Ch 8.1 Balancing Equations Indications of a Chemical Reaction • Evolution of energy as heat and light. • Production of a gas • Formation of a precipitate • Color Change Characteristics of Chemical Equations • The equation must represent known facts. • The equation must contain the correct formulas for the reactants and products. • The law of conservation of mass must be satisfied. Chemical Reactions • Chemical equations give information in two major areas: 1. Reactants and products of the reaction. 2. Coefficients of a balanced chemical equation tell us the amount of the substances involved. Example: 2H2 (g) + O2 (g) 2H2O (g) Review: Reactants are on the left side of the arrow, and the products are on the right side. The arrow means “yields”, or “to produce”. Balancing Chemical Equations Why do you have to balance a chemical equation? • Law of Conservation of Matter (or Mass) • During a chemical reaction, atoms are either joined, separated, or rearranged. The number and type of each atom stays the same. How do you balance a chemical equation? • Coefficients are placed in front of the substances involved in the chemical reaction to get the same number of atoms of each element on both sides of the equation. Rules for Balancing Chemical Equations (1) Coefficients can only be placed ___ in _________ front of a chemical formula. Practice Problems: How many atoms of each type are indicated in the following compounds? (a) 2 (NH4)3PO4 6 N= ___ 24 P= ___ 2 O= ___ 8 H= ___ (b) 4 KC2H3O2 4 C= ___ 8 H= ___ 12 O= ___ 8 K= ___ (c) 3 Ca(NO3)2 Ca= ___ 3 N= ___ 6 O= ___ 18 Rules for Balancing Chemical Equations (2) You cannot change a ________________!! subscript Example : 2 H2 + O2 2 H2O H2 O2 To balance oxygen, you cannot change water’s formula to_________! (3) You cannot place the coefficient in the ______________ of a middle formula!! Example : 2Al + N2 2 AlN To balance nitrogen, you cannot put a 2 in the middle to make _______. Al2N whole # ratio. (4) Reduce the coefficients to the simplest ____________ ___ Example: 4H2 + 2O2 4H2O can be reduced to… __H 2 2 + __O 1 2 __H 2 2O Rules for Balancing Chemical Equations (5) Get rid of any ____________! Coefficients must be _________ fractions whole #’s • You can’t have a _______________ of a molecule or atom! fraction Example: 2 x ( 1H2 + ½O2 1H2O ) __ 2 H2 + __O 1 2 __H 2 2O changes to… Balancing Equations: “Helpful Hints” a) Balance elements that appear in more than one compound ________. last 1 ___(NH 4)2CO3 2 ___NH 3 + 1 ___CO 2 + 1 2O ___H Polyatomic ions as though it were one item as long as the b) Balance ________________ ion stays together as a group on each side of the yields arrow. 2 3 ___Al + ___CuSO 4 1 2(SO4)3 + ___Al 3 ___Cu start _________ over and begin c) If you can’t seem to get it balanced, _________ with a different element the next time, or put a “2” somewhere and then try again. 2 2 2O ___Li + ___H 2 1 2 ___LiOH + ___H d) This is what I’ll constantly be telling you to do if you are stuck and you need my help... “Pick an element to balance. How many are on Fix it the left side? How many are on the right side? ________ ____!” 2 ___Fe(OH) 3 1 2O3 + ___H 3 2O ___Fe Example • Aluminum is a good choice for outdoor furniture because it reacts with oxygen in the air to form a thin protective coat of aluminum oxide. Write word, formula, and chemical equations for this reaction. Aluminum + Oxygen Aluminum Oxide Al(s) + O2(g) Al2O3(s) 4Al(s) + 3O2(g) 2Al2O3(s) Homework • 8.1 page 274 #1-3 and page 290 #1-2, 13 Ch 8.2: Five Types of Reactions 1) ________________________: Decomposition • one ______________ compound A reaction that breaks apart ______ into simpler substances, (usually two elements or an element and a smaller compound.) + General Form: Examples: _____ AX ___ A + ___ X H2 O2 H2O _____ + _____ O2 KCl + _____ KClO _____ 3 Remember that “H,N,O,F,Cl,Br,I” elements are diatomic when alone!! • Remember to balance the equation after you write the products. General Types of Reactions 2) __________: (sometimes called Combination) Synthesis • • two __________________, substances A reaction of _____ typically a one ______________. compound metal and a nonmetal to form ______ It is the opposite of decomposition. (The same categories of