 Page 1 of 1 Table 17 – NAAQS Model Results Summary Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Maximum Predicted Impacts (µg/m3) Pollutant NO2 NO2 PM25 PM25 PM10 2009 2010 0.9 1.2 0.4 0.5 5.4 3.8 2011 0.9 24.3 0.4 2.3 4.0 2012 2013 Maximum 1.1 1.1 0.5 0.4 4.3 3.7 1.2 24.3 0.4 2.3 5.4 Background Concentration (µg/m3) 2.6 15.7 5.9 16.8 29.0 Combined Impact (µg/m3) 3.8 39.9 6.3 19.0 34.4 NAAQS (µg/m3) 100 188 12 35 150 NAAQS Averaging Period Annual 1-hr Annual 24-hr 24-hr Exceeds NAAQS No No No No No Averaging Period Annual 8TH-HIGHEST MAX DAILY 1-HR Annual 8TH-HIGHEST 24-HR 24-hr Note: The impact for 1-hour NO2 represents Tier 1, where 100% of NOx is conservatively assumed to be NO2. Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 1 of 1 Table 18 – Illustrative Analysis of Possible Secondary PM2.5 Impacts Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Short Term Annual Max. Project NO2 Impacts (1-hour, Annual) 37.0 1.2 Maximum Possible Project PM2.5 Impact from Precursor Emissions (based on conversion to PM2.5 using Interpollutant Trading Ratios (below)) 0.19 0.0061 PM2.5 24-hour and Annual Class II Significant Impact Levels (SILs) NAAQS Background Concentration (provided by MDEQ) Otsego County "room" under the NAAQS Possible Project Impact vs Room (percent) 1.2 35 16.8 18.2 1.0% 0.3 12 5.9 6.1 0.10% Interpollutant Trading Ratio assumption (2008 USEPA) Tons NO2 equating to one Ton PM2.5 200 Note: See Section 6.0 of the application text for additional information. Note: The impacts in this table are estimations and are intended for illustrative purposes only. These estimated impacts show that contributions from secondary formation of PM2.5 are anticipated to be very low and do not warrant quantitative impact modeling. Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 1 of 1 Table 19 – Unitized Model Results Air Permit to Install Application Alpine Power Plant, Elmira, Michigan Averaging Period Annual 1-HR 3-HR 8-HR 24-HR CTG North Model CTG South Model FGH North Model FGH South Model Results (CTGN) Results (CTGS) Results (FGHN) Results (FGHS) (ug/m3)/(lb/hr) (ug/m3)/(lb/hr) (ug/m3)/(lb/hr) (ug/m3)/(lb/hr) 0.00064 0.00068 1.01599 0.99369 0.09818 0.09923 39.12213 39.59705 0.0565 0.07377 30.24523 30.58928 0.02534 0.03915 29.08055 29.54403 0.01324 0.01614 22.71918 23.0741 Emergency Fire Pump Model Generator Model Results Results (EMGEN) (FIREPUMP) (ug/m3)/(lb/hr) (ug/m3)/(lb/hr) 0.99802 1.28649 43.58403 97.85197 31.1687 56.49831 23.71752 42.06824 8.93468 24.99401 Note: The impacts presented in this table represent the unitized impact from each TAC emission source modeled at 1 lb/hr. Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx 12/4/2014 Page 1 of 1 Table 20 – Maximum PAI Air Permit to Install Application Alpine Power Plant, Elmira, Michigan CTGN Toxic Air Contaminant CAS No. Formaldehyde 50-00-0 Benzene 71-43-2 Xylene 1330-20-7 Acetaldehyde 75-07-0 Propylene Oxide 75-56-9 Acenaphthene Phenanthrene Fluorene 83-32-9 85-01-8 86-73-7 Naphthalene 91-20-3 2-Methyl Naphthalene 91-57-6 Ethylbenzene 100-41-4 n-Butane 106-97-8 1,3-Butadiene 106-99-0 Acrolein 107-02-8 Toluene N-Pentane N-Hexane Propylene Anthracene Pyrene Benzo (g,h,i) perylene Fluoranthene Acenaphthylene Manganese Molybdenum Nickel Arsenic Barium 108-88-3 109-66-0 110-54-3 115-07-1 120-12-7 129-00-0 191-24-2 206-44-0 208-96-8 7439-96-5 7439-98-7 7440-02-0 7440-38-2 7440-39-3 Beryllium 7440-41-7 Cadmium 7440-43-9 Chromium 18540-29-9 Cobalt 7440-48-4 Copper 7440-50-8 Selenium 7782-49-2 Polynuclear Aromatic Compounds Benzo (a) pyrene 50-32-8 Dibenz(a,h)anthracene 53-70-3 Benzo (a) anthracene 56-55-3 Dimethylbenz(a)anthracene 57-97-6 Indeno(1,2,3-c,d)pyrene 193-39-5 Benzo (b) fluoranthene 205-99-2 Benzo (k) fluoranthene 207-08-9 Chrysene 218-01-9 PAH TOTAL ---No Screening Level Compounds 3-Methylcholanthrene 56-49-5 Vanadium 7440-62-2 Zinc 7440-66-6 Dichlorobenzene, mixed isomers 25321-22-6 CTGS CTG North CTG North Model Results Emission Rate (ug/m3)/ (lb/hr) (lb/hr) 1.84E-01 0.01 1.84E-01 0.00 2.45E-02 0.00 2.45E-02 0.00 2.45E-02 0.01 1.31E-01 0.01 8.18E-02 0.01 8.18E-02 0.00 5.93E-02 0.01 5.93E-02 0.00 -0.01 -0.00 -0.01 2.66E-03 0.00 2.66E-03 0.00 2.66E-03 0.03 -0.00 6.54E-02 0.01 6.54E-02 0.00 -0.03 8.79E-04 0.01 8.79E-04 0.00 1.31E-02 0.00 1.31E-02 0.10 2.66E-01 0.01 -0.03 -0.01 -0.01 -0.01 -0.01 -0.01 -0.01 -0.01 -0.00 -0.03 -0.00 -0.00 -0.03 -0.01 -0.00 -0.00 -0.01 -0.00 -0.03 -0.03 -0.03 --------4.50E-03 ----- CTG North PAI 2.44E-03 1.18E-04 1.57E-05 1.57E-05 3.25E-04 1.73E-03 1.08E-03 5.23E-05 7.85E-04 3.79E-05 ---1.70E-06 1.70E-06 6.74E-05 -8.66E-04 4.19E-05 -1.16E-05 5.63E-07 8.37E-06 1.28E-03 3.52E-03 ---------------------- 0.00 --------0.00 0.00 0.00 0.00 0.00 ----- CTG South Emission Rate (lb/hr) 1.84E-01 1.84E-01 2.45E-02 2.45E-02 2.45E-02 1.31E-01 8.18E-02 8.18E-02 5.93E-02 5.93E-02 ---2.66E-03 2.66E-03 2.66E-03 -6.54E-02 6.54E-02 -8.79E-04 8.79E-04 1.31E-02 1.31E-02 2.66E-01 ------------------------------ 2.88E-06 4.50E-03 ----- Z:\2009\090066NEW\WORK\Rept\PTI\DRAFT PTI\WP_PTIApp_Emission Tables_2014_1204.xlsx FGHN CTG South Model Results (ug/m3)/ (lb/hr) 0.02 0.00 0.00 0.00 0.02 0.02 0.02 0.00 0.02 0.00 0.02 0.00 0.02 0.00 0.00 0.04 0.00 0.02 0.00 0.04 0.02 0.00 0.00 0.10 0.02 0.04 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.00 0.04 0.00 0.00 0.04 0.02 0.00 0.00 0.02 0.00 0.04 0.04 0.04 CTG South PAI 2.97E-03 1.25E-04 1.67E-05 1.67E-05 3.96E-04 2.11E-03 1.32E-03 5.56E-05 9.57E-04 4.03E-05 ---1.81E-06 1.81E-06 1.04E-04 -1.06E-03 4.45E-05 -1.42E-05 5.98E-07 8.90E-06 1.30E-03 4.29E-03 ---------------------- 0.00 --------0.00 0.00 0.00 0.00 0.00 ----- 3.06E-06 FGHS FGH North FGH North Model Results Emission Rate (ug/m3)/ (lb/hr) (lb/hr) 2.56E-04 22.72 