CRYO/Q Relaxation mechanisms in solids Anja Zimmer Friedrich-Schiller-University Jena, Germany 3rd ILIAS-GW Meeting, London October 27th 2006 SFB C4 06/06 1/15 Dissipation stress strain SFB C4 06/06 2/15 Dissipation per cycle depending on frequency SFB C4 06/06 3/15 Mechanical losses Single anelastic process (single relaxation time): tan 2 f 1 2 f 2 For small loss angles: tan T,f SFB C4 06/06 Maximum at 2 f 1 2 f 1 2 f 2 T relaxation strength f frequency of acoustic wave relaxation time 4/15 Mechanical losses 0 e Ea k BT Free en ergy Especially for stress induced transitions between states of minimal energy: Ea Distance SFB C4 06/06 relaxation time 0 relaxation constant Ea activation energy kB Boltzmann constant 5/15 Dissipation due to stress induced hopping of alkali-ions in a-quartz Si O SFB C4 06/06 W. P. Mason in Physical Acoustics, edited by W. P. Mason (Academic Press Inc., New York, 1965), vol. 3B, p. 247. 6/15 3“ 12 mm Q-Measurement on crystalline quartz Measurement + Fit -4 10 -5 10 -1 Damping Damping QQ-1 -6 10 910-7 s 3.4 meV 510-13 s 53 meV 110-14 s 163 meV 410-13 s 194 meV phonons defects -7 10 -8 10 -9 10 -10 10 0 20 40 60 80 100 120 140 160 180 200 Temperature Temperature[K] [K] mode shape: SFB C4 06/06 measured frequency: 11565 Hz calculated frequency : 10793 Hz @ 300 K 7/15 3“ 12 mm Q-Measurement on crystalline quartz -5 Damping Q-1 -1 Damping Q 10 -6 10 -7 10 -8 10 0 20 40 60 80 100 120 140 160 180 200 Temperature [K] Temperature [K] measured frequency : 11565 Hz 17115 Hz 61720 Hz calculated frequency: 10793 Hz 16987 Hz 61121 Hz SFB C4 06/06 @ 300 K 8/15 Mechanical losses in solids • External losses – e.g. suspension losses, residual gas damping… • Internal losses – „ideal“ solid: • thermo-elastic damping • interaction of acoustic waves with thermal phonons of the solid • interaction of acoustic waves with electrons of the solid – „real“ solid: • additional damping caused by defect induced losses SFB C4 06/06 9/15 Dissipation caused by interaction of acoustic wave with thermal phonons Damping Q-1 -6 10 -7 10 0 20 40 60 80 100 120 Temperature [K] 2 fac th 1 Landau-Rumer damping SFB C4 06/06 2 fac th 1 Akhieser damping 10/15 Dissipation caused by interaction of acoustic wave with thermal phonons 2 f ac th 1 Landau-Rumer damping • Interaction of acoustic waves with individual thermal phonons. SFB C4 06/06 2 f ac th 1 Akhieser damping • Perturbation of equilibrium of thermal phonon distribution. • Reestablishment affords increase in entropy and such leads to a partly absorbation and attenuation of the acoustic wave. 11/15 Crystalline silicon • less than 1014 doping atoms per cm3: mechanical losses are dominated by interactions of acoustical waves with thermal phonons of the crystal • higher doping concentrations: dissipation by interactions with additional electrons and holes respectively increases SFB C4 06/06 W. P. Mason in Physical Acoustics, edited by W. P. Mason (Academic Press Inc., New York, 1966), vol. 4A, pp. 299. 12/15 n-doped silicon • Origin of dissipation: Movement / transition of conduction electrons between minima of energy in k-space • Minima occur along the six <100> directions • Unstressed crystal: Minima possess same energies and numbers of occupation • Stress along crystal axis rises energy of parallel located minima and lowers that of perpendicular ones • Consequence: Reestablishing equilibrium by flow of electrons from minima of higher energy to lower ones • delay = intervalley relaxation time is origin of an effective energy transfer from the acoustic wave to the thermal bath SFB C4 06/06 13/15 p-doped silicon • Energy surfaces of the valence band become reshaped by stresses induced by acoustic waves. • It is assumed that a flow of holes from regions of higher energy to that of lower energy of the same surface occurs and not between surfaces. SFB C4 06/06 14/15 How to determine the mechanical loss factor? total damping background damping (suspension, residual gas damping…) sum of internal anelastic processes 1 Q1 f 0 ,T Qrel,i f0 ,T Qbg1 f0 ,T i Q 1 f0 , T i f0 , T i 2 f 0 i 1 2 f 0 i 2 1 Q bg f0 , T f0 , T f0 f0 T T directionality (anisotropy!) of i SFB C4 06/06 and i f 0,n f 15/15
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