reactions from above apply, just in reverse.) General Form: Examples: + ___ A + ___ X _____ AX Al + AlCl3 Cl2 _______ Pb(OH)2 PbO + H2O ______ General Types of Reactions (Continued) 3) _________________: Combustion Reacts with oxygen gas!!! O2 always • A reaction between a Carbon/Hydrogen with _____ CO2 H2O produces the same… ________ + ________ • This reaction is too easy!! Don’t miss it! General Form: Examples: 2C2H2 CO2 + ____ H2O CxHy + O2 ____ 4CO2 + _______ 2H2O + 5O2 _______ C7H6O + 7CO2 + _______ 3H2O 8O2 _______ General Types of Reactions (Continued) 4) _____________ Displacement: Single • one ______________ compound one ____________ element A reaction between ____ and ___ that produces a different _____________ and ______________. compound element General Forms: ____ AX + __ Y ____ AY + + __ X ____ AX + __ B ____ BX + __ A + General Types of Reactions (Continued) 5) _______________ Double Displacement: two ________________ compounds • A reaction between _____ that are dissolved in two ________________ compounds water that produces _____ , one of which is insoluble ________________. • Water or a gas may be one of the two compounds being produced. BX(s) (aq) + BY (aq) AY (aq) + ____ General Form: AX ____ ____ ____ + + A solid produced during a chemical reaction is called a precipitate. Examples: CaCl2 (aq) + Ca(NO3)2 (aq)+ ________ AgCl (s) AgNO3 (aq) _________ NaCl (aq) + ________ H2O (l) NaOH (aq) + HCl (aq) ________ Double Displacement Reaction Homework 8.2 pg 284 #1-2 pg 291 #27 (write formulas, balance, and then classify!) Ch 8.2 and 8.3 Notes Types of Reactions and Activity Series • Standard 3.a.: Students know how to describe chemical equations by writing balanced equations. • Content Objective: We will know how to determine products for the five types of reactions. • Language Objective: I will write the products of the chemical reaction and then balance the chemical reaction. Making Synthesis Reactions • Metals with nonmetals ionic compounds Mg + O2 MgO • Nonmetals w/ nonmetals covalent compounds C + O2 CO2 • Metal Oxides react with water to form Hydroxides CaO + H2O Ca(OH)2 • Nonmetal Oxides react with water to form acids SO2 + H2O H2SO3 Decomposition • Decomposition of Binary Compounds HgO Hg + O2 • Decomposition of Metal Carbonates CaCO3 CaO + CO2 • Decomposition of Metal Hydroxides Ca(OH)2 CaO + H2O • Decomposition of Metal Chlorates KClO3 KCl + O2 • Decomposition of Acids H2CO3 CO2 + H2O Combustion Remember, these ALWAYS produce CO2 and H2O! Single Displacement • The element that is trying to replace the other must be more reactive than the one it is replacing. • You must use the Activity Series to see if the reaction will happen. Page 286 Table 3 • The Higher up it is = the more reactive it is. • Elements from Li to Na can displace hydrogen in water to form a metallic hydroxide and H2 gas. Single Replacement Reactions Examples: NaCl NaF + _____ Cl2 + F2 _____ FeCl2 + KCl + _____ Fe K _____ HCl + H2 Zn ZnCl _____ 2 + _____ HCl + no reaction Au _____ + _____ Na H2 _____ NaOH + _____ Fe no reaction _____ + _____ AgNO3 + Cu CuNO Ag _____3 + _____ H2O + H(OH) H2O + Single Displacement • • • • Remember the Activity Series! Metals Replace Metals Al + Pb(NO3)2 Pb + Al(NO3)3 Metals Replace Hydrogen in Water Na + H2O NaOH + H2 Metals Replace Hydrogen in Acid Mg + HCl H2 + MgCl2 Halogens replace halogens below them Double Displacement • Switch the compounds and make sure the new compounds are balanced. KI + Pb(NO3)2 PbI2 + KNO3 • They will always react and switch, no activity series needed! Once you have solved for the products of the reaction, you must then BALANCE the reaction! • Standard 3.a.: Students know how to describe chemical equations by writing balanced equations. • Content Objective: We will know how to determine products for the five types of reactions. • Language Objective: I will write the products of the chemical reaction and then balance the chemical reaction. Homework 8.2 page 284 #4 (solve for products, balance, and classify the reactions.) 8.3 page 287 #2-3 (In #2, predict which reactions will occur using activity series, then in #3, solve for the products for the ones that will occur and then balance.)
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