2.56E-04 1.02 7.16E-06 1.02 7.16E-06 1.02 7.16E-06 22.72 -22.72 -22.72 -1.02 -22.72 -1.02 6.14E-09 22.72 5.80E-08 1.02 9.55E-09 22.72 2.08E-06 1.02 2.08E-06 1.02 2.08E-06 29.08 8.19E-08 1.02 -22.72 -1.02 7.16E-03 29.08 -22.72 -1.02 -1.02 -39.12 1.16E-05 22.72 8.87E-03 29.08 6.14E-03 22.72 -22.72 8.19E-09 22.72 1.71E-08 22.72 4.09E-09 22.72 1.02E-08 22.72 6.14E-09 22.72 1.30E-06 1.02 3.75E-06 29.08 7.16E-06 1.02 6.82E-07 1.02 1.50E-05 29.08 4.09E-08 22.72 4.09E-08 1.02 3.75E-06 1.02 4.78E-06 22.72 4.78E-06 1.02 2.87E-07 29.08 2.90E-06 29.08 8.19E-08 29.08 4.09E-09 4.09E-09 6.14E-09 5.46E-08 6.14E-09 6.14E-09 6.14E-09 6.14E-09 1.56E-08 6.14E-09 7.85E-06 9.89E-05 4.09E-06 FGH North PAI 5.81E-03 2.60E-04 7.28E-06 7.28E-06 1.63E-04 -----1.40E-07 5.89E-08 2.17E-07 2.11E-06 2.11E-06 6.05E-05 8.32E-08 --2.08E-01 ----2.64E-04 2.58E-01 1.40E-01 -1.86E-07 3.88E-07 9.30E-08 2.33E-07 1.40E-07 1.32E-06 1.09E-04 7.28E-06 6.93E-07 4.36E-04 9.30E-07 4.16E-08 3.81E-06 1.09E-04 4.85E-06 8.33E-06 8.43E-05 2.38E-06 FGH South FGH South Model Results Emission Rate (ug/m3)/ (lb/hr) (lb/hr) 2.56E-04 23.07 2.56E-04 0.99 7.16E-06 0.99 7.16E-06 0.99 7.16E-06 23.07 -23.07 -23.07 -0.99 -23.07 -0.99 6.14E-09 23.07 5.80E-08 0.99 9.55E-09 23.07 2.08E-06 0.99 2.08E-06 0.99 2.08E-06 29.54 8.19E-08 0.99 -23.07 -0.99 7.16E-03 29.54 -23.07 -0.99 -0.99 -39.60 1.16E-05 23.07 8.87E-03 29.54 6.14E-03 23.07 -23.07 8.19E-09 23.07 1.71E-08 23.07 4.09E-09 23.07 1.02E-08 23.07 6.14E-09 23.07 1.30E-06 0.99 3.75E-06 29.54 7.16E-06 0.99 6.82E-07 0.99 1.50E-05 29.54 4.09E-08 23.07 4.09E-08 0.99 3.75E-06 0.99 4.78E-06 23.07 4.78E-06 0.99 2.87E-07 29.54 2.90E-06 29.54 8.19E-08 29.54 FGH South PAI 5.90E-03 2.54E-04 7.12E-06 7.12E-06 1.65E-04 -----1.42E-07 5.76E-08 2.20E-07 2.07E-06 2.07E-06 6.15E-05 8.14E-08 --2.12E-01 ----2.68E-04 2.62E-01 1.42E-01 -1.89E-07 3.94E-07 9.45E-08 2.36E-07 1.42E-07 1.29E-06 1.11E-04 7.12E-06 6.78E-07 4.43E-04 9.45E-07 4.07E-08 3.73E-06 1.10E-04 4.75E-06 8.47E-06 8.57E-05 2.42E-06 Emergency Generator Emission Rate (lb/hr) 1.06E-03 1.06E-03 1.04E-02 1.04E-02 1.04E-02 2.59E-03 3.39E-04 3.39E-04 --6.29E-05 5.48E-04 1.72E-04 1.75E-03 1.75E-03 1.75E-03 ------1.06E-04 1.06E-04 3.78E-03 --3.75E-02 1.65E-05 4.99E-05 7.47E-06 5.42E-05 1.24E-04 -------------- 1.02 4.16E-09 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.58E-08 4.09E-09 4.09E-09 6.14E-09 5.46E-08 6.14E-09 6.14E-09 6.14E-09 6.14E-09 1.56E-08 0.99 4.07E-09 0.00E+00 0.00E+00 0.00E+00 -0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.55E-08 1.02 1.02 1.02 1.02 6.24E-09 7.97E-06 1.01E-04 4.16E-06 6.14E-09 7.85E-06 9.89E-05 4.09E-06 0.99 0.99 0.99 0.99 6.10E-09 7.80E-06 9.83E-05 4.07E-06 1.02 0.99 ----- 3.45E-06 4.65E-06 8.36E-06 EMGEN Emergency Generator Model Results (ug/m3)/ (lb/hr) 8.93 1.00 1.00 1.00 8.93 8.93 8.93 1.00 8.93 1.00 8.93 1.00 8.93 1.00 1.00 23.72 1.00 8.93 1.00 23.72 8.93 1.00 1.00 43.58 8.93 23.72 8.93 8.93 8.93 8.93 8.93 8.93 8.93 1.00 23.72 1.00 1.00 23.72 8.93 1.00 1.00 8.93 1.00 23.72 23.72 23.72 FIREPUMP Emergency Generator PAI 9.47E-03 1.06E-03 1.04E-02 1.04E-02 9.32E-02 2.32E-02 3.03E-03 3.38E-04 --5.62E-04 5.47E-04 1.54E-03 1.74E-03 1.74E-03 4.14E-02 ------1.06E-04 4.62E-03 3.37E-02 --3.35E-01 1.48E-04 4.45E-04 6.68E-05 4.84E-04 1.11E-03 -------------3.45E-06 0.00E+00 0.00E+00 1.00 -5.56E-06 1.49E-05 2.93E-06 2.06E-05 1.10E-05 4.35E-07 1.35E-06 3.89E-06 ----- --8.21E-05 8.75E-05 1.69E-03 2.52E-04 2.52E-04 8.25E-03 ----2.26E-03 1.16E-04 2.75E-04 2.09E-02 2.36E-02 --1.49E-01 1.08E-04 2.76E-04 2.83E-05 4.40E-04 2.92E-04 -------------5.59E-07 0.00E+00 0.00E+00 -- 8.67E-07 2.29E-07 3.58E-07 8.16E-07 2.29E-06 ----- Fire Pump PAI 6.82E-02 3.51E-03 2.78E-03 2.78E-03 5.39E-02 1.65E-02 4.43E-02 2.28E-03 1.29 -0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.10E-05 1.00 1.00 1.00 1.00 1.00 Fire Pump Fire Pump Model Results Emission Rate (ug/m3)/ (lb/hr) (lb/hr) 2.73E-03 24.99 2.73E-03 1.29 2.16E-03 1.29 2.16E-03 1.29 2.16E-03 24.99 6.59E-04 24.99 1.77E-03 24.99 1.77E-03 1.29 -24.99 -1.29 3.28E-06 24.99 6.80E-05 1.29 6.75E-05 24.99 1.96E-04 1.29 1.96E-04 1.29 1.96E-04 42.07 -1.29 -24.99 -1.29 -42.07 9.04E-05 24.99 9.04E-05 1.29 2.14E-04 1.29 2.14E-04 97.85 9.46E-04 24.99 -42.07 -24.99 5.97E-03 24.99 4.32E-06 24.99 1.11E-05 24.99 1.13E-06 24.99 1.76E-05 24.99 1.17E-05 24.99 -1.29 -42.07 -1.29 -1.29 -42.07 -24.99 -1.29 -1.29 -24.99 -1.29 -42.07 -42.07 -42.07 0.00E+00 0.00E+00 0.00E+00 0.00E+00 2.94E-06 1.29 1.29 1.29 1.29 1.29 ----- PAI Averaging Period Screening 3 (µg/m ) 9.48E-02 5.33E-03 1.32E-02 1.32E-02 1.48E-01 4.35E-02 4.98E-02 2.73E-03 1.74E-03 7.83E-05 6.44E-04 6.35E-04 3.23E-03 2.00E-03 2.00E-03 5.00E-02 1.65E-07 1.92E-03 8.64E-05 4.20E-01 2.29E-03 1.17E-04 3.98E-04 2.81E-02 6.57E-02 5.20E-01 2.81E-01 4.84E-01 2.56E-04 7.23E-04 9.52E-05 9.24E-04 1.40E-03 2.61E-06 2.20E-04 1.44E-05 1.37E-06 8.80E-04 1.87E-06 8.23E-08 7.54E-06 2.19E-04 9.60E-06 1.68E-05 1.70E-04 4.80E-06 4.01E-06 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 1.99E-05 1.23E-08 1.58E-05 1.99E-04 8.23E-06 3 Level (µg/m ) 30 0.08 30 0.1 30 100 9 0.5 30 0.3 210 0.1 140 3 0.08 520 10 1000 3 23800 2 0.03 0.16 5 5000 17700 700 1500 1000 100 12 140 35 0.3 30 0.0042 0.0002 5 0.02 0.0004 0.0006 0.008 0.000083 0.2 2 2 3 (µg/m ) Basis ITSL ITSL ITSL ITSL ITSL ITSL ITSL ITSL ITSL ITSL ITSL IRSL IRSL ITSL ITSL IRSL IRSL ITSL IRSL ITSL ITSL ITSL PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS PASS 0.0005 annual IRSL 0.8% PASS 0.0005 annual IRSL 4.0% PASS TRACE* TRACE* TRACE* TRACE* 0.0% 0.0% 0.2% 0.0% PASS PASS PASS PASS annual annual annual annual ITSL IRSL ITSL IRSL 2nd ITSL ITSL ITSL IRSL ITSL IRSL ITSL ITSL ITSL ITSL IRSL 2nd ITSL ITSL ITSL IRSL ITSL ITSL IRSL ITSL Pass/Fail 0.3% 6.7% 0.0% 13.2% 0.5% 0.0% 0.6% 0.5% 0.0% 0.0% 0.0% 0.6% 0.0% 0.1% 2.5% 0.0% 0.0% 0.0% 0.0% 0.0% 0.1% 0.4% 0.2% 0.6% 0.0% 0.0% 0.0% 0.0% 0.0% 0.0% 0.0% 0.0% 0.0% 0.0% 0.0% 0.3% 0.7% 0.0% 0.0% 0.0% 1.3% 2.7% 11.6% 0.0% 0.0% 0.0% 0.1 0.1 0.1 0.1 24 hr annual annual annual 24 hr 24 hr 24 hr annual 24 hr annual 24 hr annual 24 hr annual annual 8 hr annual 24 hr annual 8 hr 24 hr annual annual 1 hr 24 hr 8 hr 24 hr 24 hr 24 hr 24 hr 24 hr 24 hr 24 hr annual 8 hr annual annual 8 hr 24 hr annual annual 24 hr annual 8 hr 8 hr 8 hr Percent of Screening Level 12/4/2014 Appendix 1 CD Containing Modeling-Related File Appendix 2 MDEQ Data From: To: Cc: Subject: Date: Attachments: Haywood, Jim (DEQ) Dean, Amy L. Kuieck, Susan; Caudell, John F. RE: Data Request - Gaylord Area Thursday, November 13, 2014 1:55:28 PM Dean_Otsego_Background.xlsx Houghton_Lake-O3-2009.dat Houghton_Lake-O3-2010.dat Houghton_Lake-O3-2011.dat Houghton_Lake-O3-2012.dat Houghton_Lake-O3-2013.dat I did a search of all off-site sources which could significantly contribute to your proposed project. All sources within 10km were checked, using AERSCREEN, to see if any had a Significant Concentration Gradient (SCG) at your location. No facility had a SCG, therefore, there are no off-site emissions which need to be included in your NAAQS or PSD Increment analyses. Attached is a spreadsheet of representation background concentrations. Also attached are the annual O3 files from 2009-2013. Jim From: Dean, Amy L. [mailto:[email protected]] Sent: Thursday, November 06, 2014 11:46 AM To: Haywood, Jim (DEQ) Cc: Kuieck, Susan; Caudell, John F. Subject: Data Request - Gaylord Area Hi Jim, We are going to be working on a project in the Gaylord area. Can you please provide data for UTM coordinates 671165.64 m E, 4992273.72 m N, Zone 16? We will need background and additional source data for NO2, PM10, PM2.5, SO2, and CO. We are planning to use the 1-minute Gaylord met data from the MDEQ website, but anticipate that we may need a version processed with the ADJ_U* option? Can you please provide that? Also, can you please provide ozone data? Thanks! Let me know if you have any questions. Amy Year 2011 2012 2013 NO2 Houghton Lake 1-hr Annual 98th pctl Avg 8.0 1.0 9.0 1.4 8.0 1.4 8.3 1.4 ppb ppb PM-2.5 Houghton Lake 24-hr Annual 98th pctl Avg 17.8 6.2 15.4 5.9 17.1 5.5 16.8 5.9 ug/m3 ug/m3 PM-10 Grand Rapids 24-hr Annual Max Avg 41.0 13.6 29.0 12.8 28.0 12.6 13.6 ppb 1-hr 99th pctl 8.4 9.7 10.2 9.4 ppb SO2 Grand Rapids 3-hr 24-hr Max Max 8.0 4.5 7.1 4.2 8.6 2.9 8.6 4.5 ppb ppb Annual Avg 0.7 0.8 0.7 0.8 ppb CO Grand Rapids 1-hr 8-hr Max Max 6.3 1.4 2.4 1.5 2.0 1.3 6.3 1.5 ppm ppm NAAQS MODELING BACKGROUND SUMMARY NO2 15.7 ug/m3 PM-2.5 2.6 ug/m3 16.8 ug/m3 5.9 ug/m3 PM-10 29.0 ug/m3 (3-yr 4th High) SO2 13.6 ug/m3 24.7 ug/m3 22.5 ug/m3 CO 11.8 ug/m3 2.1 ug/m3 7,308.0 ug/m3 1,740.0 ug/m3
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